JP6189325B2 - エチレン／アルファオレフィン／非共役ポリエン共重合体およびその形成方法 - Google Patents
エチレン／アルファオレフィン／非共役ポリエン共重合体およびその形成方法 Download PDFInfo
- Publication number
- JP6189325B2 JP6189325B2 JP2014548874A JP2014548874A JP6189325B2 JP 6189325 B2 JP6189325 B2 JP 6189325B2 JP 2014548874 A JP2014548874 A JP 2014548874A JP 2014548874 A JP2014548874 A JP 2014548874A JP 6189325 B2 JP6189325 B2 JP 6189325B2
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- Prior art keywords
- independently
- atom
- hydrocarbyl
- heterohydrocarbyl
- unsubstituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161577720P | 2011-12-20 | 2011-12-20 | |
| US61/577,720 | 2011-12-20 | ||
| US201261731891P | 2012-11-30 | 2012-11-30 | |
| US61/731,891 | 2012-11-30 | ||
| PCT/US2012/070859 WO2013096573A1 (en) | 2011-12-20 | 2012-12-20 | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2015500920A JP2015500920A (ja) | 2015-01-08 |
| JP6189325B2 true JP6189325B2 (ja) | 2017-08-30 |
Family
ID=47559697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014548874A Active JP6189325B2 (ja) | 2011-12-20 | 2012-12-20 | エチレン／アルファオレフィン／非共役ポリエン共重合体およびその形成方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9422383B2 (2) |
| EP (1) | EP2794693B1 (2) |
| JP (1) | JP6189325B2 (2) |
| KR (1) | KR101989206B1 (2) |
| CN (1) | CN104169313B (2) |
| BR (1) | BR112014014855B1 (2) |
| ES (1) | ES2835807T3 (2) |
| IN (1) | IN2014CN04444A (2) |
| WO (1) | WO2013096573A1 (2) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9422383B2 (en) | 2011-12-20 | 2016-08-23 | Dow Global Technologies Llc | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
| JP5946331B2 (ja) * | 2012-06-01 | 2016-07-06 | 三井化学株式会社 | エチレン・α−オレフィン非共役ポリエン共重合体ゴムペレット |
| SG11201504003XA (en) * | 2012-11-30 | 2015-06-29 | Dow Global Technologies Llc | Ethylene/alpha-olefin/polyene based compositions |
| SG11201503581PA (en) * | 2012-12-27 | 2015-06-29 | Dow Global Technologies Llc | Catalyst systems for olefin polymerization |
| BR112015013530B1 (pt) | 2013-01-18 | 2021-10-13 | Dow Global Technologies Llc | Processo para formar um polímero à base de etileno e complexo metálico |
| RU2690373C2 (ru) * | 2014-05-31 | 2019-06-03 | Бриджстоун Корпорейшн | Металлокомплексный катализатор, способы полимеризации с его использованием и полученные полимерные продукты |
| JP6763857B2 (ja) * | 2014-12-04 | 2020-09-30 | ダウ グローバル テクノロジーズ エルエルシー | エチレン系ポリマーの調製物のための五配位ビス−フェニルフェノキシ触媒 |
| MY184826A (en) | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
| JP6752794B2 (ja) * | 2014-12-29 | 2020-09-09 | ダウ グローバル テクノロジーズ エルエルシー | エチレン／アルファ−オレフィンインターポリマーを形成する方法 |
| JP6718453B2 (ja) * | 2014-12-29 | 2020-07-08 | ダウ グローバル テクノロジーズ エルエルシー | 油含有エチレン系ポリマーを形成する方法 |
| JP6948948B2 (ja) * | 2015-03-31 | 2021-10-13 | ダウ グローバル テクノロジーズ エルエルシー | 低レベルの長鎖分岐を有する高分子量エチレン／α−オレフィン／非共役インターポリマーの生成方法 |
| EP3303427B1 (en) * | 2015-05-28 | 2023-11-29 | Dow Global Technologies LLC | Process to form ethylene/alpha-olefin/diene interpolymers |
| CA2996615C (en) * | 2015-09-02 | 2023-10-03 | Dow Global Technologies Llc | Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| WO2017040089A1 (en) * | 2015-09-02 | 2017-03-09 | Dow Global Technologies Llc | Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| JP6936795B2 (ja) * | 2015-10-29 | 2021-09-22 | ダウ グローバル テクノロジーズ エルエルシー | 可撓性架橋ケーブル絶縁体のための架橋性ポリマー組成物、及び可撓性架橋ケーブル絶縁体を作製するための方法 |
