JPH0215855B2 - - Google Patents
Info
- Publication number
- JPH0215855B2 JPH0215855B2 JP10495380A JP10495380A JPH0215855B2 JP H0215855 B2 JPH0215855 B2 JP H0215855B2 JP 10495380 A JP10495380 A JP 10495380A JP 10495380 A JP10495380 A JP 10495380A JP H0215855 B2 JPH0215855 B2 JP H0215855B2
- Authority
- JP
- Japan
- Prior art keywords
- dye
- photothermographic
- hydrazone
- image
- silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 silver halide Chemical class 0.000 claims description 88
- 239000004332 silver Substances 0.000 claims description 68
- 229910052709 silver Inorganic materials 0.000 claims description 68
- 239000003638 chemical reducing agent Substances 0.000 claims description 62
- 150000007857 hydrazones Chemical class 0.000 claims description 57
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 36
- 239000007800 oxidant agent Substances 0.000 claims description 32
- 150000001875 compounds Chemical class 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 22
- 125000000623 heterocyclic group Chemical group 0.000 claims description 18
- 238000011161 development Methods 0.000 claims description 16
- 125000004070 6 membered heterocyclic group Chemical group 0.000 claims description 6
- 125000002373 5 membered heterocyclic group Chemical group 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 238000003384 imaging method Methods 0.000 claims description 5
- AIGNCQCMONAWOL-UHFFFAOYSA-N 1,3-benzoselenazole Chemical compound C1=CC=C2[se]C=NC2=C1 AIGNCQCMONAWOL-UHFFFAOYSA-N 0.000 claims description 4
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical group C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 230000033116 oxidation-reduction process Effects 0.000 claims description 4
- ODIRBFFBCSTPTO-UHFFFAOYSA-N 1,3-selenazole Chemical compound C1=C[se]C=N1 ODIRBFFBCSTPTO-UHFFFAOYSA-N 0.000 claims description 3
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 claims description 3
- AMTXUWGBSGZXCJ-UHFFFAOYSA-N benzo[e][1,3]benzoselenazole Chemical compound C1=CC=C2C(N=C[se]3)=C3C=CC2=C1 AMTXUWGBSGZXCJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000009472 formulation Methods 0.000 claims description 3
- 125000005597 hydrazone group Chemical group 0.000 claims description 2
- 125000002943 quinolinyl group Chemical class N1=C(C=CC2=CC=CC=C12)* 0.000 claims 1
- 239000000975 dye Substances 0.000 description 64
- 239000010410 layer Substances 0.000 description 43
- 239000000463 material Substances 0.000 description 39
- 238000012545 processing Methods 0.000 description 38
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 28
- 239000006185 dispersion Substances 0.000 description 22
- 239000000243 solution Substances 0.000 description 22
- 125000004432 carbon atom Chemical group C* 0.000 description 17
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- 239000000987 azo dye Substances 0.000 description 11
- 125000000217 alkyl group Chemical group 0.000 description 10
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 125000002252 acyl group Chemical group 0.000 description 9
- 239000011230 binding agent Substances 0.000 description 9
- 239000000839 emulsion Substances 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 229920000139 polyethylene terephthalate Polymers 0.000 description 9
- 239000005020 polyethylene terephthalate Substances 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 7
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 7
- 238000012546 transfer Methods 0.000 description 7
- 229920000159 gelatin Polymers 0.000 description 6
- 239000008273 gelatin Substances 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 238000011160 research Methods 0.000 description 6
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 6
- 108010010803 Gelatin Proteins 0.000 description 5
- 235000019322 gelatine Nutrition 0.000 description 5
- 235000011852 gelatine desserts Nutrition 0.000 description 5
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 4
- KLSJWNVTNUYHDU-UHFFFAOYSA-N Amitrole Chemical compound NC1=NC=NN1 KLSJWNVTNUYHDU-UHFFFAOYSA-N 0.000 description 4
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 4
- 238000005859 coupling reaction Methods 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 150000002829 nitrogen Chemical class 0.000 description 4
- 229920006267 polyester film Polymers 0.000 description 4
- 230000001235 sensitizing effect Effects 0.000 description 4
- AQRYNYUOKMNDDV-UHFFFAOYSA-M silver behenate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O AQRYNYUOKMNDDV-UHFFFAOYSA-M 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 4
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 150000004668 long chain fatty acids Chemical class 0.000 description 3
- DDIZAANNODHTRB-UHFFFAOYSA-N methyl p-anisate Chemical compound COC(=O)C1=CC=C(OC)C=C1 DDIZAANNODHTRB-UHFFFAOYSA-N 0.000 description 3
- 238000005691 oxidative coupling reaction Methods 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- IJAPPYDYQCXOEF-UHFFFAOYSA-N phthalazin-1(2H)-one Chemical compound C1=CC=C2C(=O)NN=CC2=C1 IJAPPYDYQCXOEF-UHFFFAOYSA-N 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 150000003378 silver Chemical class 0.000 description 3
- 238000000859 sublimation Methods 0.000 description 3
- 230000008022 sublimation Effects 0.000 description 3
- KJUGUADJHNHALS-UHFFFAOYSA-N 1H-tetrazole Chemical compound C=1N=NNN=1 KJUGUADJHNHALS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000002837 carbocyclic group Chemical group 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000012458 free base Substances 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- 238000004949 mass spectrometry Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 150000003142 primary aromatic amines Chemical class 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 150000003248 quinolines Chemical class 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 239000001044 red dye Substances 0.000 description 2
- 150000003839 salts Chemical group 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000012258 stirred mixture Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229960002317 succinimide Drugs 0.000 description 2
- NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical compound NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- 150000003852 triazoles Chemical class 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 125000005023 xylyl group Chemical group 0.000 description 2
- UDATXMIGEVPXTR-UHFFFAOYSA-N 1,2,4-triazolidine-3,5-dione Chemical compound O=C1NNC(=O)N1 UDATXMIGEVPXTR-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- KTWCUGUUDHJVIH-UHFFFAOYSA-N 2-hydroxybenzo[de]isoquinoline-1,3-dione Chemical compound C1=CC(C(N(O)C2=O)=O)=C3C2=CC=CC3=C1 KTWCUGUUDHJVIH-UHFFFAOYSA-N 0.000 description 1
- MEEKGULDSDXFCN-UHFFFAOYSA-N 2-pentylphenol Chemical compound CCCCCC1=CC=CC=C1O MEEKGULDSDXFCN-UHFFFAOYSA-N 0.000 description 1
- BGNGWHSBYQYVRX-UHFFFAOYSA-N 4-(dimethylamino)benzaldehyde Chemical compound CN(C)C1=CC=C(C=O)C=C1 BGNGWHSBYQYVRX-UHFFFAOYSA-N 0.000 description 1
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 description 1
- YAMJITULHOEKMI-UHFFFAOYSA-N B([O-])([O-])[O-].[Ag+3] Chemical compound B([O-])([O-])[O-].[Ag+3] YAMJITULHOEKMI-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920002307 Dextran Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- AFVFQIVMOAPDHO-UHFFFAOYSA-M Methanesulfonate Chemical compound CS([O-])(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-M 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 238000007754 air knife coating Methods 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 150000001411 amidrazones Chemical class 0.000 description 1
- 229940051880 analgesics and antipyretics pyrazolones Drugs 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000004369 butenyl group Chemical group C(=CCC)* 0.000 description 1
- 125000004063 butyryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940075397 calomel Drugs 0.000 description 1
- BFJQSCVWXZOXGK-UHFFFAOYSA-N carbamimidoylsulfanyl carbamimidothioate;dihydrochloride Chemical compound [Cl-].[Cl-].[NH3+]C(=N)SSC([NH3+])=N BFJQSCVWXZOXGK-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- GTKRFUAGOKINCA-UHFFFAOYSA-M chlorosilver;silver Chemical compound [Ag].[Ag]Cl GTKRFUAGOKINCA-UHFFFAOYSA-M 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000000326 densiometry Methods 0.000 description 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 125000006038 hexenyl group Chemical group 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- PTFYQSWHBLOXRZ-UHFFFAOYSA-N imidazo[4,5-e]indazole Chemical class C1=CC2=NC=NC2=C2C=NN=C21 PTFYQSWHBLOXRZ-UHFFFAOYSA-N 0.000 description 1
- 125000002883 imidazolyl group Chemical group 0.000 description 1
- 150000002473 indoazoles Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002757 morpholinyl group Chemical group 0.000 description 1
- SQARMCGNIUBXAJ-UHFFFAOYSA-N n-(2-hydroxyphenyl)benzenesulfonamide Chemical compound OC1=CC=CC=C1NS(=O)(=O)C1=CC=CC=C1 SQARMCGNIUBXAJ-UHFFFAOYSA-N 0.000 description 1
- KFPBEVFQCXRYIR-UHFFFAOYSA-N n-(3,5-dichloro-4-hydroxyphenyl)benzenesulfonamide Chemical compound C1=C(Cl)C(O)=C(Cl)C=C1NS(=O)(=O)C1=CC=CC=C1 KFPBEVFQCXRYIR-UHFFFAOYSA-N 0.000 description 1
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920002557 polyglycidol polymer Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 125000002568 propynyl group Chemical group [*]C#CC([H])([H])[H] 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical class O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- MCSKRVKAXABJLX-UHFFFAOYSA-N pyrazolo[3,4-d]triazole Chemical class N1=NN=C2N=NC=C21 MCSKRVKAXABJLX-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- VFQAKRQRWSOZBP-UHFFFAOYSA-N silver 2H-tetrazol-5-amine Chemical compound NC1=NN=NN1.[Ag] VFQAKRQRWSOZBP-UHFFFAOYSA-N 0.000 description 1
- KBKGVINMNSFFOO-UHFFFAOYSA-N silver hydrochloride Chemical compound Cl.[Ag] KBKGVINMNSFFOO-UHFFFAOYSA-N 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- YRSQDSCQMOUOKO-KVVVOXFISA-M silver;(z)-octadec-9-enoate Chemical compound [Ag+].CCCCCCCC\C=C/CCCCCCCC([O-])=O YRSQDSCQMOUOKO-KVVVOXFISA-M 0.000 description 1
- OIZSSBDNMBMYFL-UHFFFAOYSA-M silver;decanoate Chemical compound [Ag+].CCCCCCCCCC([O-])=O OIZSSBDNMBMYFL-UHFFFAOYSA-M 0.000 description 1
- MMLCSDNEYQRUDM-UHFFFAOYSA-M silver;docosanoate;docosanoic acid Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCCCCCC([O-])=O MMLCSDNEYQRUDM-UHFFFAOYSA-M 0.000 description 1
- LTYHQUJGIQUHMS-UHFFFAOYSA-M silver;hexadecanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCC([O-])=O LTYHQUJGIQUHMS-UHFFFAOYSA-M 0.000 description 1
- ORYURPRSXLUCSS-UHFFFAOYSA-M silver;octadecanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCC([O-])=O ORYURPRSXLUCSS-UHFFFAOYSA-M 0.000 description 1
- OHGHHPYRRURLHR-UHFFFAOYSA-M silver;tetradecanoate Chemical compound [Ag+].CCCCCCCCCCCCCC([O-])=O OHGHHPYRRURLHR-UHFFFAOYSA-M 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000003831 tetrazolyl group Chemical group 0.000 description 1
- 125000000335 thiazolyl group Chemical group 0.000 description 1
- 238000004809 thin layer chromatography Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-M toluene-4-sulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-M 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 239000001043 yellow dye Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
- G03C1/498—Photothermographic systems, e.g. dry silver
- G03C1/49827—Reducing agents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
æ¬çºæã¯ãè²çŽ ç»åãäžãã也åŒç©ççŸååã
ãªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã«é¢ããã ç±çŸåæ§åçææäžã«éç»åãçæããããã
ãšã¯ããç¥ãããŠãããç±çŸåæ§åçææããã
ãªããµãŒã¢ã°ã©ãã€ãŒææãšããŠããç¥ãããŠã
ãããããã€ãåçææã¯ãç»åæ é²å ããã
åŸãé©åºŠã«é«ãããã枩床ã«å ç±ãããåŠç液ãŸ
ãã¯åŠç济ãªãã§çŸåããç»åã圢æããã該ç±
çŸåã¯ãåçææäžã«çŸåãããéç»åãçã
ãã ç±çŸåå¯èœãªåçææäžã«çŸåãããç»åãç
æãããã該æ¹æ³ã¯ã也åŒç±åŠçæ³ãšããŠãç¥ã
ããŠãããæ¬æ现æžäžã§èšãâ也åŒâãšã¯ãåç
æå ææããæ觊çã«ä¹Ÿããç¶æ ã«ããããšãæ
å³ããã æ¬æ现æžäžã§ãâæå ææïŒææïŒâã®èªã¯ãã
ãšãã°åçææãªã©ãšäœ¿çšãããå ŽåãåçèŠçŽ
ããã³åççµæç©ã®ãããããæå³ãããããšã
ã°âããªããµãŒã¢ã°ã©ãã€ãŒçšææâãšèšãå Ž
åãããªããµãŒã¢ã°ã©ãã€ãŒçšèŠçŽ ããã³ããªã
ãµãŒã¢ã°ã©ãã€ãŒçšçµæç©ã®ãããããå«ãã æ¬æ现æžäžã§ãâ也åŒç©ççŸåâãšã¯ãé²å ã«
ãã€ãŠåœ¢æãããæœåããåŠç济ãå¿ èŠãšããªã
ç©ççŸåæ©æ§ã«ãã€ãŠçŸåãããããšãæå³ã
ãããã®èšèã¯ãâã¶ã»ã»ãªãªãŒã»ãªãã»ã¶ã»ã
ãªãã°ã©ãã€ãã¯ã»ããã»ã¹âãT.H.Jamesç·š
éã第ïŒçã1977幎ã第373â374é ãããã¯ãã©
ã³ã»ãããªãã·ã³ã°ã»ã«ã³ãããŒã»ã€ã³ã³ãŒãã¬
ãŒãã€ãããããŠãŒãšãŒã¯ãããã³ãªãµãŒãã»ã
ã€ã¹ã¯ããŒãžã€ãŒã第170å·»ã1978幎ïŒæå·ã
ItemNo.17029ã«èšè¿°ãããŠããã®ãšåæ§ã«çšã
ãã 也åŒç©ççŸååããªããµãŒã¢ã°ã©ãã€ãŒçšææ
ã«ã¯å€ãã®çŸåäž»è¬ãç¥ãããŠããããããŠãã®
çš®é¡ã®ããã²ã³åéçŸåäž»è¬ããé žåããã圢æ
ã«ãããŠãè²çŽ 圢æã«ããã©ãŒãšåå¿ããŠåçæ
æäžã«ç»åè²çŽ ãçãåŸãæåãçããããã§ã¯
ãªããæçšã§ãããšæåŸ ãããŠããçã®å€ãã®è€
çŽ ç°åŒååç©ããå®éã¯ãããã²ã³åéããªããµ
ãŒã¢ã°ã©ãã€ãŒææäžã«ãããŠç»åè²çŽ 圢æåå
ç©ãšãªããªããããªããµãŒã¢ã°ã©ãã€ãŒææäžã«
å«ãŸããå ¬ç¥ã®è€çŽ ç°åŒçŸåäž»è¬ã®ïŒçš®ã«ããã
çš®ã®ã±ãã³ããã³ã¢ã«ãããã®ããã©ãŸã³ãã
ãããããã¯ãç±³åœç¹èš±ç¬¬3615533å·ã«èšèŒãã
ãŠãããæ¬ç¹èš±ã«èšè¿°ãããŠããããã©ãŸã³ã®ïŒ
äŸã¯ãïŒâãžã¡ãã«ã¢ãããã³ãºã¢ã«ããããšã
ããŒã«âïŒâã€ã«âããã©ãžã³ãšã®åå¿ããçã
ããã®ã§ããããã®ããã©ãŸã³ã¯ãããããŒã«ç³»
ã«ããã©ãŒãšåå¿ããŠææã®è²çŽ ãçæããªãã
ããã¯åŸã«å®æœäŸ14ã§èšŒæãããããã®ãããç»
åæ é²å ããã³ç±åŠçã«ãã€ãŠè²çŽ ç»åãçãã
ããšãã§ãããã€é žåæ ã«ãããŠã«ããã©ãŒãšå
å¿ããŠåçèŠçŽ äžã«è²çŽ ãç»åæ ã«çæããè€çŽ
ç°åŒéå å€ãå«ã也åŒç©ççŸååããªããµãŒã¢ã°
ã©ãã€ãŒææãæäŸããããšã«ã¯ãåŸæ¥ããåé¡
ããã€ããå¿ èŠãªã«ãããªã³ã°åå¿ãçãããã
ããã«èŠæ±ãããä»ã®æ·»å å€ãããšãã°ããçš®ã®
èèªæã¢ãã³ããã®ä»ã®å¡©åºæŸåºæ§è¬å€ãå¿ èŠãš
ããããšãªãè€çŽ ç°åŒéå å€ãå«ãŸããããšãå¿
èŠãšãããŠããã æ¬çºæã¯ãç»åæ é²å ãšç±åŠçãšã«ãã€ãŠãè²
çŽ ç»åãçãåŸã也åŒç©ççŸååããªããµãŒã¢ã°
ã©ãã€ãŒçšåçèŠçŽ ãæäŸãããã®ã§ããã該èŠ
çŽ ã¯ãæ¯æäœäžã«çµåããã(a)æå æ§ããã²ã³å
éïŒãããšåå¿ãåŸãäžäœçãŸãã¯é£æ¥çäœçœ®ã«
é 眮ããã(b)å°ãªããšãïŒçš®ã®è²çŽ 圢æã«ããã©
ãŒïŒããã³(c)é žåâéå åç»å圢ææ§é åç©ã§ã
ã€ãŠ(ii)ææ©éå¡©é žåå€ãš(i)é žåããã圢æ ã§ã«ã
ãã©ãŒãšåå¿ããŠè²çŽ ãçããè€çŽ ç°åŒéå å€ãš
ãããªãé åç©ïŒãããªããããã«è©²éå å€ã¯ã
ïŒå¡ãŸãã¯ïŒå¡ã®è€çŽ ç°ãå«ãããã©ãŸã³åéå
å€ã§ããããšãç¹åŸŽãšããŠããããããã€ãããª
ããµãŒã¢ã°ã©ãã€ãŒææã«ãã€ãŠã€ãããåŸãã¢
ãŸè²çŽ ã¯ãããšãã°ã(1)ã€ã³ãã°ã©ã«ãã¹ã¯ãšã
ãŠã(2)çŸåãããéç»åã®è£åŒ·çšãšããŠããŸãã¯
(3)äž»èŠãªç»åè²çŽ ãšããŠãæçšã§ãããšèšãããš
ãã§ããã äžè¿°ã®ä¹ŸåŒç©ççŸååããªããµãŒã¢ã°ã©ãã€ãŒ
çšåçèŠçŽ ã¯ãæ¯æäœäžã«ãé 次ãå°ãªããšãïŒ
å±€ã®å±€ïŒïŒããªãã¡ãäºãã«åºå®ããã(a)æå
æ§ããã²ã³åéïŒããã³ãããšåå¿å¯èœãªäžäœç
ãŸãã¯é£æ¥çé¢ä¿ã«é 眮ãããã(b)å°ãªããšãïŒ
çš®è²çŽ 圢æã«ããã©ãŒïŒããã³(c)(ii)ææ©éå¡©é žå
