ES2835807T3 - Interpolímeros de etileno/alfa-olefina/polieno no conjugado y procesos para formar los mismos - Google Patents

Interpolímeros de etileno/alfa-olefina/polieno no conjugado y procesos para formar los mismos Download PDF

Info

Publication number: ES2835807T3
Authority: ES; Spain
Prior art keywords: independently; hydrocarbyl; atoms; heterohydrocarbyl; atom
Prior art date: 2011-12-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

ES12815929T

Other languages

English (en)

Spanish (es)

Inventor

Colin Lipishan

Thomas W Karjala

Michael L Smith

Liam P Spencer

Jerzy Klosin

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Global Technologies LLC

Original Assignee

Dow Global Technologies LLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2011-12-20

Filing date

2012-12-20

Publication date

2021-06-23

2012-12-20 Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC

2021-06-23 Application granted granted Critical

2021-06-23 Publication of ES2835807T3 publication Critical patent/ES2835807T3/es

Status Active legal-status Critical Current

2032-12-20 Anticipated expiration legal-status Critical

Links

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239000002671 adjuvant Substances 0.000 description 1
238000013019 agitation Methods 0.000 description 1
125000002723 alicyclic group Chemical group 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
125000004183 alkoxy alkyl group Chemical group 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
125000005037 alkyl phenyl group Chemical group 0.000 description 1
125000001118 alkylidene group Chemical group 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000003738 black carbon Substances 0.000 description 1
238000007664 blowing Methods 0.000 description 1
239000004566 building material Substances 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
235000010216 calcium carbonate Nutrition 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
125000003636 chemical group Chemical group 0.000 description 1
XEHUIDSUOAGHBW-UHFFFAOYSA-N chromium;pentane-2,4-dione Chemical compound [Cr].CC(=O)CC(C)=O.CC(=O)CC(C)=O.CC(=O)CC(C)=O XEHUIDSUOAGHBW-UHFFFAOYSA-N 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000003086 colorant Substances 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000007906 compression Methods 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000008878 coupling Effects 0.000 description 1
238000010168 coupling process Methods 0.000 description 1
238000005859 coupling reaction Methods 0.000 description 1
125000000392 cycloalkenyl group Chemical group 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
UVJHQYIOXKWHFD-UHFFFAOYSA-N cyclohexa-1,4-diene Chemical compound C1C=CCC=C1 UVJHQYIOXKWHFD-UHFFFAOYSA-N 0.000 description 1
NLDGJRWPPOSWLC-UHFFFAOYSA-N deca-1,9-diene Chemical compound C=CCCCCCCC=C NLDGJRWPPOSWLC-UHFFFAOYSA-N 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
125000004983 dialkoxyalkyl group Chemical group 0.000 description 1
150000005690 diesters Chemical class 0.000 description 1
238000000113 differential scanning calorimetry Methods 0.000 description 1
125000005044 dihydroquinolinyl group Chemical group N1(CC=CC2=CC=CC=C12)* 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
238000002270 exclusion chromatography Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000000835 fiber Substances 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
238000009408 flooring Methods 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical class OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
239000002638 heterogeneous catalyst Substances 0.000 description 1
125000000687 hydroquinonyl group Chemical class C1(O)=C(C=C(O)C=C1)* 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
229910052809 inorganic oxide Inorganic materials 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
238000011068 loading method Methods 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical class [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
235000011160 magnesium carbonates Nutrition 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
238000005259 measurement Methods 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 1
125000003518 norbornenyl group Chemical class C12(C=CC(CC1)C2)* 0.000 description 1
238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
230000003534 oscillatory effect Effects 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
239000012169 petroleum derived wax Substances 0.000 description 1
235000019381 petroleum wax Nutrition 0.000 description 1
239000012071 phase Substances 0.000 description 1
229920001568 phenolic resin Polymers 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920002959 polymer blend Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
238000010926 purge Methods 0.000 description 1
238000011002 quantification Methods 0.000 description 1
230000003938 response to stress Effects 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical class OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000010703 silicon Substances 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
238000001542 size-exclusion chromatography Methods 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011877 solvent mixture Substances 0.000 description 1
235000012424 soybean oil Nutrition 0.000 description 1
239000003549 soybean oil Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
HSVFKFNNMLUVEY-UHFFFAOYSA-N sulfuryl diazide Chemical compound [N-]=[N+]=NS(=O)(=O)N=[N+]=[N-] HSVFKFNNMLUVEY-UHFFFAOYSA-N 0.000 description 1
239000012209 synthetic fiber Substances 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
239000003784 tall oil Substances 0.000 description 1
239000011269 tar Substances 0.000 description 1
GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
238000012360 testing method Methods 0.000 description 1
229920001187 thermosetting polymer Polymers 0.000 description 1
150000004684 trihydrates Chemical class 0.000 description 1
125000005591 trimellitate group Chemical group 0.000 description 1
OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
150000003751 zinc Chemical class 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1
BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)

