JP4824311B2 - 低温特性および耐溶剤性を有するフルオロエラストマー - Google Patents

低温特性および耐溶剤性を有するフルオロエラストマー Download PDF

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Publication number: JP4824311B2
Authority: JP; Japan
Prior art keywords: mol; fluoropolymer; polymerization; pmve; tfe
Prior art date: 2002-09-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

JP2004536530A

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English (en)

Japanese (ja)

Other versions

JP2005539116A5 (de

JP2005539116A (ja

Inventor

カスパー，ハラルド

ヒンツァー，クラウス

グール，ガイヴァン

マルツ，フランヅ

ウァーム，アラン，ティー．

フクシ，タツオ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

3M Innovative Properties Co

Original Assignee

3M Innovative Properties Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2002-09-12

Filing date

2003-09-11

Publication date

2011-11-30

2003-09-11 Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co

2005-12-22 Publication of JP2005539116A publication Critical patent/JP2005539116A/ja

2009-01-15 Publication of JP2005539116A5 publication Critical patent/JP2005539116A5/ja

2011-11-30 Application granted granted Critical

2011-11-30 Publication of JP4824311B2 publication Critical patent/JP4824311B2/ja

2023-09-11 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

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229920001973 fluoroelastomer Polymers 0.000 title claims abstract description 15
239000002904 solvent Substances 0.000 title description 19
229920002313 fluoropolymer Polymers 0.000 claims abstract description 60
239000004811 fluoropolymer Substances 0.000 claims abstract description 60
BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 48
BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 claims abstract description 41
BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims abstract description 40
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims abstract description 5
238000002360 preparation method Methods 0.000 claims abstract description 5
-1 perfluoro Chemical group 0.000 claims description 20
238000004073 vulcanization Methods 0.000 claims description 13
230000002902 bimodal effect Effects 0.000 claims description 3
QZGNGBWAMYFUST-UHFFFAOYSA-N 2-bromo-1,1-difluoroethene Chemical group FC(F)=CBr QZGNGBWAMYFUST-UHFFFAOYSA-N 0.000 claims description 2
GVCWGFZDSIWLMO-UHFFFAOYSA-N 4-bromo-3,3,4,4-tetrafluorobut-1-ene Chemical compound FC(F)(Br)C(F)(F)C=C GVCWGFZDSIWLMO-UHFFFAOYSA-N 0.000 claims description 2
ZPYGRBTUNITHKJ-UHFFFAOYSA-N 1-bromo-1,1,2,2-tetrafluoro-2-(1,2,2-trifluoroethenoxy)ethane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)Br ZPYGRBTUNITHKJ-UHFFFAOYSA-N 0.000 claims 1
AYCANDRGVPTASA-UHFFFAOYSA-N 1-bromo-1,2,2-trifluoroethene Chemical group FC(F)=C(F)Br AYCANDRGVPTASA-UHFFFAOYSA-N 0.000 claims 1
VVZKSCNUHGDSAC-UHFFFAOYSA-N 1-ethenoxy-3-iodopropane Chemical compound ICCCOC=C VVZKSCNUHGDSAC-UHFFFAOYSA-N 0.000 claims 1
OUJSWWHXKJQNMJ-UHFFFAOYSA-N 3,3,4,4-tetrafluoro-4-iodobut-1-ene Chemical compound FC(F)(I)C(F)(F)C=C OUJSWWHXKJQNMJ-UHFFFAOYSA-N 0.000 claims 1
239000000203 mixture Substances 0.000 description 53
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238000006116 polymerization reaction Methods 0.000 description 34
238000000034 method Methods 0.000 description 22
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ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 5
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DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 3
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
239000004215 Carbon black (E152) Substances 0.000 description 3
NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 3
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KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 3
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239000011787 zinc oxide Substances 0.000 description 3
RRZIJNVZMJUGTK-UHFFFAOYSA-N 1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene Chemical compound FC(F)=C(F)OC(F)=C(F)F RRZIJNVZMJUGTK-UHFFFAOYSA-N 0.000 description 2
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150000001447 alkali salts Chemical class 0.000 description 2
239000012935 ammoniumperoxodisulfate Substances 0.000 description 2
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235000019400 benzoyl peroxide Nutrition 0.000 description 2
125000001246 bromo group Chemical group Br* 0.000 description 2
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
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125000003710 aryl alkyl group Chemical group 0.000 description 1
125000004104 aryloxy group Chemical group 0.000 description 1
XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
235000019399 azodicarbonamide Nutrition 0.000 description 1
AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
239000002585 base Substances 0.000 description 1
230000008901 benefit Effects 0.000 description 1
QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
239000000872 buffer Substances 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
239000000292 calcium oxide Substances 0.000 description 1
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
238000007707 calorimetry Methods 0.000 description 1
150000001721 carbon Chemical group 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
150000003841 chloride salts Chemical class 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
238000013329 compounding Methods 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
239000002826 coolant Substances 0.000 description 1
239000011243 crosslinked material Substances 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
239000003814 drug Substances 0.000 description 1
229940079593 drug Drugs 0.000 description 1
125000003700 epoxy group Chemical group 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
238000007654 immersion Methods 0.000 description 1
239000011630 iodine Substances 0.000 description 1
229910000464 lead oxide Inorganic materials 0.000 description 1
UMKARVFXJJITLN-UHFFFAOYSA-N lead;phosphorous acid Chemical compound [Pb].OP(O)O UMKARVFXJJITLN-UHFFFAOYSA-N 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
UHNWOJJPXCYKCG-UHFFFAOYSA-L magnesium oxalate Chemical compound [Mg+2].[O-]C(=O)C([O-])=O UHNWOJJPXCYKCG-UHFFFAOYSA-L 0.000 description 1
239000000463 material Substances 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
UIUXUFNYAYAMOE-UHFFFAOYSA-N methylsilane Chemical compound [SiH3]C UIUXUFNYAYAMOE-UHFFFAOYSA-N 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
BLYOHBPLFYXHQA-UHFFFAOYSA-N n,n-bis(prop-2-enyl)prop-2-enamide Chemical compound C=CCN(CC=C)C(=O)C=C BLYOHBPLFYXHQA-UHFFFAOYSA-N 0.000 description 1
DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
125000002560 nitrile group Chemical group 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
239000012071 phase Substances 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920001084 poly(chloroprene) Polymers 0.000 description 1
229920000647 polyepoxide Polymers 0.000 description 1
229920001843 polymethylhydrosiloxane Polymers 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
KOPQZJAYZFAPBC-UHFFFAOYSA-N propanoyl propaneperoxoate Chemical compound CCC(=O)OOC(=O)CC KOPQZJAYZFAPBC-UHFFFAOYSA-N 0.000 description 1
229910002059 quaternary alloy Inorganic materials 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
238000010057 rubber processing Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000000565 sealant Substances 0.000 description 1
238000007789 sealing Methods 0.000 description 1
239000003566 sealing material Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
239000007921 spray Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 1
229910001866 strontium hydroxide Inorganic materials 0.000 description 1
239000000758 substrate Substances 0.000 description 1
150000003460 sulfonic acids Chemical class 0.000 description 1
DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
230000008961 swelling Effects 0.000 description 1
OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
238000010998 test method Methods 0.000 description 1
239000012085 test solution Substances 0.000 description 1
DBGVGMSCBYYSLD-UHFFFAOYSA-N tributylstannane Chemical compound CCCC[SnH](CCCC)CCCC DBGVGMSCBYYSLD-UHFFFAOYSA-N 0.000 description 1
GRPURDFRFHUDSP-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,2,4-tricarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C(C(=O)OCC=C)=C1 GRPURDFRFHUDSP-UHFFFAOYSA-N 0.000 description 1
KJWHEZXBZQXVSA-UHFFFAOYSA-N tris(prop-2-enyl) phosphite Chemical compound C=CCOP(OCC=C)OCC=C KJWHEZXBZQXVSA-UHFFFAOYSA-N 0.000 description 1
ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/30—Chemical modification of a polymer leading to the formation or introduction of aliphatic or alicyclic unsaturated groups

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Compositions Of Macromolecular Compounds (AREA)
Sealing Material Composition (AREA)
Polymerisation Methods In General (AREA)

JP2004536530A 2002-09-12 2003-09-11 低温特性および耐溶剤性を有するフルオロエラストマー Expired - Fee Related JP4824311B2 (ja)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US41022502P	2002-09-12	2002-09-12
US60/410,225		2002-09-12
PCT/US2003/028610 WO2004024786A1 (en)	2002-09-12	2003-09-11	Fluoroelastomers having low temperature characteristics and solvent resistance