å€ãš(i)é žåæ ã«ãããŠã«ããã©ãŒãšåå¿ããŠè²çŽ
ãçããããšã®ã§ããè€çŽ ç°åŒéå å€ãšãããªã
é žåâéå ç»å圢æçšé åç©ïŒãã ãéå å€ã¯æ¢
ã«è¿°ã¹ãããšããïŒå¡ãŸãã¯ïŒå¡ã®è€çŽ ç°ãå«ã
ããã©ãŸã³éå å€ã§ãããïŒïŒãããªãå±€ãšãïŒïŒ
å°ãªããšãïŒå±€ã®è²çŽ ãåããšããååå±€ãšãæ
ããŠãªãç»å転åèŠçŽ ãšããããšãã§ãããç»å
æ é²å ããã³ç±åŠçã«ãããèŠçŽ äžã«è²çŽ ãçã
ããããã次ãã§ååå±€ã«è»¢åããããååå±€
ã¯ã該è²çŽ ã®åªæå€å±€ãšããããšãã§ããã ïŒå¡ãŸãã¯ïŒå¡ã®è€çŽ ç°ãå«ãå€ãã®ããã©ãŸ
ã³éå å€ããæ¬çºæã«åŸã€ãŠã也åŒç©ççŸååã
ãªããµãŒã¢ã°ã©ãã€ãŒçšåçèŠçŽ äžã«çšããããš
ãã§ãããé žåããã圢æ ã§è²çŽ 圢æã«ããã©ãŒ
ãšåå¿ããŠè²çŽ ã圢æããªãããã©ãŸã³ååç©
ã¯ãæ¬çºæã§ã¯æçšãªååç©ã§ã¯ãªããïŒå¡ãŸã
ã¯ïŒå¡è€çŽ ç°ãå«ãæé©ã®ããã©ãŸã³éå å€ã®éž
æã¯ãææã®ç»åãææ©éå¡©é žåå€ã®çš®é¡ãè²çŽ
圢æã«ããã©ãŒã®çš®é¡ãæå æ§ããã²ã³åéã®çš®
é¡ãå¡åžçšçµæç©ã®çš®é¡ãåŠçæ¡ä»¶çã«ãã€ãŠç°
ãªããããã©ãŸã³éå å€ãå«ãïŒå¡ãŸãã¯ïŒå¡è€
çŽ ç°ã®çµåããçšããããšãã§ãããæ¬çºæã«ã
ã€ãŠæçšãªããã©ãŸã³éå å€ã¯ãäžèšã®åŒã«ãã€
ãŠè¡šããããšãã§ããã ãã ããåŒäžïœã¯ïŒãŸãã¯ïŒã§ããïŒR1ã¯æ°Ž
çŽ ãŸãã¯ã¢ã·ã«ãããšãã°ïŒã20ã®ççŽ ååãå«
ãã¢ã·ã«ãããšãã°ïŒã10ã®ççŽ ååãå«ãã¢ã·
ã«ããªãã¡ã¢ã»ãã«ããããªã«ãŸãã¯ãã³ãŸã€ã«
ãªã©ãå å«ãïŒR2ã¯æ°ŽçŽ ããŸãã¯é žåã«ãããª
ã³ã°ã®ãšãã«åé¢ããåŸã眮æåºããšãã°ãïŒã
20ã®ççŽ ååãå«ãã¢ã·ã«åºãŸãã¯ã¹ã«ããã«åº
ããªãã¡ããšãã°ãåŒãããã³âSO2R4ãå å«ããïŒR3ã¯ã¢ã«ãã«ãããšãã°ïŒã20ã®ççŽ
ååãå«ãã¢ã«ãã«ãããªãã¡ããšãã°ã¡ãã«ã
ãšãã«ããããã«ãããã«ããã·ã«ãããã·ã«ã
ãã³ãªã¯ã¿ãã·ã«ãïŒã20ã®ççŽ ååãå«ãã¢ã«
ã±ãã«ããšãã°ãšããã«ãããããã«ããããã«
ããã³ããã»ãã«ãïŒã20ã®ççŽ ååãå«ãã¢ã«
ããã«ããšãã°ãšããã«ãŸãã¯ããããã«ãã·ã¯
ãã¢ã«ãã«ããšãã°ïŒãïŒã®ççŽ ååãå«ãã·ã¯
ãã¢ã«ãã«ãããªãã¡ããšãã°ã·ã¯ããã³ãã«ã
ãã³ã·ã¯ãããã·ã«ãã¢ãªãŒã«ããšãã°ïŒã12ã®
ççŽ ååãå«ãã¢ãªãŒã«ããªãã¡ããšãã°ããšã
ã«ãããªã«ããã³ãã·ãªã«ããããã€ã«åºãç¹ã«
ïŒå¡ãŸãã¯ïŒå¡ãããã€ã«åºããšãã°ã€ãããŸãª
ã«åºããã¢ãŸãªã«åºãããã©ãŸãªã«åºãŸãã¯ã¢ã«
ããªãã«åºãããã³ïŒã20ã®ççŽ ååãå«ãã¢ã·
ã«åºãŸãã¯ã¹ã«ããã«åºããšãã°âCOR4ããã³
âSO2R4ã§ããïŒR4ã¯ããããã·ã«ãã¢ãã
ïŒâNH2ïŒãã¢ã«ãã«ãããšãã°ïŒã20ã®ççŽ å
åãå«ãã¢ã«ãã«ããªãã¡ããšãã°ã¡ãã«ããšã
ã«ããããã«ãããã«ããã·ã«ãããã·ã«ããã³
ãªã¯ã¿ãã·ã«ããŸãã¯ã¢ãªãŒã«ããšãã°ïŒã12ã®
ççŽ ååãå«ãã¢ãªãŒã«ããªãã¡ããšãã°ããšã
ã«ãããªã«ãŸãã¯ãã·ãªã«ã§ããïŒïŒºã¯ïŒå¡ãã
ãã¯ïŒå¡ã®è€çŽ ç°åŒæ žãŸãã¯ïŒå¡ãããã¯ïŒå¡ã®
è€çŽ ç°åŒæ žãå«ãçž®åç°ãããšãã°ãã¢ãŸãŒã«ã
ãªããµãŸãŒã«ãã»ã¬ããŸãŒã«ããã³ãŸã»ã¬ããŸãŒ
ã«ããããã»ã¬ããŸãŒã«ããã³ãŸãã¢ãŸãŒã«ãŸã
ã¯ãããªã³æ žãå®æããã«å¿ èŠãªééå±åå矀ã
è¡šãããïŒå¡ãŸãã¯ïŒå¡ã®è€çŽ ç°æ žãå®æããã«
èŠããééå±åå矀ã¯å žåçã«ã¯ççŽ ãç¡«é»ãé ž
çŽ ããã³çªçŽ ã®åååãå«ãã§ããã æ¬çºæã«åºãããã©ãŸã³éå å€ã¯ãæ¢ã«è¿°ã¹ã
ããã«ãéé¢ã®å¡©åºã®åœ¢ãŸãã¯å¡©ã®åœ¢ããšãã°å¡©
é žå¡©ããã©ãã«ãšã³ã¹ã«ãã³é žå¡©ãããšãã«ã¹ã«
ãã³é žå¡©ãŸãã¯ã¡ãã«ã¹ã«ãã³é žå¡©ã®åœ¢ã®ããã
ã®åœ¢æ ã§ãããªããµãŒã¢ã°ã©ãã€ãŒææäžã«ååš
ã§ãããããã©ãŸã³éå å€ã®æé©ã®åœ¢æ ã®éžæ
ã¯ãåŠçæ¡ä»¶ãææ©éå¡©é žåå€ã®çš®é¡ãã«ããã©
ãŒã®çš®é¡çã®å åã«ãã€ãŠç°ãªããæ¬æ现æžäžã«
瀺ãããã©ãŸã³éå å€ã®åŒã¯ãããšããã®åŒãé
é¢ã®å¡©åºã®åœ¢ã§èª¬æãããŠããŠããå¡©åºã®åœ¢æ ã®
ãã®ãå å«ããããšãæå³ããŠããã âã¢ã«ãã«âãâã¢ãªãŒã«âãâççŽ ç°åŒæ žâãã
ã³âè€çŽ ç°åŒæ žâãšããèªã¯ã眮æåºãå«ãŸãªã
ã¢ã«ãã«ãã¢ãªãŒã«ãççŽ ç°åŒããã³è€çŽ ç°åŒæ ž
ãå å«ããããšãæå³ããŠããããããã®èªã¯ã
ãŸããæ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒææã®æ
æã®æ§è³ªããšãã°ã»ã³ã·ãã¡ããªãŒç¹æ§ã«æ害ãª
圱é¿ãäžããªãåºãŸãã¯ææã®ç»åã«æ害ãªåœ±é¿
ãäžããªãåºã§çœ®æãããŠããåè¿°ã®åºãæ žãã
å å«ããããšãæå³ããŠãããäžè¿°ã®åºãæ žã«çµ
åããŠããããã®ææã®çµæã«æ害ãªåœ±é¿ãäžã
ãªã眮æåºã®äŸããããã°ãããããã¢ã«ã³ãã·
ããšãã°ãšããã·ãããã³ã«ã«ãã¡ãŒããªã©ã§ã
ãã æ¬çºæã«åºãæçšãªããã©ãŸã³éå å€ã®äŸã¯æ¬¡
ã®åŒã§è¡šããããïŒ ãã ãåŒäžZâ²ã¯ïŒå¡ãŸãã¯ïŒå¡ã®è€çŽ ç°åŒæ žã
ããã¯ãããã€ãïŒå¡ãŸãã¯ïŒå¡ã®è€çŽ ç°åŒæ žã
å«ãçž®åç°ïŒfused ringsïŒããšãã°ãã¢ãŸãŒã«ã
ãªããµãŸãŒã«ãã»ã¬ããŸãŒã«ããã³ãŸã»ã¬ããŸãŒ
ã«ããããã»ã¬ããŸãŒã«ããã³ãŸãã¢ãŸãŒã«ãã
ã³ãããªã³ãªã©ã®æ žãå®æããããã«å¿ èŠãªéé
å±åå矀ãè¡šããããããã€ãããã©ãŸã³éå å€
ã¯ãããšãã°ãäžèšã®ãã®ãå å«ããïŒ æ¬çºæã«åºãæçšãªä»ã®ããã©ãŸã³éå å€ã®äŸ
ãšããŠäžèšã®ãã®ãå å«ãããïŒ ãã ãäžèšåŒäžã®ïŒ²ã¯äžèšã®ãã®ã®ïŒã€ã§ã
ãïŒååç©çªå· æ¬çºæã«åºããããã©ãŸã³éå å€ãå«ãïŒå¡ãŸ
ãã¯ïŒå¡è€çŽ ç°ã¯ã¹ã«ããã«ããã©ãŸã³ã§ãã€ãŠ
ãããã ïŒå¡ãŸããïŒå¡è€çŽ ç°ãå«ãããã©ãŸã³éå å€
ã®æé©æ¿åºŠã®éžæã¯ãææã®ç»åãææ©éå¡©é žå
å€ã®çš®é¡ãè²çŽ 圢æã«ããã©ãŒã®çš®é¡ãæå æ§ã
ãã²ã³åéãåŠçæ¡ä»¶çã«ãã€ãŠç°ãªããããã©
ãŸã³éå å€ã®æçšãªæ¿åºŠã¯ãããªããµãŒã¢ã°ã©ã
ã€ãŒèŠçŽ äžã®æå æ§ããã²ã³åéïŒã¢ã«åœãã
0.25ãïŒã¢ã«ã®ããã©ãŸã³éå å€ãšãã€ãç¯å²å
ã«ããããããŠãã®å Žåãããªã³ãããªãŒããã
äžã«æ倧ã®æçšåå°æ¿åºŠãçããããããã«ã¯ã
æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«ãæ¯æ
äœïŒm2ã«ã€ãå°ãªããšã0.5ããªã¢ã«ã®ç°å å€ã
ååšããããšãå¿ èŠã§ããã該ããã©ãŸã³éå å€
ã®æ¿åºŠã®äžéã¯ãè©Šè¬ãå«ãæå å±€ãã€ãããã
ã«å¿ èŠãªå¡åžçšçµæç©äžã«ããã該詊è¬ã®æº¶è§£åºŠ
ã«ãã€ãŠåœ±é¿ãåãããç¹ã«æçšãªæ¿åºŠã¯ãæå
æ§ããã²ã³åéïŒã¢ã«ã«ã€ããè©Šè¬0.5ã1.5ã¢ã«
ã®ç¯å²å ã§ãããæå æ§ããã²ã³åéã¯ãç¹ã«æ
çšåºŠãé«ããäœæ ãªããããã¯ä»ã®æå æ§æåã«
æ¯ãé«åºŠã®æå æ§ãæããããã§ãããæå æ§ã
ãã²ã³åéã®ç²åãµã€ãºã®ç¯å²ã¯ãéåžžã«çŽ°ãã
ãã®ãããç²å€§ãªç²åãµã€ãºã®ãã®ã«å°ããŸã§æ
å¹ã§ããã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒææäžã®æå
æ§ããã²ã³åéã®å žåçãªæ¿åºŠã¯ããªããµãŒã¢ã°
ã©ãã€ãŒææäžã®åè¿°ã®ããã©ãŸã³éå å€ã®ïŒã¢
ã«ã«ã€ããçŽ0.2ãçŽïŒã¢ã«ã®æå æ§ããã²ã³å
éãšãã€ãç¯å²å ã«ããã æé©ã®éå å€ããã³æé©ã®ã«ããã©ãŒã®éžæã¯
ããã²ã³åéç²åã®å€§ããããã®ä»ã®éžæããã
ãã²ã³åéç²åã®ç¹æ§ã«ãã€ãŠéã€ãŠãããæå
æ§ããã²ã³åéã®æé©ã®æ¿åºŠã®éžæã¯ãææã®ç»
åãéžãã ææ©éå¡©é žåå€ã®çš®é¡ãéžãã è²çŽ 圢
æã«ããã©ãŒã®çš®é¡ãåŠçæ¡ä»¶çã«ãã€ãŠéã€ãŠ
ããã æå æ§ããã²ã³åéã¯ãåçæè¡äžã®å ¬ç¥ã®ä»»
æã®æ¹æ³ã§ã€ããããšãã§ãããç¹ã«ã也åŒç©ç
çŸååããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ çšã®æå æ§ã
ãã²ã³åéã®è£œé æ¹æ³ã«ãã€ãŠã€ããããšãã§ã
ããæçšãªæ¹æ³ãããªãµãŒãã»ãã€ã¹ã¯ããŒãž
ã€ã第148å·»ã1976幎ïŒæå·ã第14879é
ïŒRosenfeldïŒïŒãªãµãŒãã»ãã€ã¹ã¯ããŒãžã€ã第
125å·»ã1974幎ïŒæå·ã第12537å·ïŒUlbingïŒ
Hessããã³TerwilligerïŒïŒããã³ç±³åœç¹èš±ç¬¬
3871887å·ãããã³å第3839049å·ããã³è±åœç¹èš±
第1362970å·ã«èšè¿°ãããŠããã æ¬çºæã«åŸã€ãŠãå€ãã®è²çŽ 圢æã«ããã©ãŒã
ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«äœ¿çšããåŸãã
è²çŽ 圢æã«ããã©ãŒã¯ãåè¿°ã®ããã©ãŸã³éå å€
ã®é žåæ ã®ãã®ãšå ±ã«ã¢ãŸæçŽ ã圢æãããã®ã§
ãªããã°ãªããªããããªãã¡ãæ¬çºæã«ãããè²
çŽ åœ¢æã«ããã©ãŒã¯ãé²å åŸèŠçŽ ãå ç±ãããšã
ã«ãããã©ãŸã³éå å€ã®é žåæ ã®ãã®ãšå ±ã«ã¢ãŸ
ææã圢æãããã®ã§ãªããã°ãªããªããè²çŽ 圢
æã«ããã©ãŒã¯ãç»åæ é²å ããã³ç±åŠçãè¡ãª
ãåã¯ãããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«ãã€ãŠ
ç¡è²ã§ããããšã奜ãŸãããè²çŽ 圢æã«ããã©ãŒ
ããã³ãã®ä»ã®æåã¯ãåŠç枩床ã§ææã®ç»åã
çããããåã¯ããã¹ãŠã®é倧ãªæ害çžäºåå¿ã
åé¿ã§ããçšåºŠã«ååã«å®å®ã§ããããšãå¿ èŠã§
ãããæ¬çºæã®æé©ã®è²çŽ 圢æã«ããã©ãŒãéžæ
ããããã«ã¯ãç°¡åãªè©Šéšã圹ã«ç«ã€ããšãã
ãããããã€ãè©Šéšã®ïŒäŸãäžèšã®å®æœäŸïŒã«èš
èŒãããŠããããã®å®æœäŸã«ãããŠã¯ãè©Šéšãã
ãè²çŽ 圢æã«ããã©ãŒããå®æœäŸïŒã®è²çŽ 圢æã«
ããã©ãŒã®ä»£ãã«ããªããµãŒã¢ã°ã©ãã€èŠçŽ äžã«
å«ãŸããŠããããããå®æœäŸïŒã®æ¹æ³ãçšããŠã€
ããããè²çŽ ç»åããå°ãªããšãå®æœäŸïŒã®ç»å
ãšåãçšåºŠã«æºè¶³ã§ãããã®ã§ããã°ããã®ã«ã
ãã©ãŒéšåãå«ãååç©ã¯æçšã§ãããšèããã
ããäžé調ïŒé»ïŒãŸãã¯ã»ãšãã©äžé調ã«çŸãã
ãç»åãçããè²çŽ 圢æã«ããã©ãŒã§ããååç©
ã¯å€ãã®å Žåã«éåžžã«æçšã§ããã æ¬æ现æžäžã§çšããâè²çŽ 圢æã«ããã©ãŒâã
ãã³âã«ãããªã³ã°éšåâã®èªã¯ãããã©ãŸã³é
å å€ã®é žåæ ã®ãã®ã«ããåŠçæ¡ä»¶ã®äžã§ãæ¬çº
æã®ããªããµãŒã¢ã°ã©ãã€èŠçŽ äžã«ææã®ã¢ãŸè²
çŽ ç»åã圢æããååç©ãŸãã¯ååç©ã®äžéšåã
æå³ããã€ããã§ãããè²çŽ 圢æã«ããã©ãŒã¯ã
ã«ãããªã³ã°éšåãå«ã該ååç©ãããã©ãŸã³é
å å€ã®é žåããã圢ã®ãã®ãšã«ãããªã³ã°ããŠæ
æã®ã¢ãŸè²çŽ ãçãããšä¿¡ããããŠããããã«ã
ã®ããã«åŒã°ãããã«ãããªã³ã°éšåãå«ãé©åœ
ãªååç©ã®äžã«ã¯ãããªããµãŒã¢ã°ã©ãã€ãŒææ
ã®ã»ã³ã·ãã¡ããªãŒç¹æ§ã«æ害ãªåœ±é¿ãäžããã
ãšãªããæ¬çºæã«åºãåŠç枩床ã«èãåŸããã®ã§
ãããè²çŽ 圢æã«ããã©ãŒã§ããæçšãªååç©ã«
ã¯ãç±³åœç¹èš±ç¬¬3761270å·ã®ç¯å²å ãã®ãšããŠèš
èŒãããŠãããã®ããã¬ãŸã«ã·ããŒã«ç³»ã«ããã©
ãŒããšãã°ãResearch Disclosureã1978幎ïŒ
æå·ã第17326é ã«èšèŒããããã®çãããã 第ïŒè³éŠæã¢ãã³ã«ã©ãŒçŸåäž»è¬ãšåå¿ããŠã¢
ãŸã¡ãã³è²çŽ ãçãããã®ãšããŠåçæè¡äžç¥ã
ããŠããè²çŽ 圢æã«ããã©ãŒã¯ãã¢ãŸè²çŽ ãç¹ã«
é»è²ã¢ãŸè²çŽ ãçããããã«ãæå¹ã«æ¬çºææ¬ã®
ããªããµãŒã¢ã°ã©ãã€èŠçŽ äžã«çšããããšãã§ã
ãããããã€ãé»è²ã®ã¢ãŸè²çŽ 圢æã«ããã©ãŒã«
ã¯ãããšãã°ã掻æ§ã¡ãã¬ã³ã»ãµã€ããå«ãè€çŽ
ç°ååãå«ãã«ããã©ãŒãããšãã°æŽ»æ§ã¡ãã¬
ã³ã»ãµã€ããå«ããã©ãŸãã³ããã©ãŸãããªã¢ãŸ
ãŒã«ãã€ã³ããŸãŒã«ããã³ãã©ãŸããã³ãºã€ãã
ãŸãŒã«ãªã©ããããåæ§ã«ã第ïŒè³éŠæã¢ãã³ã«
ã©ãŒçŸåäž»è¬ãšã®åå¿ã«ãã€ãŠã€ã³ãã¢ããªã³ã·
ã¢ã³è²çŽ ã圢æããããšãåçæè¡äžç¥ãããŠã
ãããããŒã«ç³»ããã³ããšããŒã«ç³»ååç©ããæ¬
çºæã«åŸã€ãŠããŒã³ã¿ã»ã¢ãŸè²çŽ ãçããããã«
æçšã§ãããæçšãªè²çŽ 圢æã«ããã©ãŒã«ã¯ãã
ãšãã°ãâThe Theory of the Photograplui
ProâcersâãT.H.Jamesç·šéã第ïŒçã第12ç« ã
1977幎ããã³Reseach DisclosureïŒ1978幎12
æã第17643é ã第ç¯ã«èšèŒãããŠããã«ãã
ã©ãŒãããã æçšãªã¢ãŸè²çŽ 圢æã«ããã©ãŒã«ã¯ãïŒåœéã
ãã³ïŒåœéè²çŽ 圢æã«ããã©ãŒããããæçšãªïŒ
åœéè²çŽ 圢æã«ããã©ãŒã¯ãããšãã°ãU.
S.4021240ã«èšèŒãããŠãããæçšãªä»ã®è²çŽ 圢
æã«ããã©ãŒãšããŠã¯ãåçæè¡äžã«ãããªã³
ã°ã»ãªã眮æåºãšããŠç¥ãããŠãã眮æåºãããš
ãã°çŸåæå¶å€ãªã©ãå«ãã«ããã©ãŒããããæ
çšãªçŸåå€ã»æå¶å€æŸåºæ§ã«ããã©ãŒïŒDIRã«ã
ãã©ãŒãšãèšãããŠããïŒã¯ãããšãã°ã
Research DisclosureïŒ1972幎10æã第10226é
ã«èšèŒãããŠãããè²çŽ 圢æã«ããã©ãŒã®çµåã
ããæ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒæå€äžã«æ
å¹ã«çšããããšãã§ããã æçšãªããŒã³ã¿è²çŽ 圢æã«ããã©ãŒã«ã¯ãäžèš
ã®ãå®æœäŸïŒã®ç¬¬è¡šäžã«èšèŒãããŠãããã®ã
ãããä»ã®æçšãªããŒã³ã¿è²çŽ 圢æã«ããã©ãŒã«
ã¯äžèšã®ãã®ãããã æçšãªããŒã³ã¿è²çŽ 圢æDIRã«ããã©ãŒã«ã¯æ¬¡
ã®ãã®ãããïŒ æçšãªé»è²è²çŽ 圢æã«ããã©ãŒã«ã¯æ¬¡ã®ãã®ã
ããïŒ æçšãªé»è²è²çŽ 圢æDIRã«ããã©ãŒã«ã¯æ¬¡ã®ã
ã®ãããïŒ æçšãªã·ã¢ã³è²çŽ 圢æã«ããã©ãŒã«ã¯äžèšã®ã
ã®ãããïŒ (a) äžèšã®æ§é ãæãã眮æãã©ãŸãªã³ïŒ ãã ããåŒäžR5ã¯çœ®æãŸãã¯æªçœ®æã¢ã«ãã«
ããšãã°ïŒã20ã®ççŽ ååãå«ãã¢ã«ãã«ãã¢ã·
ã«ããšãã°ïŒã20ã®ççŽ ååãå«ãã¢ã·ã«ããŸã
ã¯ã¢ãªãŒã«ããšãã°ããšãã«ã§ãããR6ããã³
R7ã¯ã¢ã«ãã«ããšãã°ïŒã20ã®ççŽ ååãå«ã
ã¢ã«ãã«ãã¢ã«ã³ãã·ããšãã°ïŒã20ã®ççŽ åå
ãå«ãã¢ã«ã³ãã·ãã¢ã·ã«ããšãã°ïŒã20ã®ççŽ
ååãå«ãã¢ã·ã«ãããããã¹ã«ãã¢ãã«ããã
ã²ã³ç¹ã«å¡©çŽ ãŸãã¯èçŽ ããŸãã¯æ°ŽçŽ ã§ãããå ž
åçãªäŸã¯äžèšã®éãã§ããã ãè¡šã (b) äžèšã®ããšã眮æãããã¢ããã©ãŸã³ã䜿çš
ããåŸãïŒ ç¹ã«æçšãªè²çŽ 圢æã«ããã©ãŒã«ã¯äžèšãã®ã
ããïŒ æé©ã®è²çŽ 圢æã«ããã©ãŒãŸãã¯è²çŽ 圢æã«ã
ãã©ãŒçµåãç©ã®éžæã¯ãææã®ç»åãç¹å®ã®æ
æ©éå¡©é žåå€ã®çš®é¡ã䜿çšããç¹å®ã®æå æ§ãã
ã²ã³åéã®çš®é¡ã䜿çšããç¹å®ã®ããã©ãŸã³éå
å€ã®çš®é¡ãããã³åŠçæ¡ä»¶ãªã©ã«å åã«ãã€ãŠå·Š
å³ãããã§ãããã è²çŽ 圢æã«ããã©ãŒã®æ¿åºŠã¯ãããªããµãŒã¢ã°
ã©ãã€ãŒèŠçŽ äžã®éå å€ïŒã¢ã«åœã0.1ã10ã¢ã«
ã®è²çŽ 圢æã«ããã©ãŒãšããç¯å²å ã«ãããïŒçš®
以äžã®è²çŽ 圢æã«ããã©ãŒã®çµåãç©ã䜿çšãã
ããšãã¯ã該çµåãç©ã®å šæ¿åºŠããåè¿°ã®ç¯å²å
ã«ãããè²çŽ 圢æã«ããã©ãŒãŸãã¯è²çŽ 圢æã«ã
ãã©ãŒçµåãç©ã®æé©ã®æ¿åºŠã¯ãææã®ç»åãæ
æ©éå¡©é žåå€ã®çš®é¡ãè²çŽ 圢æã«ããã©ãŒãŸãã¯
ã«ããã©ãŒçµåãç©ã®çš®é¡ãæå æ§ããã²ã³åé
ã®çš®é¡ãããã©ãŸã³éå å€ã®çš®é¡ãåŠçæ¡ä»¶çã®
å åã«ãã€ãŠå€ããè²çŽ 圢æã«ããã©ãŒã®ç¹ã«æ
çšãªæ¿åºŠã¯ãéå å€ïŒã¢ã«ã«ã€ãè²çŽ 圢æã«ãã
ã©ãŒ0.25ã¢ã«ã2.0ã¢ã«ã®ç¯å²å ã«ããã æ¬çºæã§ã¯ãå€ãã®ææ©éå¡©é žåå€ã䜿çšãã
ããšãã§ããã æé©ã®ææ©éå¡©é žåå€ãŸãã¯ææ©éå¡©é žåå€ã®
çµåãç©ã®éžæã¯ãææã®ç»åã䜿çšããè²çŽ 圢
æã«ããã©ãŒã®çš®é¡ã䜿çšããæå æ§ããã²ã³å
éãããã©ãŸã³éå å€ãåŠçæ¡ä»¶çã®çš®é¡çã®å
åã«ãã€ãŠå€ã€ãŠãããæçšãªææ©éå¡©é žåå€ã®
çš®é¡ã®äžã€ã¯ãå ã«ããããéã«æåã«å¯Ÿããæµ
æåãæããŠããé·éèèªé žã®éå¡©ã§ããããã®
çš®é¡ã«å±ããæçšãªéå¡©é žåå€ã¯ãããšãã°ãã
ãã³é žéãã¹ãã¢ãªã³é žéããªã¬ã€ã³é žéãããŠ
é žéããªãã·ã¹ãã¢ãªã³é žéãã«ããªã³é žéãã
ãªã¹ãã³é žéããã³ãã«ããã³é žéã§ãããæ¬æ
现æžäžã§çšããâé·éèèªé žâãšããèªã¯ãéå¡©
ã®èèªé žéšåäžã«10ã30ã®ççŽ ååãå«ãã§ãã
èèªé žãå«ãã€ããã§çšããŠãããææ©éå¡©é žå
å€ã®ä»ã®æçšãªçš®é¡ã¯ãçªçŽ é žããšãã°ã€ãããŸ
ãŒã«ããã©ãŸãŒã«ããŠã©ãŸãŒã«ãïŒïŒïŒïŒïŒâã
ãªã¢ãŸãŒã«ããã³1Hâããã©ãŸãŒã«ãªã©ã®çªçŽ
é žãŸãã¯ãããã®æ··åç©ããæã矀ããéžã°ãã
çªçŽ é žãšéãšã®é¯äœã«ãã€ãŠä»£è¡šããããããã
çªçŽ é žã®éå¡©ã¯ãããšãã°ããªãµãŒãã»ãã€ã¹ã¯
ããŒãžã€ãŒïŒResearch DisclosureïŒã第150å·»ã
1976幎10æå·ãdeMauriacã®ç¬¬15026é ã«èšèŒã
ããŠããã æ¬æ现æžäžã§äœ¿çšããâå¡©âããã³âé¯äœâã®
èªã¯ãçµæãšããŠã§ããç©è³ªããåè¿°ã®ããªããµ
ãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«ãããŠãææã®ç»å圢æ
ç¹æ§ã瀺ãããã«ããããšã®ã§ããä»»æã®ã¿ã€ã
ã®çµåãŸãã¯é¯äœåœ¢æã®æ©æ§ãå å«ããã€ããã§
çšããŠããã ææ©éå¡©é žåå€ã¯ãããç¯å²å ã®æ¿åºŠã§çšãã
ããšãã§ãããæé©æ¿åºŠã®éžæã¯ãææã®ç»åã
çšããç¹å®ã®ææ©éå¡©é žåå€ã®çš®é¡ãçšããç¹å®
ã®ããã©ãŸã³éå å€ãè²çŽ 圢æã«ããã©ãŒãæå
æ§ããã²ã³åéããã³åŠçæ¡ä»¶ãªã©ã«ãã€ãŠç°ãª
ããææ©éå¡©é žåå€ã®æçšãªæ¿åºŠã¯ãããã²ã³å
éïŒã¢ã«ã«ã€ãææ©éå¡©é žåå€0.1ã¢ã«ã10ã¢ã«
ã®ç¯å²å ã«ãããææ©éå¡©é žåå€ã®ç¹ã«æçšãªæ¿
床ã¯ãããã²ã³åéïŒã¢ã«ã«ã€ããææ©éå¡©é žå
å€0.5ã¢ã«ãïŒã¢ã«ã®ç¯å²å ã«ããã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã¯ããã
ã¯ã«ããã³çµåå€ãšããŠãåçš®ã®ã³ãã€ãããã³
ãã€ã³ããŒãåç¬ãŸãã¯çµåããŠå«ãããšãã§ã
ãããããã¯ãåçš®ã®å±€äžã«å«ãŸããããšãã§ã
ããåèšã®æçšãªã³ãã€ãããã³ãã€ã³ããŒã¯ã
芪氎æ§ç©è³ªãŸãã¯çæ°Žæ§ç©è³ªã®ãããã§ãã€ãŠã
ããããããã¯éæãŸãã¯åéæã§ãã€ãŠãèçœ
質ããšãã°ãŒã©ãã³ããŒã©ãã³èªå°äœãã»ã«ããŒ
ã¹èªå°äœãå€ç³é¡ããšãã°ããã¹ãã©ã³çã®å€©ç¶
ç£ã®ç©è³ªãå«ãããããã¯ãŸããããªïŒããã«ã
ããªãã³ïŒãã¢ã¯ãªã«ã¢ããããªããŒçã®ããšã
芪氎æ§ããªããã«ååç©ã®ãããªåæéåç©è³ªã
å«ãããã®ä»ã®æçšã§ããåŸãåæéåç©è³ªã«
ã¯ãåæ£æ ããã«ååç©ããšãã°ã©ããã¯ã¹åœ¢ã®
ãã®ãããã³ç¹ã«ãããªããµãŒã¢ã°ã©ãã€ãŒææ
ã®å¯žæ³å®å®æ§ãåäžããããã®ãªã©ããããæå¹
ãªããªããŒã«ã¯ãé«ååéç©è³ªãæ¬çºæã®ããªã
ãµãŒã¢ã°ã©ãã€ãŒææã®åèšç»å圢ææç©ãšäœµçš
ã§ããããªããŒããã³æš¹èãå«ãŸããã æ¬çºæã«ãã€ãŠçããçŸåãããéç»åããã³
è²çŽ ç»åã®ããŒã³ã¯ãçŸåãããéç»åã®é圢æ
åŠãç¹å®ã®ã«ããã©ãŒãç¹å®ã®ããã©ãŸã³éå
å€ãåŠçæ¡ä»¶çã®å åã«ãã€ãŠå€ã€ãŠãããã«ã
ãã©ãŒããã³éå å€ã¯ãææã®éãšè²çŽ ç»åã®çµ
åããåŸãããã«ãè²çžã«ãããŠçŸåãããéç»
åãšè£è²ã®é¢ä¿ã«ããè²çŽ ãçããããã«éžæã
ãããšãã§ããã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã¯ãæ¬çº
æã§æçšãªåŠç枩床ã«èããããšã®ã§ããåçš®ã®
æ¯æäœãå«ãããšãã§ããã代衚çãªæ¯æäœã«
ã¯ãã»ã«ããŒã¹ãšã¹ãã«ãããªïŒããã«ã¢ã»ã¿ãŒ
ã«ïŒãããªïŒãšãã¬ã³ãã¬ãã¿ã¬ãŒãïŒãããªã«ãŒ
ãããŒãããã³ããªãšã¹ãã«ãã€ã«ã æ¯æäœãªã©
ãããã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã¯ãåç
æè¡äžå ¬ç¥ã®åçš®ã®å¡åžæ³ãããšãã°ãã€ããã³
ãŒãã³ã°ããšã¢ãã€ãã³ãŒãã³ã°ãã«ãŒãã³ã³ãŒ
ãã³ã°ãŸãã¯ããããŒãçšããæŒåºãå¡åžãªã©ã®
æ¹æ³ã«ãã€ãŠé©åœãªæ¯æäœäžã«å¡åžããããšãã§
ããã â溶èäœåœ¢æååç©âã¯ãæ¬çºæã®ããçš®ã®ã
ãªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã«ãããŠãæ¹åããã
çŸåç»åãçããããã«æçšã§ããããšãã§ã
ãã溶èäœåœ¢æååç©ã¯ãçªçŽ é žã®éå¡©ãå«ãã
ãªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ãšå ±ã«çšãããšç¹ã«æ
çšã§ããããšãã§ãããæ¬æ现æžäžã§ãâ溶èäœ
圢æååç©âã®èªã¯ãåè¿°ã®åŠç枩床ã«å ç±ãã
å Žåã«æ¹åãããåå¿åªäœãå žåçã«ã¯ãã®äžã§
åè¿°ã®ç»å圢ææ§çµåãç©ãçŸåã«ãã€ãŠããè¯
奜ãªç»åãäžãã溶èåªäœãçãããããªååç©
ãæå³ããã€ããã§çšããŠããã該åå¿åªäœã®åŠ
ç枩床ã«ãããæ£ç¢ºãªæ§è³ªã¯ååã«ç解ãããŠã
ãªããåŠç枩床ã«ãããŠæº¶èäœãçãããããå
å¿æåã®ããããçžäºåå¿ãå¯èœãªãããããã®
ãšä¿¡ãããããæçšãªæº¶èäœåœ¢ææ§ååç©ã®äŸã«
ã¯ãå¯èãïŒïŒïŒâãããµã³ãžãªãŒã«ãã¡ãã«ã¢
ãã»âãã¹ã«ãã¢ãããã¢ã»ãã¢ãããã¹ã¯ã·ã³
ã€ããããã³ïŒâïŒ2HïŒâãã¿ã©ãžãã³ãå«ãŸ
ããã 該ææ©éå¡©é žåå€ã¯ãããç¯å²å ã®æ¯ã®(1)çªçŽ
é žéšåãŸãã¯é·éèèªé žéšåã®ããšãææ©éšå察
(2)éã€ãªã³ãå«ãããšãã§ããã該ææ©éå¡©é žå
å€äžã®ææ©éšå察éã€ãªã³ã®æé©ã®æ¯ã¯ããã®æ
æ©éšåãäœã§ããããããšãã°ã©ããªçªçŽ é žã§ã
ãããã©ããªããã©ãŸã³éå å€ã§ããããã©ããª
åŠçæ¡ä»¶ã§ããããã©ããªè²çŽ 圢æã«ããã©ãŒã
çšããŠããããªã©ã«ããç°ãªããéå¡©é žåå€äžã«
ãããææ©éšå察éã€ãªã³ãšããŠã®éã®ã¢ã«æ¯
ã¯ã10ïŒïŒãïŒïŒïŒã®ç¯å²å ãæçšã§ãããäžè¿°
ã®ææ©éšå察éã€ãªã³ãšããŠã®éã®ç¹ã«æçšãªæ¯
ã¯ãïŒïŒïŒãïŒïŒïŒã®ç¯å²å ã«ããã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã¯ãŸãã
ããç¯å²å ã®pAgãå«ãããšãã§ãããpAgã¯ã
åžè²©ã®ãã€ãžã¿ã«pHã¡ãŒã¿ãŒã«é£çµãããŠãã
éåžžã®ã«ãã¡ã«ããã³éâå¡©åéé»æ¥µãçšããŠæž¬
å®ããããšãã§ãããæ¬çºæã®äžè¿°ã®ç»å圢ææ
åãå«ãåæ£ç©äžã®å žåçãªpAgã¯ãçŽïŒãçŽ
9.5ã®ç¯å²å ã«ãããç¹ã«æçšãªpAgã¯4.5ãïŒã®
ç¯å²å ã«ãããæé©ã®pAgã¯ãç¹å®ã®ææ©éå¡©é ž
åå€ãææã®ç»åãããã©ãŸã³éå å€ãåŠçæ¡ä»¶
çã®ããšãäžè¿°ã®å åã«ãã€ãŠç°ãªãã æ¬çºæã®äžè¿°ã®æåãå«ãåæ£ç©ã¯çŽ1.5ãçŽ
8.5ã®ç¯å²å ã§ããPHãæããŠãããäžè¿°ã®ããš
ããããã©ãŸã³éå å€ãšä»ã®æåãšãå«ãåæ£ç©
ã®ããã®ç¹ã«æçšãªPHã¯ãçŽ4.5ãçŽïŒã®ç¯å²å
ã«ãããç¹ã«å¥œãŸããç¯å²ã¯çŽ4.5ãçŽ5.5ã§ã
ãã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«åå
å¢æè²çŽ ãçšããããšã¯æå¹ã§ãããããã«ã
ãã該ææã«ããã«è¿œå ã®æ床ãäžããããšãã§
ãããæçšãªåå å¢æè²çŽ ã¯ãããšãã°
Research DisclosureïŒ1978幎ïŒæïŒJ.W.