ES12815929T 2011-12-20 2012-12-20 Interpolímeros de etileno/alfa-olefina/polieno no conjugado y procesos para formar los mismos Active ES2835807T3 (es)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US201161577720P	2011-12-20	2011-12-20
US201261731891P	2012-11-30	2012-11-30
PCT/US2012/070859 WO2013096573A1 (en)	2011-12-20	2012-12-20	Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same

Publications (1)

Publication Number	Publication Date
ES2835807T3 true ES2835807T3 (es)	2021-06-23

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US (1)	US9422383B2 (2)
EP (1)	EP2794693B1 (2)
JP (1)	JP6189325B2 (2)
KR (1)	KR101989206B1 (2)
CN (1)	CN104169313B (2)
BR (1)	BR112014014855B1 (2)
ES (1)	ES2835807T3 (2)
IN (1)	IN2014CN04444A (2)
WO (1)	WO2013096573A1 (2)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US9422383B2 (en)	2011-12-20	2016-08-23	Dow Global Technologies Llc	Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same
JP5946331B2 (ja) *	2012-06-01	2016-07-06	三井化学株式会社	エチレン・α−オレフィン非共役ポリエン共重合体ゴムペレット
SG11201504003XA (en) *	2012-11-30	2015-06-29	Dow Global Technologies Llc	Ethylene/alpha-olefin/polyene based compositions
SG11201503581PA (en) *	2012-12-27	2015-06-29	Dow Global Technologies Llc	Catalyst systems for olefin polymerization
BR112015013530B1 (pt)	2013-01-18	2021-10-13	Dow Global Technologies Llc	Processo para formar um polímero à base de etileno e complexo metálico
RU2690373C2 (ru) *	2014-05-31	2019-06-03	Бриджстоун Корпорейшн	Металлокомплексный катализатор, способы полимеризации с его использованием и полученные полимерные продукты
JP6763857B2 (ja) *	2014-12-04	2020-09-30	ダウグローバルテクノロジーズエルエルシー	エチレン系ポリマーの調製物のための五配位ビス−フェニルフェノキシ触媒
MY184826A (en)	2014-12-04	2021-04-24	Dow Technology Investments Llc	Hydroformylation process
JP6752794B2 (ja) *	2014-12-29	2020-09-09	ダウグローバルテクノロジーズエルエルシー	エチレン／アルファ−オレフィンインターポリマーを形成する方法
JP6718453B2 (ja) *	2014-12-29	2020-07-08	ダウグローバルテクノロジーズエルエルシー	油含有エチレン系ポリマーを形成する方法
JP6948948B2 (ja) *	2015-03-31	2021-10-13	ダウグローバルテクノロジーズエルエルシー	低レベルの長鎖分岐を有する高分子量エチレン／α−オレフィン／非共役インターポリマーの生成方法
EP3303427B1 (en) *	2015-05-28	2023-11-29	Dow Global Technologies LLC	Process to form ethylene/alpha-olefin/diene interpolymers
CA2996615C (en) *	2015-09-02	2023-10-03	Dow Global Technologies Llc	Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
WO2017040089A1 (en) *	2015-09-02	2017-03-09	Dow Global Technologies Llc	Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
JP6936795B2 (ja) *	2015-10-29	2021-09-22	ダウグローバルテクノロジーズエルエルシー	可撓性架橋ケーブル絶縁体のための架橋性ポリマー組成物、及び可撓性架橋ケーブル絶縁体を作製するための方法
WO2017206009A1 (en)	2016-05-30	2017-12-07	Dow Global Technologies Llc	Ethylene/alpha-olefin/diene interpolymers compositions
WO2017206008A1 (en) *	2016-05-30	2017-12-07	Dow Global Technologies Llc	Ethylene/alpha-olefin/diene interpolymer
US11981802B2 (en)	2016-06-30	2024-05-14	Dow Global Technologies Llc	Ethylene/alpha-olefin/polyene based compositions
