JPH0451227B2 - - Google Patents

Info

Publication number: JPH0451227B2
Authority: JP; Japan
Prior art keywords: catalyst; silica; surface area; specific surface; silica sol
Prior art date: 1987-09-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP62219589A

Other languages

English (en)

Japanese (ja)

Other versions

JPH01207136A (ja

Inventor

Noboru Hirooka

Tatsuya Nobusawa

Jusaku Arima

Susumu Fujii

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

JFE Steel Corp

Original Assignee

Kawasaki Steel Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-09-02

Filing date

1987-09-02

Publication date

1992-08-18

1987-09-02 Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp

1987-09-02 Priority to JP62219589A priority Critical patent/JPH01207136A/ja

1989-08-21 Publication of JPH01207136A publication Critical patent/JPH01207136A/ja

1992-08-18 Publication of JPH0451227B2 publication Critical patent/JPH0451227B2/ja

Status Granted legal-status Critical Current

Links

VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 176
239000003054 catalyst Substances 0.000 claims description 165
239000000377 silicon dioxide Substances 0.000 claims description 76
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 51
239000000017 hydrogel Substances 0.000 claims description 50
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 42
239000002245 particle Substances 0.000 claims description 40
238000010438 heat treatment Methods 0.000 claims description 21
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 20
239000008119 colloidal silica Substances 0.000 claims description 19
230000003197 catalytic effect Effects 0.000 claims description 18
230000003647 oxidation Effects 0.000 claims description 16
238000007254 oxidation reaction Methods 0.000 claims description 16
238000004519 manufacturing process Methods 0.000 claims description 14
239000002253 acid Substances 0.000 claims description 13
238000002156 mixing Methods 0.000 claims description 11
238000001694 spray drying Methods 0.000 claims description 9
230000002378 acidificating effect Effects 0.000 claims description 7
150000003112 potassium compounds Chemical class 0.000 claims description 6
150000003682 vanadium compounds Chemical class 0.000 claims description 5
-1 sulfuric acid compound Chemical class 0.000 claims description 4
238000005245 sintering Methods 0.000 claims description 2
239000011148 porous material Substances 0.000 description 31
238000000034 method Methods 0.000 description 26
229910004298 SiO 2 Inorganic materials 0.000 description 21
239000000243 solution Substances 0.000 description 19
239000011734 sodium Substances 0.000 description 16
230000007423 decrease Effects 0.000 description 15
239000000499 gel Substances 0.000 description 14
239000004480 active ingredient Substances 0.000 description 13
238000006243 chemical reaction Methods 0.000 description 13
230000000052 comparative effect Effects 0.000 description 13
230000000694 effects Effects 0.000 description 13
239000012071 phase Substances 0.000 description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
239000000203 mixture Substances 0.000 description 10
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 10
229910052939 potassium sulfate Inorganic materials 0.000 description 10
239000004115 Sodium Silicate Substances 0.000 description 9
239000007789 gas Substances 0.000 description 9
235000011151 potassium sulphates Nutrition 0.000 description 9
229910052911 sodium silicate Inorganic materials 0.000 description 9
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 9
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
239000011268 mixed slurry Substances 0.000 description 8
238000002360 preparation method Methods 0.000 description 8
229910052708 sodium Inorganic materials 0.000 description 8
239000002585 base Substances 0.000 description 7
238000005470 impregnation Methods 0.000 description 7
230000003472 neutralizing effect Effects 0.000 description 7
239000000843 powder Substances 0.000 description 7
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 6
229910052921 ammonium sulfate Inorganic materials 0.000 description 6
235000011130 ammonium sulphate Nutrition 0.000 description 6
230000006866 deterioration Effects 0.000 description 6
238000009826 distribution Methods 0.000 description 6
238000006386 neutralization reaction Methods 0.000 description 6
229910052700 potassium Inorganic materials 0.000 description 6
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 5
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 5
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 5
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
239000004111 Potassium silicate Substances 0.000 description 5
235000011114 ammonium hydroxide Nutrition 0.000 description 5
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 5
239000003729 cation exchange resin Substances 0.000 description 5
238000000151 deposition Methods 0.000 description 5
238000011156 evaluation Methods 0.000 description 5
239000007788 liquid Substances 0.000 description 5
239000011591 potassium Substances 0.000 description 5
NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 5
229910052913 potassium silicate Inorganic materials 0.000 description 5
235000019353 potassium silicate Nutrition 0.000 description 5
235000012239 silicon dioxide Nutrition 0.000 description 5
239000012798 spherical particle Substances 0.000 description 5
UUUGYDOQQLOJQA-UHFFFAOYSA-L vanadyl sulfate Chemical compound [V+2]=O.[O-]S([O-])(=O)=O UUUGYDOQQLOJQA-UHFFFAOYSA-L 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 4
238000001354 calcination Methods 0.000 description 4
229910017604 nitric acid Inorganic materials 0.000 description 4
239000007787 solid Substances 0.000 description 4
239000000126 substance Substances 0.000 description 4
229910052720 vanadium Inorganic materials 0.000 description 4
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 4
229910000352 vanadyl sulfate Inorganic materials 0.000 description 4
