JPH0812390B2 - ハロゲン化銀写真乳剤 - Google Patents
ハロゲン化銀写真乳剤Info
- Publication number
- JPH0812390B2 JPH0812390B2 JP20604386A JP20604386A JPH0812390B2 JP H0812390 B2 JPH0812390 B2 JP H0812390B2 JP 20604386 A JP20604386 A JP 20604386A JP 20604386 A JP20604386 A JP 20604386A JP H0812390 B2 JPH0812390 B2 JP H0812390B2
- Authority
- JP
- Japan
- Prior art keywords
- emulsion
- silver halide
- silver
- crystal
- grain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 Silver halide Chemical class 0.000 title claims description 200
- 239000000839 emulsion Substances 0.000 title claims description 193
- 229910052709 silver Inorganic materials 0.000 title claims description 190
- 239000004332 silver Substances 0.000 title claims description 190
- 239000013078 crystal Substances 0.000 claims description 210
- 230000005855 radiation Effects 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 14
- 239000002245 particle Substances 0.000 description 98
- 230000012010 growth Effects 0.000 description 75
- 239000003607 modifier Substances 0.000 description 60
- 239000000975 dye Substances 0.000 description 47
- 150000001875 compounds Chemical class 0.000 description 46
- 239000010410 layer Substances 0.000 description 43
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 43
- 239000002585 base Substances 0.000 description 42
- 238000001556 precipitation Methods 0.000 description 39
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 35
- 230000003595 spectral effect Effects 0.000 description 32
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 31
- 230000001235 sensitizing effect Effects 0.000 description 31
- 239000000243 solution Substances 0.000 description 31
- 229910052736 halogen Inorganic materials 0.000 description 25
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
- 230000015572 biosynthetic process Effects 0.000 description 24
- 238000000635 electron micrograph Methods 0.000 description 24
- 108010010803 Gelatin Proteins 0.000 description 23
- 229920000159 gelatin Polymers 0.000 description 23
- 239000008273 gelatin Substances 0.000 description 23
- 235000019322 gelatine Nutrition 0.000 description 23
- 235000011852 gelatine desserts Nutrition 0.000 description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- 238000011160 research Methods 0.000 description 20
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 18
- 238000002360 preparation method Methods 0.000 description 17
- 238000000034 method Methods 0.000 description 15
- 230000035945 sensitivity Effects 0.000 description 15
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 15
- 238000000151 deposition Methods 0.000 description 14
- 101710134784 Agnoprotein Proteins 0.000 description 13
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 13
- 230000008021 deposition Effects 0.000 description 13
- 150000002500 ions Chemical class 0.000 description 13
- 229910021607 Silver chloride Inorganic materials 0.000 description 10
- 230000008901 benefit Effects 0.000 description 10
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 10
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 9
- 229910052794 bromium Inorganic materials 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000002344 surface layer Substances 0.000 description 9
- 238000001179 sorption measurement Methods 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 7
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 7
- 238000003384 imaging method Methods 0.000 description 7
- 239000003381 stabilizer Substances 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 6
- 238000001228 spectrum Methods 0.000 description 6
- 230000007704 transition Effects 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 206010070834 Sensitisation Diseases 0.000 description 5
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 210000000988 bone and bone Anatomy 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000001788 irregular Effects 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- 230000008313 sensitization Effects 0.000 description 5