CN109601004B (zh) *	2016-06-30	2022-08-09	陶氏环球技术有限责任公司	乙烯/α-烯烃/多烯互聚物以及含有其的组合物
CN109641990B (zh)	2016-07-13	2022-08-19	埃克森美孚化学专利公司	双金属茂催化剂共聚物组合物
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US10221260B2 (en)	2016-07-29	2019-03-05	Exxonmobil Chemical Patents Inc.	Phenolate transition metal complexes, production and use thereof
WO2018022279A1 (en)	2016-07-29	2018-02-01	Exxonmobil Chemical Patents Inc.	Phenolate transition metal complexes, production and use thereof
KR102413982B1 (ko) *	2016-07-29	2022-06-30	다우 글로벌 테크놀로지스 엘엘씨	다중모드 엘라스토머 생산용 혼합 촉매 시스템
KR102653792B1 (ko) *	2016-12-26	2024-04-03	다우 글로벌 테크놀로지스 엘엘씨	에틸렌/α-올레핀/비공액 폴리엔 혼성 중합체 조성물 및 이로부터 제조된 물품
BR112019020417B1 (pt) *	2017-03-31	2023-04-04	Dow Global Technologies Llc	Sistema catalisador e processo de polimerização para produzir um polímero à base de etileno
US11390704B2 (en)	2017-06-14	2022-07-19	Exxonmobil Chemical Patents Inc.	Ethylene copolymer blends for cross-linking applications
CN111148641B (zh)	2017-08-24	2023-03-31	陶氏环球技术有限责任公司	乙烯/C5-C10α-烯烃/多烯互聚物
EP3752560B1 (en)	2018-02-14	2024-09-25	Dow Global Technologies LLC	Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance
WO2020046597A1 (en)	2018-08-29	2020-03-05	Exxonmobil Chemical Patents Inc.	Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes
KR102538844B1 (ko) *	2018-12-21	2023-06-01	주식회사 엘지화학	방향족 비닐 화합물-비닐시안 화합물 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법
EP3940009A4 (en)	2019-03-12	2023-03-15	Mitsui Chemicals, Inc.	OLEFIN-BASED RESIN, CROSSLINKER THEREOF, AND METHODS OF PRODUCTION THEREOF
KR102715918B1 (ko) *	2019-03-29	2024-10-15	다우 글로벌 테크놀로지스 엘엘씨	열가소성 가황물을 위한 오일-증량된 펠릿 형태 에틸렌 알파-올레핀 디엔 인터폴리머
CN113874439B (zh) *	2019-04-30	2024-03-29	陶氏环球技术有限责任公司	乙烯/丙烯/非共轭二烯互聚物组合物
EP4034597B1 (en)	2019-09-24	2025-12-31	Dow Global Technologies LLC	ETHYLENE/ALPHA-OLEFIN/POLYENE INTERPOLYMER COMPOSITIONS
US12448506B2 (en)	2019-09-24	2025-10-21	Dow Global Technologies Llc	Polymer compositions for extruded profiles
EP4034598A1 (en)	2019-09-24	2022-08-03	Dow Global Technologies LLC	Polymer compositions with excellent electrical and mechanical properties
CN114846035A (zh) *	2019-12-27	2022-08-02	陶氏环球技术有限责任公司	乙烯/丁烯多嵌段共聚物及其制备方法
JP2021147420A (ja) *	2020-03-16	2021-09-27	三井化学株式会社	オレフィン・環状オレフィン共重合体の製造方法
EP4127001A1 (en) *	2020-03-27	2023-02-08	Dow Global Technologies LLC	A process for producing long-chain branched ethylene-based polymers
US12410273B2 (en)	2020-03-30	2025-09-09	Exxonmobil Chemical Patents Inc.	Comb-block copolymers and methods thereof
JP2024500603A (ja) *	2020-12-28	2024-01-10	サビックエスケーネクスレンカンパニープライヴェートリミテッド	金属－リガンド錯体、これを含むエチレン系重合体製造用の触媒組成物およびこれを用いたエチレン系重合体の製造方法
KR20240074467A (ko) *	2022-11-21	2024-05-28	롯데케미칼 주식회사	에틸렌-알파-올레핀 공중합체 제조방법
WO2025117273A1 (en)	2023-12-01	2025-06-05	ExxonMobil Technology and Engineering Company	Support-bound activators, supported catalyst systems, and processes for use thereof

