JPS5764687A - Preparation of 5-amino-1,2,3-thiadiazoles - Google Patents
Preparation of 5-amino-1,2,3-thiadiazolesInfo
- Publication number
- JPS5764687A JPS5764687A JP13936580A JP13936580A JPS5764687A JP S5764687 A JPS5764687 A JP S5764687A JP 13936580 A JP13936580 A JP 13936580A JP 13936580 A JP13936580 A JP 13936580A JP S5764687 A JPS5764687 A JP S5764687A
- Authority
- JP
- Japan
- Prior art keywords
- amino
- pref
- reacting
- solvent
- equivalent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)
Abstract
PURPOSE: To prepare the titled compound useful as a raw material of pharmaceuticals, pesticides, etc., from a low-cost, easily available and easily preparable raw material, economically, in an industrial scale, by reacting diazoacetonitriles with hydrogen sulfide in a solvent in the presence of an inorganic base.
CONSTITUTION: 5-Amino-1,2,3-thiadiazole compound of formula II (R is H, lower alkyl or aryl) is prepared by reacting (A) 1mol of a diazoacetonitrile compound of formulaIwith (B) hydrogen sulfide in the presence of (C) ≥0.05g-equivalent, pref. 0.1W0.5g-equivalent of an inorganic base[e.g. NaOH, KOH, Ca(OH)2], in a solvent (e.g. n-hexane, n-heptane, chloroform, methylene chloride, etc.) at ≤15°C, pref. -5W +10°C under normal pressure.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13936580A JPS6041069B2 (en) | 1980-10-07 | 1980-10-07 | Method for producing 5-amino-1,2,3-thiadiazoles |
| EP19800107981 EP0031548B1 (en) | 1979-12-27 | 1980-12-17 | Process for preparing 5-amino-1,2,3-thiadiazoles |
| BR8008508A BR8008508A (en) | 1979-12-27 | 1980-12-23 | PROCESS FOR PREPARING A 5-AMINO-1,2,3-TIADIAZOL |
| ES498612A ES498612A0 (en) | 1979-12-27 | 1980-12-24 | PROCEDURE FOR THE MANUFACTURE OF 5-AMINO-1,2,3-TIADIAZO-LES |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13936580A JPS6041069B2 (en) | 1980-10-07 | 1980-10-07 | Method for producing 5-amino-1,2,3-thiadiazoles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5764687A true JPS5764687A (en) | 1982-04-19 |
| JPS6041069B2 JPS6041069B2 (en) | 1985-09-13 |
Family
ID=15243625
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13936580A Expired JPS6041069B2 (en) | 1979-12-27 | 1980-10-07 | Method for producing 5-amino-1,2,3-thiadiazoles |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6041069B2 (en) |
-
1980
- 1980-10-07 JP JP13936580A patent/JPS6041069B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6041069B2 (en) | 1985-09-13 |
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