- 238000013459 approach Methods 0.000 description 4
- 238000000149 argon plasma sintering Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 238000002050 diffraction method Methods 0.000 description 4
- 238000001493 electron microscopy Methods 0.000 description 4
- 230000003993 interaction Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- INVVMIXYILXINW-UHFFFAOYSA-N 5-methyl-1h-[1,2,4]triazolo[1,5-a]pyrimidin-7-one Chemical compound CC1=CC(=O)N2NC=NC2=N1 INVVMIXYILXINW-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229940006460 bromide ion Drugs 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010894 electron beam technology Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000000386 microscopy Methods 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- OXFSTTJBVAAALW-UHFFFAOYSA-N 1,3-dihydroimidazole-2-thione Chemical class SC1=NC=CN1 OXFSTTJBVAAALW-UHFFFAOYSA-N 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229910021612 Silver iodide Inorganic materials 0.000 description 2
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 2
- 241000276425 Xiphophorus maculatus Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 235000021028 berry Nutrition 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000002612 dispersion medium Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 230000007773 growth pattern Effects 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229940045105 silver iodide Drugs 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000006557 surface reaction Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 239000013598 vector Substances 0.000 description 2
- 238000011179 visual inspection Methods 0.000 description 2
- IHKFGLYNWLIHOK-UHFFFAOYSA-N 1-dodecylquinolin-1-ium Chemical compound C1=CC=C2[N+](CCCCCCCCCCCC)=CC=CC2=C1 IHKFGLYNWLIHOK-UHFFFAOYSA-N 0.000 description 1
- KWOPWPWSHCGQMK-UHFFFAOYSA-M 1-dodecylquinolin-1-ium;bromide Chemical compound [Br-].C1=CC=C2[N+](CCCCCCCCCCCC)=CC=CC2=C1 KWOPWPWSHCGQMK-UHFFFAOYSA-M 0.000 description 1
- KRTDQDCPEZRVGC-UHFFFAOYSA-N 2-nitro-1h-benzimidazole Chemical compound C1=CC=C2NC([N+](=O)[O-])=NC2=C1 KRTDQDCPEZRVGC-UHFFFAOYSA-N 0.000 description 1
- XPAZGLFMMUODDK-UHFFFAOYSA-N 6-nitro-1h-benzimidazole Chemical compound [O-][N+](=O)C1=CC=C2N=CNC2=C1 XPAZGLFMMUODDK-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 229940090898 Desensitizer Drugs 0.000 description 1
- 229920002307 Dextran Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 244000151018 Maranta arundinacea Species 0.000 description 1
- 235000010804 Maranta arundinacea Nutrition 0.000 description 1
- ATSUZWSBVKDCRP-UHFFFAOYSA-N N1=C(C)C=C(O)N2N=C(SC)N=C21 Chemical compound N1=C(C)C=C(O)N2N=C(SC)N=C21 ATSUZWSBVKDCRP-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 241000700159 Rattus Species 0.000 description 1
- YASAKCUCGLMORW-UHFFFAOYSA-N Rosiglitazone Chemical compound C=1C=CC=NC=1N(C)CCOC(C=C1)=CC=C1CC1SC(=O)NC1=O YASAKCUCGLMORW-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical class [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 235000012419 Thalia geniculata Nutrition 0.000 description 1
- 241000534944 Thia Species 0.000 description 1
- 229920002494 Zein Polymers 0.000 description 1
- RVUMMKAOECEYND-UHFFFAOYSA-N [Na].Cc1cc(O)n2ncnc2n1 Chemical compound [Na].Cc1cc(O)n2ncnc2n1 RVUMMKAOECEYND-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000003190 augmentative effect Effects 0.000 description 1
- WLZRMCYVCSSEQC-UHFFFAOYSA-N cadmium(2+) Chemical compound [Cd+2] WLZRMCYVCSSEQC-UHFFFAOYSA-N 0.000 description 1
- 239000000298 carbocyanine Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229910052798 chalcogen Inorganic materials 0.000 description 1
- 150000001787 chalcogens Chemical class 0.000 description 1