229940041260 vanadyl sulfate Drugs 0.000 description 4
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
238000005299 abrasion Methods 0.000 description 3
229910052681 coesite Inorganic materials 0.000 description 3
229910052906 cristobalite Inorganic materials 0.000 description 3
238000010304 firing Methods 0.000 description 3
238000005342 ion exchange Methods 0.000 description 3
238000002844 melting Methods 0.000 description 3
239000002002 slurry Substances 0.000 description 3
239000007921 spray Substances 0.000 description 3
229910001220 stainless steel Inorganic materials 0.000 description 3
239000010935 stainless steel Substances 0.000 description 3
229910052682 stishovite Inorganic materials 0.000 description 3
229910052905 tridymite Inorganic materials 0.000 description 3
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
229930192627 Naphthoquinone Natural products 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000001035 drying Methods 0.000 description 2
230000020169 heat generation Effects 0.000 description 2
230000008018 melting Effects 0.000 description 2
239000011259 mixed solution Substances 0.000 description 2
150000002791 naphthoquinones Chemical class 0.000 description 2
FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000009827 uniform distribution Methods 0.000 description 2
229910001935 vanadium oxide Inorganic materials 0.000 description 2
238000004438 BET method Methods 0.000 description 1
MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
AZFNGPAYDKGCRB-XCPIVNJJSA-M [(1s,2s)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;chlororuthenium(1+);1-methyl-4-propan-2-ylbenzene Chemical compound [Ru+]Cl.CC(C)C1=CC=C(C)C=C1.C1=CC(C)=CC=C1S(=O)(=O)[N-][C@@H](C=1C=CC=CC=1)[C@@H](N)C1=CC=CC=C1 AZFNGPAYDKGCRB-XCPIVNJJSA-M 0.000 description 1
CPLPNZFTIJOEIN-UHFFFAOYSA-I [V+5].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O Chemical compound [V+5].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O CPLPNZFTIJOEIN-UHFFFAOYSA-I 0.000 description 1
LXASOGUHMSNFCR-UHFFFAOYSA-D [V+5].[V+5].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O Chemical compound [V+5].[V+5].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O LXASOGUHMSNFCR-UHFFFAOYSA-D 0.000 description 1
230000032683 aging Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
229910052910 alkali metal silicate Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000003125 aqueous solvent Substances 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
230000001276 controlling effect Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
230000002596 correlated effect Effects 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
FGRVOLIFQGXPCT-UHFFFAOYSA-L dipotassium;dioxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound [K+].[K+].[O-]S([O-])(=O)=S FGRVOLIFQGXPCT-UHFFFAOYSA-L 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
235000013305 food Nutrition 0.000 description 1
238000001879 gelation Methods 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
150000002500 ions Chemical group 0.000 description 1
230000007774 longterm Effects 0.000 description 1
239000012528 membrane Substances 0.000 description 1
238000001000 micrograph Methods 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
238000009828 non-uniform distribution Methods 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
238000010979 pH adjustment Methods 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
235000007686 potassium Nutrition 0.000 description 1
CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 description 1
229910000343 potassium bisulfate Inorganic materials 0.000 description 1
DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 description 1
239000001103 potassium chloride Substances 0.000 description 1
235000011164 potassium chloride Nutrition 0.000 description 1
235000010259 potassium hydrogen sulphite Nutrition 0.000 description 1
JMTCDHVHZSGGJA-UHFFFAOYSA-M potassium hydrogenoxalate Chemical compound [K+].OC(=O)C([O-])=O JMTCDHVHZSGGJA-UHFFFAOYSA-M 0.000 description 1
235000011118 potassium hydroxide Nutrition 0.000 description 1
235000010333 potassium nitrate Nutrition 0.000 description 1
239000004323 potassium nitrate Substances 0.000 description 1
235000010289 potassium nitrite Nutrition 0.000 description 1
239000004304 potassium nitrite Substances 0.000 description 1
BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
235000019252 potassium sulphite Nutrition 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000011160 research Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
235000011121 sodium hydroxide Nutrition 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
238000005507 spraying Methods 0.000 description 1
238000012360 testing method Methods 0.000 description 1
238000004448 titration Methods 0.000 description 1
238000000108 ultra-filtration Methods 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Furan Compounds (AREA)
Catalysts (AREA)

JP62219589A 1987-09-02 1987-09-02 ナフタリンの気相接触酸化用流動触媒の製造方法 Granted JPH01207136A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP62219589A JPH01207136A (ja)	1987-09-02	1987-09-02	ナフタリンの気相接触酸化用流動触媒の製造方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP62219589A JPH01207136A (ja)	1987-09-02	1987-09-02	ナフタリンの気相接触酸化用流動触媒の製造方法

Publications (2)

Publication Number	Publication Date
JPH01207136A JPH01207136A (ja)	1989-08-21
JPH0451227B2 true JPH0451227B2 (sr)	1992-08-18

Family

ID=16737903

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP62219589A Granted JPH01207136A (ja)	1987-09-02	1987-09-02	ナフタリンの気相接触酸化用流動触媒の製造方法

Country Status (1)

Country	Link
JP (1)	JPH01207136A (sr)

1987
- 1987-09-02 JP JP62219589A patent/JPH01207136A/ja active Granted

Also Published As

Publication number	Publication date
JPH01207136A (ja)	1989-08-21

Legal Events

Date	Code	Title	Description
2007-08-18	LAPS	Cancellation because of no payment of annual fees

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