Carpenterããã³P.W.Laufã®ç¬¬17029é ã第ïŒâ
15é ã«èšèŒãããŠãããã®ã®äžããéžã¶ããšãã§
ããã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®äžè¿°ã®
æåã¯ãææã®ç»åãçããä»»æã®é©åœãªäœçœ®ã«
å ¥ããããšãã§ãããããšãã°ã該æåã®ïŒã€ãŸ
ãã¯ãã以äžã該èŠçŽ ã®ïŒã€ãŸãã¯ãã以äžã®å±
äžã«å«ãŸããããšãã§ãããããå Žåã«ã¯ããã
ïŒ ã®ããã©ãŸã³éå å€ãææ©éå¡©é žåå€ããã
ã³ïŒãŸãã¯ä»ã®æ·»å å€ãä¿è·å±€ïŒäžè¢«èŠå±€ãšãèš
è¿°ããŠãããïŒäžã«å«ãŸããããšãæãŸããããš
ããããããããªãããè«žæåã¯ãåŠçããããš
ãã«ãããã®ææã®çžäºåå¿ãèµ·ãåŸãäœçœ®ã«å ¥
ããªããã°ãªããªãã ææã®ç»åãçããããã«ã¯ãæå æ§ããã²ã³
åéããã³ããªããµãŒã¢ã°ã©ãã€ãŒææã®ä»ã®è«ž
æåã¯ãçžäºã«âåå¿å¯èœãªäœçœ®é¢ä¿ã«çœ®ãããŠ
ããããšâãå¿ èŠã§ãããæ¬æ现æžäžã§âåå¿å¯
èœãªäœçœ®é¢ä¿ã«çœ®ãããŠããâãšããè¡šçŸããã
å Žåããã¯æå æ§ããã²ã³åéãšãæ¢è¿°ã®è²çŽ 圢
æã«ããã©ãŒãå«ãç»å圢æçµåãç©ãšããç»å
æ é²å åŸã®åŠç枩床ã«ãããŠææã®åŠçãåãæ
çšãªè²çŽ ç»åãçããããšãã§ãããããªçžäºã®
äœçœ®é¢ä¿ã«çœ®ãããŠããããšãæå³ããã€ããã§
ãããæå æ§ããã²ã³åéã®ç»åæ é²å ã«ãã€ãŠ
圢æãããæœåã¯ãææ©éå¡©é žåå€ãšããã©ãŸã³
éå å€ãšãå«ãç»å圢ææ§çµåãç©ã®ããã®è§Šåª
ãšããŠäœçšãããšä¿¡ããããã次ã«ãåŠçã®çµæ
ã§ããéå å€ã®é žåæ ã®åœ¢ã®ãã®ã¯ãæ¢è¿°ã®è²çŽ
圢ææ§ã«ããã©ãŒãšåå¿ããŠãããªããµãŒã¢ã°ã©
ãã€èŠçŽ ã®ç»ååã«ææã®è²çŽ ã圢æãããã®ãš
ä¿¡ããããã æ¬çºæã®ç¹ã«æçšãªå ·äœäŸã¯ãæ¯æäœäžã«ã(a)
æå æ§ããã²ã³åéããã³ãããšåå¿å¯èœãªäœçœ®
é¢ä¿ã«çœ®ãããŠãã(b)å°ãªããšãïŒã€ã®è²çŽ 圢æ
æ§ã«ããã©ãŒãããšãã°ïŒâããããã·âïŒâã
ããã¢ã³ããããã³(c)äžèš(i)ãš(ii)ãšãããªãé žå
âéå ç»å圢ææ§çµåãç©ããã€ã³ããŒäžãããš
ãã°ããªïŒããã«ããã©ãŒã«ïŒäžã«å«ãŸãããã
ãã®ãæããŠãªã也åŒç©ççŸåããªããµãŒã¢ã°ã©
ãã€ãŒèŠçŽ ã§ããïŒ (i) ææ©éå¡©é žåå€ããšãã°ããã³é žéïŒ (ii) å®è³ªçã«äžèšã®åŒã«ãã€ãŠè¡šããããããã©
ãŸã³ ãããªãè€çŽ ç°éå å€ïŒ 該èŠçŽ ã¯ç»åæ é²å ããã³ç±åŠçã«ãã€ãŠè²çŽ
ç»åã圢æããããšãã§ããããã®å ·äœäŸã«ãã
ãŠãæ¢è¿°ã®æ§é ã®ãããåºã¯ãã¹ã«ããã«åºã«é¢
ããŠã¡ã¿ãŸãã¯ãã©ã®äœçœ®ã«ããããšã奜ãŸã
ãã æ¬çºæã®å¥ã®å ·äœäŸã¯ãããªïŒããã«ããã©ãŒ
ã«ïŒã®ãããªãã€ã³ããŒäžã«ã(a)æå æ§ããã²ã³
åéããããšåå¿å¯èœãªäœçœ®é¢ä¿ã«çœ®ããã(b)å°
ãªããšãïŒã€ã®è²çŽ 圢ææ§ã«ããã©ãŒãããšãã°
ïŒâããããã·âïŒâãããã¢ããªãã(c)(i)ææ©
éå¡©é žåå€ããšãã°ããã³é žéããã³(ii)åè¿°ã®ã
ãšãïŒå¡ãŸãã¯ïŒå¡è€çŽ ç°ãå«ãããã©ãŸã³éå
å€ã ããšãã°åŒïŒ ã«ãã€ãŠè¡šããããããã©ãŸã³ããããªãé žåé
å ç»å圢ææ§çµåãç©ããå«ãã ãã®ãããªãå°
ãªããšãïŒå±€ã®å±€ïŒïŒãšã該èŠçŽ ã®ç»åæ é²å
ãšç±åŠçãšã«ãã圢æãããè²çŽ ã®ããã®åªæå€
ãå«ãå°ãªããšãïŒå±€ã®ç»åååå±€ïŒïŒãšãæ¯
æäœäžã«é 次æããŠãªãç»å転å也åŒç©ççŸåå
ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã§ãããäžè¿°ã®æ§é
ã«ãããŠããããåºã¯ãã¹ã«ããã«åºã«é¢ããŠã¡
ã¿ãŸãã¯ãã©ã®äœçœ®ã«ããã®ã奜ãŸããã äžè¿°ã®æ¡æ£è»¢åããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äž
ã«ã¯ã該èŠçŽ ã®åŠçã«ãã€ãŠçããè²çŽ ç»åã®ã
ãã®åçš®ã®ç»åååå±€ãååšãããããšãã§ã
ããäžè¿°ã®ãè²çŽ ç»åã®ããã®ç»åååå±€ã¯ã(1)
é©åœãªæ¯æäœäžã«ååå±€ãå«ãå¥åã®ååèŠçŽ ã§
ãã€ãŠããããããããã¯ãŸãã(2)ååå±€ããäž
è¿°ã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®äžéšã§ããïŒ
å±€ã®å±€ã§ãã€ãŠããããååå±€ã¯ãå žåçã«ã¯ã
è²çŽ ç»åã®ããã®åªæå€ããæã€ãŠãããæ¬çºæ
ã®æ¡æ£è»¢åããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®å ·äœäŸ
ã«ããã°ãåçš®ã®åªæå€ãååå±€äžã«äœ¿çšã§ã
ãã ããå¿ èŠãªãã°ãæ¡æ£è»¢åããªããµãŒã¢ã°ã©ã
ã€ãŒèŠçŽ äžã«âäžéæåå±€âãå«ãŸããããšãã§
ããããããã€ãå±€ã¯ãååå±€äžã®è²çŽ ç»åã芳
å¯ããããã«äœ¿çšããåŸãææã®çšåºŠã®æŸå°ç·
ïŒradiationïŒããšãã°å¯èŠå ç·ãåå°ããããã
ã«äœ¿çšãããŠãããâäžéæåå±€âã¯å¿ èŠãªåå°
ãäžããçš®ã ã®è©Šè¬ãããšãã°äºé žåãã¿ã³ãã
å«ãããšãã§ããã å€ãã®å Žåãæ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒ
èŠçŽ ã®åè¿°ã®çš®ã ã®å±€ã®äžéã«ãåé¢å±€ãèšãã
ããšãæçšã§ããããã®åé¢å±€ã¯ãè«žå±€éã«ãã
ãè«žæåã®æ¡æ£ã®ææã®ã¿ã€ãã³ã°ãæäŸãããš
ãã€ããããªå©çãããããããšãã§ãããŸãæ¬
çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®ç°ãªãæå
å±€ã®æ¥çã®æ¹åãäžããããšãã§ãããå žåçãª
åé¢å±€ã¯ãäžè¿°ã®ãã€ã³ããŒã®ä»»æãã®ãå«ãã
ãšãã§ããã ããå¿ èŠãªãã°ãé²å ããã³åŠçãããæ¬çºæ
ã®ããªããµãŒã¢ã°ã©ãã€èŠçŽ äžã«æ®åããéã¯ã
é©åœãªæŒçœå€ã«ãã€ãŠæŒçœããããšãã§ãããã
ãªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«ååšããéã®æŒçœ
ã¯ãããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«ãã¬ã®è²çŽ
ç»åãçããããšãã§ããã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒæå€ã«é¢ã
ãŠãçš®ã ã®ç»åæ é²å æ段ãçšããããšãã§ã
ãã該ããªããµãŒã¢ã°ã©ãã€ãŒææã¯ãé»ç£ã¹ã
ã¯ãã«ã®çŽ«å€åããã³éè²åã«æå¿ããã ããªããµãŒã¢ã°ã©ãã€ãŒææãé©åºŠã«é«ããã
ã枩床ã«åã«åäžã«å ç±ããã ãã§ãçããæé
å ãããšãã°æ°ç§éå ã«ãç»åæ é²å ããããªã
ãµãŒã¢ã°ã©ãã€ãŒææäžã«å¯èŠåãçŸåããããš
ãã§ãããããšãã°ãç»åæ é²å ããããªããµãŒ
ã¢ã°ã©ãã€ãŒææã¯ãçŽ80âãçŽ200âã®ç¯å²å
ã®æž©åºŠã奜ãŸããã¯çŽ120âãçŽ150âã®ç¯å²å ã®
枩床ã«ãææã®ç»åãçãããŸã§å ç±ããããšã
ã§ãããå ç±ã¯ãããšãã°çŽïŒãçŽ90ç§ã®ç¯å²
å ã奜ãŸããã¯çŽïŒãçŽ30ç§ã®ç¯å²å ã§ãææã®
è²çŽ ç»åãçãããŸã§è¡ãªããããããšãã°çŽ
125â以äžãšããäœãåŠç枩床ã«ãããŠã¯ãç»å
ã®çŸåã«ãã€ãšé·ãåŠçæéãå¿ èŠãšãããããš
ãããã äžèšã®å®æœäŸã¯ãæ¬çºæãããã«ããç解ããŠ
ãããããã®ãã®ã§ããã å®æœäŸ ïŒ è²çŽ 圢ææ§ã«ããã©ãŒã®äœ¿çš æ¬å®æœäŸã¯æ¬çºæãäŸç€ºãããã®ã§ããã äžèšã®ããã©ãŸã³éå å€ïŒ ããã³åçš®ã®è²çŽ 圢ææ§ã«ããã©ãŒãå«ãäžé£ã®
æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ããäžèšã®
æé ã«åŸã€ãŠã€ãã€ãã äžèšã®è«žæåïŒ ããã³é žéïŒé žåå€ïŒ 33.6ïœ ããã³é žïŒã«ããªé²æ¢å€ïŒ 25.4ïœ ããªïŒããã«ããã©ãŒã«ïŒïŒãã€ã³ããŒïŒ
ïŒBUTV AR â76ãåæšãç±³ãã¢ã³ãµã³ã
ç€Ÿè£œïŒ 12.0ïœ ã¢ã»ãã³âãã«ãšã³ïŒæº¶å€ïŒ 400ml ããããŒã«ãã«ã§72æéäžç·ã«åŠçããŠåæ£ç©ã
ã€ãã€ãã ãã®ããã«ããŠåŸãåæ£ç©ããåæ£ç©ïŒ¡ãšã
ãããã®åæ£ç©ïŒmlããããã©ãŸã³No.ïŒãšåä»ã
ãããã©ãŸã³éå å€0.3ããªã¢ã«ïŒ105.5mgïŒãã
ã³ãäžæ¥ç¬¬è¡šã«ç€ºããã«ããã©ãŒ0.3ããªã¢ã«
ããå容ç©ã®ã¢ã»ãã³ãšãã«ãšã³ãšã®æ··åç©äžã«
2.0ééïŒ ã®ããªïŒããã«ããã©ãŒã«ïŒãå«ã溶
液ïŒmläžã«æº¶è§£ãããã溶液ã«æ·»å ãããããã
ãŠã§ããæ··åç©ãæ¹æãããã®ã«ãã¢ã»ãã³ã«æº¶
ãããèæ²åéã®ä¹³å€ïŒïŒïŒ æ²åç©ïŒïŒããªïŒã
ãã«ããã©ãŒã«ïŒäžã«è§£åãããããã®ïŒïŒéã€
ãªã³0.3ããªã¢ã«ïŒ0.8mlãæ·»å ããããã®ããã«
ããŠã§ããçµæç©ã¯ãéã€ãªã³ïŒã¢ã«åœã40ïœã®
ããªïŒããã«ããã©ãŒã«ïŒãå«ãã§ããã ããããŠã§ããããªããµãŒã¢ã°ã©ãã€ãŒçšçµæ
ç©ããïŒãã«åã®ããªïŒãšãã¬ã³ãã¬ãã¿ã¬ãŒ
ãïŒãã€ã«ã æ¯æäœäžã«ã38âã§6.0ãã«ã®æ¹¿æœ€
å¡åžåã«å¡åžãããã§ããããªããµãŒã¢ã°ã©ãã€
ãŒçšèŠçŽ ã也ç¥ãããã 也ç¥ããããªããµãŒã¢ã°ã©ãã€ãŒçšèŠçŽ ãå
ïŒãŒãã©ã«ã»ãšã¬ã¯ããªãã¯ã»ã«ã³ãããŒè£œã®ã
ã©ããã©ã³ãã3200ãããçšããŠïŒã«ç»åæ é²å
ãããæéã¯ïŒç§éãè·é¢ã¯38cmã§ãã€ãããã
ã«ãããããªããµãŒã¢ã°ã©ãã€ãŒçšèŠçŽ äžã«ãçŸ
åå¯èœãªæœåãçããããã®ç»åæ é²å ããããª
ããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã次ã«ç¬¬è¡šã«ç€ºãæå®
ã®æéãããªããµãŒã¢ã°ã©ãã€ãŒçšèŠçŽ ã®æ¯æäœ
åŽããã«ãŒãããå ç±ããã¯é¢ã«æ¥è§Šãããããš
ã«ãã€ãŠãåäžã«å ç±ããã äžèšã®ç¬¬è¡šã¯ãããããã®å Žåã«äœ¿çšããç¹
å®ã®ã«ããã©ãŒããã³åŠçæã®é²å âçŸåã®æé
ããã³æž©åºŠãšããã®çµæã§ããç»åè²çŽ ã®è²çžã
瀺ããŠããã ãè¡šã ãè¡šã ãè¡šã ãè¡šã å®æœäŸïŒ ç°ãªãããã©ãŸã³éå å€ã®äœ¿çš ããã©ãŸã³No.ïŒã®ä»£ãã«ãäžèšã«ç€ºãããã©ãŸ
ã³ååç©ïœâïœãçã¢ã«éçšããããšä»¥å€ã¯ãå®
æœäŸïŒãšåæ§ã«ããŠãããªããµãŒã¢ã°ã©ãã€ãŒçš
èŠçŽ ãã€ãã€ããååç©ïœâïœã§ã¯ãããã©ãŸã³
No.ïŒã®ã¹ã«ããã«åºãããããæå®ã®ã¹ã«ããã«
åºã«ãã€ãŠçœ®æãããŠããã ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«å«ãŸãããã
ã«ããã©ãŒã¯äžèšã®ãã®ã§ãã€ãïŒ åããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®è©Šæãå®æœäŸ
äŸïŒã§è¿°ã¹ããšåæ§ã«ãïŒç§éç»åæ é²å ããèŠ
çŽ äžã«çŸåå¯èœãªæœåãäžããããã®ããã«ãã
ç»åæ é²å ããèŠçŽ ããå®æœäŸïŒã§è¿°ã¹ãããã«
ããŠã110âã§15ç§éç±åŠçãããåå Žåã«ãé²
å ããããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®é²å åã«é
ç»åãšããŒã³ã¿è²çŽ ç»åãšãçããã å®æœäŸïŒ ãããŒã®äœ¿çš å®æœäŸïŒã§è¿°ã¹ãããã«ããŠãããã©ãŸã³éå
å€ãšããŠã®æ¢è¿°ã®ããã©ãŸã³No.ïŒã0.3ããªã¢ã«
ããã³å®æœäŸïŒã§è¿°ã¹ãè²çŽ 圢ææ§ã«ããã©ãŒ
0.3ããªã¢ã«ãå«ãããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ
ãã€ãã€ãããã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ
ã¯ããããŒçŸåä¿é²å€ãšãèšè¿°ãããŠããïŒçš®ã®
ãããŒã®äžã€ããå«ãã§ãããïŒçš®ã®ãããŒã¯ã
ãããããã¿ã«ã€ããããã³ïŒâïŒ2HïŒâãã¿
ã«ã¢ãžãã³ã§ãã€ãã ãã®ããã«ããŠåŸãããããªããµãŒã¢ã°ã©ãã€
ãŒèŠçŽ ã¯ãå®æœäŸïŒã«è¿°ã¹ãããŠããããã«ããŠ
ç»åæ é²å ãããèŠçŽ äžã«ãçŸåå¯èœãªæœåãç
ãããé²å ãããèŠçŽ ã®è©Šæã¯110âããã³125â
ã§å ç±ãããããããŒãå«ãŸãªãããã«å¥ã®ããª
ããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ãåæ§ã«ããŠã€ãããåŠ
çãããã«ããªããã³ç»åâ圢æã®äž¡é床ã¯ãå
çæè¡äžå ¬ç¥ã®èµ€å€åå°ãã³ã·ãã¡ããªãŒã«ãã
åŠçæéã§åŠçãè¡ãªãå Žåã«åŸã€ãã ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®è©Šæã®åã ã¯ã
ãããŒãååšãããšåŠãšã«ããããããè²çŽ ãã
ã³éç»åã®äž¡æ¹ãçãããçµæã¯ããããŒã®ååš
ããçŸåã®é床ãšãç»ååããã³éç»ååã®äž¡æ¹
ã®åã«ãããŠåŸãããæçµçéæ¿åºŠãšã®äž¡æ¹ãå€
åãããããšã瀺ãããæ¢è¿°ã®ãããŒã®äœ¿çšã«ã
ããç»åâã«ããªã®åºå¥ã¯äžè¬ã«æ¹åãããã å®æœäŸ ïŒ çŸåå€æå¶å€æŸåºæ§è²çŽ 圢ææ§ã«ããã©ãŒã®äœ¿
çš æ¬å®æœäŸã¯ãæ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒ
èŠçŽ äžã«ãããã©ãŸã³éå å€ãšå ±ã«ãçŸåå€æå¶
å€æŸåºæ§è²çŽ 圢ææ§ã«ããã©ãŒäœ¿çšã®å¹æãäŸç€º
ããããã®ãã®ã§ããã ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã0.3ããªã¢ã«ã®
äžèšã®éå å€ããã³è²çŽ 圢ææ§ã«ããã©ãŒãå«ã
ã§ããããšä»¥å€ã¯ãå®æœäŸïŒã®æ¹æ³ã«åŸã€ãŠãã
ãªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ãã€ãã€ãã ãè¡šã ãè¡šã åããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®è©Šæãå®æœäŸ
ïŒã§è¿°ã¹ããšåæ§ã«ããŠïŒç§éç»åæ é²å ãã該
ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«çŸåå¯èœãªæœå
ãã€ãã€ããé²å åŸã®åããªããµãŒã¢ã°ã©ãã€ãŒ
èŠçŽ ãã次ã«ããããã100âã125âããã³150
âã§30ç§éåŠçããããšã«ãããæå³çã«éå°åŠ
çããã 4Aããã³4Bãšèå¥èšå·ãä»ããããªããµãŒã¢
ã°ã©ãã€ãŒèŠçŽ äžã«éç»åããã³ããŒã³ã¿è²çŽ ç»
åãçãããããããªããã150âã§åŠçããå Ž
åãèŠçŽ 4BïŒçŸåå€æå¶å€æŸåºæ§è²çŽ 圢ææ§ã«ã
ãã©ãŒãå«ãïŒã®è©Šæã ããã«ããªä»¥äžã«èå¥ã§
ããç»åãçããã 4Cããã³4Dãšå®ããèŠçŽ ã®è©Šæäžã«ã¯éç»å
ãçããããè²çŽ ç»åã¯çããªãã€ããè²çŽ 圢æ
æ§ã«ããã©ãŒã«é¢ä¿ãªããéçŸåã¯åãã§ããã
150âã§éçŸåã¯å šé¢ã«çãããç»åã¯çŸãããª
ãã€ãã å®æœäŸ ïŒ äžèšã®åŠããå€å±€èŠçŽ ãã€ãã€ãã ããªïŒããã«ããã©ãŒã«ïŒïŒButvarïŒåæšãç±³
åœã¢ã³ãµã³ã瀟補ïŒã®2.0ééïŒ æº¶æ¶²ïŒmlã«å¯Ÿãã
å®æœäŸïŒã§è¿°ã¹ãåæ£ç©3.0mlãèæ²åéä¹³å€
ïŒæ²åéïŒïŒ ïŒ0.8mlãç·è²å¢æè²çŽ 溶液ïŒ0.2
mgïŒmlã®å¢æè²çŽ ãå«ãïŒ0.5mlãã¢ã»ãã³0.5
mlãããã³ãïŒééïŒ ã®ããªïŒããã«ããã©ãŒ
ã«ïŒïŒButvarïŒããã«ãšã³äžã«å«ã溶液äžã«åè¿°
ã®ããã©ãŸã³No.ïŒã156mgå«ãåæ£ç©3.0mlããã
ã³ããã«ãäžèšã®è²çŽ 圢ææ§ã«ããã©ãŒ195mgã
æ·»å ããïŒ è©²æº¶æ¶²ããïŒãã«åã®ããªïŒãšãã¬ã³ãã¬ãã¿
ã¬ãŒãïŒãã€ã«ã æ¯æäœäžã«ïŒãã«ã®æ¹¿æœ€åã«å¡
åžããã ããããŠã§ããããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ
ã«ãïŒééïŒ ã®ããªïŒããã«ã¢ã«ã³ãŒã«ïŒæº¶æ¶²
ãã湿最æã®åããïŒãã«ãšãªãããã«äžå¡ãã
ãã ããªïŒããã«ã¢ã«ã³ãŒã«ïŒã®äžå¡ãã也ç¥ãã
åŸã該ããªïŒããã«ã¢ã«ã³ãŒã«ïŒã®å±€ã®äžã«ã第
ïŒã®å±€ã湿最æã®åãïŒãã«ã§å¡åžããããã®ç¬¬
ïŒã®å±€ã¯ã6.2mlã®ïŒïŒ ããªïŒããã«ããã©ãŒã«ïŒ
ïŒButvar â76ïŒã3.0mlã®å®æœäŸïŒã§è¿°ã¹ãã
ãã³é žéâããã³é žåæ£ç©ã0.8mlã®èæ²åéä¹³
å€ïŒïŒïŒ æ²åç©ïŒã10mlã®ã¢ã»ãã³ã200mgã®äžèš
è²çŽ 圢ææ§ã«ããã©ãŒïŒ ããã³140mgã®äžèšããã©ãŸã³éå å€ïŒ ããæããã®ã§ãã€ãã ãã®ããã«ããŠã§ããããªããµãŒã¢ã°ã©ãã€ãŒ
èŠçŽ ã®ããã€ããå ã«å¯ŸããŠç»åæ é²å ããèŠçŽ
äžã«çŸåå¯èœãªæœåãäžããå®æœäŸïŒã§è¿°ã¹ãã
ãã«ããŠã110âã§15ç§éç±åŠçãããåŠçãã
è©Šæã¯ãç·è²å ã«ç»åæ é²å ããé åã«éç»åã
ãã³ããŒã³ã¿è²çŽ ç»åãçããããããã®æå å±€
ãèµ€è²å æå¿æ§ã§ã¯ãªãã€ããããèµ€è²å ã«ãã
ããé åã«ã¯ç»åãçŸãããªãã€ããçœè²å ã«ã
ãããé åã«ã¯ãéç»åã®ã»ãã«èµ€è²ã®è²çŽ ç»å
ã芳å¯ãããã å®æœäŸïŒ ããªãšã¹ãã«ãã€ã«ã æ¯æäœã®æè² ããã©ãŸã³çŸåå€ã®ç»åæ é žåã«ãããªã³ã°ã
ãçããã¢ãŸè²çŽ ã¯ãããªãšã¹ãã«ãã€ã«ã ã®ã
ããªããªãšã¹ãã«ææãæè²ããã®ã«æçšã§ãã
ãšããããããã¯ããã枩床ãè²çŽ ã®æè¯æž©åºŠã
ãã³ããªãšã¹ãã«ååäœã®ã¬ã©ã¹è»¢äœæž©åºŠã®äž¡è
ãè¶ ãããªãã°ãçŽæ¥ãæè¯ã«ãã€ãŠèµ·ãå Žåã
ããããããäžæ¹ã«ãããŠãè²çŽ ãã€ãªã€ãŒãšèš
ãããã®ããããªããµãŒã¢ã°ã©ãã€ãŒææã«æ·»å
ãããã°ãçããè²çŽ ã¯ããã€ãšé¥ãã«äœã枩床
ã§ããªãšã¹ãã«è²çŽ ååå±€äžã«å ¥ã蟌ãããšãã§
ãããæ¬æ现æžäžã§æ¡çšããâè²çŽ ãã€ãªã€ãŒâ
ã®èªã¯ãåŠç枩床ã«ãããŠç»åè²çŽ ããã€ã«ã ã
