JPH0816128B1 - - Google Patents

Info

Publication number
JPH0816128B1
JPH0816128B1 JP63500755A JP50075588A JPH0816128B1 JP H0816128 B1 JPH0816128 B1 JP H0816128B1 JP 63500755 A JP63500755 A JP 63500755A JP 50075588 A JP50075588 A JP 50075588A JP H0816128 B1 JPH0816128 B1 JP H0816128B1
Authority
JP
Japan
Prior art keywords
transition metal
group
aluminoxane
cycloalkadienyl
compd
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63500755A
Other languages
English (en)
Other versions
JPWO1988005058A1 (ja
JPH0816128B2 (ja
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of JPWO1988005058A1 publication Critical patent/JPWO1988005058A1/ja
Publication of JPH0816128B2 publication Critical patent/JPH0816128B2/ja
Publication of JPH0816128B1 publication Critical patent/JPH0816128B1/ja
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP63-500755A 1986-12-30 1987-12-28 オレフイン重合用固体触媒およびその製造法 Expired - Lifetime JPH0816128B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP61-311286 1986-12-30
JP31128686 1986-12-30
JP31128786 1986-12-30
JP61-311287 1986-12-30
PCT/JP1987/001047 WO1988005058A1 (fr) 1986-12-30 1987-12-28 Catalyseur a l'etat solide pour la polymerisation d'olefines et procede de preparation

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP9041455A Division JP2889205B2 (ja) 1986-12-30 1997-02-10 オレフイン重合用固体触媒およびそれを用いるオレフイン重合体の製造方法

Publications (3)

Publication Number Publication Date
JPWO1988005058A1 JPWO1988005058A1 (ja) 1988-10-06
JPH0816128B2 JPH0816128B2 (ja) 1996-02-21
JPH0816128B1 true JPH0816128B1 (ja) 1996-02-21

Family

ID=

Also Published As

Publication number Publication date
DE3789666T2 (de) 1994-08-04
EP0295312B1 (en) 1994-04-20
JP2889205B2 (ja) 1999-05-10
WO1988005058A1 (fr) 1988-07-14
EP0295312A4 (en) 1989-05-16
DE3789666D1 (de) 1994-05-26
JPH09176224A (ja) 1997-07-08
ATE104682T1 (de) 1994-05-15
KR910008277B1 (ko) 1991-10-12
EP0295312A1 (en) 1988-12-21
US4921825A (en) 1990-05-01
KR890700138A (ko) 1989-03-10

Similar Documents

Publication Publication Date Title
EP0295312A4 (en) SOLID STATE CATALYST FOR POLYMERIZATION OF OLEFINS AND METHOD OF PREPARATION.
KR890700135A (ko) 올레핀중합용 촉매 및 그 제조법
CA1307516C (en) Process for producing solid catalyst for polymerization of olefins
ES8603511A1 (es) Un procedimiento para preparar catalizadores soportados adecuados para polimerizar olefinas
MY101752A (en) Process for the preparation of a fischer-tropsch catalyst, a catalyst so prepared and use of this catalyst in the preparation of hydrocarbons
EP0279863A4 (en) Catalyst for polymerizing alpha-olefin and polymerization process.
JPS6445406A (en) Polymerization of ethylene
IL110219A0 (en) Supported catalysts for the polymerization of olefins and their preparation
EP0372979A3 (en) Hole transporting material
AU4149193A (en) Metallocenes containing aryl-substituted indenyl derivatives as ligands, process for their preparation, and their use as catalysts
HU896859D0 (en) Process for producing polyethylene wax by means of polymerization of gas phase
CA2155621A1 (en) Olefin Polymerization Catalyst and Process for Olefin Polymerization
KR880004003A (ko) 교차-결합된 오르가노실라잔 중합체
EP0587440A2 (en) Catalyst component for the polymerisation of olefins and process for preparing olefin polymers using same
EP0906914A3 (en) Solid aluminoxane for catalyst carrier, process for preparing the same, and uses thereof
TW363985B (en) Metallocene compound
JPS56155205A (en) Production of polyolefin
DE3274647D1 (en) A catalyst for polymerization of olefins
JPS5647408A (en) Polymerization of olefin
KR910000756A (ko) 알룸옥산의 비수성 제조방법
FR2451924B1 (ja)
KR880701742A (ko) α-올레핀의 중합용 촉매 및 중합법
KR960022583A (ko) 폴리올레핀 피복의 제조방법, 상기 피복이 제공된 기판, 및 이동분말과의 접촉용 용도
JPS6424806A (en) Catalyst for polymerizing olefin
JPS57209902A (en) Catalyst for olefin polymerization

Legal Events

Date Code Title Description
EXPY Cancellation because of completion of term