JPH0624982B2 - 四塩化ジルコニュウムと四塩化ハフニユウムを分離する方法 - Google Patents

四塩化ジルコニュウムと四塩化ハフニユウムを分離する方法

Info

Publication number: JPH0624982B2
Authority: JP; Japan
Prior art keywords: hafnium; tetrachloride; zirconium; zirconium tetrachloride; low
Prior art date: 1988-01-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP63004416A

Other languages

English (en)

Japanese (ja)

Other versions

JPH01179726A (ja

Inventor

朝夫桐原

一兵中川

義辰関

裕本田

祺夫市原

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mitsubishi Nuclear Fuel Co Ltd

Original Assignee

Mitsubishi Nuclear Fuel Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-01-12

Filing date

1988-01-12

Publication date

1994-04-06

1988-01-12 Application filed by Mitsubishi Nuclear Fuel Co Ltd filed Critical Mitsubishi Nuclear Fuel Co Ltd

1988-01-12 Priority to JP63004416A priority Critical patent/JPH0624982B2/ja

1988-12-28 Priority to CA000587064A priority patent/CA1333781C/fr

1989-01-05 Priority to US07/293,791 priority patent/US5009751A/en

1989-01-09 Priority to AU28322/89A priority patent/AU612452B2/en

1989-01-11 Priority to FR898900263A priority patent/FR2625739B1/fr

1989-07-17 Publication of JPH01179726A publication Critical patent/JPH01179726A/ja

1994-04-06 Publication of JPH0624982B2 publication Critical patent/JPH0624982B2/ja

2009-04-06 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 title claims description 78
PDPJQWYGJJBYLF-UHFFFAOYSA-J hafnium tetrachloride Chemical compound Cl[Hf](Cl)(Cl)Cl PDPJQWYGJJBYLF-UHFFFAOYSA-J 0.000 title claims description 36
238000000034 method Methods 0.000 title claims description 11
238000005868 electrolysis reaction Methods 0.000 claims description 52
229910052735 hafnium Inorganic materials 0.000 claims description 33
235000019341 magnesium sulphate Nutrition 0.000 claims description 33
CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 32
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 30
150000003839 salts Chemical class 0.000 claims description 15
PFXYQVJESZAMSV-UHFFFAOYSA-K zirconium(iii) chloride Chemical compound Cl[Zr](Cl)Cl PFXYQVJESZAMSV-UHFFFAOYSA-K 0.000 claims description 8
-1 hafnium zirconium trichloride Chemical compound 0.000 claims description 7
150000001875 compounds Chemical class 0.000 claims description 3
229910001515 alkali metal fluoride Inorganic materials 0.000 claims description 2
229910001514 alkali metal chloride Inorganic materials 0.000 claims 1
229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
229910001617 alkaline earth metal chloride Inorganic materials 0.000 claims 1
150000001342 alkaline earth metals Chemical class 0.000 claims 1
230000003247 decreasing effect Effects 0.000 claims 1
150000004673 fluoride salts Chemical class 0.000 claims 1
UJLQXGFCYFUENB-UHFFFAOYSA-J lithium zirconium(4+) tetrachloride Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Zr+4].[Li+] UJLQXGFCYFUENB-UHFFFAOYSA-J 0.000 claims 1
239000013589 supplement Substances 0.000 claims 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 18
239000000460 chlorine Substances 0.000 description 17
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 13
229910052726 zirconium Inorganic materials 0.000 description 13
238000006243 chemical reaction Methods 0.000 description 12
BUKHSQBUKZIMLB-UHFFFAOYSA-L potassium;sodium;dichloride Chemical compound [Na+].[Cl-].[Cl-].[K+] BUKHSQBUKZIMLB-UHFFFAOYSA-L 0.000 description 12
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 11
229910007926 ZrCl Inorganic materials 0.000 description 11
229910052801 chlorine Inorganic materials 0.000 description 11
229910052799 carbon Inorganic materials 0.000 description 9
239000007789 gas Substances 0.000 description 9
229910002804 graphite Inorganic materials 0.000 description 7
239000010439 graphite Substances 0.000 description 7
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
238000000926 separation method Methods 0.000 description 6
KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 5
238000004821 distillation Methods 0.000 description 5
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 5
229910001928 zirconium oxide Inorganic materials 0.000 description 5
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
229910004298 SiO 2 Inorganic materials 0.000 description 4
QFFMXYURYVMWLF-UHFFFAOYSA-J [Cl-].[Cl-].[Cl-].[Cl-].[Zr+4].[Hf+4] Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Zr+4].[Hf+4] QFFMXYURYVMWLF-UHFFFAOYSA-J 0.000 description 4
229910052783 alkali metal Inorganic materials 0.000 description 4
150000001340 alkali metals Chemical class 0.000 description 4
150000001805 chlorine compounds Chemical class 0.000 description 4
238000001704 evaporation Methods 0.000 description 4
230000008020 evaporation Effects 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 3
229910003902 SiCl 4 Inorganic materials 0.000 description 3
239000003638 chemical reducing agent Substances 0.000 description 3
238000005660 chlorination reaction Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
239000000463 material Substances 0.000 description 3
238000011084 recovery Methods 0.000 description 3
239000000126 substance Substances 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
GJEONJVNTMLKMR-UHFFFAOYSA-K [Cl-].[Cl-].[Cl-].[Hf+3] Chemical compound [Cl-].[Cl-].[Cl-].[Hf+3] GJEONJVNTMLKMR-UHFFFAOYSA-K 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
239000012298 atmosphere Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical compound [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 description 2
229910002090 carbon oxide Inorganic materials 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
230000007423 decrease Effects 0.000 description 2
230000005518 electrochemistry Effects 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
239000002994 raw material Substances 0.000 description 2
FGDZQCVHDSGLHJ-UHFFFAOYSA-M rubidium chloride Chemical compound [Cl-].[Rb+] FGDZQCVHDSGLHJ-UHFFFAOYSA-M 0.000 description 2
239000004576 sand Substances 0.000 description 2
238000010517 secondary reaction Methods 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
238000000859 sublimation Methods 0.000 description 2
230000008022 sublimation Effects 0.000 description 2
229910016036 BaF 2 Inorganic materials 0.000 description 1
229910004261 CaF 2 Inorganic materials 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
101100496858 Mus musculus Colec12 gene Proteins 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000003513 alkali Substances 0.000 description 1
239000012300 argon atmosphere Substances 0.000 description 1
229910052729 chemical element Inorganic materials 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000004020 conductor Substances 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
238000010304 firing Methods 0.000 description 1
230000014509 gene expression Effects 0.000 description 1
229910000449 hafnium oxide Inorganic materials 0.000 description 1
WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
229910052943 magnesium sulfate Inorganic materials 0.000 description 1
238000005259 measurement Methods 0.000 description 1
229910001510 metal chloride Inorganic materials 0.000 description 1
229910052914 metal silicate Inorganic materials 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
238000005192 partition Methods 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/04—Halides
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G27/00—Compounds of hafnium
- C01G27/04—Halides