ããªãã¯ã¹ãéã€ãŠç§»åã§ããããã«ããããšã®
ã§ããååç©ãæå³ããããã®ééã¯æããã溶
èãããã€ãªã€ãŒäžã«ãããè²çŽ ã®ããªãšã¹ãã«
ææãžã®æè¯ã«ãããã®ã§ããããã€ãªã€ãŒã¯ã
ããšãã°ããªãšã¹ãã«ãã€ã«ã æ¯æäœçšãªã©ã®ã
ãªãšã¹ãã«ææçšã®å¯å¡å€ãšããŠäœçšãããã®ãš
ä¿¡ããããã å®æœäŸïŒã§è¿°ã¹ãããã«ããŠã€ããããããã
ãŠããã©ãŸã³éå å€ãšããŠã®ããã©ãŸã³No.ïŒãã
ã³å®æœäŸïŒã®ç¬¬è¡šããéžãã è²çŽ 圢ææ§ã«ãã
ã©ãŒ(e)ãšåäžã®è²çŽ 圢ææ§ã«ããã©ãŒãå«ãããª
ããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®è©Šæãç»åæ é²å ã
ãŠã該ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«çŸåå¯èœ
ãªæœåãã€ãã€ãããã®ç»åæ é²å ããããªããµ
ãŒã¢ã°ã©ãã€ãŒèŠçŽ ãã次ã«ãå®æœäŸïŒã§è¿°ã¹ã
ããã«ç±åŠçãããåŠçããè©Šæã次ã«ã90âã§
120ç§éå ç±ããããã®éã500mgã®ã¡ãã«ã¢ãã»
ãŒããå«ã第ïŒã®èŠçŽ ãšæ¥è§Šããããã¡ãã«ã¢ã
ã»ãŒãã¯ãè²çŽ ãã€ãªã€ãŒãšããŠäœçšããããã€
ã³ããŒãšããŠäœçšããã¡ãã«ã¢ãã»ãŒããå«ãèŠ
çŽ äžã«ã¯ãïŒå¹³æ¹ãã€ãŒãåœãã200mgã®ããª
ïŒããã«ããã©ãŒã«ïŒãååšãããå ç±åŸããã
ãã®èŠçŽ ã¯åé¢ãããããã©ãŸã³éå å€ãå«ãã§
ããå±€ã¯ããã€ã«ã æ¯æäœããç©ççã«é€å»ãã
ãã該ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®ããªïŒãšã
ã¬ã³ãã¬ãã¿ã¬ãŒãïŒãã€ã«ã æ¯æäœäžã«ã茪é
ã®ã¯ã€ãããšããããŒã³ã¿è²çŽ åãçŸãããã å®æœäŸïŒã§è¿°ã¹ãæ¹æ³ã«åŸã€ãŠãä»ã®è²çŽ ã補
é ããããšãã§ãããããããªãããè²çŽ ã®è»¢å
ã®ããã«æãæçšãªæž©åºŠããã³è²çŽ å容èŠçŽ ãžã®
è²çŽ ã®è»¢åã®å¹çã¯è²çŽ ã®æ§é ãç¹å®ã®è²çŽ ãã€
ãªã€ãŒãåŠçæ¡ä»¶çã®å åã«ãã€ãŠéã€ãŠããã å®æœäŸ ïŒ ïŒâã¢ããâïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«ã®éå¡©
ã®äœ¿çš äžèšã®ããšãããŠãïŒâã¢ããâïŒïŒïŒïŒïŒâ
ããªã¢ãŸãŒã«ã®éå¡©ãå«ãããªããµãŒã¢ã°ã©ãã€
ãŒèŠçŽ ãã€ãã€ãïŒ 10.0mlã®èžçæ°Žã50mlã®20ïŒ ãŒã©ãã³æ°Žæº¶æ¶²ã
ãã³0.84ïœã®ïŒââïŒâã¢ããâïŒïŒïŒïŒïŒâ
ããªã¢ãŸãŒã«ãå«ã溶液ã«ãïŒå以å ã«10.0mlã®
1Mç¡é žéãæ·»å ããããšã«ãããåæ£æ¶²ãã€ã
ã€ããæ·»å å·¥çšãéããåžžã«ãçµæç©ãååã«æ··
åããåæ£æ段ã«ããã溶液ãé£ç¶çã«åæ£ãã
ãããã®ããã«ããŠã€ãã€ãåæ£æ¶²ïŒmlã¯ã143
mgã®ãŒã©ãã³ããã³15.4mgã®ïŒââïŒâã¢ãã
âïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«ã®éå¡©ãå«ãã§ã
ãã äžèšã®ããšãè²çŽ 圢ææ§ã«ããã©ãŒïŒ ãå«ãåæ£æ¶²ã次ã®ããã«ããŠã€ãã€ããããªã
ã¡ãè¡šé¢æŽ»æ§å€ïŒAlkanol XCãç±³åœãE.I.ããŠ
ãã³ç€Ÿãã販売ãããŠããååã®åæšïŒã®10ïŒ æ°Ž
溶液48mlãå«ã溶液ãã5.0mlã®ãšãã«ã¢ã»ããŒ
ãã4.5mlã®ïŒïŒïŒâãžâïœâã¢ãã«ããšããŒã«
ïŒã«ããã©ãŒæº¶å€ïŒããã³6.15ïœã®è²çŽ 圢ææ§ã«
ããã©ãŒãå«ã第ïŒã®æº¶æ¶²ãšæ··åããã§ããæ··å
ç©ãã³ãã€ããã«äžã§åæ£ãããã äžèšã®åŒïŒ ã«ãã€ãŠè¡šããããããã©ãŸã³éå å€ã®70mgãã
ïŒâã¢ããâïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«ã®éå¡©ã
å«ãåæ£æ¶²5.0mlãåè¿°ã®è²çŽ 圢ææ§ã«ããã©ãŒ
åæ£æ¶²4.0mlã1.0ééïŒ è¡šé¢æŽ»æ§å€æº¶æ¶²
ïŒSurfactant 10Gãããªã°ãªã·ããŒã«ãšãŒãã«ã
ç±³åœOlin Corp.ããã®åžè²©åïŒ1.0mlããã³èæ²
åéä¹³å€ïŒïŒã¢ã«ïŒ æ²åç©ïŒ0.5mlãããªãæ··å
液äžã«æº¶è§£ããããšã«ããããªããµãŒã¢ã°ã©ãã€
ãŒèŠçŽ ãã€ãã€ããã§ããçµæç©ããããªïŒãšã
ã¬ã³ãã¬ãã¿ã¬ãŒãïŒãã€ã«ã æ¯æäœäžã«ãïŒã
ã«ã®æ¹¿æœ€æå¡åžåã«å¡åžããã ãã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã也ç¥ããã
次ãã§å ã«ç»åæ é²å ããèŠçŽ äžã«çŸåå¯èœãªæœ
åãã€ãã€ãããã®ç»åæ é²å ããèŠçŽ ãã150
âã§30ç§éåäžã«å ç±ãããèŠçŽ äžã«ãé»è²ã€ãœ
ãè€è²ã®ãéããã³è²çŽ ç»åãåŸãããã次ã«ã
ã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ããäžèšã®è«žæå
ãå«ãæŒçœâå®ç济äžã«ãŠïŒåéåŠçãã次ãã§
æ°Žã§æŽã也ç¥ããã é ¢é ž 20.0ml NH4S2O3ïŒ60ïŒ æ°Žæº¶æ¶²ïŒ 150.0ml Na2SO3 15.0ïœ CoïŒNH3ïŒ6Cl3 3.0ïœ ïŒâããããã·ãããªã¡ãã¬ã³ãžãããªããã
ã©é ¢é ž 3.0ïœ äžèšã«æ°Žãå ã㊠1.0ãšããã ãã®æŒçœäžå®ç液ã®PHã¯4.5ã§ãã€ãã æŒçœâå®ç液äžã§ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ
ããéããã³ããã²ã³åéãé€å»ããåŸã«ã匷ã
é»è²ã®è²çŽ ç»åãçŸãããã ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®æªé²å ã®è©Šæã
åè¿°ã®æŒçœâå®ç济äžã§15åéåŠçãããããªã
ãµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã«ã¯å®è³ªçã«è²çŽ ã圢æã
ããªãã€ããããã«ãã€ãŠãæŒçœâå®ç液ã¯ãã
ãªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã®åè¿°ã®ããã©ãŸã³
éå å€ãçŽæ¥é žåããªãããšã蚌æãããã å®æœäŸïŒ è²çŽ 圢ææ§ã«ããã©ãŒã®äœ¿çš åè¿°ã®å®æœäŸïŒã®è²çŽ 圢ææ§ã«ããã©ãŒã®ä»£ã
ã«ãäžèšã®ç¬¬9Aè¡šã«ç€ºãè²çŽ 圢ææ§ã«ããã©ãŒ
ãããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«å ããããã
ãšä»¥å€ã¯ãå®æœäŸïŒã§è¿°ã¹ãæ¹æ³ãšåæ§ã«ããŠã
ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ãã€ãããç»åæ é²
å ããçŸååŠçãããåå Žåã«åŠçã«ãã€ãŠãäž
èšç¬¬9Aè¡šã«ç€ºãç»åã®è²çžãæãããã¬ã®è²çŽ
ç»åãçããã ãè¡šã ãè¡šã å®æœäŸïŒ ä»ã®éå¡©é žåå€ã®äœ¿çš ïŒâã¢ããâïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«ã®éå¡©
ãå«ããŒã©ãã³åæ£æ¶²ã®ä»£ãã«ãåœéïŒéã€ãªã³
åºæºïŒã®éã¢ããããã©ãŸãŒã«ãŸãã¯éã¡ãã«ã€
ãããŸãŒã«âïŒâããªãŒã«å¡©ã®ããããã䜿çšã
ãããšä»¥å€ã¯ãå®æœäŸïŒããã³ïŒã§è¿°ã¹ããã®ãš
åæ§ã®ã«ã©ãŒããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ãã€ã
ã€ãã å®æœäŸïŒããã³ïŒã§è¿°ã¹ããšåæ§ã«ç»åæ é²å
ããã³åŠçããåŸãäžè¿°ã®éå¡©é žåå€ã«ãã€ãŠã
å®æœäŸïŒããã³ïŒã§çãããã®ãšåæ§ã®ãã¬è²çŽ
ç»åãçããã å®æœäŸ10 ç±æº¶å€ã®äœ¿çš çŽ20âã§ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã§åºäœ
ã§ãããã該ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®ç±åŠ
çæéã«æº¶èããåçš®ã®æ°Žæº¶æ§ååç©ããæ¬çºæ
ã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã«æ·»å ããããã
ããã®ååç©ã¯ãæ¬æ现æžäžã§ç±æº¶å€ïŒthermal
solventsïŒãšåŒã¶ãããããã¯åŠç枩床ã«ãã
ãŠãããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«ãããåå
ç©ã®ç§»å床ãé«ããããšã芳å¯ãããã å®æœäŸïŒããã³ïŒã«èšè¿°ãããã®ã®ãããªããª
ããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ãã€ãã€ãããã ããã
ãã¯ããã«ãæ¯æäœïŒå¹³æ¹ãã€ãŒãåœãïŒæ¯æäœ
929cm2åœãïŒ40ã60ã100ããã³200mgã®äžèšç±æº¶
å€ã®ïŒã€ãå«ãã§ããïŒã¹ã«ãã¢ãããã¢ã»ãã¢
ãããã¹ã¯ã·ã³ã€ãããïŒâïŒ2HïŒâãã¿ã«ã¢
ãžãã³ããã³ïŒ®âããããã·ããã¿ãªããã ããããŠã§ããããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®
è©Šæããå®æœäŸïŒã§è¿°ã¹ãããã«ããŠç»åæ é²å
ããŠãããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«ãçŸåå¯
èœãªæœåãã€ãã€ããé²å ããããªããµãŒã¢ã°ã©
ãã€ãŒèŠçŽ ã¯ãå®æœäŸïŒã§è¿°ã¹ãããã«ããŠç±åŠ
çãããåè©Šæã«ã€ããŠã®ãã®åŠçã®çµæãšã
ãŠãæŒçœåã«ãããå€ãçŸåãããéãçããäž
è¿°ã®ç±æº¶å€ãå«ãŸãªãåæ§ã®è©Šæã«æ¯èŒããŠãæ
倧è²çŽ æ¿åºŠã¯å®è³ªçã«äžæããã å®æœäŸ11 å€å±€èŠçŽ äžèšã®æ¹æ³ã«ãããïŒè²ããªããµãŒã¢ã°ã©ãã€
ãŒèŠçŽ ãã€ãã€ãïŒ äžèšã®ããšãããŠãããªïŒãšãã¬ã³ãã¬ãã¿ã¬
ãŒãïŒãã€ã«ã æ¯æäœäžã«ãéããã³ç·æå¿æ§ã
ãŒã³ã¿ãŒåœ¢ææ§æå å±€ãå¡åžããïŒ äžèšã®è«žæåãå«ãããªããµãŒã¢ã°ã©ãã€ãŒçµ
æç©ãã€ãã€ãïŒ 5.0mlã®ãå®æœäŸïŒã§è¿°ã¹ãïŒâã¢ããâïŒïŒ
ïŒïŒïŒâããªã¢ãŸãŒã«âãŒã©ãã³åæ£æ¶² 4.0mlã®ãå®æœäŸïŒã§è¿°ã¹ããã®ãšé¡äŒŒã®ã«ã
ãã©ãŒåæ£æ¶²ããã ããå®æœäŸïŒã®è²çŽ 圢ææ§ã«
ããã©ãŒ(b)ããžâïœâããã«ãã¿ã¬ãŒãäžã«æº¶è§£
ãããã®ãå«ãç¹ãçžéããã 1.0mlã®è¡šé¢æŽ»æ§å€æº¶æ¶²ïŒSurfactant 10GïŒ70
mgã®ããã©ãŸã³éå å€ïŒ 200mgã®ã¹ã«ãã¢ãã 0.6mlã®éããã³ç·æå¿æ§èæ²åéïŒ3.0ã¢ã«ïŒ
æ²åç©ïŒä¹³å€ã ãã®ããã«ããŠã§ããããªããµãŒã¢ã°ã©ãã€ãŒ
çšçµæç©ããããªïŒãšãã¬ã³ãã¬ãã¿ã¬ãŒãïŒã
ã€ã«ã æ¯æäœäžã«ã60âã§ïŒãã«ã®æ¹¿æœ€æåãã«
å¡åžããåŸã也ç¥ãããã ç·æå¿æ§ããªããµãŒã¢ã°ã©ãã€ãŒå±€ã®äžã«ãé
æå¿æ§ãé»è²è²çŽ 圢ææ§å±€ãå¡åžããã第ïŒã®å±€
ã®ããã®çµæç©ã¯ãã«ããã©ãŒåæ£æ¶²ããå®æœäŸ
ïŒããã®è²çŽ 圢ææ§ã«ããã©ãŒã®4.0mlã«ãã€ãŠ
眮ããããããããšãããã³ãéããã³ç·æå¿æ§
ããã²ã³åéä¹³å€ãåœéã®éæå¿æ§ããã²ã³åé
ä¹³å€ã«ãã€ãŠçœ®ããããããããšä»¥å€ã¯ã第ïŒã®
å±€ãšåãã§ãã€ãããã®ããã«ããŠã§ããããªã
ãµãŒã¢ã°ã©ãã€ãŒçšçµæç©ãã也ç¥ããéããã³
ç·æå¿æ§å±€ã®äžã«ã湿最æã®åãïŒãã«ã§ãçŽæ¥
å¡åžããã ãã®å€å±€ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã也ç¥ã
ãã次ãã§ããã€ã«ã¿ãŒãéããå ïŒåå¥ã«ã
éãç·ããã³èµ€ãããªãïŒã«ç»åæ é²å ããããª
ããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã次ã«ã140âã§15ç§é
åäžã«å ç±ãããåŠçããããªããµãŒã¢ã°ã©ãã€
ãŒèŠçŽ ãã次ã«å®æœäŸïŒã§è¿°ã¹ãæŒçœâå®ç液äž
ã«ïŒåé浞挬ããæ°Žäžã§ïŒåéæŽãã也ç¥ãã
ããããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®ãéè²å ã«é²
å ããé åã«ãèµ€è²ã®è²çŽ ç»åãçŸãããã該èŠ
çŽ ã®ç·è²å ã«ããããéšåã«ã¯ãããŒã³ã¿è²çŽ ç»
åãçŸãããã該ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®
èµ€è²å ã«ããããéšåã«ã¯ãè²çŽ ç»åãçŸãããª
ãã€ãã å®æœäŸ12 æŒçœâå®çå±€ã®äœ¿çš å®æœäŸïŒããã®è²çŽ 圢ææ§ã«ããã©ãŒ(b)ãå«ã
å®æœäŸïŒã§è¿°ã¹ãã«ã©ãŒããªããµãŒã¢ã°ã©ãã€ãŒ
èŠçŽ ã®è©Šæããç»åæ ã«é²å ããããªããµãŒã¢ã°
ã©ãã€ãŒèŠçŽ äžã«ãçŸåå¯èœãªæœåãã€ãã€ãã
ãã®ç»åæ é²å ããããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ
ãã次ã«ã150âã«ãŠ30ç§éåäžã«å ç±ãããåŠ
çããããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã次ã«ãããª
ïŒãšãã¬ã³ãã¬ãã¿ã¬ãŒãïŒãã€ã«ã æ¯æäœäžã®
æŒçœâå®çå±€ãšæ¥è§Šãããªããã120âã§30ç§é
å ç±ãããæŒçœâå®çå±€ã¯ãæ¯æäœ929cm2åœãã
äžèšã®è«žæåãå«ãã§ããïŒ ïŒïŒïŒâãããµã³ãžãªãŒã« 500mg ïŒç±æº¶å€ïŒ ããªå°¿çŽ ïŒé¯åå€ïŒ 125mg ïŒïŒ1â²âãžããªãžãã«ã ã¢ããžã³ãžãããã¯ã
ãªã 125mg ïŒé žåå€ïŒ ããªïŒããã«ãããªãã³ïŒ 500mg ïŒãã€ã³ããŒïŒ ãã©âãã«ãšã³ã¹ã«ãã³é ž 250mg ïŒé žïŒ ããã²ã³åéãå«ãããªããµãŒã¢ã°ã©ãã€ãŒèŠ
çŽ ã®å±€ãšæ¥è§ŠãããæŒçœâå®çå±€ãå ç±ãããšã
éç»åããã³æªçŸåã®ããã²ã³åéã¯æŒçœâå®ç
ãããŠãç¡è²éæã®è£œåãšãªã€ããããªããµãŒã¢
ã°ã©ãã€ãŒèŠçŽ äžã«ã¯ããã¬ã®ããŒã³ã¿è²çŽ ç»å
ãçŸãããã å®äŸäŸ 13 ããã¯ã也åŒç©ççŸåããªããµãŒã¢ã°ã©ãã€ãŒ
ææäžã®ã«ããã©ãŒãšããŠã®ãã³ãŒã³ã¹ã«ãã³ã¢
ããããšããŒã«ãšã¹ã«ããã«ããã©ãŸã³éå å€ãš
ã®é žåã«ãããªã³ã°ã«ãããäžé調ã«çŸãããç»
åã®åœ¢æãäŸç€ºãããã®ã§ããã å®æœäŸïŒã§è¿°ã¹ããããªããã³é žéã®åæ£æ¶²ïŒ¡
ã®ïŒmlãã2.0ééïŒ ããªïŒããã«ããã©ãŒã«ïŒ
ã®ã¢ã»ãã³æº¶æ¶²3.2mlãšãè¿œå ã®ã¢ã»ãã³1.0mlãš
ã®äžã«äžèšã®ç¬¬14Aè¡šäžã«ç€ºãããšãçš®ã ã®éã®
ããã©ãŸã³No.ïŒããã³ïŒïŒïŒâãžã¯ããâïŒâã
ã³ãŒã³ã¹ã«ãã³ã¢ããããšããŒã«ãšãå«ã溶液ã«
æ·»å ãããã§ããæ··åç©ãæ¹æãããæ¹æããæ··
åç©ã«ãã¢ã»ãã³äžèæ²åéä¹³å€ïŒïŒã¢ã«ïŒ æ²å
ç©ïŒå«æã®æ¶²0.8mlïŒ0.3ããªã¢ã«éã€ãªã³ïŒãæ·»
å ããããªïŒããã«ããã©ãŒã«ïŒäžã§ããã¿ã€ãº
ããã ããããŠã§ããããªããµãŒã¢ã°ã©ãã€ãŒçšçµæ
ç©ãã38âã«ãŠäžåŒããããªãããªïŒãšãã¬ã³ã
ã¬ãã¿ã¬ãŒãïŒãã€ã«ã æ¯æäœäžã«ã6.0ãã«ã®
湿最æå¡åžåãšãªãããã«å¡åžããã ããããŠã§ããããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã
也ç¥ããã次ã«å ã«ç»åæ é²å ããããªããµãŒã¢
ã°ã©ãã€ãŒèŠçŽ äžã«ãçŸåå¯èœãªæœåãçããã
ãã該ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ãã次ã«ãèŠ
çŽ ã®æ¯æäœåŽããäžèšç¬¬14Aè¡šäžã«ç€ºã枩床ã«ã
ããå ç±ããã¡ã¿ã«ãããã¯ãšãåè¡šäžã«ç€ºãæ
éæ¥è§Šãããããšã«ãããåäžã«å ç±ããã次
ã«ã該èŠçŽ ã®ããªããµãŒã¢ã°ã©ãã€ãŒå±€åŽããã¡
ã¿ããŒã«ã§æ¹¿ãããå¥åã®åå°ç»åååã·ãŒãã«
察ããŠæŒãã€ãããããããŠã§ããããããããµ
ã³ãã€ãããã次ã«150âã«ãŠ60ç§éå ç±ããã
該ååã·ãŒãã¯ã次ã«ãåè¿°ã®èŠçŽ ããåé¢ãã
ããäžé調ïŒé»ãã¿ããïŒãŸãã¯éè²ã®ç»åãã
ååã·ãŒãäžã«èŠ³å¯ãããããããã®çµæã¯ãå
è¿°ã®ããã©ãŸã³ååç©ã®éããããªããµãŒã¢ã°ã©
ãã€ãŒå±€äžã®åœéã®ã«ããã©ãŒãè¶ ãããšãã«äž
é調ã®è²çŽ ã圢æãããããšã瀺ããŠãããã«ã
ãã©ãŒãéå°ã§ãã€ããšãã¯ã圢æãããè²çŽ ã¯
éè²ã§ãã€ãã æ¯èŒäŸäœæãè¡ãªãããããã®äŸã«ãããŠã¯ã
ã¹ã«ãã³ã¢ããããšããŒã«ã«ããã©ãŒã®ä»£ãã«ã
åœéã®ïŒ®ïŒïŒ®âãžã¡ãã«âïŒâãã³ãŒã³ã¹ã«ãã³
ã¢ããã¢ããªã³ãçšãããããåå Žåã«ãåè¿°ã®
ããšãç»åæ é²å ããã³ç±åŠçãè¡ãªã€ãŠããæ€
åºã§ããè²çŽ ãŸãã¯è»¢åå¯èœãªè²çŽ ã¯èŠ³å¯ãããª
ãã€ãã ãè¡šã æ¯èŒäŸ ããã¯æ¯èŒäŸã§ããã 295ïœã®äžèšããããŒã«ç³»ã«ããã©ãŒïŒ ãšã25mlã®ãžã¡ãã«ãã«ã ã¢ããïŒæ¬æ现æžäžã§
DMFãšèšããïŒãšã®æ··åç©ãã¹ã¿ãŒã©ãŒãã³ã³ã
ã³ãµãŒããã³æ»Žäžæãå ·åããïŒã€éŠååºãã©
ã¹ã³äžã«å ¥ãããã2.9ïœã®äžèšååç©7AïŒ ãš25mlã®DMFãšã«æ·»å ããã20mlã®2Næ°Žé žåã
ããªãŠã ãš50mlã®DMFãšããæ¹æããªããå ãã
æ··åç©ã溶解ããã次ã«ã35mlã®æ°Žäžã«6.6ïœ
ïŒ0.02ã¢ã«ïŒã®K3FeïŒCNïŒ6ãå«ã溶液ã滎äžããŠ
å ããããã®æ·»å äžã«ã¬ã¹ãçºçãã溶液ã¯æç·
è²ã«å€ã€ããïŒæéæ¹æåŸãæ··åç©ãéããé»
ãã€è²ã®åºäœãæéãããèå±€ã¯ãããã°ã©ãã€
ãŒã«ããåæã®çµæãè²çŽ ããããªã³ååç©ãå
åšããªãããšãæãããšãªã€ããæéããç©è³ªã®
è©Šæãããã«ãã¹ã¹ãã¯ããã¡ããªãŒã«ããåæ
ããŠã¢ãŸè²çŽ ã圢æãããŠããªãããšã確èªã
ãã äžè¿°ã®ååç©7Aã®ä»£ãã«äžèšã®ååç©7EïŒ ãçšããŠãäžè¿°ã®æ¹æ³ãããè¿ãããããŒã³ã¿ã¢
ãŸè²çŽ ãçãããããã¯ããã¹ã¹ãã¯ããã¡ããª
ãŒã«ããåæãã確èªãããã
ãªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã«é¢ããã ç±çŸåæ§åçææäžã«éç»åãçæããããã
ãšã¯ããç¥ãããŠãããç±çŸåæ§åçææããã
ãªããµãŒã¢ã°ã©ãã€ãŒææãšããŠããç¥ãããŠã
ãããããã€ãåçææã¯ãç»åæ é²å ããã
