JPH03144938A - 光メモリ素子 - Google Patents

光メモリ素子

Info

Publication number
JPH03144938A
JPH03144938A JP1284602A JP28460289A JPH03144938A JP H03144938 A JPH03144938 A JP H03144938A JP 1284602 A JP1284602 A JP 1284602A JP 28460289 A JP28460289 A JP 28460289A JP H03144938 A JPH03144938 A JP H03144938A
Authority
JP
Japan
Prior art keywords
optical memory
layer
light
memory element
memory layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1284602A
Other languages
English (en)
Inventor
Kenji Ota
賢司 太田
Kazuo Ban
和夫 伴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sharp Corp
Original Assignee
Sharp Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sharp Corp filed Critical Sharp Corp
Priority to JP1284602A priority Critical patent/JPH03144938A/ja
Priority to US07/604,581 priority patent/US5192644A/en
Priority to EP90311890A priority patent/EP0426437B1/en
Priority to DE69032173T priority patent/DE69032173T2/de
Publication of JPH03144938A publication Critical patent/JPH03144938A/ja
Pending legal-status Critical Current

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Classifications

    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • G11B7/246Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/257Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
    • G11B7/2578Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/257Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
    • G11B2007/25705Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials
    • G11B2007/25708Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials containing group 13 elements (B, Al, Ga)
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/257Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
    • G11B2007/25705Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials
    • G11B2007/2571Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials containing group 14 elements except carbon (Si, Ge, Sn, Pb)
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/257Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
    • G11B2007/25705Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials
    • G11B2007/25713Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials containing nitrogen
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/257Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
    • G11B2007/25705Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials
    • G11B2007/25715Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials containing oxygen
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • G11B7/245Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing a polymeric component
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • G11B7/246Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
    • G11B7/2467Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes azo-dyes
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/253Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
    • G11B7/2531Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising glass
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S430/00Radiation imagery chemistry: process, composition, or product thereof
    • Y10S430/146Laser beam
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S430/00Radiation imagery chemistry: process, composition, or product thereof
    • Y10S430/163Radiation-chromic compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Optical Record Carriers And Manufacture Thereof (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。

