JPH1046194A - 漂白活性化剤としてのシアノピリジニウム化合物 - Google Patents

漂白活性化剤としてのシアノピリジニウム化合物

Info

Publication number: JPH1046194A
Authority: JP; Japan
Prior art keywords: alkyl; weight; composition according; amount; bleach activator
Prior art date: 1996-05-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

JP11715297A

Other languages

English (en)

Japanese (ja)

Inventor

Matthias Dr Loeffler

マッテイアス・レッフラー

Bernhard Dr Mees

ベルンハルト・メッス

Gerd Dr Reinhardt

ゲルト・ラインハルト

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Hoechst AG

Original Assignee

Hoechst AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-05-08

Filing date

1997-05-07

Publication date

1998-02-17

1997-05-07 Application filed by Hoechst AG filed Critical Hoechst AG

1998-02-17 Publication of JPH1046194A publication Critical patent/JPH1046194A/ja

Status Withdrawn legal-status Critical Current

Links

239000012190 activator Substances 0.000 title claims abstract description 40
-1 Cyanopyridinium compound Chemical class 0.000 title claims abstract description 32
238000004061 bleaching Methods 0.000 title claims abstract description 19
125000004093 cyano group Chemical group *C#N 0.000 claims abstract description 9
125000003118 aryl group Chemical group 0.000 claims abstract description 7
238000000034 method Methods 0.000 claims abstract description 6
150000001450 anions Chemical group 0.000 claims abstract description 4
239000007844 bleaching agent Substances 0.000 claims description 35
239000000203 mixture Substances 0.000 claims description 34
239000003599 detergent Substances 0.000 claims description 21
150000001875 compounds Chemical class 0.000 claims description 17
239000000344 soap Substances 0.000 claims description 9
239000001257 hydrogen Substances 0.000 claims description 8
229910052739 hydrogen Inorganic materials 0.000 claims description 8
239000004094 surface-active agent Substances 0.000 claims description 5
238000005406 washing Methods 0.000 claims description 5
125000006656 (C2-C4) alkenyl group Chemical group 0.000 claims description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
230000000694 effects Effects 0.000 claims description 4
150000002431 hydrogen Chemical class 0.000 claims description 4
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
102000004190 Enzymes Human genes 0.000 claims description 3
108090000790 Enzymes Proteins 0.000 claims description 3
229910019142 PO4 Inorganic materials 0.000 claims description 3
229940088598 enzyme Drugs 0.000 claims description 3
125000005342 perphosphate group Chemical group 0.000 claims description 3
HKDBAJMMXFKTMM-UHFFFAOYSA-M 1-ethylpyridin-1-ium-4-carbonitrile;chloride Chemical compound [Cl-].CC[N+]1=CC=C(C#N)C=C1 HKDBAJMMXFKTMM-UHFFFAOYSA-M 0.000 claims description 2
PYELEJKETYDRGH-UHFFFAOYSA-M 1-hexylpyridin-1-ium-4-carbonitrile;chloride Chemical compound [Cl-].CCCCCC[N+]1=CC=C(C#N)C=C1 PYELEJKETYDRGH-UHFFFAOYSA-M 0.000 claims description 2
DLMHDPRZMAVGGG-UHFFFAOYSA-M 1-methylpyridin-1-ium-4-carbonitrile;chloride Chemical compound [Cl-].C[N+]1=CC=C(C#N)C=C1 DLMHDPRZMAVGGG-UHFFFAOYSA-M 0.000 claims description 2
FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 claims description 2
102000013142 Amylases Human genes 0.000 claims description 2
108010065511 Amylases Proteins 0.000 claims description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical group [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 2
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical group [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 2
239000004367 Lipase Substances 0.000 claims description 2
102000004882 Lipase Human genes 0.000 claims description 2
108090001060 Lipase Proteins 0.000 claims description 2
AFVFQIVMOAPDHO-UHFFFAOYSA-M Methanesulfonate Chemical compound CS([O-])(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-M 0.000 claims description 2
229910002651 NO3 Inorganic materials 0.000 claims description 2
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
108091005804 Peptidases Proteins 0.000 claims description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 claims description 2
239000004365 Protease Substances 0.000 claims description 2
235000019418 amylase Nutrition 0.000 claims description 2
239000012459 cleaning agent Substances 0.000 claims description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 claims description 2
XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims description 2
235000011180 diphosphates Nutrition 0.000 claims description 2
YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 claims description 2
229940071161 dodecylbenzenesulfonate Drugs 0.000 claims description 2
CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 claims description 2
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical group I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 2
QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical group OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims description 2
235000019421 lipase Nutrition 0.000 claims description 2
125000005341 metaphosphate group Chemical group 0.000 claims description 2
OPUAWDUYWRUIIL-UHFFFAOYSA-L methanedisulfonate Chemical compound [O-]S(=O)(=O)CS([O-])(=O)=O OPUAWDUYWRUIIL-UHFFFAOYSA-L 0.000 claims description 2
YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 claims description 2
229910052757 nitrogen Inorganic materials 0.000 claims description 2
125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