åŸãé©åºŠã«é«ãããã枩床ã«å ç±ãããåŠç液ãŸ
ãã¯åŠç济ãªãã§çŸåããç»åã圢æããã該ç±
çŸåã¯ãåçææäžã«çŸåãããéç»åãçã
ãã ç±çŸåå¯èœãªåçææäžã«çŸåãããç»åãç
æãããã該æ¹æ³ã¯ã也åŒç±åŠçæ³ãšããŠãç¥ã
ããŠãããæ¬æ现æžäžã§èšãâ也åŒâãšã¯ãåç
æå ææããæ觊çã«ä¹Ÿããç¶æ ã«ããããšãæ
å³ããã æ¬æ现æžäžã§ãâæå ææïŒææïŒâã®èªã¯ãã
ãšãã°åçææãªã©ãšäœ¿çšãããå ŽåãåçèŠçŽ
ããã³åççµæç©ã®ãããããæå³ãããããšã
ã°âããªããµãŒã¢ã°ã©ãã€ãŒçšææâãšèšãå Ž
åãããªããµãŒã¢ã°ã©ãã€ãŒçšèŠçŽ ããã³ããªã
ãµãŒã¢ã°ã©ãã€ãŒçšçµæç©ã®ãããããå«ãã æ¬æ现æžäžã§ãâ也åŒç©ççŸåâãšã¯ãé²å ã«
ãã€ãŠåœ¢æãããæœåããåŠç济ãå¿ èŠãšããªã
ç©ççŸåæ©æ§ã«ãã€ãŠçŸåãããããšãæå³ã
ãããã®èšèã¯ãâã¶ã»ã»ãªãªãŒã»ãªãã»ã¶ã»ã
ãªãã°ã©ãã€ãã¯ã»ããã»ã¹âãT.H.Jamesç·š
éã第ïŒçã1977幎ã第373â374é ãããã¯ãã©
ã³ã»ãããªãã·ã³ã°ã»ã«ã³ãããŒã»ã€ã³ã³ãŒãã¬
ãŒãã€ãããããŠãŒãšãŒã¯ãããã³ãªãµãŒãã»ã
ã€ã¹ã¯ããŒãžã€ãŒã第170å·»ã1978幎ïŒæå·ã
ItemNo.17029ã«èšè¿°ãããŠããã®ãšåæ§ã«çšã
ãã 也åŒç©ççŸååããªããµãŒã¢ã°ã©ãã€ãŒçšææ
ã«ã¯å€ãã®çŸåäž»è¬ãç¥ãããŠããããããŠãã®
çš®é¡ã®ããã²ã³åéçŸåäž»è¬ããé žåããã圢æ
ã«ãããŠãè²çŽ 圢æã«ããã©ãŒãšåå¿ããŠåçæ
æäžã«ç»åè²çŽ ãçãåŸãæåãçããããã§ã¯
ãªããæçšã§ãããšæåŸ ãããŠããçã®å€ãã®è€
çŽ ç°åŒååç©ããå®éã¯ãããã²ã³åéããªããµ
ãŒã¢ã°ã©ãã€ãŒææäžã«ãããŠç»åè²çŽ 圢æåå
ç©ãšãªããªããããªããµãŒã¢ã°ã©ãã€ãŒææäžã«
å«ãŸããå ¬ç¥ã®è€çŽ ç°åŒçŸåäž»è¬ã®ïŒçš®ã«ããã
çš®ã®ã±ãã³ããã³ã¢ã«ãããã®ããã©ãŸã³ãã
ãããããã¯ãç±³åœç¹èš±ç¬¬3615533å·ã«èšèŒãã
ãŠãããæ¬ç¹èš±ã«èšè¿°ãããŠããããã©ãŸã³ã®ïŒ
äŸã¯ãïŒâãžã¡ãã«ã¢ãããã³ãºã¢ã«ããããšã
ããŒã«âïŒâã€ã«âããã©ãžã³ãšã®åå¿ããçã
ããã®ã§ããããã®ããã©ãŸã³ã¯ãããããŒã«ç³»
ã«ããã©ãŒãšåå¿ããŠææã®è²çŽ ãçæããªãã
ããã¯åŸã«å®æœäŸ14ã§èšŒæãããããã®ãããç»
åæ é²å ããã³ç±åŠçã«ãã€ãŠè²çŽ ç»åãçãã
ããšãã§ãããã€é žåæ ã«ãããŠã«ããã©ãŒãšå
å¿ããŠåçèŠçŽ äžã«è²çŽ ãç»åæ ã«çæããè€çŽ
ç°åŒéå å€ãå«ã也åŒç©ççŸååããªããµãŒã¢ã°
ã©ãã€ãŒææãæäŸããããšã«ã¯ãåŸæ¥ããåé¡
ããã€ããå¿ èŠãªã«ãããªã³ã°åå¿ãçãããã
ããã«èŠæ±ãããä»ã®æ·»å å€ãããšãã°ããçš®ã®
èèªæã¢ãã³ããã®ä»ã®å¡©åºæŸåºæ§è¬å€ãå¿ èŠãš
ããããšãªãè€çŽ ç°åŒéå å€ãå«ãŸããããšãå¿
èŠãšãããŠããã æ¬çºæã¯ãç»åæ é²å ãšç±åŠçãšã«ãã€ãŠãè²
çŽ ç»åãçãåŸã也åŒç©ççŸååããªããµãŒã¢ã°
ã©ãã€ãŒçšåçèŠçŽ ãæäŸãããã®ã§ããã該èŠ
çŽ ã¯ãæ¯æäœäžã«çµåããã(a)æå æ§ããã²ã³å
éïŒãããšåå¿ãåŸãäžäœçãŸãã¯é£æ¥çäœçœ®ã«
é 眮ããã(b)å°ãªããšãïŒçš®ã®è²çŽ 圢æã«ããã©
ãŒïŒããã³(c)é žåâéå åç»å圢ææ§é åç©ã§ã
ã€ãŠ(ii)ææ©éå¡©é žåå€ãš(i)é žåããã圢æ ã§ã«ã
ãã©ãŒãšåå¿ããŠè²çŽ ãçããè€çŽ ç°åŒéå å€ãš
ãããªãé åç©ïŒãããªããããã«è©²éå å€ã¯ã
ïŒå¡ãŸãã¯ïŒå¡ã®è€çŽ ç°ãå«ãããã©ãŸã³åéå
å€ã§ããããšãç¹åŸŽãšããŠããããããã€ãããª
ããµãŒã¢ã°ã©ãã€ãŒææã«ãã€ãŠã€ãããåŸãã¢
ãŸè²çŽ ã¯ãããšãã°ã(1)ã€ã³ãã°ã©ã«ãã¹ã¯ãšã
ãŠã(2)çŸåãããéç»åã®è£åŒ·çšãšããŠããŸãã¯
(3)äž»èŠãªç»åè²çŽ ãšããŠãæçšã§ãããšèšãããš
ãã§ããã äžè¿°ã®ä¹ŸåŒç©ççŸååããªããµãŒã¢ã°ã©ãã€ãŒ
çšåçèŠçŽ ã¯ãæ¯æäœäžã«ãé 次ãå°ãªããšãïŒ
å±€ã®å±€ïŒïŒããªãã¡ãäºãã«åºå®ããã(a)æå
æ§ããã²ã³åéïŒããã³ãããšåå¿å¯èœãªäžäœç
ãŸãã¯é£æ¥çé¢ä¿ã«é 眮ãããã(b)å°ãªããšãïŒ
çš®è²çŽ 圢æã«ããã©ãŒïŒããã³(c)(ii)ææ©éå¡©é žå
å€ãš(i)é žåæ ã«ãããŠã«ããã©ãŒãšåå¿ããŠè²çŽ
ãçããããšã®ã§ããè€çŽ ç°åŒéå å€ãšãããªã
é žåâéå ç»å圢æçšé åç©ïŒãã ãéå å€ã¯æ¢
ã«è¿°ã¹ãããšããïŒå¡ãŸãã¯ïŒå¡ã®è€çŽ ç°ãå«ã
ããã©ãŸã³éå å€ã§ãããïŒïŒãããªãå±€ãšãïŒïŒ
å°ãªããšãïŒå±€ã®è²çŽ ãåããšããååå±€ãšãæ
ããŠãªãç»å転åèŠçŽ ãšããããšãã§ãããç»å
æ é²å ããã³ç±åŠçã«ãããèŠçŽ äžã«è²çŽ ãçã
ããããã次ãã§ååå±€ã«è»¢åããããååå±€
ã¯ã該è²çŽ ã®åªæå€å±€ãšããããšãã§ããã ïŒå¡ãŸãã¯ïŒå¡ã®è€çŽ ç°ãå«ãå€ãã®ããã©ãŸ
ã³éå å€ããæ¬çºæã«åŸã€ãŠã也åŒç©ççŸååã
ãªããµãŒã¢ã°ã©ãã€ãŒçšåçèŠçŽ äžã«çšããããš
ãã§ãããé žåããã圢æ ã§è²çŽ 圢æã«ããã©ãŒ
ãšåå¿ããŠè²çŽ ã圢æããªãããã©ãŸã³ååç©
ã¯ãæ¬çºæã§ã¯æçšãªååç©ã§ã¯ãªããïŒå¡ãŸã
ã¯ïŒå¡è€çŽ ç°ãå«ãæé©ã®ããã©ãŸã³éå å€ã®éž
æã¯ãææã®ç»åãææ©éå¡©é žåå€ã®çš®é¡ãè²çŽ
圢æã«ããã©ãŒã®çš®é¡ãæå æ§ããã²ã³åéã®çš®
é¡ãå¡åžçšçµæç©ã®çš®é¡ãåŠçæ¡ä»¶çã«ãã€ãŠç°
ãªããããã©ãŸã³éå å€ãå«ãïŒå¡ãŸãã¯ïŒå¡è€
çŽ ç°ã®çµåããçšããããšãã§ãããæ¬çºæã«ã
ã€ãŠæçšãªããã©ãŸã³éå å€ã¯ãäžèšã®åŒã«ãã€
ãŠè¡šããããšãã§ããã ãã ããåŒäžïœã¯ïŒãŸãã¯ïŒã§ããïŒR1ã¯æ°Ž
çŽ ãŸãã¯ã¢ã·ã«ãããšãã°ïŒã20ã®ççŽ ååãå«
ãã¢ã·ã«ãããšãã°ïŒã10ã®ççŽ ååãå«ãã¢ã·
ã«ããªãã¡ã¢ã»ãã«ããããªã«ãŸãã¯ãã³ãŸã€ã«
ãªã©ãå å«ãïŒR2ã¯æ°ŽçŽ ããŸãã¯é žåã«ãããª
ã³ã°ã®ãšãã«åé¢ããåŸã眮æåºããšãã°ãïŒã
20ã®ççŽ ååãå«ãã¢ã·ã«åºãŸãã¯ã¹ã«ããã«åº
ããªãã¡ããšãã°ãåŒãããã³âSO2R4ãå å«ããïŒR3ã¯ã¢ã«ãã«ãããšãã°ïŒã20ã®ççŽ
ååãå«ãã¢ã«ãã«ãããªãã¡ããšãã°ã¡ãã«ã
ãšãã«ããããã«ãããã«ããã·ã«ãããã·ã«ã
ãã³ãªã¯ã¿ãã·ã«ãïŒã20ã®ççŽ ååãå«ãã¢ã«
ã±ãã«ããšãã°ãšããã«ãããããã«ããããã«
ããã³ããã»ãã«ãïŒã20ã®ççŽ ååãå«ãã¢ã«
ããã«ããšãã°ãšããã«ãŸãã¯ããããã«ãã·ã¯
ãã¢ã«ãã«ããšãã°ïŒãïŒã®ççŽ ååãå«ãã·ã¯
ãã¢ã«ãã«ãããªãã¡ããšãã°ã·ã¯ããã³ãã«ã
ãã³ã·ã¯ãããã·ã«ãã¢ãªãŒã«ããšãã°ïŒã12ã®
ççŽ ååãå«ãã¢ãªãŒã«ããªãã¡ããšãã°ããšã
ã«ãããªã«ããã³ãã·ãªã«ããããã€ã«åºãç¹ã«
ïŒå¡ãŸãã¯ïŒå¡ãããã€ã«åºããšãã°ã€ãããŸãª
ã«åºããã¢ãŸãªã«åºãããã©ãŸãªã«åºãŸãã¯ã¢ã«
ããªãã«åºãããã³ïŒã20ã®ççŽ ååãå«ãã¢ã·
ã«åºãŸãã¯ã¹ã«ããã«åºããšãã°âCOR4ããã³
âSO2R4ã§ããïŒR4ã¯ããããã·ã«ãã¢ãã
ïŒâNH2ïŒãã¢ã«ãã«ãããšãã°ïŒã20ã®ççŽ å
åãå«ãã¢ã«ãã«ããªãã¡ããšãã°ã¡ãã«ããšã
ã«ããããã«ãããã«ããã·ã«ãããã·ã«ããã³
ãªã¯ã¿ãã·ã«ããŸãã¯ã¢ãªãŒã«ããšãã°ïŒã12ã®
ççŽ ååãå«ãã¢ãªãŒã«ããªãã¡ããšãã°ããšã
ã«ãããªã«ãŸãã¯ãã·ãªã«ã§ããïŒïŒºã¯ïŒå¡ãã
ãã¯ïŒå¡ã®è€çŽ ç°åŒæ žãŸãã¯ïŒå¡ãããã¯ïŒå¡ã®
è€çŽ ç°åŒæ žãå«ãçž®åç°ãããšãã°ãã¢ãŸãŒã«ã
ãªããµãŸãŒã«ãã»ã¬ããŸãŒã«ããã³ãŸã»ã¬ããŸãŒ
ã«ããããã»ã¬ããŸãŒã«ããã³ãŸãã¢ãŸãŒã«ãŸã
ã¯ãããªã³æ žãå®æããã«å¿ èŠãªééå±åå矀ã
è¡šãããïŒå¡ãŸãã¯ïŒå¡ã®è€çŽ ç°æ žãå®æããã«
èŠããééå±åå矀ã¯å žåçã«ã¯ççŽ ãç¡«é»ãé ž
çŽ ããã³çªçŽ ã®åååãå«ãã§ããã æ¬çºæã«åºãããã©ãŸã³éå å€ã¯ãæ¢ã«è¿°ã¹ã
ããã«ãéé¢ã®å¡©åºã®åœ¢ãŸãã¯å¡©ã®åœ¢ããšãã°å¡©
é žå¡©ããã©ãã«ãšã³ã¹ã«ãã³é žå¡©ãããšãã«ã¹ã«
ãã³é žå¡©ãŸãã¯ã¡ãã«ã¹ã«ãã³é žå¡©ã®åœ¢ã®ããã
ã®åœ¢æ ã§ãããªããµãŒã¢ã°ã©ãã€ãŒææäžã«ååš
ã§ãããããã©ãŸã³éå å€ã®æé©ã®åœ¢æ ã®éžæ
ã¯ãåŠçæ¡ä»¶ãææ©éå¡©é žåå€ã®çš®é¡ãã«ããã©
ãŒã®çš®é¡çã®å åã«ãã€ãŠç°ãªããæ¬æ现æžäžã«
瀺ãããã©ãŸã³éå å€ã®åŒã¯ãããšããã®åŒãé
é¢ã®å¡©åºã®åœ¢ã§èª¬æãããŠããŠããå¡©åºã®åœ¢æ ã®
ãã®ãå å«ããããšãæå³ããŠããã âã¢ã«ãã«âãâã¢ãªãŒã«âãâççŽ ç°åŒæ žâãã
ã³âè€çŽ ç°åŒæ žâãšããèªã¯ã眮æåºãå«ãŸãªã
ã¢ã«ãã«ãã¢ãªãŒã«ãççŽ ç°åŒããã³è€çŽ ç°åŒæ ž
ãå å«ããããšãæå³ããŠããããããã®èªã¯ã
ãŸããæ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒææã®æ
æã®æ§è³ªããšãã°ã»ã³ã·ãã¡ããªãŒç¹æ§ã«æ害ãª
圱é¿ãäžããªãåºãŸãã¯ææã®ç»åã«æ害ãªåœ±é¿
ãäžããªãåºã§çœ®æãããŠããåè¿°ã®åºãæ žãã
å å«ããããšãæå³ããŠãããäžè¿°ã®åºãæ žã«çµ
åããŠããããã®ææã®çµæã«æ害ãªåœ±é¿ãäžã
ãªã眮æåºã®äŸããããã°ãããããã¢ã«ã³ãã·
ããšãã°ãšããã·ãããã³ã«ã«ãã¡ãŒããªã©ã§ã
ãã æ¬çºæã«åºãæçšãªããã©ãŸã³éå å€ã®äŸã¯æ¬¡
ã®åŒã§è¡šããããïŒ ãã ãåŒäžZâ²ã¯ïŒå¡ãŸãã¯ïŒå¡ã®è€çŽ ç°åŒæ žã
ããã¯ãããã€ãïŒå¡ãŸãã¯ïŒå¡ã®è€çŽ ç°åŒæ žã
å«ãçž®åç°ïŒfused ringsïŒããšãã°ãã¢ãŸãŒã«ã
ãªããµãŸãŒã«ãã»ã¬ããŸãŒã«ããã³ãŸã»ã¬ããŸãŒ
ã«ããããã»ã¬ããŸãŒã«ããã³ãŸãã¢ãŸãŒã«ãã
ã³ãããªã³ãªã©ã®æ žãå®æããããã«å¿ èŠãªéé
å±åå矀ãè¡šããããããã€ãããã©ãŸã³éå å€
ã¯ãããšãã°ãäžèšã®ãã®ãå å«ããïŒ æ¬çºæã«åºãæçšãªä»ã®ããã©ãŸã³éå å€ã®äŸ
ãšããŠäžèšã®ãã®ãå å«ãããïŒ ãã ãäžèšåŒäžã®ïŒ²ã¯äžèšã®ãã®ã®ïŒã€ã§ã
ãïŒååç©çªå· æ¬çºæã«åºããããã©ãŸã³éå å€ãå«ãïŒå¡ãŸ
ãã¯ïŒå¡è€çŽ ç°ã¯ã¹ã«ããã«ããã©ãŸã³ã§ãã€ãŠ
ãããã ïŒå¡ãŸããïŒå¡è€çŽ ç°ãå«ãããã©ãŸã³éå å€
ã®æé©æ¿åºŠã®éžæã¯ãææã®ç»åãææ©éå¡©é žå
å€ã®çš®é¡ãè²çŽ 圢æã«ããã©ãŒã®çš®é¡ãæå æ§ã
ãã²ã³åéãåŠçæ¡ä»¶çã«ãã€ãŠç°ãªããããã©
ãŸã³éå å€ã®æçšãªæ¿åºŠã¯ãããªããµãŒã¢ã°ã©ã
ã€ãŒèŠçŽ äžã®æå æ§ããã²ã³åéïŒã¢ã«åœãã
0.25ãïŒã¢ã«ã®ããã©ãŸã³éå å€ãšãã€ãç¯å²å
ã«ããããããŠãã®å Žåãããªã³ãããªãŒããã
äžã«æ倧ã®æçšåå°æ¿åºŠãçããããããã«ã¯ã
æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«ãæ¯æ
äœïŒm2ã«ã€ãå°ãªããšã0.5ããªã¢ã«ã®ç°å å€ã
ååšããããšãå¿ èŠã§ããã該ããã©ãŸã³éå å€
ã®æ¿åºŠã®äžéã¯ãè©Šè¬ãå«ãæå å±€ãã€ãããã
ã«å¿ èŠãªå¡åžçšçµæç©äžã«ããã該詊è¬ã®æº¶è§£åºŠ
ã«ãã€ãŠåœ±é¿ãåãããç¹ã«æçšãªæ¿åºŠã¯ãæå
æ§ããã²ã³åéïŒã¢ã«ã«ã€ããè©Šè¬0.5ã1.5ã¢ã«
ã®ç¯å²å ã§ãããæå æ§ããã²ã³åéã¯ãç¹ã«æ
çšåºŠãé«ããäœæ ãªããããã¯ä»ã®æå æ§æåã«
æ¯ãé«åºŠã®æå æ§ãæããããã§ãããæå æ§ã
ãã²ã³åéã®ç²åãµã€ãºã®ç¯å²ã¯ãéåžžã«çŽ°ãã
ãã®ãããç²å€§ãªç²åãµã€ãºã®ãã®ã«å°ããŸã§æ
å¹ã§ããã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒææäžã®æå
æ§ããã²ã³åéã®å žåçãªæ¿åºŠã¯ããªããµãŒã¢ã°
ã©ãã€ãŒææäžã®åè¿°ã®ããã©ãŸã³éå å€ã®ïŒã¢
ã«ã«ã€ããçŽ0.2ãçŽïŒã¢ã«ã®æå æ§ããã²ã³å
éãšãã€ãç¯å²å ã«ããã æé©ã®éå å€ããã³æé©ã®ã«ããã©ãŒã®éžæã¯
ããã²ã³åéç²åã®å€§ããããã®ä»ã®éžæããã
ãã²ã³åéç²åã®ç¹æ§ã«ãã€ãŠéã€ãŠãããæå
æ§ããã²ã³åéã®æé©ã®æ¿åºŠã®éžæã¯ãææã®ç»
åãéžãã ææ©éå¡©é žåå€ã®çš®é¡ãéžãã è²çŽ 圢
æã«ããã©ãŒã®çš®é¡ãåŠçæ¡ä»¶çã«ãã€ãŠéã€ãŠ
ããã æå æ§ããã²ã³åéã¯ãåçæè¡äžã®å ¬ç¥ã®ä»»
æã®æ¹æ³ã§ã€ããããšãã§ãããç¹ã«ã也åŒç©ç
çŸååããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ çšã®æå æ§ã
ãã²ã³åéã®è£œé æ¹æ³ã«ãã€ãŠã€ããããšãã§ã
ããæçšãªæ¹æ³ãããªãµãŒãã»ãã€ã¹ã¯ããŒãž
ã€ã第148å·»ã1976幎ïŒæå·ã第14879é
ïŒRosenfeldïŒïŒãªãµãŒãã»ãã€ã¹ã¯ããŒãžã€ã第
125å·»ã1974幎ïŒæå·ã第12537å·ïŒUlbingïŒ
Hessããã³TerwilligerïŒïŒããã³ç±³åœç¹èš±ç¬¬
3871887å·ãããã³å第3839049å·ããã³è±åœç¹èš±
第1362970å·ã«èšè¿°ãããŠããã æ¬çºæã«åŸã€ãŠãå€ãã®è²çŽ 圢æã«ããã©ãŒã
ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«äœ¿çšããåŸãã
è²çŽ 圢æã«ããã©ãŒã¯ãåè¿°ã®ããã©ãŸã³éå å€
ã®é žåæ ã®ãã®ãšå ±ã«ã¢ãŸæçŽ ã圢æãããã®ã§
ãªããã°ãªããªããããªãã¡ãæ¬çºæã«ãããè²
çŽ åœ¢æã«ããã©ãŒã¯ãé²å åŸèŠçŽ ãå ç±ãããšã
ã«ãããã©ãŸã³éå å€ã®é žåæ ã®ãã®ãšå ±ã«ã¢ãŸ
ææã圢æãããã®ã§ãªããã°ãªããªããè²çŽ 圢
æã«ããã©ãŒã¯ãç»åæ é²å ããã³ç±åŠçãè¡ãª
ãåã¯ãããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«ãã€ãŠ
ç¡è²ã§ããããšã奜ãŸãããè²çŽ 圢æã«ããã©ãŒ
ããã³ãã®ä»ã®æåã¯ãåŠç枩床ã§ææã®ç»åã
çããããåã¯ããã¹ãŠã®é倧ãªæ害çžäºåå¿ã
åé¿ã§ããçšåºŠã«ååã«å®å®ã§ããããšãå¿ èŠã§
ãããæ¬çºæã®æé©ã®è²çŽ 圢æã«ããã©ãŒãéžæ
ããããã«ã¯ãç°¡åãªè©Šéšã圹ã«ç«ã€ããšãã
ãããããã€ãè©Šéšã®ïŒäŸãäžèšã®å®æœäŸïŒã«èš
èŒãããŠããããã®å®æœäŸã«ãããŠã¯ãè©Šéšãã
ãè²çŽ 圢æã«ããã©ãŒããå®æœäŸïŒã®è²çŽ 圢æã«
ããã©ãŒã®ä»£ãã«ããªããµãŒã¢ã°ã©ãã€èŠçŽ äžã«
å«ãŸããŠããããããå®æœäŸïŒã®æ¹æ³ãçšããŠã€
ããããè²çŽ ç»åããå°ãªããšãå®æœäŸïŒã®ç»å
ãšåãçšåºŠã«æºè¶³ã§ãããã®ã§ããã°ããã®ã«ã
ãã©ãŒéšåãå«ãååç©ã¯æçšã§ãããšèããã
ããäžé調ïŒé»ïŒãŸãã¯ã»ãšãã©äžé調ã«çŸãã
ãç»åãçããè²çŽ 圢æã«ããã©ãŒã§ããååç©
ã¯å€ãã®å Žåã«éåžžã«æçšã§ããã æ¬æ现æžäžã§çšããâè²çŽ 圢æã«ããã©ãŒâã
ãã³âã«ãããªã³ã°éšåâã®èªã¯ãããã©ãŸã³é
å å€ã®é žåæ ã®ãã®ã«ããåŠçæ¡ä»¶ã®äžã§ãæ¬çº
æã®ããªããµãŒã¢ã°ã©ãã€èŠçŽ äžã«ææã®ã¢ãŸè²
çŽ ç»åã圢æããååç©ãŸãã¯ååç©ã®äžéšåã
æå³ããã€ããã§ãããè²çŽ 圢æã«ããã©ãŒã¯ã
ã«ãããªã³ã°éšåãå«ã該ååç©ãããã©ãŸã³é
å å€ã®é žåããã圢ã®ãã®ãšã«ãããªã³ã°ããŠæ
æã®ã¢ãŸè²çŽ ãçãããšä¿¡ããããŠããããã«ã
ã®ããã«åŒã°ãããã«ãããªã³ã°éšåãå«ãé©åœ
ãªååç©ã®äžã«ã¯ãããªããµãŒã¢ã°ã©ãã€ãŒææ
ã®ã»ã³ã·ãã¡ããªãŒç¹æ§ã«æ害ãªåœ±é¿ãäžããã
ãšãªããæ¬çºæã«åºãåŠç枩床ã«èãåŸããã®ã§
ãããè²çŽ 圢æã«ããã©ãŒã§ããæçšãªååç©ã«
ã¯ãç±³åœç¹èš±ç¬¬3761270å·ã®ç¯å²å ãã®ãšããŠèš
èŒãããŠãããã®ããã¬ãŸã«ã·ããŒã«ç³»ã«ããã©
ãŒããšãã°ãResearch Disclosureã1978幎ïŒ
æå·ã第17326é ã«èšèŒããããã®çãããã 第ïŒè³éŠæã¢ãã³ã«ã©ãŒçŸåäž»è¬ãšåå¿ããŠã¢
ãŸã¡ãã³è²çŽ ãçãããã®ãšããŠåçæè¡äžç¥ã
ããŠããè²çŽ 圢æã«ããã©ãŒã¯ãã¢ãŸè²çŽ ãç¹ã«
é»è²ã¢ãŸè²çŽ ãçããããã«ãæå¹ã«æ¬çºææ¬ã®
ããªããµãŒã¢ã°ã©ãã€èŠçŽ äžã«çšããããšãã§ã
ãããããã€ãé»è²ã®ã¢ãŸè²çŽ 圢æã«ããã©ãŒã«
ã¯ãããšãã°ã掻æ§ã¡ãã¬ã³ã»ãµã€ããå«ãè€çŽ
ç°ååãå«ãã«ããã©ãŒãããšãã°æŽ»æ§ã¡ãã¬
ã³ã»ãµã€ããå«ããã©ãŸãã³ããã©ãŸãããªã¢ãŸ
ãŒã«ãã€ã³ããŸãŒã«ããã³ãã©ãŸããã³ãºã€ãã
ãŸãŒã«ãªã©ããããåæ§ã«ã第ïŒè³éŠæã¢ãã³ã«
ã©ãŒçŸåäž»è¬ãšã®åå¿ã«ãã€ãŠã€ã³ãã¢ããªã³ã·
ã¢ã³è²çŽ ã圢æããããšãåçæè¡äžç¥ãããŠã
ãããããŒã«ç³»ããã³ããšããŒã«ç³»ååç©ããæ¬
çºæã«åŸã€ãŠããŒã³ã¿ã»ã¢ãŸè²çŽ ãçããããã«
æçšã§ãããæçšãªè²çŽ 圢æã«ããã©ãŒã«ã¯ãã
ãšãã°ãâThe Theory of the Photograplui
ProâcersâãT.H.Jamesç·šéã第ïŒçã第12ç« ã
1977幎ããã³Reseach DisclosureïŒ1978幎12
æã第17643é ã第ç¯ã«èšèŒãããŠããã«ãã
ã©ãŒãããã æçšãªã¢ãŸè²çŽ 圢æã«ããã©ãŒã«ã¯ãïŒåœéã
ãã³ïŒåœéè²çŽ 圢æã«ããã©ãŒããããæçšãªïŒ
åœéè²çŽ 圢æã«ããã©ãŒã¯ãããšãã°ãU.
