JPH03177581A - 人工的に錆表面仕上げを形成するために鉛または鉛合金からなる若しくは鉛または鉛合金で被覆された金属材料の表面処理方法及び本方法によって得られた製品 - Google Patents

人工的に錆表面仕上げを形成するために鉛または鉛合金からなる若しくは鉛または鉛合金で被覆された金属材料の表面処理方法及び本方法によって得られた製品

Info

Publication number: JPH03177581A
Authority: JP; Japan
Prior art keywords: lead; sulfate; rust; persulfate; coated
Prior art date: 1989-10-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP29349290A

Other languages

English (en)

Japanese (ja)

Inventor

Pascal Amelot

パスカル・アメロ

Jean-Claude Edmond Bavay

ジヤン―クロード・エドモン・バベ

Raymond Invernizzi

レーモン・アンベルニージ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Ugine Aciers de Chatillon et Guegnon

Original Assignee

Ugine Aciers de Chatillon et Guegnon

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-10-30

Filing date

1990-10-30

Publication date

1991-08-01

1990-10-30 Application filed by Ugine Aciers de Chatillon et Guegnon filed Critical Ugine Aciers de Chatillon et Guegnon

1991-08-01 Publication of JPH03177581A publication Critical patent/JPH03177581A/ja

Status Pending legal-status Critical Current

Links

JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 41
229910000978 Pb alloy Inorganic materials 0.000 title claims abstract description 26
239000007769 metal material Substances 0.000 title claims abstract description 23
238000000034 method Methods 0.000 title claims description 46
238000011282 treatment Methods 0.000 title claims description 14
229910052736 halogen Inorganic materials 0.000 claims abstract description 19
239000002253 acid Substances 0.000 claims abstract description 15
PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 claims abstract description 15
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 14
150000002367 halogens Chemical class 0.000 claims abstract description 12
239000000126 substance Substances 0.000 claims abstract description 12
JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims abstract description 11
-1 sulfuric acid ion Chemical class 0.000 claims abstract description 9
230000003647 oxidation Effects 0.000 claims abstract description 8
238000007254 oxidation reaction Methods 0.000 claims abstract description 8
238000002848 electrochemical method Methods 0.000 claims abstract description 7
239000000243 solution Substances 0.000 claims description 26
229910000831 Steel Inorganic materials 0.000 claims description 15
239000010959 steel Substances 0.000 claims description 15
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 12
238000004381 surface treatment Methods 0.000 claims description 11
239000000047 product Substances 0.000 claims description 10
235000002639 sodium chloride Nutrition 0.000 claims description 10
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
239000000758 substrate Substances 0.000 claims description 9
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 8
229910001220 stainless steel Inorganic materials 0.000 claims description 7
KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 claims description 6
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 6
150000002500 ions Chemical class 0.000 claims description 6
QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims description 5
229910052751 metal Inorganic materials 0.000 claims description 5
239000002184 metal Substances 0.000 claims description 5
LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical group NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 4
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 4
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 4
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 4
NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 claims description 4
239000011780 sodium chloride Substances 0.000 claims description 4
PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 4
CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 4
239000010935 stainless steel Substances 0.000 claims description 4
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
229910001870 ammonium persulfate Inorganic materials 0.000 claims description 3
ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 claims description 3
229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
235000011152 sodium sulphate Nutrition 0.000 claims description 3
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
235000011130 ammonium sulphate Nutrition 0.000 claims description 2
235000011132 calcium sulphate Nutrition 0.000 claims description 2
229910052943 magnesium sulfate Inorganic materials 0.000 claims description 2
235000019341 magnesium sulphate Nutrition 0.000 claims description 2
229910017604 nitric acid Inorganic materials 0.000 claims description 2
CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 claims description 2
229910000343 potassium bisulfate Inorganic materials 0.000 claims description 2
239000001103 potassium chloride Substances 0.000 claims description 2
235000011164 potassium chloride Nutrition 0.000 claims description 2
239000011698 potassium fluoride Substances 0.000 claims description 2
235000003270 potassium fluoride Nutrition 0.000 claims description 2
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 2
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
235000011151 potassium sulphates Nutrition 0.000 claims description 2
239000002244 precipitate Substances 0.000 claims description 2
WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 claims description 2
229910000342 sodium bisulfate Inorganic materials 0.000 claims description 2
239000011775 sodium fluoride Substances 0.000 claims description 2
235000013024 sodium fluoride Nutrition 0.000 claims description 2
239000012487 rinsing solution Substances 0.000 claims 3
239000007864 aqueous solution Substances 0.000 claims 1
125000005843 halogen group Chemical group 0.000 claims 1
230000001590 oxidative effect Effects 0.000 claims 1
239000000463 material Substances 0.000 abstract description 15
230000015572 biosynthetic process Effects 0.000 abstract description 9
238000005260 corrosion Methods 0.000 description 6
230000007797 corrosion Effects 0.000 description 6
229910045601 alloy Inorganic materials 0.000 description 4
239000000956 alloy Substances 0.000 description 4
239000000203 mixture Substances 0.000 description 4
238000010276 construction Methods 0.000 description 3
238000000151 deposition Methods 0.000 description 3
230000008021 deposition Effects 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
230000001681 protective effect Effects 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
229910000975 Carbon steel Inorganic materials 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
229910001209 Low-carbon steel Inorganic materials 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
241001311547 Patina Species 0.000 description 1
238000003916 acid precipitation Methods 0.000 description 1
238000003915 air pollution Methods 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
229910000963 austenitic stainless steel Inorganic materials 0.000 description 1
239000010962 carbon steel Substances 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
238000005238 degreasing Methods 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
238000004070 electrodeposition Methods 0.000 description 1
238000009472 formulation Methods 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
238000007654 immersion Methods 0.000 description 1
XMFOQHDPRMAJNU-UHFFFAOYSA-N lead(ii,iv) oxide Chemical compound O1[Pb]O[Pb]11O[Pb]O1 XMFOQHDPRMAJNU-UHFFFAOYSA-N 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
229910001092 metal group alloy Inorganic materials 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
238000007747 plating Methods 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
239000000779 smoke Substances 0.000 description 1
238000005476 soldering Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
238000010301 surface-oxidation reaction Methods 0.000 description 1
229910001174 tin-lead alloy Inorganic materials 0.000 description 1
230000001256 tonic effect Effects 0.000 description 1
239000002699 waste material Substances 0.000 description 1
238000003466 welding Methods 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D9/00—Electrolytic coating other than with metals
- C25D9/04—Electrolytic coating other than with metals with inorganic materials
- C25D9/06—Electrolytic coating other than with metals with inorganic materials by anodic processes
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/58—Treatment of other metallic material

