JPS5985880A - 溶融した塩類の混合物の中で塩化リチウムを電解してリチウムを連続的に製造する方法および装置 - Google Patents
溶融した塩類の混合物の中で塩化リチウムを電解してリチウムを連続的に製造する方法および装置Info
- Publication number
- JPS5985880A JPS5985880A JP15817183A JP15817183A JPS5985880A JP S5985880 A JPS5985880 A JP S5985880A JP 15817183 A JP15817183 A JP 15817183A JP 15817183 A JP15817183 A JP 15817183A JP S5985880 A JPS5985880 A JP S5985880A
- Authority
- JP
- Japan
- Prior art keywords
- mixture
- lithium
- anode
- cathode
- chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 title claims description 42
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims description 24
- 229910052744 lithium Inorganic materials 0.000 title claims description 24
- 239000011833 salt mixture Substances 0.000 title claims description 15
- 238000000034 method Methods 0.000 title claims description 13
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000000203 mixture Substances 0.000 claims description 43
- 238000005868 electrolysis reaction Methods 0.000 claims description 15
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 14
- 239000000460 chlorine Substances 0.000 claims description 14
- 229910052801 chlorine Inorganic materials 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 10
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 8
- 230000005496 eutectics Effects 0.000 claims description 6
- 239000001103 potassium chloride Substances 0.000 claims description 4
- 235000011164 potassium chloride Nutrition 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 239000003779 heat-resistant material Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 210000004027 cell Anatomy 0.000 description 23
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 4
- 239000001110 calcium chloride Substances 0.000 description 4
- 229910001628 calcium chloride Inorganic materials 0.000 description 4
- HCQWRNRRURULEY-UHFFFAOYSA-L lithium;potassium;dichloride Chemical compound [Li+].[Cl-].[Cl-].[K+] HCQWRNRRURULEY-UHFFFAOYSA-L 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910000882 Ca alloy Inorganic materials 0.000 description 3
- 230000006798 recombination Effects 0.000 description 3
- 238000005215 recombination Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 2
- 229910001617 alkaline earth metal chloride Inorganic materials 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- FGDZQCVHDSGLHJ-UHFFFAOYSA-M rubidium chloride Chemical compound [Cl-].[Rb+] FGDZQCVHDSGLHJ-UHFFFAOYSA-M 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- WULWWVRGKDUITB-UHFFFAOYSA-L [Cl-].[Ca+2].[Cl-].[Li+] Chemical compound [Cl-].[Ca+2].[Cl-].[Li+] WULWWVRGKDUITB-UHFFFAOYSA-L 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 1
- USOPFYZPGZGBEB-UHFFFAOYSA-N calcium lithium Chemical compound [Li].[Ca] USOPFYZPGZGBEB-UHFFFAOYSA-N 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000000374 eutectic mixture Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229940102127 rubidium chloride Drugs 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910001631 strontium chloride Inorganic materials 0.000 description 1
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 229910003452 thorium oxide Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/02—Electrolytic production, recovery or refining of metals by electrolysis of melts of alkali or alkaline earth metals
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8214865 | 1982-08-31 | ||
| FR8214865A FR2532332B1 (fr) | 1982-08-31 | 1982-08-31 | Procede pour la preparation continue de lithium par electrolyse du chlorure de lithium dans un melange de sels fondus et appareillage pour la mise en oeuvre dudit procede |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5985880A true JPS5985880A (ja) | 1984-05-17 |
Family
ID=9277145
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15817183A Pending JPS5985880A (ja) | 1982-08-31 | 1983-08-31 | 溶融した塩類の混合物の中で塩化リチウムを電解してリチウムを連続的に製造する方法および装置 |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0107521B1 (fr) |
| JP (1) | JPS5985880A (fr) |
| CA (1) | CA1202596A (fr) |
| DE (1) | DE3372295D1 (fr) |
| FR (1) | FR2532332B1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007026565A1 (fr) * | 2005-08-30 | 2007-03-08 | Osaka Titanium Technologies Co., Ltd. | PROCÉDÉ D’ÉLECTROLYSE DE SEL FONDU, PILE ÉLECTROLYTIQUE, ET PROCÉDÉ DE PRODUCTION DE Ti À L’AIDE DUDIT PROCÉDÉ |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2560221B1 (fr) * | 1984-02-24 | 1989-09-08 | Rhone Poulenc Spec Chim | Procede et dispositif pour la fabrication de lithium en continu |
| DE3532956A1 (de) * | 1985-09-14 | 1987-03-19 | Metallgesellschaft Ag | Verfahren und vorrichtung zur herstellung von lithiummetall hoher reinheit durch schmelzflusselektrolyse |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3344049A (en) * | 1967-09-26 | Method of producing lithium | ||
| US2075150A (en) * | 1932-11-07 | 1937-03-30 | Justin F Wait | Process for the producing of metals and utilization thereof |
| FR2243277B1 (fr) * | 1973-09-07 | 1976-06-18 | Commissariat Energie Atomique | |
| JPS5443811A (en) * | 1977-09-16 | 1979-04-06 | Asahi Glass Co Ltd | Production of metallic lithium |
-
1982
- 1982-08-31 FR FR8214865A patent/FR2532332B1/fr not_active Expired
-
1983
- 1983-08-16 DE DE8383401664T patent/DE3372295D1/de not_active Expired
- 1983-08-16 EP EP83401664A patent/EP0107521B1/fr not_active Expired
- 1983-08-30 CA CA000435666A patent/CA1202596A/fr not_active Expired
- 1983-08-31 JP JP15817183A patent/JPS5985880A/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007026565A1 (fr) * | 2005-08-30 | 2007-03-08 | Osaka Titanium Technologies Co., Ltd. | PROCÉDÉ D’ÉLECTROLYSE DE SEL FONDU, PILE ÉLECTROLYTIQUE, ET PROCÉDÉ DE PRODUCTION DE Ti À L’AIDE DUDIT PROCÉDÉ |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2532332B1 (fr) | 1986-04-04 |
| EP0107521B1 (fr) | 1987-07-01 |
| DE3372295D1 (en) | 1987-08-06 |
| CA1202596A (fr) | 1986-04-01 |
| EP0107521A1 (fr) | 1984-05-02 |
| FR2532332A1 (fr) | 1984-03-02 |
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