S.4021240ã«èšèŒãããŠãããæçšãªä»ã®è²çŽ 圢
æã«ããã©ãŒãšããŠã¯ãåçæè¡äžã«ãããªã³
ã°ã»ãªã眮æåºãšããŠç¥ãããŠãã眮æåºãããš
ãã°çŸåæå¶å€ãªã©ãå«ãã«ããã©ãŒããããæ
çšãªçŸåå€ã»æå¶å€æŸåºæ§ã«ããã©ãŒïŒDIRã«ã
ãã©ãŒãšãèšãããŠããïŒã¯ãããšãã°ã
Research DisclosureïŒ1972幎10æã第10226é
ã«èšèŒãããŠãããè²çŽ 圢æã«ããã©ãŒã®çµåã
ããæ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒæå€äžã«æ
å¹ã«çšããããšãã§ããã æçšãªããŒã³ã¿è²çŽ 圢æã«ããã©ãŒã«ã¯ãäžèš
ã®ãå®æœäŸïŒã®ç¬¬è¡šäžã«èšèŒãããŠãããã®ã
ãããä»ã®æçšãªããŒã³ã¿è²çŽ 圢æã«ããã©ãŒã«
ã¯äžèšã®ãã®ãããã æçšãªããŒã³ã¿è²çŽ 圢æDIRã«ããã©ãŒã«ã¯æ¬¡
ã®ãã®ãããïŒ æçšãªé»è²è²çŽ 圢æã«ããã©ãŒã«ã¯æ¬¡ã®ãã®ã
ããïŒ æçšãªé»è²è²çŽ 圢æDIRã«ããã©ãŒã«ã¯æ¬¡ã®ã
ã®ãããïŒ æçšãªã·ã¢ã³è²çŽ 圢æã«ããã©ãŒã«ã¯äžèšã®ã
ã®ãããïŒ (a) äžèšã®æ§é ãæãã眮æãã©ãŸãªã³ïŒ ãã ããåŒäžR5ã¯çœ®æãŸãã¯æªçœ®æã¢ã«ãã«
ããšãã°ïŒã20ã®ççŽ ååãå«ãã¢ã«ãã«ãã¢ã·
ã«ããšãã°ïŒã20ã®ççŽ ååãå«ãã¢ã·ã«ããŸã
ã¯ã¢ãªãŒã«ããšãã°ããšãã«ã§ãããR6ããã³
R7ã¯ã¢ã«ãã«ããšãã°ïŒã20ã®ççŽ ååãå«ã
ã¢ã«ãã«ãã¢ã«ã³ãã·ããšãã°ïŒã20ã®ççŽ åå
ãå«ãã¢ã«ã³ãã·ãã¢ã·ã«ããšãã°ïŒã20ã®ççŽ
ååãå«ãã¢ã·ã«ãããããã¹ã«ãã¢ãã«ããã
ã²ã³ç¹ã«å¡©çŽ ãŸãã¯èçŽ ããŸãã¯æ°ŽçŽ ã§ãããå ž
åçãªäŸã¯äžèšã®éãã§ããã ãè¡šã (b) äžèšã®ããšã眮æãããã¢ããã©ãŸã³ã䜿çš
ããåŸãïŒ ç¹ã«æçšãªè²çŽ 圢æã«ããã©ãŒã«ã¯äžèšãã®ã
ããïŒ æé©ã®è²çŽ 圢æã«ããã©ãŒãŸãã¯è²çŽ 圢æã«ã
ãã©ãŒçµåãç©ã®éžæã¯ãææã®ç»åãç¹å®ã®æ
æ©éå¡©é žåå€ã®çš®é¡ã䜿çšããç¹å®ã®æå æ§ãã
ã²ã³åéã®çš®é¡ã䜿çšããç¹å®ã®ããã©ãŸã³éå
å€ã®çš®é¡ãããã³åŠçæ¡ä»¶ãªã©ã«å åã«ãã€ãŠå·Š
å³ãããã§ãããã è²çŽ 圢æã«ããã©ãŒã®æ¿åºŠã¯ãããªããµãŒã¢ã°
ã©ãã€ãŒèŠçŽ äžã®éå å€ïŒã¢ã«åœã0.1ã10ã¢ã«
ã®è²çŽ 圢æã«ããã©ãŒãšããç¯å²å ã«ãããïŒçš®
以äžã®è²çŽ 圢æã«ããã©ãŒã®çµåãç©ã䜿çšãã
ããšãã¯ã該çµåãç©ã®å šæ¿åºŠããåè¿°ã®ç¯å²å
ã«ãããè²çŽ 圢æã«ããã©ãŒãŸãã¯è²çŽ 圢æã«ã
ãã©ãŒçµåãç©ã®æé©ã®æ¿åºŠã¯ãææã®ç»åãæ
æ©éå¡©é žåå€ã®çš®é¡ãè²çŽ 圢æã«ããã©ãŒãŸãã¯
ã«ããã©ãŒçµåãç©ã®çš®é¡ãæå æ§ããã²ã³åé
ã®çš®é¡ãããã©ãŸã³éå å€ã®çš®é¡ãåŠçæ¡ä»¶çã®
å åã«ãã€ãŠå€ããè²çŽ 圢æã«ããã©ãŒã®ç¹ã«æ
çšãªæ¿åºŠã¯ãéå å€ïŒã¢ã«ã«ã€ãè²çŽ 圢æã«ãã
ã©ãŒ0.25ã¢ã«ã2.0ã¢ã«ã®ç¯å²å ã«ããã æ¬çºæã§ã¯ãå€ãã®ææ©éå¡©é žåå€ã䜿çšãã
ããšãã§ããã æé©ã®ææ©éå¡©é žåå€ãŸãã¯ææ©éå¡©é žåå€ã®
çµåãç©ã®éžæã¯ãææã®ç»åã䜿çšããè²çŽ 圢
æã«ããã©ãŒã®çš®é¡ã䜿çšããæå æ§ããã²ã³å
éãããã©ãŸã³éå å€ãåŠçæ¡ä»¶çã®çš®é¡çã®å
åã«ãã€ãŠå€ã€ãŠãããæçšãªææ©éå¡©é žåå€ã®
çš®é¡ã®äžã€ã¯ãå ã«ããããéã«æåã«å¯Ÿããæµ
æåãæããŠããé·éèèªé žã®éå¡©ã§ããããã®
çš®é¡ã«å±ããæçšãªéå¡©é žåå€ã¯ãããšãã°ãã
ãã³é žéãã¹ãã¢ãªã³é žéããªã¬ã€ã³é žéãããŠ
é žéããªãã·ã¹ãã¢ãªã³é žéãã«ããªã³é žéãã
ãªã¹ãã³é žéããã³ãã«ããã³é žéã§ãããæ¬æ
现æžäžã§çšããâé·éèèªé žâãšããèªã¯ãéå¡©
ã®èèªé žéšåäžã«10ã30ã®ççŽ ååãå«ãã§ãã
èèªé žãå«ãã€ããã§çšããŠãããææ©éå¡©é žå
å€ã®ä»ã®æçšãªçš®é¡ã¯ãçªçŽ é žããšãã°ã€ãããŸ
ãŒã«ããã©ãŸãŒã«ããŠã©ãŸãŒã«ãïŒïŒïŒïŒïŒâã
ãªã¢ãŸãŒã«ããã³1Hâããã©ãŸãŒã«ãªã©ã®çªçŽ
é žãŸãã¯ãããã®æ··åç©ããæã矀ããéžã°ãã
çªçŽ é žãšéãšã®é¯äœã«ãã€ãŠä»£è¡šããããããã
çªçŽ é žã®éå¡©ã¯ãããšãã°ããªãµãŒãã»ãã€ã¹ã¯
ããŒãžã€ãŒïŒResearch DisclosureïŒã第150å·»ã
1976幎10æå·ãdeMauriacã®ç¬¬15026é ã«èšèŒã
ããŠããã æ¬æ现æžäžã§äœ¿çšããâå¡©âããã³âé¯äœâã®
èªã¯ãçµæãšããŠã§ããç©è³ªããåè¿°ã®ããªããµ
ãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«ãããŠãææã®ç»å圢æ
ç¹æ§ã瀺ãããã«ããããšã®ã§ããä»»æã®ã¿ã€ã
ã®çµåãŸãã¯é¯äœåœ¢æã®æ©æ§ãå å«ããã€ããã§
çšããŠããã ææ©éå¡©é žåå€ã¯ãããç¯å²å ã®æ¿åºŠã§çšãã
ããšãã§ãããæé©æ¿åºŠã®éžæã¯ãææã®ç»åã
çšããç¹å®ã®ææ©éå¡©é žåå€ã®çš®é¡ãçšããç¹å®
ã®ããã©ãŸã³éå å€ãè²çŽ 圢æã«ããã©ãŒãæå
æ§ããã²ã³åéããã³åŠçæ¡ä»¶ãªã©ã«ãã€ãŠç°ãª
ããææ©éå¡©é žåå€ã®æçšãªæ¿åºŠã¯ãããã²ã³å
éïŒã¢ã«ã«ã€ãææ©éå¡©é žåå€0.1ã¢ã«ã10ã¢ã«
ã®ç¯å²å ã«ãããææ©éå¡©é žåå€ã®ç¹ã«æçšãªæ¿
床ã¯ãããã²ã³åéïŒã¢ã«ã«ã€ããææ©éå¡©é žå
å€0.5ã¢ã«ãïŒã¢ã«ã®ç¯å²å ã«ããã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã¯ããã
ã¯ã«ããã³çµåå€ãšããŠãåçš®ã®ã³ãã€ãããã³
ãã€ã³ããŒãåç¬ãŸãã¯çµåããŠå«ãããšãã§ã
ãããããã¯ãåçš®ã®å±€äžã«å«ãŸããããšãã§ã
ããåèšã®æçšãªã³ãã€ãããã³ãã€ã³ããŒã¯ã
芪氎æ§ç©è³ªãŸãã¯çæ°Žæ§ç©è³ªã®ãããã§ãã€ãŠã
ããããããã¯éæãŸãã¯åéæã§ãã€ãŠãèçœ
質ããšãã°ãŒã©ãã³ããŒã©ãã³èªå°äœãã»ã«ããŒ
ã¹èªå°äœãå€ç³é¡ããšãã°ããã¹ãã©ã³çã®å€©ç¶
ç£ã®ç©è³ªãå«ãããããã¯ãŸããããªïŒããã«ã
ããªãã³ïŒãã¢ã¯ãªã«ã¢ããããªããŒçã®ããšã
芪氎æ§ããªããã«ååç©ã®ãããªåæéåç©è³ªã
å«ãããã®ä»ã®æçšã§ããåŸãåæéåç©è³ªã«
ã¯ãåæ£æ ããã«ååç©ããšãã°ã©ããã¯ã¹åœ¢ã®
ãã®ãããã³ç¹ã«ãããªããµãŒã¢ã°ã©ãã€ãŒææ
ã®å¯žæ³å®å®æ§ãåäžããããã®ãªã©ããããæå¹
ãªããªããŒã«ã¯ãé«ååéç©è³ªãæ¬çºæã®ããªã
ãµãŒã¢ã°ã©ãã€ãŒææã®åèšç»å圢ææç©ãšäœµçš
ã§ããããªããŒããã³æš¹èãå«ãŸããã æ¬çºæã«ãã€ãŠçããçŸåãããéç»åããã³
è²çŽ ç»åã®ããŒã³ã¯ãçŸåãããéç»åã®é圢æ
åŠãç¹å®ã®ã«ããã©ãŒãç¹å®ã®ããã©ãŸã³éå
å€ãåŠçæ¡ä»¶çã®å åã«ãã€ãŠå€ã€ãŠãããã«ã
ãã©ãŒããã³éå å€ã¯ãææã®éãšè²çŽ ç»åã®çµ
åããåŸãããã«ãè²çžã«ãããŠçŸåãããéç»
åãšè£è²ã®é¢ä¿ã«ããè²çŽ ãçããããã«éžæã
ãããšãã§ããã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã¯ãæ¬çº
æã§æçšãªåŠç枩床ã«èããããšã®ã§ããåçš®ã®
æ¯æäœãå«ãããšãã§ããã代衚çãªæ¯æäœã«
ã¯ãã»ã«ããŒã¹ãšã¹ãã«ãããªïŒããã«ã¢ã»ã¿ãŒ
ã«ïŒãããªïŒãšãã¬ã³ãã¬ãã¿ã¬ãŒãïŒãããªã«ãŒ
ãããŒãããã³ããªãšã¹ãã«ãã€ã«ã æ¯æäœãªã©
ãããã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã¯ãåç
æè¡äžå ¬ç¥ã®åçš®ã®å¡åžæ³ãããšãã°ãã€ããã³
ãŒãã³ã°ããšã¢ãã€ãã³ãŒãã³ã°ãã«ãŒãã³ã³ãŒ
ãã³ã°ãŸãã¯ããããŒãçšããæŒåºãå¡åžãªã©ã®
æ¹æ³ã«ãã€ãŠé©åœãªæ¯æäœäžã«å¡åžããããšãã§
ããã â溶èäœåœ¢æååç©âã¯ãæ¬çºæã®ããçš®ã®ã
ãªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã«ãããŠãæ¹åããã
çŸåç»åãçããããã«æçšã§ããããšãã§ã
ãã溶èäœåœ¢æååç©ã¯ãçªçŽ é žã®éå¡©ãå«ãã
ãªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ãšå ±ã«çšãããšç¹ã«æ
çšã§ããããšãã§ãããæ¬æ现æžäžã§ãâ溶èäœ
圢æååç©âã®èªã¯ãåè¿°ã®åŠç枩床ã«å ç±ãã
å Žåã«æ¹åãããåå¿åªäœãå žåçã«ã¯ãã®äžã§
åè¿°ã®ç»å圢ææ§çµåãç©ãçŸåã«ãã€ãŠããè¯
奜ãªç»åãäžãã溶èåªäœãçãããããªååç©
ãæå³ããã€ããã§çšããŠããã該åå¿åªäœã®åŠ
ç枩床ã«ãããæ£ç¢ºãªæ§è³ªã¯ååã«ç解ãããŠã
ãªããåŠç枩床ã«ãããŠæº¶èäœãçãããããå
å¿æåã®ããããçžäºåå¿ãå¯èœãªãããããã®
ãšä¿¡ãããããæçšãªæº¶èäœåœ¢ææ§ååç©ã®äŸã«
ã¯ãå¯èãïŒïŒïŒâãããµã³ãžãªãŒã«ãã¡ãã«ã¢
ãã»âãã¹ã«ãã¢ãããã¢ã»ãã¢ãããã¹ã¯ã·ã³
ã€ããããã³ïŒâïŒ2HïŒâãã¿ã©ãžãã³ãå«ãŸ
ããã 該ææ©éå¡©é žåå€ã¯ãããç¯å²å ã®æ¯ã®(1)çªçŽ
é žéšåãŸãã¯é·éèèªé žéšåã®ããšãææ©éšå察
(2)éã€ãªã³ãå«ãããšãã§ããã該ææ©éå¡©é žå
å€äžã®ææ©éšå察éã€ãªã³ã®æé©ã®æ¯ã¯ããã®æ
æ©éšåãäœã§ããããããšãã°ã©ããªçªçŽ é žã§ã
ãããã©ããªããã©ãŸã³éå å€ã§ããããã©ããª
åŠçæ¡ä»¶ã§ããããã©ããªè²çŽ 圢æã«ããã©ãŒã
çšããŠããããªã©ã«ããç°ãªããéå¡©é žåå€äžã«
ãããææ©éšå察éã€ãªã³ãšããŠã®éã®ã¢ã«æ¯
ã¯ã10ïŒïŒãïŒïŒïŒã®ç¯å²å ãæçšã§ãããäžè¿°
ã®ææ©éšå察éã€ãªã³ãšããŠã®éã®ç¹ã«æçšãªæ¯
ã¯ãïŒïŒïŒãïŒïŒïŒã®ç¯å²å ã«ããã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã¯ãŸãã
ããç¯å²å ã®pAgãå«ãããšãã§ãããpAgã¯ã
åžè²©ã®ãã€ãžã¿ã«pHã¡ãŒã¿ãŒã«é£çµãããŠãã
éåžžã®ã«ãã¡ã«ããã³éâå¡©åéé»æ¥µãçšããŠæž¬
å®ããããšãã§ãããæ¬çºæã®äžè¿°ã®ç»å圢ææ
åãå«ãåæ£ç©äžã®å žåçãªpAgã¯ãçŽïŒãçŽ
9.5ã®ç¯å²å ã«ãããç¹ã«æçšãªpAgã¯4.5ãïŒã®
ç¯å²å ã«ãããæé©ã®pAgã¯ãç¹å®ã®ææ©éå¡©é ž
åå€ãææã®ç»åãããã©ãŸã³éå å€ãåŠçæ¡ä»¶
çã®ããšãäžè¿°ã®å åã«ãã€ãŠç°ãªãã æ¬çºæã®äžè¿°ã®æåãå«ãåæ£ç©ã¯çŽ1.5ãçŽ
8.5ã®ç¯å²å ã§ããPHãæããŠãããäžè¿°ã®ããš
ããããã©ãŸã³éå å€ãšä»ã®æåãšãå«ãåæ£ç©
ã®ããã®ç¹ã«æçšãªPHã¯ãçŽ4.5ãçŽïŒã®ç¯å²å
ã«ãããç¹ã«å¥œãŸããç¯å²ã¯çŽ4.5ãçŽ5.5ã§ã
ãã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«åå
å¢æè²çŽ ãçšããããšã¯æå¹ã§ãããããã«ã
ãã該ææã«ããã«è¿œå ã®æ床ãäžããããšãã§
ãããæçšãªåå å¢æè²çŽ ã¯ãããšãã°
Research DisclosureïŒ1978幎ïŒæïŒJ.W.
