JPS5638302A - Vinyl polymer emulsion - Google Patents
Vinyl polymer emulsionInfo
- Publication number
- JPS5638302A JPS5638302A JP11401879A JP11401879A JPS5638302A JP S5638302 A JPS5638302 A JP S5638302A JP 11401879 A JP11401879 A JP 11401879A JP 11401879 A JP11401879 A JP 11401879A JP S5638302 A JPS5638302 A JP S5638302A
- Authority
- JP
- Japan
- Prior art keywords
- ring opening
- opening polymer
- emulsion
- dicyclopentadiene
- emulsifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
Abstract
PURPOSE: The titled emulsion useful for an aqueous coating material etc., capably of giving a film having improved water resistance and corrosion resistance, and prepared by the emulsion polymerization of a vinyl monomer in the presence of a neutralized water-soluble adduct of an amorphous dicyclopentadiene ring opening polymer with maleic acid as an emulsifier.
CONSTITUTION: A ring opening polymer of dicyclopentadiene which is expressed by the formula and substantially amorphous is dissolved in a slovent, e.g. tetralin, and subjected to the addition reaction with maleic acid (anhydride) in the presence of a gelation inhibitor at 190°C, and then dispersed in ion exchange water. Butyl cellosolve, triethylamine, etc. are added to the dispersion and heated at 80W90°C to form a uniform transparent neutralized substance, which is used as an emulsifier to carry out the emulsion polymerization of a vinyl monomer, e.g. an acrylic or methacrylic ester. Thus, the aimed emulsion is obtained. Preferably, the number- average molecular weight of the maleinized dicyclopentadiene ring opening polymer is 500W50,000, and the acid value thereof is 30W500.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11401879A JPS5638302A (en) | 1979-09-04 | 1979-09-04 | Vinyl polymer emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11401879A JPS5638302A (en) | 1979-09-04 | 1979-09-04 | Vinyl polymer emulsion |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5638302A true JPS5638302A (en) | 1981-04-13 |
| JPS647082B2 JPS647082B2 (en) | 1989-02-07 |
Family
ID=14626980
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11401879A Granted JPS5638302A (en) | 1979-09-04 | 1979-09-04 | Vinyl polymer emulsion |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5638302A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56127672A (en) * | 1980-03-12 | 1981-10-06 | Kowa Kagaku Kogyo Kk | Coating composition for metal |
| EP0049479A1 (en) * | 1980-10-03 | 1982-04-14 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Vinyl type polymer composition and its use |
-
1979
- 1979-09-04 JP JP11401879A patent/JPS5638302A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56127672A (en) * | 1980-03-12 | 1981-10-06 | Kowa Kagaku Kogyo Kk | Coating composition for metal |
| EP0049479A1 (en) * | 1980-10-03 | 1982-04-14 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Vinyl type polymer composition and its use |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS647082B2 (en) | 1989-02-07 |
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