239000010452 phosphate Substances 0.000 claims description 2
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 2
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 2
AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 claims description 2
239000004382 Amylase Substances 0.000 claims 1
108010059892 Cellulase Proteins 0.000 claims 1
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims 1
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
229940106157 cellulase Drugs 0.000 claims 1
150000003841 chloride salts Chemical group 0.000 claims 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
229910010272 inorganic material Inorganic materials 0.000 claims 1
239000011147 inorganic material Substances 0.000 claims 1
239000011368 organic material Substances 0.000 claims 1
AHKZTVQIVOEVFO-UHFFFAOYSA-N oxide(2-) Chemical compound [O-2] AHKZTVQIVOEVFO-UHFFFAOYSA-N 0.000 claims 1
125000000217 alkyl group Chemical group 0.000 abstract description 15
FKNQCJSGGFJEIZ-UHFFFAOYSA-N 4-methylpyridine Chemical compound CC1=CC=NC=C1 FKNQCJSGGFJEIZ-UHFFFAOYSA-N 0.000 abstract description 6
GPHQHTOMRSGBNZ-UHFFFAOYSA-N pyridine-4-carbonitrile Chemical compound N#CC1=CC=NC=C1 GPHQHTOMRSGBNZ-UHFFFAOYSA-N 0.000 abstract description 6
NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 abstract description 4
239000000835 fiber Substances 0.000 abstract description 4
125000003342 alkenyl group Chemical group 0.000 abstract description 3
230000029936 alkylation Effects 0.000 abstract description 2
238000005804 alkylation reaction Methods 0.000 abstract description 2
239000003795 chemical substances by application Substances 0.000 abstract description 2
VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 abstract description 2
229940050176 methyl chloride Drugs 0.000 abstract description 2
230000003647 oxidation Effects 0.000 abstract description 2
238000007254 oxidation reaction Methods 0.000 abstract description 2
230000011987 methylation Effects 0.000 abstract 1
238000007069 methylation reaction Methods 0.000 abstract 1
239000000126 substance Substances 0.000 description 11
229910052708 sodium Inorganic materials 0.000 description 9
239000011734 sodium Substances 0.000 description 9
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
239000007788 liquid Substances 0.000 description 7
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
239000003945 anionic surfactant Substances 0.000 description 6
239000000194 fatty acid Substances 0.000 description 6
239000007795 chemical reaction product Substances 0.000 description 5
235000014113 dietary fatty acids Nutrition 0.000 description 5
229930195729 fatty acid Natural products 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
229910052783 alkali metal Inorganic materials 0.000 description 4
125000000129 anionic group Chemical group 0.000 description 4
150000004665 fatty acids Chemical class 0.000 description 4
239000008187 granular material Substances 0.000 description 4
CSPHPKQCLCBONW-UHFFFAOYSA-N pyridin-1-ium-1-carbonitrile Chemical class N#C[N+]1=CC=CC=C1 CSPHPKQCLCBONW-UHFFFAOYSA-N 0.000 description 4
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 4
XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
150000001298 alcohols Chemical class 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
239000004744 fabric Substances 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
239000002736 nonionic surfactant Substances 0.000 description 3
150000004965 peroxy acids Chemical class 0.000 description 3
125000000864 peroxy group Chemical group O(O*)* 0.000 description 3
239000002243 precursor Substances 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
239000007787 solid Substances 0.000 description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
102000005701 Calcium-Binding Proteins Human genes 0.000 description 2
108010045403 Calcium-Binding Proteins Proteins 0.000 description 2
244000060011 Cocos nucifera Species 0.000 description 2
235000013162 Cocos nucifera Nutrition 0.000 description 2
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical class [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
244000269722 Thea sinensis Species 0.000 description 2
239000001083 [(2R,3R,4S,5R)-1,2,4,5-tetraacetyloxy-6-oxohexan-3-yl] acetate Substances 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
239000011575 calcium Substances 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
125000002091 cationic group Chemical group 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
239000013256 coordination polymer Substances 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
239000006260 foam Substances 0.000 description 2
230000007062 hydrolysis Effects 0.000 description 2
238000006460 hydrolysis reaction Methods 0.000 description 2
239000003112 inhibitor Substances 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
150000002978 peroxides Chemical class 0.000 description 2
235000021317 phosphate Nutrition 0.000 description 2
239000000047 product Substances 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
229910052938 sodium sulfate Inorganic materials 0.000 description 2
235000011152 sodium sulphate Nutrition 0.000 description 2
239000007790 solid phase Substances 0.000 description 2
150000003871 sulfonates Chemical class 0.000 description 2
150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
239000004753 textile Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