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Mechanical Engineering (AREA)
Inorganic Chemistry (AREA)
Electrochemistry (AREA)
Chemical Treatment Of Metals (AREA)
Other Surface Treatments For Metallic Materials (AREA)

JP29349290A 1989-10-30 1990-10-30 人工的に錆表面仕上げを形成するために鉛または鉛合金からなる若しくは鉛または鉛合金で被覆された金属材料の表面処理方法及び本方法によって得られた製品 Pending JPH03177581A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR8914222A FR2653785A1 (fr)	1989-10-30	1989-10-30	Procede de traitement de surface d'un materiau metallique compose ou revetu de plomb ou d'un alliage de plomb et produit obtenu par le procede.
FR8914222		1989-10-30

Publications (1)

Publication Number	Publication Date
JPH03177581A true JPH03177581A (ja)	1991-08-01

Family

ID=9386926

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP29349290A Pending JPH03177581A (ja)	1989-10-30	1990-10-30	人工的に錆表面仕上げを形成するために鉛または鉛合金からなる若しくは鉛または鉛合金で被覆された金属材料の表面処理方法及び本方法によって得られた製品

Country Status (3)

Country	Link
EP (1)	EP0430726A1 (fr)
JP (1)	JPH03177581A (fr)
FR (1)	FR2653785A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB9409811D0 (en) *	1994-05-17	1994-07-06	Imi Yorkshire Fittings	Improvements in copper alloy water fittings

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4089707A (en) *	1976-07-19	1978-05-16	Republic Steel Corporation	Method of improving corrosion resistance of lead and lead alloy coated metal
JPS59104480A (ja) *	1982-12-03	1984-06-16	Nippon Steel Corp	アルコ−ルもしくはアルコ−ルを含有する燃料容器用鋼板の製造法

1989
- 1989-10-30 FR FR8914222A patent/FR2653785A1/fr not_active Withdrawn
1990
- 1990-10-23 EP EP90402984A patent/EP0430726A1/fr not_active Withdrawn
- 1990-10-30 JP JP29349290A patent/JPH03177581A/ja active Pending

Also Published As

Publication number	Publication date
FR2653785A1 (fr)	1991-05-03
EP0430726A1 (fr)	1991-06-05

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