Carpenterããã³P.W.Laufã®ç¬¬17029é ã第ïŒâ
15é ã«èšèŒãããŠãããã®ã®äžããéžã¶ããšãã§
ããã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®äžè¿°ã®
æåã¯ãææã®ç»åãçããä»»æã®é©åœãªäœçœ®ã«
å ¥ããããšãã§ãããããšãã°ã該æåã®ïŒã€ãŸ
ãã¯ãã以äžã該èŠçŽ ã®ïŒã€ãŸãã¯ãã以äžã®å±
äžã«å«ãŸããããšãã§ãããããå Žåã«ã¯ããã
ïŒ ã®ããã©ãŸã³éå å€ãææ©éå¡©é žåå€ããã
ã³ïŒãŸãã¯ä»ã®æ·»å å€ãä¿è·å±€ïŒäžè¢«èŠå±€ãšãèš
è¿°ããŠãããïŒäžã«å«ãŸããããšãæãŸããããš
ããããããããªãããè«žæåã¯ãåŠçããããš
ãã«ãããã®ææã®çžäºåå¿ãèµ·ãåŸãäœçœ®ã«å ¥
ããªããã°ãªããªãã ææã®ç»åãçããããã«ã¯ãæå æ§ããã²ã³
åéããã³ããªããµãŒã¢ã°ã©ãã€ãŒææã®ä»ã®è«ž
æåã¯ãçžäºã«âåå¿å¯èœãªäœçœ®é¢ä¿ã«çœ®ãããŠ
ããããšâãå¿ èŠã§ãããæ¬æ现æžäžã§âåå¿å¯
èœãªäœçœ®é¢ä¿ã«çœ®ãããŠããâãšããè¡šçŸããã
å Žåããã¯æå æ§ããã²ã³åéãšãæ¢è¿°ã®è²çŽ 圢
æã«ããã©ãŒãå«ãç»å圢æçµåãç©ãšããç»å
æ é²å åŸã®åŠç枩床ã«ãããŠææã®åŠçãåãæ
çšãªè²çŽ ç»åãçããããšãã§ãããããªçžäºã®
äœçœ®é¢ä¿ã«çœ®ãããŠããããšãæå³ããã€ããã§
ãããæå æ§ããã²ã³åéã®ç»åæ é²å ã«ãã€ãŠ
圢æãããæœåã¯ãææ©éå¡©é žåå€ãšããã©ãŸã³
éå å€ãšãå«ãç»å圢ææ§çµåãç©ã®ããã®è§Šåª
ãšããŠäœçšãããšä¿¡ããããã次ã«ãåŠçã®çµæ
ã§ããéå å€ã®é žåæ ã®åœ¢ã®ãã®ã¯ãæ¢è¿°ã®è²çŽ
圢ææ§ã«ããã©ãŒãšåå¿ããŠãããªããµãŒã¢ã°ã©
ãã€èŠçŽ ã®ç»ååã«ææã®è²çŽ ã圢æãããã®ãš
ä¿¡ããããã æ¬çºæã®ç¹ã«æçšãªå ·äœäŸã¯ãæ¯æäœäžã«ã(a)
æå æ§ããã²ã³åéããã³ãããšåå¿å¯èœãªäœçœ®
é¢ä¿ã«çœ®ãããŠãã(b)å°ãªããšãïŒã€ã®è²çŽ 圢æ
æ§ã«ããã©ãŒãããšãã°ïŒâããããã·âïŒâã
ããã¢ã³ããããã³(c)äžèš(i)ãš(ii)ãšãããªãé žå
âéå ç»å圢ææ§çµåãç©ããã€ã³ããŒäžãããš
ãã°ããªïŒããã«ããã©ãŒã«ïŒäžã«å«ãŸãããã
ãã®ãæããŠãªã也åŒç©ççŸåããªããµãŒã¢ã°ã©
ãã€ãŒèŠçŽ ã§ããïŒ (i) ææ©éå¡©é žåå€ããšãã°ããã³é žéïŒ (ii) å®è³ªçã«äžèšã®åŒã«ãã€ãŠè¡šããããããã©
ãŸã³ ãããªãè€çŽ ç°éå å€ïŒ 該èŠçŽ ã¯ç»åæ é²å ããã³ç±åŠçã«ãã€ãŠè²çŽ
ç»åã圢æããããšãã§ããããã®å ·äœäŸã«ãã
ãŠãæ¢è¿°ã®æ§é ã®ãããåºã¯ãã¹ã«ããã«åºã«é¢
ããŠã¡ã¿ãŸãã¯ãã©ã®äœçœ®ã«ããããšã奜ãŸã
ãã æ¬çºæã®å¥ã®å ·äœäŸã¯ãããªïŒããã«ããã©ãŒ
ã«ïŒã®ãããªãã€ã³ããŒäžã«ã(a)æå æ§ããã²ã³
åéããããšåå¿å¯èœãªäœçœ®é¢ä¿ã«çœ®ããã(b)å°
ãªããšãïŒã€ã®è²çŽ 圢ææ§ã«ããã©ãŒãããšãã°
ïŒâããããã·âïŒâãããã¢ããªãã(c)(i)ææ©
éå¡©é žåå€ããšãã°ããã³é žéããã³(ii)åè¿°ã®ã
ãšãïŒå¡ãŸãã¯ïŒå¡è€çŽ ç°ãå«ãããã©ãŸã³éå
å€ã ããšãã°åŒïŒ ã«ãã€ãŠè¡šããããããã©ãŸã³ããããªãé žåé
å ç»å圢ææ§çµåãç©ããå«ãã ãã®ãããªãå°
ãªããšãïŒå±€ã®å±€ïŒïŒãšã該èŠçŽ ã®ç»åæ é²å
ãšç±åŠçãšã«ãã圢æãããè²çŽ ã®ããã®åªæå€
ãå«ãå°ãªããšãïŒå±€ã®ç»åååå±€ïŒïŒãšãæ¯
æäœäžã«é 次æããŠãªãç»å転å也åŒç©ççŸåå
ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã§ãããäžè¿°ã®æ§é
ã«ãããŠããããåºã¯ãã¹ã«ããã«åºã«é¢ããŠã¡
ã¿ãŸãã¯ãã©ã®äœçœ®ã«ããã®ã奜ãŸããã äžè¿°ã®æ¡æ£è»¢åããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äž
ã«ã¯ã該èŠçŽ ã®åŠçã«ãã€ãŠçããè²çŽ ç»åã®ã
ãã®åçš®ã®ç»åååå±€ãååšãããããšãã§ã
ããäžè¿°ã®ãè²çŽ ç»åã®ããã®ç»åååå±€ã¯ã(1)
é©åœãªæ¯æäœäžã«ååå±€ãå«ãå¥åã®ååèŠçŽ ã§
ãã€ãŠããããããããã¯ãŸãã(2)ååå±€ããäž
è¿°ã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®äžéšã§ããïŒ
å±€ã®å±€ã§ãã€ãŠããããååå±€ã¯ãå žåçã«ã¯ã
è²çŽ ç»åã®ããã®åªæå€ããæã€ãŠãããæ¬çºæ
ã®æ¡æ£è»¢åããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®å ·äœäŸ
ã«ããã°ãåçš®ã®åªæå€ãååå±€äžã«äœ¿çšã§ã
ãã ããå¿ èŠãªãã°ãæ¡æ£è»¢åããªããµãŒã¢ã°ã©ã
ã€ãŒèŠçŽ äžã«âäžéæåå±€âãå«ãŸããããšãã§
ããããããã€ãå±€ã¯ãååå±€äžã®è²çŽ ç»åã芳
å¯ããããã«äœ¿çšããåŸãææã®çšåºŠã®æŸå°ç·
ïŒradiationïŒããšãã°å¯èŠå ç·ãåå°ããããã
ã«äœ¿çšãããŠãããâäžéæåå±€âã¯å¿ èŠãªåå°
ãäžããçš®ã ã®è©Šè¬ãããšãã°äºé žåãã¿ã³ãã
å«ãããšãã§ããã å€ãã®å Žåãæ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒ
èŠçŽ ã®åè¿°ã®çš®ã ã®å±€ã®äžéã«ãåé¢å±€ãèšãã
ããšãæçšã§ããããã®åé¢å±€ã¯ãè«žå±€éã«ãã
ãè«žæåã®æ¡æ£ã®ææã®ã¿ã€ãã³ã°ãæäŸãããš
ãã€ããããªå©çãããããããšãã§ãããŸãæ¬
çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®ç°ãªãæå
å±€ã®æ¥çã®æ¹åãäžããããšãã§ãããå žåçãª
åé¢å±€ã¯ãäžè¿°ã®ãã€ã³ããŒã®ä»»æãã®ãå«ãã
ãšãã§ããã ããå¿ èŠãªãã°ãé²å ããã³åŠçãããæ¬çºæ
ã®ããªããµãŒã¢ã°ã©ãã€èŠçŽ äžã«æ®åããéã¯ã
é©åœãªæŒçœå€ã«ãã€ãŠæŒçœããããšãã§ãããã
ãªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«ååšããéã®æŒçœ
ã¯ãããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«ãã¬ã®è²çŽ
ç»åãçããããšãã§ããã æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒæå€ã«é¢ã
ãŠãçš®ã ã®ç»åæ é²å æ段ãçšããããšãã§ã
ãã該ããªããµãŒã¢ã°ã©ãã€ãŒææã¯ãé»ç£ã¹ã
ã¯ãã«ã®çŽ«å€åããã³éè²åã«æå¿ããã ããªããµãŒã¢ã°ã©ãã€ãŒææãé©åºŠã«é«ããã
ã枩床ã«åã«åäžã«å ç±ããã ãã§ãçããæé
å ãããšãã°æ°ç§éå ã«ãç»åæ é²å ããããªã
ãµãŒã¢ã°ã©ãã€ãŒææäžã«å¯èŠåãçŸåããããš
ãã§ãããããšãã°ãç»åæ é²å ããããªããµãŒ
ã¢ã°ã©ãã€ãŒææã¯ãçŽ80âãçŽ200âã®ç¯å²å
ã®æž©åºŠã奜ãŸããã¯çŽ120âãçŽ150âã®ç¯å²å ã®
枩床ã«ãææã®ç»åãçãããŸã§å ç±ããããšã
ã§ãããå ç±ã¯ãããšãã°çŽïŒãçŽ90ç§ã®ç¯å²
å ã奜ãŸããã¯çŽïŒãçŽ30ç§ã®ç¯å²å ã§ãææã®
è²çŽ ç»åãçãããŸã§è¡ãªããããããšãã°çŽ
125â以äžãšããäœãåŠç枩床ã«ãããŠã¯ãç»å
ã®çŸåã«ãã€ãšé·ãåŠçæéãå¿ èŠãšãããããš
ãããã äžèšã®å®æœäŸã¯ãæ¬çºæãããã«ããç解ããŠ
ãããããã®ãã®ã§ããã å®æœäŸ ïŒ è²çŽ 圢ææ§ã«ããã©ãŒã®äœ¿çš æ¬å®æœäŸã¯æ¬çºæãäŸç€ºãããã®ã§ããã äžèšã®ããã©ãŸã³éå å€ïŒ ããã³åçš®ã®è²çŽ 圢ææ§ã«ããã©ãŒãå«ãäžé£ã®
æ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ããäžèšã®
æé ã«åŸã€ãŠã€ãã€ãã äžèšã®è«žæåïŒ ããã³é žéïŒé žåå€ïŒ 33.6ïœ ããã³é žïŒã«ããªé²æ¢å€ïŒ 25.4ïœ ããªïŒããã«ããã©ãŒã«ïŒïŒãã€ã³ããŒïŒ
ïŒBUTV AR â76ãåæšãç±³ãã¢ã³ãµã³ã
ç€Ÿè£œïŒ 12.0ïœ ã¢ã»ãã³âãã«ãšã³ïŒæº¶å€ïŒ 400ml ããããŒã«ãã«ã§72æéäžç·ã«åŠçããŠåæ£ç©ã
ã€ãã€ãã ãã®ããã«ããŠåŸãåæ£ç©ããåæ£ç©ïŒ¡ãšã
ãããã®åæ£ç©ïŒmlããããã©ãŸã³No.ïŒãšåä»ã
ãããã©ãŸã³éå å€0.3ããªã¢ã«ïŒ105.5mgïŒãã
ã³ãäžæ¥ç¬¬è¡šã«ç€ºããã«ããã©ãŒ0.3ããªã¢ã«
ããå容ç©ã®ã¢ã»ãã³ãšãã«ãšã³ãšã®æ··åç©äžã«
2.0ééïŒ ã®ããªïŒããã«ããã©ãŒã«ïŒãå«ã溶
液ïŒmläžã«æº¶è§£ãããã溶液ã«æ·»å ãããããã
ãŠã§ããæ··åç©ãæ¹æãããã®ã«ãã¢ã»ãã³ã«æº¶
ãããèæ²åéã®ä¹³å€ïŒïŒïŒ æ²åç©ïŒïŒããªïŒã
ãã«ããã©ãŒã«ïŒäžã«è§£åãããããã®ïŒïŒéã€
ãªã³0.3ããªã¢ã«ïŒ0.8mlãæ·»å ããããã®ããã«
ããŠã§ããçµæç©ã¯ãéã€ãªã³ïŒã¢ã«åœã40ïœã®
ããªïŒããã«ããã©ãŒã«ïŒãå«ãã§ããã ããããŠã§ããããªããµãŒã¢ã°ã©ãã€ãŒçšçµæ
ç©ããïŒãã«åã®ããªïŒãšãã¬ã³ãã¬ãã¿ã¬ãŒ
ãïŒãã€ã«ã æ¯æäœäžã«ã38âã§6.0ãã«ã®æ¹¿æœ€
å¡åžåã«å¡åžãããã§ããããªããµãŒã¢ã°ã©ãã€
ãŒçšèŠçŽ ã也ç¥ãããã 也ç¥ããããªããµãŒã¢ã°ã©ãã€ãŒçšèŠçŽ ãå
ïŒãŒãã©ã«ã»ãšã¬ã¯ããªãã¯ã»ã«ã³ãããŒè£œã®ã
ã©ããã©ã³ãã3200ãããçšããŠïŒã«ç»åæ é²å
ãããæéã¯ïŒç§éãè·é¢ã¯38cmã§ãã€ãããã
ã«ãããããªããµãŒã¢ã°ã©ãã€ãŒçšèŠçŽ äžã«ãçŸ
åå¯èœãªæœåãçããããã®ç»åæ é²å ããããª
ããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã次ã«ç¬¬è¡šã«ç€ºãæå®
ã®æéãããªããµãŒã¢ã°ã©ãã€ãŒçšèŠçŽ ã®æ¯æäœ
åŽããã«ãŒãããå ç±ããã¯é¢ã«æ¥è§Šãããããš
ã«ãã€ãŠãåäžã«å ç±ããã äžèšã®ç¬¬è¡šã¯ãããããã®å Žåã«äœ¿çšããç¹
å®ã®ã«ããã©ãŒããã³åŠçæã®é²å âçŸåã®æé
ããã³æž©åºŠãšããã®çµæã§ããç»åè²çŽ ã®è²çžã
瀺ããŠããã ãè¡šã ãè¡šã ãè¡šã ãè¡šã å®æœäŸïŒ ç°ãªãããã©ãŸã³éå å€ã®äœ¿çš ããã©ãŸã³No.ïŒã®ä»£ãã«ãäžèšã«ç€ºãããã©ãŸ
ã³ååç©ïœâïœãçã¢ã«éçšããããšä»¥å€ã¯ãå®
æœäŸïŒãšåæ§ã«ããŠãããªããµãŒã¢ã°ã©ãã€ãŒçš
èŠçŽ ãã€ãã€ããååç©ïœâïœã§ã¯ãããã©ãŸã³
No.ïŒã®ã¹ã«ããã«åºãããããæå®ã®ã¹ã«ããã«
åºã«ãã€ãŠçœ®æãããŠããã ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«å«ãŸãããã
ã«ããã©ãŒã¯äžèšã®ãã®ã§ãã€ãïŒ åããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®è©Šæãå®æœäŸ
äŸïŒã§è¿°ã¹ããšåæ§ã«ãïŒç§éç»åæ é²å ããèŠ
çŽ äžã«çŸåå¯èœãªæœåãäžããããã®ããã«ãã
ç»åæ é²å ããèŠçŽ ããå®æœäŸïŒã§è¿°ã¹ãããã«
ããŠã110âã§15ç§éç±åŠçãããåå Žåã«ãé²
å ããããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®é²å åã«é
ç»åãšããŒã³ã¿è²çŽ ç»åãšãçããã å®æœäŸïŒ ãããŒã®äœ¿çš å®æœäŸïŒã§è¿°ã¹ãããã«ããŠãããã©ãŸã³éå
å€ãšããŠã®æ¢è¿°ã®ããã©ãŸã³No.ïŒã0.3ããªã¢ã«
ããã³å®æœäŸïŒã§è¿°ã¹ãè²çŽ 圢ææ§ã«ããã©ãŒ
0.3ããªã¢ã«ãå«ãããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ
ãã€ãã€ãããã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ
ã¯ããããŒçŸåä¿é²å€ãšãèšè¿°ãããŠããïŒçš®ã®
ãããŒã®äžã€ããå«ãã§ãããïŒçš®ã®ãããŒã¯ã
ãããããã¿ã«ã€ããããã³ïŒâïŒ2HïŒâãã¿
ã«ã¢ãžãã³ã§ãã€ãã ãã®ããã«ããŠåŸãããããªããµãŒã¢ã°ã©ãã€
ãŒèŠçŽ ã¯ãå®æœäŸïŒã«è¿°ã¹ãããŠããããã«ããŠ
ç»åæ é²å ãããèŠçŽ äžã«ãçŸåå¯èœãªæœåãç
ãããé²å ãããèŠçŽ ã®è©Šæã¯110âããã³125â
ã§å ç±ãããããããŒãå«ãŸãªãããã«å¥ã®ããª
ããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ãåæ§ã«ããŠã€ãããåŠ
çãããã«ããªããã³ç»åâ圢æã®äž¡é床ã¯ãå
çæè¡äžå ¬ç¥ã®èµ€å€åå°ãã³ã·ãã¡ããªãŒã«ãã
åŠçæéã§åŠçãè¡ãªãå Žåã«åŸã€ãã ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®è©Šæã®åã ã¯ã
ãããŒãååšãããšåŠãšã«ããããããè²çŽ ãã
ã³éç»åã®äž¡æ¹ãçãããçµæã¯ããããŒã®ååš
ããçŸåã®é床ãšãç»ååããã³éç»ååã®äž¡æ¹
ã®åã«ãããŠåŸãããæçµçéæ¿åºŠãšã®äž¡æ¹ãå€
åãããããšã瀺ãããæ¢è¿°ã®ãããŒã®äœ¿çšã«ã
ããç»åâã«ããªã®åºå¥ã¯äžè¬ã«æ¹åãããã å®æœäŸ ïŒ çŸåå€æå¶å€æŸåºæ§è²çŽ 圢ææ§ã«ããã©ãŒã®äœ¿
çš æ¬å®æœäŸã¯ãæ¬çºæã®ããªããµãŒã¢ã°ã©ãã€ãŒ
èŠçŽ äžã«ãããã©ãŸã³éå å€ãšå ±ã«ãçŸåå€æå¶
å€æŸåºæ§è²çŽ 圢ææ§ã«ããã©ãŒäœ¿çšã®å¹æãäŸç€º
ããããã®ãã®ã§ããã ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã0.3ããªã¢ã«ã®
äžèšã®éå å€ããã³è²çŽ 圢ææ§ã«ããã©ãŒãå«ã
ã§ããããšä»¥å€ã¯ãå®æœäŸïŒã®æ¹æ³ã«åŸã€ãŠãã
ãªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ãã€ãã€ãã ãè¡šã ãè¡šã åããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®è©Šæãå®æœäŸ
ïŒã§è¿°ã¹ããšåæ§ã«ããŠïŒç§éç»åæ é²å ãã該
ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«çŸåå¯èœãªæœå
ãã€ãã€ããé²å åŸã®åããªããµãŒã¢ã°ã©ãã€ãŒ
èŠçŽ ãã次ã«ããããã100âã125âããã³150
âã§30ç§éåŠçããããšã«ãããæå³çã«éå°åŠ
çããã 4Aããã³4Bãšèå¥èšå·ãä»ããããªããµãŒã¢
ã°ã©ãã€ãŒèŠçŽ äžã«éç»åããã³ããŒã³ã¿è²çŽ ç»
åãçãããããããªããã150âã§åŠçããå Ž
åãèŠçŽ 4BïŒçŸåå€æå¶å€æŸåºæ§è²çŽ 圢ææ§ã«ã
ãã©ãŒãå«ãïŒã®è©Šæã ããã«ããªä»¥äžã«èå¥ã§
ããç»åãçããã 4Cããã³4Dãšå®ããèŠçŽ ã®è©Šæäžã«ã¯éç»å
ãçããããè²çŽ ç»åã¯çããªãã€ããè²çŽ 圢æ
æ§ã«ããã©ãŒã«é¢ä¿ãªããéçŸåã¯åãã§ããã
150âã§éçŸåã¯å šé¢ã«çãããç»åã¯çŸãããª
ãã€ãã å®æœäŸ ïŒ äžèšã®åŠããå€å±€èŠçŽ ãã€ãã€ãã ããªïŒããã«ããã©ãŒã«ïŒïŒButvarïŒåæšãç±³
åœã¢ã³ãµã³ã瀟補ïŒã®2.0ééïŒ æº¶æ¶²ïŒmlã«å¯Ÿãã
å®æœäŸïŒã§è¿°ã¹ãåæ£ç©3.0mlãèæ²åéä¹³å€
ïŒæ²åéïŒïŒ ïŒ0.8mlãç·è²å¢æè²çŽ 溶液ïŒ0.2
mgïŒmlã®å¢æè²çŽ ãå«ãïŒ0.5mlãã¢ã»ãã³0.5
mlãããã³ãïŒééïŒ ã®ããªïŒããã«ããã©ãŒ
ã«ïŒïŒButvarïŒããã«ãšã³äžã«å«ã溶液äžã«åè¿°
ã®ããã©ãŸã³No.ïŒã156mgå«ãåæ£ç©3.0mlããã
ã³ããã«ãäžèšã®è²çŽ 圢ææ§ã«ããã©ãŒ195mgã
æ·»å ããïŒ è©²æº¶æ¶²ããïŒãã«åã®ããªïŒãšãã¬ã³ãã¬ãã¿
ã¬ãŒãïŒãã€ã«ã æ¯æäœäžã«ïŒãã«ã®æ¹¿æœ€åã«å¡
åžããã ããããŠã§ããããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ
ã«ãïŒééïŒ ã®ããªïŒããã«ã¢ã«ã³ãŒã«ïŒæº¶æ¶²
ãã湿最æã®åããïŒãã«ãšãªãããã«äžå¡ãã
ãã ããªïŒããã«ã¢ã«ã³ãŒã«ïŒã®äžå¡ãã也ç¥ãã
åŸã該ããªïŒããã«ã¢ã«ã³ãŒã«ïŒã®å±€ã®äžã«ã第
ïŒã®å±€ã湿最æã®åãïŒãã«ã§å¡åžããããã®ç¬¬
ïŒã®å±€ã¯ã6.2mlã®ïŒïŒ ããªïŒããã«ããã©ãŒã«ïŒ
ïŒButvar â76ïŒã3.0mlã®å®æœäŸïŒã§è¿°ã¹ãã
ãã³é žéâããã³é žåæ£ç©ã0.8mlã®èæ²åéä¹³
å€ïŒïŒïŒ æ²åç©ïŒã10mlã®ã¢ã»ãã³ã200mgã®äžèš
è²çŽ 圢ææ§ã«ããã©ãŒïŒ ããã³140mgã®äžèšããã©ãŸã³éå å€ïŒ ããæããã®ã§ãã€ãã ãã®ããã«ããŠã§ããããªããµãŒã¢ã°ã©ãã€ãŒ
èŠçŽ ã®ããã€ããå ã«å¯ŸããŠç»åæ é²å ããèŠçŽ
äžã«çŸåå¯èœãªæœåãäžããå®æœäŸïŒã§è¿°ã¹ãã
ãã«ããŠã110âã§15ç§éç±åŠçãããåŠçãã
è©Šæã¯ãç·è²å ã«ç»åæ é²å ããé åã«éç»åã
ãã³ããŒã³ã¿è²çŽ ç»åãçããããããã®æå å±€
ãèµ€è²å æå¿æ§ã§ã¯ãªãã€ããããèµ€è²å ã«ãã
ããé åã«ã¯ç»åãçŸãããªãã€ããçœè²å ã«ã
ãããé åã«ã¯ãéç»åã®ã»ãã«èµ€è²ã®è²çŽ ç»å
ã芳å¯ãããã å®æœäŸïŒ ããªãšã¹ãã«ãã€ã«ã æ¯æäœã®æè² ããã©ãŸã³çŸåå€ã®ç»åæ é žåã«ãããªã³ã°ã
ãçããã¢ãŸè²çŽ ã¯ãããªãšã¹ãã«ãã€ã«ã ã®ã
ããªããªãšã¹ãã«ææãæè²ããã®ã«æçšã§ãã
ãšããããããã¯ããã枩床ãè²çŽ ã®æè¯æž©åºŠã
ãã³ããªãšã¹ãã«ååäœã®ã¬ã©ã¹è»¢äœæž©åºŠã®äž¡è
ãè¶ ãããªãã°ãçŽæ¥ãæè¯ã«ãã€ãŠèµ·ãå Žåã
ããããããäžæ¹ã«ãããŠãè²çŽ ãã€ãªã€ãŒãšèš
ãããã®ããããªããµãŒã¢ã°ã©ãã€ãŒææã«æ·»å
ãããã°ãçããè²çŽ ã¯ããã€ãšé¥ãã«äœã枩床
ã§ããªãšã¹ãã«è²çŽ ååå±€äžã«å ¥ã蟌ãããšãã§
ãããæ¬æ现æžäžã§æ¡çšããâè²çŽ ãã€ãªã€ãŒâ
ã®èªã¯ãåŠç枩床ã«ãããŠç»åè²çŽ ããã€ã«ã ã
ããªãã¯ã¹ãéã€ãŠç§»åã§ããããã«ããããšã®
ã§ããååç©ãæå³ããããã®ééã¯æããã溶
èãããã€ãªã€ãŒäžã«ãããè²çŽ ã®ããªãšã¹ãã«
ææãžã®æè¯ã«ãããã®ã§ããããã€ãªã€ãŒã¯ã
ããšãã°ããªãšã¹ãã«ãã€ã«ã æ¯æäœçšãªã©ã®ã
ãªãšã¹ãã«ææçšã®å¯å¡å€ãšããŠäœçšãããã®ãš
ä¿¡ããããã å®æœäŸïŒã§è¿°ã¹ãããã«ããŠã€ããããããã
ãŠããã©ãŸã³éå å€ãšããŠã®ããã©ãŸã³No.ïŒãã
ã³å®æœäŸïŒã®ç¬¬è¡šããéžãã è²çŽ 圢ææ§ã«ãã
ã©ãŒ(e)ãšåäžã®è²çŽ 圢ææ§ã«ããã©ãŒãå«ãããª
ããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®è©Šæãç»åæ é²å ã
ãŠã該ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«çŸåå¯èœ
ãªæœåãã€ãã€ãããã®ç»åæ é²å ããããªããµ
ãŒã¢ã°ã©ãã€ãŒèŠçŽ ãã次ã«ãå®æœäŸïŒã§è¿°ã¹ã
ããã«ç±åŠçãããåŠçããè©Šæã次ã«ã90âã§
120ç§éå ç±ããããã®éã500mgã®ã¡ãã«ã¢ãã»
ãŒããå«ã第ïŒã®èŠçŽ ãšæ¥è§Šããããã¡ãã«ã¢ã
ã»ãŒãã¯ãè²çŽ ãã€ãªã€ãŒãšããŠäœçšããããã€
ã³ããŒãšããŠäœçšããã¡ãã«ã¢ãã»ãŒããå«ãèŠ
çŽ äžã«ã¯ãïŒå¹³æ¹ãã€ãŒãåœãã200mgã®ããª
ïŒããã«ããã©ãŒã«ïŒãååšãããå ç±åŸããã
ãã®èŠçŽ ã¯åé¢ãããããã©ãŸã³éå å€ãå«ãã§
ããå±€ã¯ããã€ã«ã æ¯æäœããç©ççã«é€å»ãã
ãã該ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®ããªïŒãšã
ã¬ã³ãã¬ãã¿ã¬ãŒãïŒãã€ã«ã æ¯æäœäžã«ã茪é
ã®ã¯ã€ãããšããããŒã³ã¿è²çŽ åãçŸãããã å®æœäŸïŒã§è¿°ã¹ãæ¹æ³ã«åŸã€ãŠãä»ã®è²çŽ ã補
é ããããšãã§ãããããããªãããè²çŽ ã®è»¢å
ã®ããã«æãæçšãªæž©åºŠããã³è²çŽ å容èŠçŽ ãžã®
è²çŽ ã®è»¢åã®å¹çã¯è²çŽ ã®æ§é ãç¹å®ã®è²çŽ ãã€
ãªã€ãŒãåŠçæ¡ä»¶çã®å åã«ãã€ãŠéã€ãŠããã å®æœäŸ ïŒ ïŒâã¢ããâïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«ã®éå¡©
ã®äœ¿çš äžèšã®ããšãããŠãïŒâã¢ããâïŒïŒïŒïŒïŒâ
ããªã¢ãŸãŒã«ã®éå¡©ãå«ãããªããµãŒã¢ã°ã©ãã€
ãŒèŠçŽ ãã€ãã€ãïŒ 10.0mlã®èžçæ°Žã50mlã®20ïŒ ãŒã©ãã³æ°Žæº¶æ¶²ã
ãã³0.84ïœã®ïŒââïŒâã¢ããâïŒïŒïŒïŒïŒâ
ããªã¢ãŸãŒã«ãå«ã溶液ã«ãïŒå以å ã«10.0mlã®
1Mç¡é žéãæ·»å ããããšã«ãããåæ£æ¶²ãã€ã
ã€ããæ·»å å·¥çšãéããåžžã«ãçµæç©ãååã«æ··
åããåæ£æ段ã«ããã溶液ãé£ç¶çã«åæ£ãã
ãããã®ããã«ããŠã€ãã€ãåæ£æ¶²ïŒmlã¯ã143
mgã®ãŒã©ãã³ããã³15.4mgã®ïŒââïŒâã¢ãã
âïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«ã®éå¡©ãå«ãã§ã
ãã äžèšã®ããšãè²çŽ 圢ææ§ã«ããã©ãŒïŒ ãå«ãåæ£æ¶²ã次ã®ããã«ããŠã€ãã€ããããªã
ã¡ãè¡šé¢æŽ»æ§å€ïŒAlkanol XCãç±³åœãE.I.ããŠ
ãã³ç€Ÿãã販売ãããŠããååã®åæšïŒã®10ïŒ æ°Ž
溶液48mlãå«ã溶液ãã5.0mlã®ãšãã«ã¢ã»ããŒ
ãã4.5mlã®ïŒïŒïŒâãžâïœâã¢ãã«ããšããŒã«
ïŒã«ããã©ãŒæº¶å€ïŒããã³6.15ïœã®è²çŽ 圢ææ§ã«
ããã©ãŒãå«ã第ïŒã®æº¶æ¶²ãšæ··åããã§ããæ··å
ç©ãã³ãã€ããã«äžã§åæ£ãããã äžèšã®åŒïŒ ã«ãã€ãŠè¡šããããããã©ãŸã³éå å€ã®70mgãã
ïŒâã¢ããâïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«ã®éå¡©ã
å«ãåæ£æ¶²5.0mlãåè¿°ã®è²çŽ 圢ææ§ã«ããã©ãŒ
åæ£æ¶²4.0mlã1.0ééïŒ è¡šé¢æŽ»æ§å€æº¶æ¶²
ïŒSurfactant 10Gãããªã°ãªã·ããŒã«ãšãŒãã«ã
ç±³åœOlin Corp.ããã®åžè²©åïŒ1.0mlããã³èæ²
åéä¹³å€ïŒïŒã¢ã«ïŒ æ²åç©ïŒ0.5mlãããªãæ··å
液äžã«æº¶è§£ããããšã«ããããªããµãŒã¢ã°ã©ãã€