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Manufacture And Refinement Of Metals (AREA)
Inorganic Compounds Of Heavy Metals (AREA)
Electrolytic Production Of Metals (AREA)

JP63004416A 1988-01-12 1988-01-12 四塩化ジルコニュウムと四塩化ハフニユウムを分離する方法 Expired - Lifetime JPH0624982B2 (ja)

Priority Applications (5)

Application Number	Priority Date	Filing Date	Title
JP63004416A JPH0624982B2 (ja)	1988-01-12	1988-01-12	四塩化ジルコニュウムと四塩化ハフニユウムを分離する方法
CA000587064A CA1333781C (fr)	1988-01-12	1988-12-28	Procede pour la separation du tetrachlorure d'hafnium du tetrachlorure de zirconium
US07/293,791 US5009751A (en)	1988-01-12	1989-01-05	Process for separation of hafnium tetrachloride from zirconium tetrachloride
AU28322/89A AU612452B2 (en)	1988-01-12	1989-01-09	A process for separation of hafnium tetrachloride from zirconium tetrachloride
FR898900263A FR2625739B1 (fr)	1988-01-12	1989-01-11	Procede de separation du tetrachlorure de hafnium d'avec du tetrachlorure de zirconium

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP63004416A JPH0624982B2 (ja)	1988-01-12	1988-01-12	四塩化ジルコニュウムと四塩化ハフニユウムを分離する方法

Publications (2)

Publication Number	Publication Date
JPH01179726A JPH01179726A (ja)	1989-07-17
JPH0624982B2 true JPH0624982B2 (ja)	1994-04-06

Family

ID=11583689

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP63004416A Expired - Lifetime JPH0624982B2 (ja)	1988-01-12	1988-01-12	四塩化ジルコニュウムと四塩化ハフニユウムを分離する方法

Country Status (5)