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6545088B1 (en)	1991-12-30	2003-04-08	Dow Global Technologies Inc.	Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
US5977251A (en)	1996-04-01	1999-11-02	The Dow Chemical Company	Non-adiabatic olefin solution polymerization
US6680361B1 (en) *	1998-11-02	2004-01-20	Dupont Dow Elastomers Llc	Shear thinning ethylene/α-olefin interpolymers and their preparation
US6897276B2 (en) *	2002-04-24	2005-05-24	Symyx Technologies, Inc.	Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
JP2008509277A (ja)	2004-08-09	2008-03-27	ダウグローバルテクノロジーズインコーポレイティド	ポリマーの製造のための担持ビス（ヒドロキシアリールアリールオキシ）触媒
CN101490094B (zh)	2006-05-17	2013-06-26	陶氏环球技术有限责任公司	高温聚乙烯溶液聚合法
US8420760B2 (en)	2007-11-19	2013-04-16	Dow Global Technologies Llc	Long chain branched propylene-alpha-olefin copolymers
EP2328944B1 (en)	2008-09-16	2018-01-24	Dow Global Technologies LLC	Polymeric compositions and foams, methods of making the same, and articles prepared from the same
EP2448979B1 (en)	2009-07-01	2013-05-01	Dow Global Technologies LLC	Ethylenic polymer and its use
SG177446A1 (en)	2009-07-01	2012-02-28	Dow Global Technologies Llc	Ethylenic polymer and its use
KR101741857B1 (ko)	2009-07-15	2017-05-30	다우 글로벌 테크놀로지스 엘엘씨	중합체 조성물, 그의 제조 방법 및 그로부터 제조된 용품
ES2659733T3 (es) *	2010-08-25	2018-03-19	Dow Global Technologies Llc	Proceso de polimerización de olefina polimerizable y catalizador para ello
JP6104277B2 (ja) *	2011-12-13	2017-03-29	ダウグローバルテクノロジーズエルエルシー	エチレン−プロピレン−ジエン共重合体組成物
US9422383B2 (en)	2011-12-20	2016-08-23	Dow Global Technologies Llc	Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same

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KR20140107263A (ko)	2014-09-04
EP2794693A1 (en)	2014-10-29
IN2014CN04444A (2)	2015-09-04
JP6189325B2 (ja)	2017-08-30
CN104169313A (zh)	2014-11-26
US20150322185A1 (en)	2015-11-12
JP2015500920A (ja)	2015-01-08
BR112014014855A2 (pt)	2017-06-13
BR112014014855B1 (pt)	2022-01-11
KR101989206B1 (ko)	2019-09-24
WO2013096573A1 (en)	2013-06-27
CN104169313B (zh)	2016-09-21
US9422383B2 (en)	2016-08-23
EP2794693B1 (en)	2020-09-23

Publication	Publication Date	Title
ES2835807T3 (es)	2021-06-23	Interpolímeros de etileno/alfa-olefina/polieno no conjugado y procesos para formar los mismos
US9534070B2 (en)	2017-01-03	Polymerization processes for high molecular weight polymers
CN104812783B (zh)	2021-07-16	乙烯/α-烯烃/多烯基组合物
KR20010085372A (ko)	2001-09-07	에틸렌 (공)중합체 및 그 용도
SG177650A1 (en)	2012-03-29	Polymer compositions, methods of making the same, and articles prepared from the same
CN109476893B (zh)	2021-11-26	乙烯/α-烯烃/二烯互聚物组合物
EP2885326A1 (en)	2015-06-24	Highly branched compositions and processes for the production thereof
ES2949785T3 (es)	2023-10-03	Composiciones de interpolímero de etileno/alfa-olefina con resistencia mejorada a altas temperaturas continuas
WO2017206008A1 (en)	2017-12-07	Ethylene/alpha-olefin/diene interpolymer
BR112018077402B1 (pt)	2023-04-25	Composições à base de etileno/alfa-olefina/polieno
CN107709384A (zh)	2018-02-16	形成乙烯/α‑烯烃互聚物的方法
JP7702383B2 (ja)	2025-07-03	分岐を有するエチレン系ポリマー組成物
JP5128233B2 (ja)	2013-01-23	ポリオレフィン系樹脂組成物及びその成形品並びに電線・ケーブル
ES2974890T3 (es)	2024-07-02	Proceso para formar polímeros a base de etileno con distribuciones de insaturaciones terminales e internas
JP2009102521A (ja)	2009-05-14	エチレン系共重合体及びその製造方法並びにそのエチレン系共重合体の利用製品
MXPA00002787A (en)	2001-07-09	Enhanced crosslinking terpolymer