| WO2017206009A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymers compositions |
| WO2017206008A1 (en) * | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymer |
| US11981802B2 (en) | 2016-06-30 | 2024-05-14 | Dow Global Technologies Llc | Ethylene/alpha-olefin/polyene based compositions |
| CN109601004B (zh) * | 2016-06-30 | 2022-08-09 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃/多烯互聚物以及含有其的组合物 |
| CN109641990B (zh) | 2016-07-13 | 2022-08-19 | 埃克森美孚化学专利公司 | 双金属茂催化剂共聚物组合物 |
| CN109641989B (zh) | 2016-07-13 | 2022-05-03 | 埃克森美孚化学专利公司 | 双金属茂催化剂共聚物组合物 |
| JP6850862B2 (ja) | 2016-07-14 | 2021-03-31 | エクソンモービル・ケミカル・パテンツ・インク | 粘度調整剤として有用な、２元メタロセン触媒で重合されたバイモーダルのコポリマー組成物 |
| US10221260B2 (en) | 2016-07-29 | 2019-03-05 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| WO2018022279A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| KR102413982B1 (ko) * | 2016-07-29 | 2022-06-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 다중모드 엘라스토머 생산용 혼합 촉매 시스템 |
| KR102653792B1 (ko) * | 2016-12-26 | 2024-04-03 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌/α-올레핀/비공액 폴리엔 혼성 중합체 조성물 및 이로부터 제조된 물품 |
| BR112019020417B1 (pt) * | 2017-03-31 | 2023-04-04 | Dow Global Technologies Llc | Sistema catalisador e processo de polimerização para produzir um polímero à base de etileno |
| US11390704B2 (en) | 2017-06-14 | 2022-07-19 | Exxonmobil Chemical Patents Inc. | Ethylene copolymer blends for cross-linking applications |
| CN111148641B (zh) | 2017-08-24 | 2023-03-31 | 陶氏环球技术有限责任公司 | 乙烯/C5-C10α-烯烃/多烯互聚物 |
| EP3752560B1 (en) | 2018-02-14 | 2024-09-25 | Dow Global Technologies LLC | Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance |
| WO2020046597A1 (en) | 2018-08-29 | 2020-03-05 | Exxonmobil Chemical Patents Inc. | Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes |
| KR102538844B1 (ko) * | 2018-12-21 | 2023-06-01 | 주식회사 엘지화학 | 방향족 비닐 화합물-비닐시안 화합물 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법 |
| EP3940009A4 (en) | 2019-03-12 | 2023-03-15 | Mitsui Chemicals, Inc. | OLEFIN-BASED RESIN, CROSSLINKER THEREOF, AND METHODS OF PRODUCTION THEREOF |
| KR102715918B1 (ko) * | 2019-03-29 | 2024-10-15 | 다우 글로벌 테크놀로지스 엘엘씨 | 열가소성 가황물을 위한 오일-증량된 펠릿 형태 에틸렌 알파-올레핀 디엔 인터폴리머 |
| CN113874439B (zh) * | 2019-04-30 | 2024-03-29 | 陶氏环球技术有限责任公司 | 乙烯/丙烯/非共轭二烯互聚物组合物 |
| EP4034597B1 (en) | 2019-09-24 | 2025-12-31 | Dow Global Technologies LLC | ETHYLENE/ALPHA-OLEFIN/POLYENE INTERPOLYMER COMPOSITIONS |
| US12448506B2 (en) | 2019-09-24 | 2025-10-21 | Dow Global Technologies Llc | Polymer compositions for extruded profiles |
| EP4034598A1 (en) | 2019-09-24 | 2022-08-03 | Dow Global Technologies LLC | Polymer compositions with excellent electrical and mechanical properties |
| CN114846035A (zh) * | 2019-12-27 | 2022-08-02 | 陶氏环球技术有限责任公司 | 乙烯/丁烯多嵌段共聚物及其制备方法 |
| JP2021147420A (ja) * | 2020-03-16 | 2021-09-27 | 三井化学株式会社 | オレフィン・環状オレフィン共重合体の製造方法 |
| EP4127001A1 (en) * | 2020-03-27 | 2023-02-08 | Dow Global Technologies LLC | A process for producing long-chain branched ethylene-based polymers |
| US12410273B2 (en) | 2020-03-30 | 2025-09-09 | Exxonmobil Chemical Patents Inc. | Comb-block copolymers and methods thereof |