ãŒèŠçŽ ãã€ãã€ããã§ããçµæç©ããããªïŒãšã
ã¬ã³ãã¬ãã¿ã¬ãŒãïŒãã€ã«ã æ¯æäœäžã«ãïŒã
ã«ã®æ¹¿æœ€æå¡åžåã«å¡åžããã ãã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã也ç¥ããã
次ãã§å ã«ç»åæ é²å ããèŠçŽ äžã«çŸåå¯èœãªæœ
åãã€ãã€ãããã®ç»åæ é²å ããèŠçŽ ãã150
âã§30ç§éåäžã«å ç±ãããèŠçŽ äžã«ãé»è²ã€ãœ
ãè€è²ã®ãéããã³è²çŽ ç»åãåŸãããã次ã«ã
ã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ããäžèšã®è«žæå
ãå«ãæŒçœâå®ç济äžã«ãŠïŒåéåŠçãã次ãã§
æ°Žã§æŽã也ç¥ããã é ¢é ž 20.0ml NH4S2O3ïŒ60ïŒ æ°Žæº¶æ¶²ïŒ 150.0ml Na2SO3 15.0ïœ CoïŒNH3ïŒ6Cl3 3.0ïœ ïŒâããããã·ãããªã¡ãã¬ã³ãžãããªããã
ã©é ¢é ž 3.0ïœ äžèšã«æ°Žãå ã㊠1.0ãšããã ãã®æŒçœäžå®ç液ã®PHã¯4.5ã§ãã€ãã æŒçœâå®ç液äžã§ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ
ããéããã³ããã²ã³åéãé€å»ããåŸã«ã匷ã
é»è²ã®è²çŽ ç»åãçŸãããã ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®æªé²å ã®è©Šæã
åè¿°ã®æŒçœâå®ç济äžã§15åéåŠçãããããªã
ãµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã«ã¯å®è³ªçã«è²çŽ ã圢æã
ããªãã€ããããã«ãã€ãŠãæŒçœâå®ç液ã¯ãã
ãªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã®åè¿°ã®ããã©ãŸã³
éå å€ãçŽæ¥é žåããªãããšã蚌æãããã å®æœäŸïŒ è²çŽ 圢ææ§ã«ããã©ãŒã®äœ¿çš åè¿°ã®å®æœäŸïŒã®è²çŽ 圢ææ§ã«ããã©ãŒã®ä»£ã
ã«ãäžèšã®ç¬¬9Aè¡šã«ç€ºãè²çŽ 圢ææ§ã«ããã©ãŒ
ãããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«å ããããã
ãšä»¥å€ã¯ãå®æœäŸïŒã§è¿°ã¹ãæ¹æ³ãšåæ§ã«ããŠã
ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ãã€ãããç»åæ é²
å ããçŸååŠçãããåå Žåã«åŠçã«ãã€ãŠãäž
èšç¬¬9Aè¡šã«ç€ºãç»åã®è²çžãæãããã¬ã®è²çŽ
ç»åãçããã ãè¡šã ãè¡šã å®æœäŸïŒ ä»ã®éå¡©é žåå€ã®äœ¿çš ïŒâã¢ããâïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«ã®éå¡©
ãå«ããŒã©ãã³åæ£æ¶²ã®ä»£ãã«ãåœéïŒéã€ãªã³
åºæºïŒã®éã¢ããããã©ãŸãŒã«ãŸãã¯éã¡ãã«ã€
ãããŸãŒã«âïŒâããªãŒã«å¡©ã®ããããã䜿çšã
ãããšä»¥å€ã¯ãå®æœäŸïŒããã³ïŒã§è¿°ã¹ããã®ãš
åæ§ã®ã«ã©ãŒããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ãã€ã
ã€ãã å®æœäŸïŒããã³ïŒã§è¿°ã¹ããšåæ§ã«ç»åæ é²å
ããã³åŠçããåŸãäžè¿°ã®éå¡©é žåå€ã«ãã€ãŠã
å®æœäŸïŒããã³ïŒã§çãããã®ãšåæ§ã®ãã¬è²çŽ
ç»åãçããã å®æœäŸ10 ç±æº¶å€ã®äœ¿çš çŽ20âã§ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã§åºäœ
ã§ãããã該ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®ç±åŠ
çæéã«æº¶èããåçš®ã®æ°Žæº¶æ§ååç©ããæ¬çºæ
ã®ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã«æ·»å ããããã
ããã®ååç©ã¯ãæ¬æ现æžäžã§ç±æº¶å€ïŒthermal
solventsïŒãšåŒã¶ãããããã¯åŠç枩床ã«ãã
ãŠãããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«ãããåå
ç©ã®ç§»å床ãé«ããããšã芳å¯ãããã å®æœäŸïŒããã³ïŒã«èšè¿°ãããã®ã®ãããªããª
ããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ãã€ãã€ãããã ããã
ãã¯ããã«ãæ¯æäœïŒå¹³æ¹ãã€ãŒãåœãïŒæ¯æäœ
929cm2åœãïŒ40ã60ã100ããã³200mgã®äžèšç±æº¶
å€ã®ïŒã€ãå«ãã§ããïŒã¹ã«ãã¢ãããã¢ã»ãã¢
ãããã¹ã¯ã·ã³ã€ãããïŒâïŒ2HïŒâãã¿ã«ã¢
ãžãã³ããã³ïŒ®âããããã·ããã¿ãªããã ããããŠã§ããããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®
è©Šæããå®æœäŸïŒã§è¿°ã¹ãããã«ããŠç»åæ é²å
ããŠãããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ äžã«ãçŸåå¯
èœãªæœåãã€ãã€ããé²å ããããªããµãŒã¢ã°ã©
ãã€ãŒèŠçŽ ã¯ãå®æœäŸïŒã§è¿°ã¹ãããã«ããŠç±åŠ
çãããåè©Šæã«ã€ããŠã®ãã®åŠçã®çµæãšã
ãŠãæŒçœåã«ãããå€ãçŸåãããéãçããäž
è¿°ã®ç±æº¶å€ãå«ãŸãªãåæ§ã®è©Šæã«æ¯èŒããŠãæ
倧è²çŽ æ¿åºŠã¯å®è³ªçã«äžæããã å®æœäŸ11 å€å±€èŠçŽ äžèšã®æ¹æ³ã«ãããïŒè²ããªããµãŒã¢ã°ã©ãã€
ãŒèŠçŽ ãã€ãã€ãïŒ äžèšã®ããšãããŠãããªïŒãšãã¬ã³ãã¬ãã¿ã¬
ãŒãïŒãã€ã«ã æ¯æäœäžã«ãéããã³ç·æå¿æ§ã
ãŒã³ã¿ãŒåœ¢ææ§æå å±€ãå¡åžããïŒ äžèšã®è«žæåãå«ãããªããµãŒã¢ã°ã©ãã€ãŒçµ
æç©ãã€ãã€ãïŒ 5.0mlã®ãå®æœäŸïŒã§è¿°ã¹ãïŒâã¢ããâïŒïŒ
ïŒïŒïŒâããªã¢ãŸãŒã«âãŒã©ãã³åæ£æ¶² 4.0mlã®ãå®æœäŸïŒã§è¿°ã¹ããã®ãšé¡äŒŒã®ã«ã
ãã©ãŒåæ£æ¶²ããã ããå®æœäŸïŒã®è²çŽ 圢ææ§ã«
ããã©ãŒ(b)ããžâïœâããã«ãã¿ã¬ãŒãäžã«æº¶è§£
ãããã®ãå«ãç¹ãçžéããã 1.0mlã®è¡šé¢æŽ»æ§å€æº¶æ¶²ïŒSurfactant 10GïŒ70
mgã®ããã©ãŸã³éå å€ïŒ 200mgã®ã¹ã«ãã¢ãã 0.6mlã®éããã³ç·æå¿æ§èæ²åéïŒ3.0ã¢ã«ïŒ
æ²åç©ïŒä¹³å€ã ãã®ããã«ããŠã§ããããªããµãŒã¢ã°ã©ãã€ãŒ
çšçµæç©ããããªïŒãšãã¬ã³ãã¬ãã¿ã¬ãŒãïŒã
ã€ã«ã æ¯æäœäžã«ã60âã§ïŒãã«ã®æ¹¿æœ€æåãã«
å¡åžããåŸã也ç¥ãããã ç·æå¿æ§ããªããµãŒã¢ã°ã©ãã€ãŒå±€ã®äžã«ãé
æå¿æ§ãé»è²è²çŽ 圢ææ§å±€ãå¡åžããã第ïŒã®å±€
ã®ããã®çµæç©ã¯ãã«ããã©ãŒåæ£æ¶²ããå®æœäŸ
ïŒããã®è²çŽ 圢ææ§ã«ããã©ãŒã®4.0mlã«ãã€ãŠ
眮ããããããããšãããã³ãéããã³ç·æå¿æ§
ããã²ã³åéä¹³å€ãåœéã®éæå¿æ§ããã²ã³åé
ä¹³å€ã«ãã€ãŠçœ®ããããããããšä»¥å€ã¯ã第ïŒã®
å±€ãšåãã§ãã€ãããã®ããã«ããŠã§ããããªã
ãµãŒã¢ã°ã©ãã€ãŒçšçµæç©ãã也ç¥ããéããã³
ç·æå¿æ§å±€ã®äžã«ã湿最æã®åãïŒãã«ã§ãçŽæ¥
å¡åžããã ãã®å€å±€ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã也ç¥ã
ãã次ãã§ããã€ã«ã¿ãŒãéããå ïŒåå¥ã«ã
éãç·ããã³èµ€ãããªãïŒã«ç»åæ é²å ããããª
ããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã次ã«ã140âã§15ç§é
åäžã«å ç±ãããåŠçããããªããµãŒã¢ã°ã©ãã€
ãŒèŠçŽ ãã次ã«å®æœäŸïŒã§è¿°ã¹ãæŒçœâå®ç液äž
ã«ïŒåé浞挬ããæ°Žäžã§ïŒåéæŽãã也ç¥ãã
ããããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®ãéè²å ã«é²
å ããé åã«ãèµ€è²ã®è²çŽ ç»åãçŸãããã該èŠ
çŽ ã®ç·è²å ã«ããããéšåã«ã¯ãããŒã³ã¿è²çŽ ç»
åãçŸãããã該ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã®
èµ€è²å ã«ããããéšåã«ã¯ãè²çŽ ç»åãçŸãããª
ãã€ãã å®æœäŸ12 æŒçœâå®çå±€ã®äœ¿çš å®æœäŸïŒããã®è²çŽ 圢ææ§ã«ããã©ãŒ(b)ãå«ã
å®æœäŸïŒã§è¿°ã¹ãã«ã©ãŒããªããµãŒã¢ã°ã©ãã€ãŒ
èŠçŽ ã®è©Šæããç»åæ ã«é²å ããããªããµãŒã¢ã°
ã©ãã€ãŒèŠçŽ äžã«ãçŸåå¯èœãªæœåãã€ãã€ãã
ãã®ç»åæ é²å ããããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ
ãã次ã«ã150âã«ãŠ30ç§éåäžã«å ç±ãããåŠ
çããããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã次ã«ãããª
ïŒãšãã¬ã³ãã¬ãã¿ã¬ãŒãïŒãã€ã«ã æ¯æäœäžã®
æŒçœâå®çå±€ãšæ¥è§Šãããªããã120âã§30ç§é
å ç±ãããæŒçœâå®çå±€ã¯ãæ¯æäœ929cm2åœãã
äžèšã®è«žæåãå«ãã§ããïŒ ïŒïŒïŒâãããµã³ãžãªãŒã« 500mg ïŒç±æº¶å€ïŒ ããªå°¿çŽ ïŒé¯åå€ïŒ 125mg ïŒïŒ1â²âãžããªãžãã«ã ã¢ããžã³ãžãããã¯ã
ãªã 125mg ïŒé žåå€ïŒ ããªïŒããã«ãããªãã³ïŒ 500mg ïŒãã€ã³ããŒïŒ ãã©âãã«ãšã³ã¹ã«ãã³é ž 250mg ïŒé žïŒ ããã²ã³åéãå«ãããªããµãŒã¢ã°ã©ãã€ãŒèŠ
çŽ ã®å±€ãšæ¥è§ŠãããæŒçœâå®çå±€ãå ç±ãããšã
éç»åããã³æªçŸåã®ããã²ã³åéã¯æŒçœâå®ç
ãããŠãç¡è²éæã®è£œåãšãªã€ããããªããµãŒã¢
ã°ã©ãã€ãŒèŠçŽ äžã«ã¯ããã¬ã®ããŒã³ã¿è²çŽ ç»å
ãçŸãããã å®äŸäŸ 13 ããã¯ã也åŒç©ççŸåããªããµãŒã¢ã°ã©ãã€ãŒ
ææäžã®ã«ããã©ãŒãšããŠã®ãã³ãŒã³ã¹ã«ãã³ã¢
ããããšããŒã«ãšã¹ã«ããã«ããã©ãŸã³éå å€ãš
ã®é žåã«ãããªã³ã°ã«ãããäžé調ã«çŸãããç»
åã®åœ¢æãäŸç€ºãããã®ã§ããã å®æœäŸïŒã§è¿°ã¹ããããªããã³é žéã®åæ£æ¶²ïŒ¡
ã®ïŒmlãã2.0ééïŒ ããªïŒããã«ããã©ãŒã«ïŒ
ã®ã¢ã»ãã³æº¶æ¶²3.2mlãšãè¿œå ã®ã¢ã»ãã³1.0mlãš
ã®äžã«äžèšã®ç¬¬14Aè¡šäžã«ç€ºãããšãçš®ã ã®éã®
ããã©ãŸã³No.ïŒããã³ïŒïŒïŒâãžã¯ããâïŒâã
ã³ãŒã³ã¹ã«ãã³ã¢ããããšããŒã«ãšãå«ã溶液ã«
æ·»å ãããã§ããæ··åç©ãæ¹æãããæ¹æããæ··
åç©ã«ãã¢ã»ãã³äžèæ²åéä¹³å€ïŒïŒã¢ã«ïŒ æ²å
ç©ïŒå«æã®æ¶²0.8mlïŒ0.3ããªã¢ã«éã€ãªã³ïŒãæ·»
å ããããªïŒããã«ããã©ãŒã«ïŒäžã§ããã¿ã€ãº
ããã ããããŠã§ããããªããµãŒã¢ã°ã©ãã€ãŒçšçµæ
ç©ãã38âã«ãŠäžåŒããããªãããªïŒãšãã¬ã³ã
ã¬ãã¿ã¬ãŒãïŒãã€ã«ã æ¯æäœäžã«ã6.0ãã«ã®
湿最æå¡åžåãšãªãããã«å¡åžããã ããããŠã§ããããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ã
也ç¥ããã次ã«å ã«ç»åæ é²å ããããªããµãŒã¢
ã°ã©ãã€ãŒèŠçŽ äžã«ãçŸåå¯èœãªæœåãçããã
ãã該ããªããµãŒã¢ã°ã©ãã€ãŒèŠçŽ ãã次ã«ãèŠ
çŽ ã®æ¯æäœåŽããäžèšç¬¬14Aè¡šäžã«ç€ºã枩床ã«ã
ããå ç±ããã¡ã¿ã«ãããã¯ãšãåè¡šäžã«ç€ºãæ
éæ¥è§Šãããããšã«ãããåäžã«å ç±ããã次
ã«ã該èŠçŽ ã®ããªããµãŒã¢ã°ã©ãã€ãŒå±€åŽããã¡
ã¿ããŒã«ã§æ¹¿ãããå¥åã®åå°ç»åååã·ãŒãã«
察ããŠæŒãã€ãããããããŠã§ããããããããµ
ã³ãã€ãããã次ã«150âã«ãŠ60ç§éå ç±ããã
該ååã·ãŒãã¯ã次ã«ãåè¿°ã®èŠçŽ ããåé¢ãã
ããäžé調ïŒé»ãã¿ããïŒãŸãã¯éè²ã®ç»åãã
ååã·ãŒãäžã«èŠ³å¯ãããããããã®çµæã¯ãå
è¿°ã®ããã©ãŸã³ååç©ã®éããããªããµãŒã¢ã°ã©
ãã€ãŒå±€äžã®åœéã®ã«ããã©ãŒãè¶ ãããšãã«äž
é調ã®è²çŽ ã圢æãããããšã瀺ããŠãããã«ã
ãã©ãŒãéå°ã§ãã€ããšãã¯ã圢æãããè²çŽ ã¯
éè²ã§ãã€ãã æ¯èŒäŸäœæãè¡ãªãããããã®äŸã«ãããŠã¯ã
ã¹ã«ãã³ã¢ããããšããŒã«ã«ããã©ãŒã®ä»£ãã«ã
åœéã®ïŒ®ïŒïŒ®âãžã¡ãã«âïŒâãã³ãŒã³ã¹ã«ãã³
ã¢ããã¢ããªã³ãçšãããããåå Žåã«ãåè¿°ã®
ããšãç»åæ é²å ããã³ç±åŠçãè¡ãªã€ãŠããæ€
åºã§ããè²çŽ ãŸãã¯è»¢åå¯èœãªè²çŽ ã¯èŠ³å¯ãããª
ãã€ãã ãè¡šã æ¯èŒäŸ ããã¯æ¯èŒäŸã§ããã 295ïœã®äžèšããããŒã«ç³»ã«ããã©ãŒïŒ ãšã25mlã®ãžã¡ãã«ãã«ã ã¢ããïŒæ¬æ现æžäžã§
DMFãšèšããïŒãšã®æ··åç©ãã¹ã¿ãŒã©ãŒãã³ã³ã
ã³ãµãŒããã³æ»Žäžæãå ·åããïŒã€éŠååºãã©
ã¹ã³äžã«å ¥ãããã2.9ïœã®äžèšååç©7AïŒ ãš25mlã®DMFãšã«æ·»å ããã20mlã®2Næ°Žé žåã
ããªãŠã ãš50mlã®DMFãšããæ¹æããªããå ãã
æ··åç©ã溶解ããã次ã«ã35mlã®æ°Žäžã«6.6ïœ
ïŒ0.02ã¢ã«ïŒã®K3FeïŒCNïŒ6ãå«ã溶液ã滎äžããŠ
å ããããã®æ·»å äžã«ã¬ã¹ãçºçãã溶液ã¯æç·
è²ã«å€ã€ããïŒæéæ¹æåŸãæ··åç©ãéããé»
ãã€è²ã®åºäœãæéãããèå±€ã¯ãããã°ã©ãã€
ãŒã«ããåæã®çµæãè²çŽ ããããªã³ååç©ãå
åšããªãããšãæãããšãªã€ããæéããç©è³ªã®
è©Šæãããã«ãã¹ã¹ãã¯ããã¡ããªãŒã«ããåæ
ããŠã¢ãŸè²çŽ ã圢æãããŠããªãããšã確èªã
ãã äžè¿°ã®ååç©7Aã®ä»£ãã«äžèšã®ååç©7EïŒ ãçšããŠãäžè¿°ã®æ¹æ³ãããè¿ãããããŒã³ã¿ã¢
ãŸè²çŽ ãçãããããã¯ããã¹ã¹ãã¯ããã¡ããª
ãŒã«ããåæãã確èªãããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æå æ§ããã²ã³åé(a)ãè²çŽ 圢æã«ããã©ãŒ
(b)ããã³(i)é žåããã圢æ ã§åèšã«ããã©ãŒãšå
å¿ããŠè²çŽ ãçããè€çŽ ç°åŒéå å€ãš(ii)ææ©éå¡©
é žåå€ãšãããªãé žåâéå åç»å圢ææ§é åç©
(c)ãå«æããçµæç©ãæ¯æäœäžã«è¢«èŠããããšã
ãæã也åŒç©ççŸååããªããµãŒã¢ã°ã©ãã€ãŒèŠ
çŽ ã§ãã€ãŠãåèšéå å€ããã¢ãŸãŒã«ããªããµãŸ
ãŒã«ãã»ã¬ããŸãŒã«ããã³ãŸã»ã¬ããŸãŒã«ããã
ãã»ã¬ããŸãŒã«ããã³ãŸãã¢ãŸãŒã«ãŸãã¯ãããª
ã³æ žã§ããïŒå¡ãŸãã¯ïŒå¡ã®è€çŽ ç°æ žãæããã
ãã©ãŸã³éå å€ã§ããåèšããªããµãŒã¢ã°ã©ãã€
ãŒèŠçŽ ã ïŒ åèšããã©ãŸã³éå å€ãã¹ã«ããã«ããã©ãŸ
ã³ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®ããªããµ
ãŒã¢ã°ã©ãã€ãŒèŠçŽ ã ïŒ åèšããã©ãŸã³éå å€ããäžèšã®åŒã®ãã¡ã
ãããïŒã€ã«ãã€ãŠè¡šããããååç©ã§ãããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®ããªããµãŒã¢ã°ã©ã
ã€ãŒèŠçŽ ã
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6158679A | 1979-07-30 | 1979-07-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5627132A JPS5627132A (en) | 1981-03-16 |
| JPH0215855B2 true JPH0215855B2 (ja) | 1990-04-13 |
Family
ID=22036749
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10495380A Granted JPS5627132A (en) | 1979-07-30 | 1980-07-30 | Dry phsycalldeveloping photoothermography element |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS5627132A (ja) |
| FR (1) | FR2462732A1 (ja) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57179840A (en) * | 1981-04-30 | 1982-11-05 | Fuji Photo Film Co Ltd | Heat developing color photosensitive material |
| JPS57198458A (en) * | 1981-06-01 | 1982-12-06 | Fuji Photo Film Co Ltd | Heat developing color photosensitive material |
| JPS5858543A (ja) * | 1981-10-02 | 1983-04-07 | Fuji Photo Film Co Ltd | ç±çŸåã«ã©âæå ææããã³ãããçšããã«ã©âç»å圢ææ¹æ³ |
| JPS60115934A (ja) * | 1983-11-29 | 1985-06-22 | Konishiroku Photo Ind Co Ltd | ç±çŸåã«ã©âæå ææ |
| JPS6142650A (ja) * | 1984-08-07 | 1986-03-01 | Fuji Photo Film Co Ltd | ç±çŸåæå ææ |
| US5374496A (en) * | 1988-10-04 | 1994-12-20 | Canon Kabushiki Kaisha | Image forming method |
| US5171657A (en) * | 1988-10-04 | 1992-12-15 | Canon Kabushiki Kaisha | Light sensitive image forming medium |
| JPH0358047A (ja) * | 1989-07-27 | 1991-03-13 | Canon Inc | ç»å圢æè£ çœ® |
| US5187041A (en) * | 1990-04-04 | 1993-02-16 | Canon Kabushiki Kaisha | Image forming method and image forming apparatus |
| JPH08234390A (ja) * | 1995-02-24 | 1996-09-13 | Fuji Photo Film Co Ltd | ç»å圢ææ¹æ³ããã³ããã²ã³åéæå ææ |
| US6124242A (en) * | 1998-06-26 | 2000-09-26 | Basf Aktiengesellschaft | Herbicidal compositions and processes based on ferrodoxin:NADP reductase inhibitors |
| US20110287931A1 (en) * | 2009-02-03 | 2011-11-24 | Nippon Soda Co., Ltd. | Rewritable recording material |
| EP2612847B1 (en) | 2010-09-01 | 2018-04-18 | Nippon Soda Co., Ltd. | Recording material using phenol compound |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3615533A (en) * | 1968-03-11 | 1971-10-26 | Eastman Kodak Co | Heat and light sensitive layers containing hydrazones |
-
1980
- 1980-07-29 FR FR8016680A patent/FR2462732A1/fr active Pending
- 1980-07-30 JP JP10495380A patent/JPS5627132A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5627132A (en) | 1981-03-16 |
| FR2462732A1 (fr) | 1981-02-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4021240A (en) | Photothermographic and thermographic compositions and uses therefor containing sulfonamidophenol reducing agents and four equivalent color couplers | |
| US3985565A (en) | Photothermographic, composition using a phenolic leuco dye as a reducing agent | |
| US4022617A (en) | Photothermographic element, composition and process for producing a color image from leuco dye | |
| US4426441A (en) | Dye-forming developers in an imaging material and process | |
| IT7354343A1 (it) | Materiale di copiatura a secco | |
| US4235957A (en) | Thermal silver-dye bleach element and process | |
| JPH0215855B2 (ja) | ||
| GB2056103A (en) | Silver Halide-containing Photothermographic Materials | |
| US4124387A (en) | Positive images in photothermographic materials containing nitroxyl compounds | |
| US4088491A (en) | Light sensitive photographic material | |
| CA1116916A (en) | Photographic and thermographic material containing a resorcinol dye-forming coupler | |
| US4469773A (en) | Carbamoyloxy substituted couplers in a photothermographic element and process | |
| JP3247492B2 (ja) | åçèŠçŽ ã«æçšãªè²çŽ ãåã³åçèŠçŽ | |
| US4774162A (en) | Photographic element | |
| US4124392A (en) | Cobalt complex amplification imaging system with blocked dye precursor | |
| JPS58201852A (ja) | è²çŽ ãã¬ã«âãµååç© | |
| JPS6332177B2 (ja) | ||
| US4123273A (en) | Stable free radical nitroxyl bleaching agents for photographic processes | |
| JPS6033258B2 (ja) | æå æ§ã«ã©ãŒåçææ | |
| JPH0215856B2 (ja) | ||
| US4124398A (en) | Thiyl bleaching agents for photographic processes | |
| US4174969A (en) | Light sensitive photographic material | |
| JPH10502460A (ja) | å ç±åçèŠçŽ çšãããã¯åãã€ã³ææ | |
| US4548897A (en) | Photothermographic element and process | |
| US4142901A (en) | Photographic materials comprising azo sensitizing dyes |