Publications (3)

Publication Number	Publication Date
JP2005539116A JP2005539116A (ja)	2005-12-22
JP2005539116A5 JP2005539116A5 (de)	2009-01-15
JP4824311B2 true JP4824311B2 (ja)	2011-11-30

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JP2004536530A Expired - Fee Related JP4824311B2 (ja)	2002-09-12	2003-09-11	低温特性および耐溶剤性を有するフルオロエラストマー

Country Status (11)

Country	Link
US (1)	US6864336B2 (de)
EP (1)	EP1537152B9 (de)
JP (1)	JP4824311B2 (de)
KR (1)	KR101177123B1 (de)
CN (1)	CN1289545C (de)
AT (1)	ATE389675T1 (de)
AU (1)	AU2003270575A1 (de)
DE (1)	DE60319844T2 (de)
RU (1)	RU2349608C2 (de)
WO (1)	WO2004024786A1 (de)
ZA (1)	ZA200502922B (de)

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US9486408B2 (en)	2005-12-01	2016-11-08	University Of Massachusetts Lowell	Botulinum nanoemulsions
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GB201108963D0 (en) *	2011-05-27	2011-07-13	3M Innovative Properties Co	Composite materials comprising polyamides and fluoroelastomers
CN102558719B (zh) *	2011-12-29	2014-07-02	中昊晨光化工研究院	一种耐低温含氟弹性体及其制备方法
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US10227484B2 (en)	2014-08-22	2019-03-12	3M Innovative Properties Company	Fluorothermoplastic polymer compositions
EP3183279B1 (de) *	2014-08-22	2018-08-01	3M Innovative Properties Company	Fluorothermoplastischen polymer
JP2019530737A (ja)	2016-08-23	2019-10-24	アコーオスインコーポレイテッド	ヒト対象において非加齢性聴力障害を治療するための組成物および方法
AU2017360346B2 (en)	2016-11-21	2023-11-23	Eirion Therapeutics, Inc.	Transdermal delivery of large agents
EP3333229A1 (de) *	2016-12-08	2018-06-13	3M Innovative Properties Company	Fluorpolymerzusammensetzungen und beschichtungen
EP3722340B1 (de) *	2017-12-06	2023-10-11	AGC Inc.	Fluor enthaltendes elastisches copolymer und verfahren zur herstellung eines fluor enthaltenden elastischen copolymers
US20230015548A1 (en) *	2019-12-17	2023-01-19	The Chemours Company Fc, Llc	Ultra-low temperature elastomeric fluoropolymer compositions and processes for preparing the same
JP7807380B2 (ja)	2020-02-21	2026-01-27	アコーオスインコーポレイテッド	ヒト対象において非加齢関連聴力障害を処置するための組成物および方法
JP2023536649A (ja) *	2020-08-06	2023-08-28	アーケマ・インコーポレイテッド	加工可能なテトラフルオロエチレンコポリマー

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2003
- 2003-09-11 JP JP2004536530A patent/JP4824311B2/ja not_active Expired - Fee Related
- 2003-09-11 AU AU2003270575A patent/AU2003270575A1/en not_active Abandoned
- 2003-09-11 AT AT03752278T patent/ATE389675T1/de not_active IP Right Cessation
- 2003-09-11 EP EP03752278A patent/EP1537152B9/de not_active Expired - Lifetime
- 2003-09-11 US US10/660,437 patent/US6864336B2/en not_active Expired - Lifetime
- 2003-09-11 KR KR1020057004293A patent/KR101177123B1/ko not_active Expired - Fee Related
- 2003-09-11 CN CNB038211947A patent/CN1289545C/zh not_active Expired - Fee Related
- 2003-09-11 DE DE60319844T patent/DE60319844T2/de not_active Expired - Lifetime
- 2003-09-11 RU RU2005103392/04A patent/RU2349608C2/ru not_active IP Right Cessation
- 2003-09-11 WO PCT/US2003/028610 patent/WO2004024786A1/en not_active Ceased
2005
- 2005-04-11 ZA ZA200502922A patent/ZA200502922B/en unknown

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JP2001181350A (ja) *	1999-12-22	2001-07-03	Nippon Mektron Ltd	フルオロエラストマー、その製造方法、架橋性組成物およびその硬化物

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