| JP2024500603A (ja) * | 2020-12-28 | 2024-01-10 | サビック エスケー ネクスレン カンパニー プライヴェート リミテッド | 金属－リガンド錯体、これを含むエチレン系重合体製造用の触媒組成物およびこれを用いたエチレン系重合体の製造方法 |
| KR20240074467A (ko) * | 2022-11-21 | 2024-05-28 | 롯데케미칼 주식회사 | 에틸렌-알파-올레핀 공중합체 제조방법 |
| WO2025117273A1 (en) | 2023-12-01 | 2025-06-05 | ExxonMobil Technology and Engineering Company | Support-bound activators, supported catalyst systems, and processes for use thereof |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
| US6680361B1 (en) * | 1998-11-02 | 2004-01-20 | Dupont Dow Elastomers Llc | Shear thinning ethylene/α-olefin interpolymers and their preparation |
| US6897276B2 (en) * | 2002-04-24 | 2005-05-24 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom |
| JP2008509277A (ja) | 2004-08-09 | 2008-03-27 | ダウ グローバル テクノロジーズ インコーポレイティド | ポリマーの製造のための担持ビス（ヒドロキシアリールアリールオキシ）触媒 |
| CN101490094B (zh) | 2006-05-17 | 2013-06-26 | 陶氏环球技术有限责任公司 | 高温聚乙烯溶液聚合法 |
| US8420760B2 (en) | 2007-11-19 | 2013-04-16 | Dow Global Technologies Llc | Long chain branched propylene-alpha-olefin copolymers |
| EP2328944B1 (en) | 2008-09-16 | 2018-01-24 | Dow Global Technologies LLC | Polymeric compositions and foams, methods of making the same, and articles prepared from the same |
| EP2448979B1 (en) | 2009-07-01 | 2013-05-01 | Dow Global Technologies LLC | Ethylenic polymer and its use |
| SG177446A1 (en) | 2009-07-01 | 2012-02-28 | Dow Global Technologies Llc | Ethylenic polymer and its use |
| KR101741857B1 (ko) | 2009-07-15 | 2017-05-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 중합체 조성물, 그의 제조 방법 및 그로부터 제조된 용품 |
| ES2659733T3 (es) * | 2010-08-25 | 2018-03-19 | Dow Global Technologies Llc | Proceso de polimerización de olefina polimerizable y catalizador para ello |
| JP6104277B2 (ja) * | 2011-12-13 | 2017-03-29 | ダウ グローバル テクノロジーズ エルエルシー | エチレン−プロピレン−ジエン共重合体組成物 |
| US9422383B2 (en) | 2011-12-20 | 2016-08-23 | Dow Global Technologies Llc | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
-
2012
- 2012-12-20 US US14/367,478 patent/US9422383B2/en active Active
- 2012-12-20 CN CN201280063427.5A patent/CN104169313B/zh active Active
- 2012-12-20 JP JP2014548874A patent/JP6189325B2/ja active Active
- 2012-12-20 EP EP12815929.0A patent/EP2794693B1/en active Active
- 2012-12-20 IN IN4444CHN2014 patent/IN2014CN04444A/en unknown
- 2012-12-20 WO PCT/US2012/070859 patent/WO2013096573A1/en not_active Ceased
- 2012-12-20 BR BR112014014855-4A patent/BR112014014855B1/pt active IP Right Grant
- 2012-12-20 KR KR1020147016448A patent/KR101989206B1/ko active Active
- 2012-12-20 ES ES12815929T patent/ES2835807T3/es active Active
Also Published As
| Publication number | Publication date |
|---|---|
| KR20140107263A (ko) | 2014-09-04 |
| EP2794693A1 (en) | 2014-10-29 |
| IN2014CN04444A (2) | 2015-09-04 |
| ES2835807T3 (es) | 2021-06-23 |
| CN104169313A (zh) | 2014-11-26 |
| US20150322185A1 (en) | 2015-11-12 |
| JP2015500920A (ja) | 2015-01-08 |
| BR112014014855A2 (pt) | 2017-06-13 |
| BR112014014855B1 (pt) | 2022-01-11 |
| KR101989206B1 (ko) | 2019-09-24 |
| WO2013096573A1 (en) | 2013-06-27 |
| CN104169313B (zh) | 2016-09-21 |
| US9422383B2 (en) | 2016-08-23 |
| EP2794693B1 (en) | 2020-09-23 |
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