239000004711 α-olefin Substances 0.000 description 2
125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical compound OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
HLNJFEXZDGURGZ-UHFFFAOYSA-M 1-methylpyridin-1-ium;iodide Chemical compound [I-].C[N+]1=CC=CC=C1 HLNJFEXZDGURGZ-UHFFFAOYSA-M 0.000 description 1
CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
YTWUZAQZEVOPGG-UHFFFAOYSA-N 3-acetyl-1-phenylimidazolidine-2,4-dione Chemical compound O=C1N(C(=O)C)C(=O)CN1C1=CC=CC=C1 YTWUZAQZEVOPGG-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
244000025254 Cannabis sativa Species 0.000 description 1
102000005575 Cellulases Human genes 0.000 description 1
108010084185 Cellulases Proteins 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
239000000253 Denture Cleanser Substances 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 1
SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical class CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
235000019482 Palm oil Nutrition 0.000 description 1
102000035195 Peptidases Human genes 0.000 description 1
229930182556 Polyacetal Natural products 0.000 description 1
229920000388 Polyphosphate Polymers 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
101100386054 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) CYS3 gene Proteins 0.000 description 1
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
235000006468 Thea sinensis Nutrition 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 1
ZYPMNZKYVVSXOJ-YNEHKIRRSA-N [(2r,3s,4r)-2,3,4-triacetyloxy-5-oxopentyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O ZYPMNZKYVVSXOJ-YNEHKIRRSA-N 0.000 description 1
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000004973 alkali metal peroxides Chemical class 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
229920013820 alkyl cellulose Polymers 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
229940025131 amylases Drugs 0.000 description 1
XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
235000020279 black tea Nutrition 0.000 description 1
ONANWDUDFJIIGP-UHFFFAOYSA-N carbamoyl carbamoperoxoate Chemical compound NC(=O)OOC(N)=O ONANWDUDFJIIGP-UHFFFAOYSA-N 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000003086 colorant Substances 0.000 description 1
229940126214 compound 3 Drugs 0.000 description 1
238000001816 cooling Methods 0.000 description 1
235000021438 curry Nutrition 0.000 description 1
239000000645 desinfectant Substances 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
238000004851 dishwashing Methods 0.000 description 1
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
229940043264 dodecyl sulfate Drugs 0.000 description 1
238000007580 dry-mixing Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
230000032050 esterification Effects 0.000 description 1
238000005886 esterification reaction Methods 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
239000002657 fibrous material Substances 0.000 description 1
239000004088 foaming agent Substances 0.000 description 1
239000003205 fragrance Substances 0.000 description 1
239000008233 hard water Substances 0.000 description 1
150000002432 hydroperoxides Chemical class 0.000 description 1
239000002563 ionic surfactant Substances 0.000 description 1
229940045996 isethionic acid Drugs 0.000 description 1
229940057995 liquid paraffin Drugs 0.000 description 1
150000004668 long chain fatty acids Chemical class 0.000 description 1
239000000463 material Substances 0.000 description 1
VUQUOGPMUUJORT-UHFFFAOYSA-N methyl 4-methylbenzenesulfonate Chemical compound COS(=O)(=O)C1=CC=C(C)C=C1 VUQUOGPMUUJORT-UHFFFAOYSA-N 0.000 description 1
239000012022 methylating agents‎ Substances 0.000 description 1
229930014626 natural product Natural products 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
150000002825 nitriles Chemical group 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
150000004028 organic sulfates Chemical class 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
239000002540 palm oil Substances 0.000 description 1
235000011837 pasties Nutrition 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920005862 polyol Polymers 0.000 description 1
150000003077 polyols Chemical class 0.000 description 1
229920006324 polyoxymethylene Polymers 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
230000008092 positive effect Effects 0.000 description 1
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
PHIMXFJEDZOCMI-UHFFFAOYSA-M sodium;2-hexanoyloxy-3,4,5-trimethylbenzenesulfonate Chemical compound [Na+].CCCCCC(=O)OC1=C(C)C(C)=C(C)C=C1S([O-])(=O)=O PHIMXFJEDZOCMI-UHFFFAOYSA-M 0.000 description 1
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
OVONNAXAHAIEDF-UHFFFAOYSA-M sodium;4-benzoyloxybenzenesulfonate Chemical compound [Na+].C1=CC(S(=O)(=O)[O-])=CC=C1OC(=O)C1=CC=CC=C1 OVONNAXAHAIEDF-UHFFFAOYSA-M 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
101150035983 str1 gene Proteins 0.000 description 1
125000000547 substituted alkyl group Chemical group 0.000 description 1
230000019635 sulfation Effects 0.000 description 1
238000005670 sulfation reaction Methods 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
150000003462 sulfoxides Chemical class 0.000 description 1
239000003760 tallow Substances 0.000 description 1
235000013616 tea Nutrition 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
- C11D3/392—Heterocyclic compounds, e.g. cyclic imides or lactames