- 230000005591 charge neutralization Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000012866 crystallographic experiment Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000003398 denaturant Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000586 desensitisation Methods 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- IBIKHMZPHNKTHM-RDTXWAMCSA-N merck compound 25 Chemical compound C1C[C@@H](C(O)=O)[C@H](O)CN1C(C1=C(F)C=CC=C11)=NN1C(=O)C1=C(Cl)C=CC=C1C1CC1 IBIKHMZPHNKTHM-RDTXWAMCSA-N 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 210000004088 microvessel Anatomy 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- QWYZFXLSWMXLDM-UHFFFAOYSA-M pinacyanol iodide Chemical compound [I-].C1=CC2=CC=CC=C2N(CC)C1=CC=CC1=CC=C(C=CC=C2)C2=[N+]1CC QWYZFXLSWMXLDM-UHFFFAOYSA-M 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 239000000837 restrainer Substances 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000005019 zein Substances 0.000 description 1
- 229940093612 zein Drugs 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/0051—Tabular grain emulsions
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/04—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with macromolecular additives; with layer-forming substances
- G03C1/047—Proteins, e.g. gelatine derivatives; Hydrolysis or extraction products of proteins
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/07—Substances influencing grain growth during silver salt formation
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/0051—Tabular grain emulsions
- G03C2001/0055—Aspect ratio of tabular grains in general; High aspect ratio; Intermediate aspect ratio; Low aspect ratio
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
- G03C2001/03511—Bromide content
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C2200/00—Details
- G03C2200/03—111 crystal face
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/772,271 US4643966A (en) | 1985-09-03 | 1985-09-03 | Emulsions and photographic elements containing ruffled silver halide grains |
| US81113285A | 1985-12-19 | 1985-12-19 | |
| US81113385A | 1985-12-19 | 1985-12-19 | |
| US811132 | 1985-12-19 | ||
| US811133 | 1985-12-19 | ||
| US772271 | 1985-12-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62124552A JPS62124552A (ja) | 1987-06-05 |
| JPH0812390B2 true JPH0812390B2 (ja) | 1996-02-07 |
Family
ID=27419684
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20604386A Expired - Lifetime JPH0812390B2 (ja) | 1985-09-03 | 1986-09-03 | ハロゲン化銀写真乳剤 |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0215612B1 (fr) |
| JP (1) | JPH0812390B2 (fr) |
| CA (1) | CA1280312C (fr) |
| DE (1) | DE3687808T2 (fr) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1189111B (it) * | 1986-05-08 | 1988-01-28 | Minnesota Mining & Mfg | Elementi radiografici con un ridotto cross-over e ridotta colorazione residua |
| JP2631720B2 (ja) * | 1988-10-31 | 1997-07-16 | コニカ株式会社 | ハロゲン化銀結晶粒子及びハロゲン化銀感光材料 |
| JP2767493B2 (ja) * | 1990-11-14 | 1998-06-18 | 富士写真フイルム株式会社 | ハロゲン化銀乳剤 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE342528A (fr) | 1926-05-20 | |||
| GB504283A (en) | 1937-10-21 | 1939-04-21 | Kodak Ltd | Improvements in or relating to light-sensitive or image-bearing layers |
| BE530381A (fr) | 1953-07-16 | |||
| US3140179A (en) | 1959-10-22 | 1964-07-07 | Eastman Kodak Co | Photographic element having increased speed and contrast |
| US3206313A (en) | 1961-05-15 | 1965-09-14 | Eastman Kodak Co | Chemically sensitized emulsions having low surface sensitivity and high internal sensitivity |
| US3367778A (en) | 1965-04-15 | 1968-02-06 | Eastman Kodak Co | Silver salt direct positive emulsion |
| US3317322A (en) | 1965-08-27 | 1967-05-02 | Eastman Kodak Co | Photographic emulsions having high internal sensitivity |
| US3519426A (en) | 1966-12-27 | 1970-07-07 | Eastman Kodak Co | Preparation of silver halide emulsions having high covering power |
| US3761276A (en) | 1971-03-10 | 1973-09-25 | Eastman Kodak Co | Photographic element containing monodispersed unfogged silver halide grains chemically sensitized internally and externally |
| GB1376443A (en) | 1971-05-11 | 1974-12-04 | Agfa Gevaert | Manufacture of photographic silver halide materials |