Description

【発明の詳細な説明】 (イ)産業上の利用分野 本発明は、光メモリ素子に関する。
(ロ)従来の技術 近年、光により情報の記録、再生及び消去を行う光メモ
リ素子は高密度大容量メモリ素子として年々その必要性
が高まっている。従来の光メモリ素子としては、第2図
に示すように、基[11の上に、波長λ、の光で記録で
きる光メモリ層R1を設け、該光メモリ層R7の上に波
長λ、の光で記録できる光メモリ層R3を設け、以下順
次波長λnの光で記録できる光メモリ層Rnを設けた構
造を有し、それぞれの光メモリ層に、異なる波長の光を
照射してn層の多重記録ができる光メモリ素子が知られ
ている(特開昭82−165751号公報)。
(ハ)発明が解決しようとする課題 ところが、上記光メモリ素子の第1層(i≦n)に光を
照射して情報を記録しようとするとき、i層の温度上昇
により、i層の前後の層[(+−1)層と(i層1)層
]の温度が上昇し、(i−1)層や(i層1)層に記録
が消失したり、場合によっては光メモリ層(第1層)そ
のものが破壊されるという問題がある。
この発明は、この問題を解決するためになされたもので
あって、光の照射による温度上昇が小さく記録の消失や
光メモリ層の破滅を起こさない光メモリ素子を提供しよ
うとするものである。
(ニ)課題を解決するための手段 この発明によれば、基板上に、フォトクロミック材料か
らなる襟敗の光メモリ層が熱伝導性透明膜を介して積層
されてなる光メモリ素子が提供される。
この発明における1&仮は、光メモリ素子を支持するた
めのものであって、例えばガラス、プラスチック、アル
ミニウム等を用いて形成することができろ。この中でも
ガラス、プラスチック等の透明な材料によって形成した
基板は基板の上方または下方のいずれの側からも光を照
射することができるので好ましい。また基板の下方から
基板を通して光を入射させるときは、基板の厚みは0.
5〜2.01+m程度が好ましい。
この発明におけるフォトクロミック材料は、前記基板の
上に光メモリ層を形成するためのものであって、光の照
射により互変異性化など構造変化か可逆的に生じ同時に
吸収スペクトルが変化する有機化合物を用いることがで
き、例えばスピロベンゾビラン誘導体、フルギド化合物
等が挙げられる。
この発明における光メモリ層は、光の照射によって光メ
モリ層に生じた露光を記録するためのものであって、光
メモリ層を構成するフォトクロミック材料の化学構造に
対応して特有の波長の光に対して感光することができる
。また、この光メモリ層は、複数で光メモリ素子を構成
することができ、通常それぞれ異なった波長の光に対し
て感光性を有するように構成することができる。また、
この光メモリ層は前記フォトクロミック材料のみで作製
してもよいが、適宜色素材料を混合して作製してしよい
この発明における熱伝導性透明膜は、露光によって感光
した光メモリ層において発生する熱を放散させ光メモリ
層の温度を抑制するためのちのであって、複数の光メモ
リ層の間に介在させて用いられ、熱伝導率が光メモリ層
よりも高く、かつ光メモリに使用する光を充分透過する
ことが必要であることから、例えば窒化アルミニウム、
窒化シリコン、酸化アルミニウム等の薄膜を用いるのが
適している。
この薄膜(熱伝導性透明膜)は、形成する薄膜のW類に
よって、例えばCVD法、スパッタリング法等の手段を
適宜選択して用いることにより形成することができ、そ
の膜厚を、通常50〜350nm。
好ましくは60〜75nm、もしくは330nm〜34
5rvとすることができる。また、この熱伝導性透明膜
は、複数の光メモリ層の間に適宜介在させればよいが、
それぞれの光メモリ層毎にその上面と下面に配置する方
が光メモリ層の温度上昇をよく抑えることができるので
好ましい。
この発明においては、基板上に光メモリ層が熱伝導性透
明膜を介して積層した後、この上に、例えばUV硬化樹
111i1 (ハードコート膜)からなる保ffl@を
形成してもよい。
(ホ)作用 熱伝導性透明膜が、光が照射された光メモリ層に発生す
る熱を放牧し光メモリ層の温度上昇を抑制する。
(へ)実施例 本発明の実施列を図面をもとにして説明する。
まず、第1図に示すように直径1aQmms厚さ1.2
1のガラス基板lの上に、CVD法によって膜厚0.3
3μmの窒化アルミニウム嘆2a(pA伝導率約20J
/m−54,透明)を形成する。次に、この上にスピン
コード法によって、膜厚的0.7μ龜の式で表されるオ
キサゾール誘導体置換へテロ型フルギド化合物の層3(
波長462nmの光に感応性の光メモリ層)を形成する
この上に、再び膜厚0.33μmの窒化アルミニウム1
i2bを形成し、この上にスピンコード法によって膜厚
的0.7μmの式 で表されるチオフェン誘導体置換へテロ型フルギド化合
物の層4(波長523nmの光に感応性の光メモリ層)
を形成する。
この上に、3回目の膜厚0.33μmの窒化アルミニウ
ム@2cを形成し、更にこの上にスピンコード法によっ
て膜厚約0.7μmの式 で表されるビロール誘導体置換へテロ型フルギド化合物
の層5(波&614nmの光に感応性の光メモリ層)を
形成する。
この上に4回目の膜厚0133μ九の窒化アルミニウム
膜2dを形成して光メモリ素子を作製する。
得られた、光メモリ素子は、462nn、 523nn
および614nnの光を照射して記録試験を行ったとこ
ろ、光メモリ層の温度上昇は小さくなり記録の安定性が
向上することが認められた。
(ト)発明の効果 この発明によれば、光の照射による温度上昇が小さく、
記録の消失や光メモリ層の破壊を起こさない光メモリ素
子を提供することができる。
【図面の簡単な説明】
第1図は、本発明の実施例で作製した光メモリ素子の説
明図、第2図は、従来の光メモリ素子の説明図である。 し・・・・・ガラス基板、 2a、2b、2c、2d・・・・・・窒化アルミニウム
膜、 3・・・・・・オキサゾール誘導体置換へテロ型フルギ
ド化合物の層、 4・・・・・・チオフェン誘導体置換へテロ型フルギド
化合物の層、 5・・・・・・ビロール誘導体置換へテロ型フルギド化
合物の層。

Claims (1)

    【特許請求の範囲】
  1. 1、基板上に、フォトクロミック材料からなる複数の光
    メモリ層が熱伝導性透明膜を介して積層されてなる光メ
    モリ素子。
JP1284602A 1989-10-30 1989-10-30 光メモリ素子 Pending JPH03144938A (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP1284602A JPH03144938A (ja) 1989-10-30 1989-10-30 光メモリ素子
US07/604,581 US5192644A (en) 1989-10-30 1990-10-29 Optical memory device
EP90311890A EP0426437B1 (en) 1989-10-30 1990-10-30 Optical memory device
DE69032173T DE69032173T2 (de) 1989-10-30 1990-10-30 Optische Speichervorrichtung

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1284602A JPH03144938A (ja) 1989-10-30 1989-10-30 光メモリ素子

Publications (1)

Publication Number Publication Date
JPH03144938A true JPH03144938A (ja) 1991-06-20

Family

ID=17680583

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1284602A Pending JPH03144938A (ja) 1989-10-30 1989-10-30 光メモリ素子

Country Status (4)

Country Link
US (1) US5192644A (ja)
EP (1) EP0426437B1 (ja)
JP (1) JPH03144938A (ja)
DE (1) DE69032173T2 (ja)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5346740A (en) * 1990-09-25 1994-09-13 Matsushita Electric Industrial Co., Ltd. Optical information recording medium
US6964890B1 (en) 1992-03-17 2005-11-15 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for forming the same
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EP0426437B1 (en) 1998-03-25
DE69032173D1 (de) 1998-04-30
DE69032173T2 (de) 1998-10-08
EP0426437A2 (en) 1991-05-08
US5192644A (en) 1993-03-09
EP0426437A3 (en) 1992-04-15

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