Landscapes

Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)
Pyridine Compounds (AREA)

JP11715297A 1996-05-08 1997-05-07 漂白活性化剤としてのシアノピリジニウム化合物 Withdrawn JPH1046194A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE1996118408 DE19618408A1 (de)	1996-05-08	1996-05-08	Cyanopyridinium-Verbindungen als Bleichaktivatoren
DE19618408:8		1996-05-08

Publications (1)

Publication Number	Publication Date
JPH1046194A true JPH1046194A (ja)	1998-02-17

Family

ID=7793653

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP11715297A Withdrawn JPH1046194A (ja)	1996-05-08	1997-05-07	漂白活性化剤としてのシアノピリジニウム化合物

Country Status (3)

Country	Link
EP (1)	EP0806473A3 (fr)
JP (1)	JPH1046194A (fr)
DE (1)	DE19618408A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2023199938A1 (fr) *	2022-04-13	2023-10-19	花王株式会社	Nouveau composé de pyridinium

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE102006041292A1 (de) *	2006-09-01	2008-03-06	Henkel Kgaa	Wasserstoffperoxid-Aktivierung mit N-Heterocyclen

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB2175621B (en) *	1985-05-28	1989-07-05	Lion Corp	Bleaching compositions
JPS63220135A (ja) *	1987-03-09	1988-09-13	Mitsubishi Paper Mills Ltd	直接ポジ用ハロゲン化銀写真乳剤
US4915863A (en) *	1987-08-14	1990-04-10	Kao Corporation	Bleaching composition
DE19605526A1 (de) *	1996-02-15	1997-08-21	Hoechst Ag	Ammoniumnitrile und deren Verwendung als Bleichaktivatoren
US5739096A (en) *	1996-05-06	1998-04-14	S. C. Johnson & Son, Inc.	Cyanopyridine N-oxide peroxide bleach activators