| BE787868A (fr) | 1971-09-03 | 1973-02-23 | Agfa Gevaert Nv | Procede voor de vervaardiging van een voor vlekken ongevoelige fotografische zilverhalogenideemulsie |
| US4011083A (en) * | 1974-12-10 | 1977-03-08 | Eastman Kodak Company | Surface sensitive silver halide emulsion containing a silver complexing azaindene to reduce desensitization of optical sensitizing dye incorporated therein |
| US3989527A (en) | 1975-01-08 | 1976-11-02 | Eastman Kodak Company | Silver halide photographic element containing blended grains |
| US4183756A (en) | 1978-05-03 | 1980-01-15 | Eastman Kodak Company | Pre-precipitation spectral sensitizing dye addition process |
| US4225666A (en) | 1979-02-02 | 1980-09-30 | Eastman Kodak Company | Silver halide precipitation and methine dye spectral sensitization process and products thereof |
| US4349622A (en) | 1979-06-01 | 1982-09-14 | Konishiroku Photo Industry Co., Ltd. | Photographic silver halide emulsion comprising epitaxial composite silver halide crystals, silver iodobromide emulsion and process for preparing the same |
| US4387154A (en) | 1980-09-08 | 1983-06-07 | Eastman Kodak Company | Receivers with nonplanar support elements |
| JPS6054662B2 (ja) | 1981-09-28 | 1985-11-30 | 富士写真フイルム株式会社 | ハロゲン化銀乳剤 |
| US4400463A (en) | 1981-11-12 | 1983-08-23 | Eastman Kodak Company | Silver chloride emulsions of modified crystal habit and processes for their preparation |
| US4414306A (en) | 1981-11-12 | 1983-11-08 | Eastman Kodak Company | Silver chlorobromide emulsions and processes for their preparation |
| US4425425A (en) | 1981-11-12 | 1984-01-10 | Eastman Kodak Company | Radiographic elements exhibiting reduced crossover |
| US4386156A (en) | 1981-11-12 | 1983-05-31 | Eastman Kodak Company | Silver bromide emulsions of narrow grain size distribution and processes for their preparation |
| US4433048A (en) | 1981-11-12 | 1984-02-21 | Eastman Kodak Company | Radiation-sensitive silver bromoiodide emulsions, photographic elements, and processes for their use |
| US4399215A (en) | 1981-11-12 | 1983-08-16 | Eastman Kodak Company | Double-jet precipitation processes and products thereof |
| US4434226A (en) | 1981-11-12 | 1984-02-28 | Eastman Kodak Company | High aspect ratio silver bromoiodide emulsions and processes for their preparation |
| US4414304A (en) | 1981-11-12 | 1983-11-08 | Eastman Kodak Company | Forehardened high aspect ratio silver halide photographic elements and processes for their use |
| US4439520A (en) | 1981-11-12 | 1984-03-27 | Eastman Kodak Company | Sensitized high aspect ratio silver halide emulsions and photographic elements |
| US4435501A (en) | 1981-11-12 | 1984-03-06 | Eastman Kodak Company | Controlled site epitaxial sensitization |
| US4414310A (en) | 1981-11-12 | 1983-11-08 | Eastman Kodak Company | Process for the preparation of high aspect ratio silver bromoiodide emulsions |
| US4504570A (en) | 1982-09-30 | 1985-03-12 | Eastman Kodak Company | Direct reversal emulsions and photographic elements useful in image transfer film units |
| US4478929A (en) | 1982-09-30 | 1984-10-23 | Eastman Kodak Company | Dye image transfer film unit with tabular silver halide |
| US4463087A (en) | 1982-12-20 | 1984-07-31 | Eastman Kodak Company | Controlled site epitaxial sensitization of limited iodide silver halide emulsions |
-
1986
- 1986-08-14 CA CA000515953A patent/CA1280312C/fr not_active Expired - Fee Related
- 1986-09-03 JP JP20604386A patent/JPH0812390B2/ja not_active Expired - Lifetime
- 1986-09-03 EP EP19860306797 patent/EP0215612B1/fr not_active Expired - Lifetime
- 1986-09-03 DE DE19863687808 patent/DE3687808T2/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0215612A2 (fr) | 1987-03-25 |
| EP0215612B1 (fr) | 1993-02-24 |
| EP0215612A3 (en) | 1988-11-30 |
| JPS62124552A (ja) | 1987-06-05 |
| CA1280312C (fr) | 1991-02-19 |
| DE3687808T2 (de) | 1993-09-02 |
| DE3687808D1 (de) | 1993-04-01 |
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