Country	Link
US (1)	US5009751A (fr)
JP (1)	JPH0624982B2 (fr)
AU (1)	AU612452B2 (fr)
CA (1)	CA1333781C (fr)
FR (1)	FR2625739B1 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH06104912B2 (ja) *	1988-04-01	1994-12-21	三菱原子燃料株式会社	四塩化ジルコニユウムと四塩化ハフニユウムを分離する方法及び電極
US4874475A (en) *	1988-09-12	1989-10-17	Westinghouse Electric Corp.	Molten salt extractive distillation process for zirconium-hafnium separation
FR2823740B1 (fr) *	2001-04-18	2004-02-06	Cezus Co Europ Zirconium	Procede de separation des tetrachlorures de zirconium et de hafnium
US20060062910A1 (en) *	2004-03-01	2006-03-23	Meiere Scott H	Low zirconium, hafnium-containing compositions, processes for the preparation thereof and methods of use thereof
US20050214458A1 (en) *	2004-03-01	2005-09-29	Meiere Scott H	Low zirconium hafnium halide compositions
FR2876369B1 (fr) *	2004-10-11	2006-12-22	Cie Europ Du Zirconium Cezus S	Procede de separation du zirconium et du hafnium
CN111041512A (zh) *	2019-12-25	2020-04-21	中国科学院高能物理研究所	一种变价金属的低价卤化物的制备方法
CN111249761B (zh) *	2020-03-04	2022-01-28	中国科学院上海应用物理研究所	一种熔盐蒸馏纯化方法及设备
CN116750793A (zh) *	2023-07-07	2023-09-15	朝阳东锆新材料有限公司	一种生产精四氯化锆的方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA627327A (en) *		1961-09-12	W. Ancrum Robert	Production of metallic halides
CA611153A (en) *		1960-12-20	W. Ancrum Robert	Electrolytic preparation of titanium tetrahalides
US679997A (en) *	1898-11-14	1901-08-06	Charles W Roepper	Electrolytic process of obtaining metals from their fused compounds.
GB708595A (en) *	1951-06-12	1954-05-05	Titan Co Inc	A method and apparatus for the purification of titanium tetrachloride
US2791485A (en) *	1952-12-03	1957-05-07	Commw Scient Ind Res Org	Process for removal of hafnium from zirconium-containing material
US2894886A (en) *	1954-07-16	1959-07-14	Horizons Titanium Corp	Fused salt bath for electrodeposition of transition metals
US2961293A (en) *	1957-02-19	1960-11-22	Mallory Sharon Metals Corp	Purification of hafnium tetrahalide
US3734689A (en) *	1969-02-07	1973-05-22	Wisconsin Alumni Res Found	Process for separation of hafnium from zirconium
US3600284A (en) *	1969-02-18	1971-08-17	Us Interior	Method of adding refractory metal halides to molten salt electrolytes
US3856477A (en) *	1970-12-28	1974-12-24	H Ishizuka	Process for refining zirconium tetrachloride containing hafnium tetrachloride
US3725221A (en) *	1972-01-26	1973-04-03	M Wong	Recovery of niobium and tantalum
FR2494727A1 (fr) *	1980-11-27	1982-05-28	Armand Marcel	Cellule pour la preparation de metaux polyvalents tels que zr ou hf par electrolyse d'halogenures fondus et procede de mise en oeuvre de cette cellule
JPS6044119A (ja) *	1983-08-19	1985-03-09	Sumitomo Metal Ind Ltd	可動スリ−ブ式圧延ロ−ルのスリ−ブ移動装置
FR2560896B1 (fr) *	1984-03-12	1989-10-20	Pechiney	Procede d'obtention d'un metal par electrolyse d'halogenures en bain de sels fondus comportant un double depot simultane et continu et dispositifs d'application
US4578252A (en) *	1985-05-14	1986-03-25	Hughes Aircraft Company	Method for preparing ultra-pure zirconium and hafnium tetrafluorides
JPH0633476B2 (ja) *	1987-05-27	1994-05-02	三菱原子燃料株式会社	融解塩電解によるジルコニユウムとハフニユウムの分離方法
JPH06104912B2 (ja) *	1988-04-01	1994-12-21	三菱原子燃料株式会社	四塩化ジルコニユウムと四塩化ハフニユウムを分離する方法及び電極
US4874475A (en) *	1988-09-12	1989-10-17	Westinghouse Electric Corp.	Molten salt extractive distillation process for zirconium-hafnium separation
US4865695A (en) *	1988-09-12	1989-09-12	Westinghouse Electric Corp.	Preparation of complexes of zirconium and hafnium tetrachlorides with phosphorus oxychloride

1988
- 1988-01-12 JP JP63004416A patent/JPH0624982B2/ja not_active Expired - Lifetime
- 1988-12-28 CA CA000587064A patent/CA1333781C/fr not_active Expired - Fee Related
1989
- 1989-01-05 US US07/293,791 patent/US5009751A/en not_active Expired - Fee Related
- 1989-01-09 AU AU28322/89A patent/AU612452B2/en not_active Ceased
- 1989-01-11 FR FR898900263A patent/FR2625739B1/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
FR2625739A1 (fr)	1989-07-13
US5009751A (en)	1991-04-23
CA1333781C (fr)	1995-01-03
AU2832289A (en)	1989-07-13
AU612452B2 (en)	1991-07-11
JPH01179726A (ja)	1989-07-17
FR2625739B1 (fr)	1991-10-25

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