1996
- 1996-05-08 DE DE1996118408 patent/DE19618408A1/de not_active Withdrawn
1997
- 1997-04-29 EP EP97107051A patent/EP0806473A3/fr not_active Withdrawn
- 1997-05-07 JP JP11715297A patent/JPH1046194A/ja not_active Withdrawn

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2023199938A1 (fr) *	2022-04-13	2023-10-19	花王株式会社	Nouveau composé de pyridinium

Also Published As

Publication number	Publication date
DE19618408A1 (de)	1997-11-13
EP0806473A3 (fr)	1998-12-23
EP0806473A2 (fr)	1997-11-12

Legal Events

Date

Code

Title

Description

2004-08-03

A300

Withdrawal of application because of no request for examination

Free format text: JAPANESE INTERMEDIATE CODE: A300

Effective date: 20040803

Publication	Publication Date	Title
US4988451A (en)	1991-01-29	Stabilization of particles containing quaternary ammonium bleach precursors
JPH09316063A (ja)	1997-12-09	アンモニウムニトリル類及びこれを漂白活性化剤として使用する方法
CA2016030C (fr)	1994-12-06	Compositions de detachage et de blanchissage
JP3450326B2 (ja)	2003-09-22	過酸前駆物質としてのアシル化クエン酸エステル
US5236616A (en)	1993-08-17	Bleaching composition
US4818426A (en)	1989-04-04	Quaternary ammonium or phosphonium substituted peroxy carbonic acid precursors and their use in detergent bleach compositions
US5281361A (en)	1994-01-25	Bleaching composition
US5952282A (en)	1999-09-14	Sulfonylimine derivatives as bleach catalysts
JPH07103075B2 (ja)	1995-11-08	第４アンモニウムもしくはホスホニウムペルオキシ炭酸先駆体および洗剤漂白組成物におけるその使用
JPH09505090A (ja)	1997-05-20	漂白触媒としてのイミン塩
MXPA97002315A (en)	1997-06-01	Compositions liquid detergents containing non-aqueous bleach
JP4021075B2 (ja)	2007-12-12	アミノニトリルｎ−オキシドまたはその塩を含む漂白活性化剤ならびにそれを含む洗剤、クリーナー組成物
AU2003219043B2 (en)	2008-06-12	Ammonium nitriles and the use thereof as hydrophobic bleaching activators
AU635381B2 (en)	1993-03-18	Bleaching process and bleach compositions
US6498133B2 (en)	2002-12-24	Particulate bleach activators based on acetonitriles
JPH1059934A (ja)	1998-03-03	漂白活性化剤としての第四級アンモニウム化合物及びその製造法
US6028047A (en)	2000-02-22	Use of formamidinium salts as bleach activators
EP0337274B1 (fr)	1994-11-30	Compositions détergentes pour tissus
US5002687A (en)	1991-03-26	Fabric washing compositions
JPH1046194A (ja)	1998-02-17	漂白活性化剤としてのシアノピリジニウム化合物
US5320775A (en)	1994-06-14	Bleach precursors with novel leaving groups
JPH10152464A (ja)	1998-06-09	漂白活性化剤としてのシアナミド類の塩
JPH062724B2 (ja)	1994-01-12	漂白剤の前駆物質並びにその漂白剤及び／又は洗剤組成物への使用
JPH0267399A (ja)	1990-03-07	漂白洗剤組成物
CA2034665A1 (fr)	1991-07-24	Procede de blanchissage et composition utilisees pour la mise en application dudit procede

JPH1046194A - 漂白活性化剤としてのシアノピリジニウム化合物 - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (2)

Publications (1)

Family

ID=7793653

Family Applications (1)

Country Status (3)

Cited By (1)

Families Citing this family (1)

Family Cites Families (5)

Cited By (1)

Also Published As

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