JPS60153903A - 限外口過膜の製造法 - Google Patents
限外口過膜の製造法Info
- Publication number
- JPS60153903A JPS60153903A JP59009884A JP988484A JPS60153903A JP S60153903 A JPS60153903 A JP S60153903A JP 59009884 A JP59009884 A JP 59009884A JP 988484 A JP988484 A JP 988484A JP S60153903 A JPS60153903 A JP S60153903A
- Authority
- JP
- Japan
- Prior art keywords
- hydrophobic polymer
- ultrafiltration membrane
- hydrophilic silica
- membrane
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 68
- 238000000108 ultra-filtration Methods 0.000 title claims description 19
- 238000002360 preparation method Methods 0.000 title description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 55
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 27
- 229920001600 hydrophobic polymer Polymers 0.000 claims abstract description 22
- 238000009987 spinning Methods 0.000 claims abstract description 15
- 239000007822 coupling agent Substances 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 7
- 239000011550 stock solution Substances 0.000 claims abstract description 7
- 239000007864 aqueous solution Substances 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- 230000002378 acidificating effect Effects 0.000 claims abstract description 4
- 239000002798 polar solvent Substances 0.000 claims abstract description 4
- 239000012510 hollow fiber Substances 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 230000002209 hydrophobic effect Effects 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 230000001112 coagulating effect Effects 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 14
- 230000035699 permeability Effects 0.000 abstract description 10
- 238000000034 method Methods 0.000 abstract description 9
- 229920001291 polyvinyl halide Polymers 0.000 abstract description 3
- 229920006214 polyvinylidene halide Polymers 0.000 abstract description 3
- 239000006185 dispersion Substances 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 9
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000006087 Silane Coupling Agent Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000011148 porous material Substances 0.000 description 4
- 239000002033 PVDF binder Substances 0.000 description 3
- 238000001891 gel spinning Methods 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- UMHKOAYRTRADAT-UHFFFAOYSA-N [hydroxy(octoxy)phosphoryl] octyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OP(O)(=O)OCCCCCCCC UMHKOAYRTRADAT-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 description 1
- OBPQOFOPKSWFPC-UHFFFAOYSA-N 1,2,3-tridodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC(CCCCCCCCCCCC)=C1CCCCCCCCCCCC OBPQOFOPKSWFPC-UHFFFAOYSA-N 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- SRORDPCXIPXEAX-UHFFFAOYSA-N CCCCCCCCCCCCCP(CCCCCCCCCCCCC)(O)(OCCCCCCCC)OCCCCCCCC.CCCCCCCCCCCCCP(CCCCCCCCCCCCC)(O)(OCCCCCCCC)OCCCCCCCC Chemical compound CCCCCCCCCCCCCP(CCCCCCCCCCCCC)(O)(OCCCCCCCC)OCCCCCCCC.CCCCCCCCCCCCCP(CCCCCCCCCCCCC)(O)(OCCCCCCCC)OCCCCCCCC SRORDPCXIPXEAX-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- -1 Ethoxysilane Vinyltris(β-methoxyethoxy)silane Chemical compound 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- CZHYKKAKFWLGJO-UHFFFAOYSA-N dimethyl phosphite Chemical compound COP([O-])OC CZHYKKAKFWLGJO-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- AJFDBNQQDYLMJN-UHFFFAOYSA-N n,n-diethylacetamide Chemical compound CCN(CC)C(C)=O AJFDBNQQDYLMJN-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/30—Polyalkenyl halides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/14—Dynamic membranes
- B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
- B01D69/1411—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes containing dispersed material in a continuous matrix
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59009884A JPS60153903A (ja) | 1984-01-23 | 1984-01-23 | 限外口過膜の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59009884A JPS60153903A (ja) | 1984-01-23 | 1984-01-23 | 限外口過膜の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60153903A true JPS60153903A (ja) | 1985-08-13 |
| JPH042291B2 JPH042291B2 (fr) | 1992-01-17 |
Family
ID=11732572
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59009884A Granted JPS60153903A (ja) | 1984-01-23 | 1984-01-23 | 限外口過膜の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60153903A (fr) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2625690A1 (fr) * | 1988-01-11 | 1989-07-13 | Inst Francais Du Petrole | Procede de separation des constituants d'un melange en phase gazeuse au moyen d'une membrane composite |
| JPH05258190A (ja) * | 1991-03-26 | 1993-10-08 | Honshu Paper Co Ltd | 過熱検知装置及びそれを用いた過熱警告装置 |
| WO1998044348A1 (fr) * | 1997-04-02 | 1998-10-08 | The Perkin-Elmer Corporation | Detection d'analytes hydrophobes a faible niveau dans des echantillons d'environment |
| EP1096591A1 (fr) * | 1999-10-26 | 2001-05-02 | MERCK PATENT GmbH | Membrane à électrolyte polymère employée dans des batteries au lithium |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50109242A (fr) * | 1974-02-05 | 1975-08-28 | ||
| JPS5123492A (en) * | 1974-08-22 | 1976-02-25 | Shionogi Seiyaku Kk | Kyuchakuseishiito oyobi sonoseizohoho |
| JPS5893734A (ja) * | 1981-11-30 | 1983-06-03 | Asahi Chem Ind Co Ltd | 親水性ポリフツ化ビニリデン樹脂多孔膜の製造方法 |
| JPS5955722A (ja) * | 1982-09-27 | 1984-03-30 | Nichias Corp | 弗素樹脂製隔膜の製造法 |
-
1984
- 1984-01-23 JP JP59009884A patent/JPS60153903A/ja active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50109242A (fr) * | 1974-02-05 | 1975-08-28 | ||
| JPS5123492A (en) * | 1974-08-22 | 1976-02-25 | Shionogi Seiyaku Kk | Kyuchakuseishiito oyobi sonoseizohoho |
| JPS5893734A (ja) * | 1981-11-30 | 1983-06-03 | Asahi Chem Ind Co Ltd | 親水性ポリフツ化ビニリデン樹脂多孔膜の製造方法 |
| JPS5955722A (ja) * | 1982-09-27 | 1984-03-30 | Nichias Corp | 弗素樹脂製隔膜の製造法 |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2625690A1 (fr) * | 1988-01-11 | 1989-07-13 | Inst Francais Du Petrole | Procede de separation des constituants d'un melange en phase gazeuse au moyen d'une membrane composite |
| US4925459A (en) * | 1988-01-11 | 1990-05-15 | Institut Francais Du Petrole | Process for separation of the constituents of a mixture in the gas phase using a composite membrane |
| JPH05258190A (ja) * | 1991-03-26 | 1993-10-08 | Honshu Paper Co Ltd | 過熱検知装置及びそれを用いた過熱警告装置 |
| WO1998044348A1 (fr) * | 1997-04-02 | 1998-10-08 | The Perkin-Elmer Corporation | Detection d'analytes hydrophobes a faible niveau dans des echantillons d'environment |
| EP1096591A1 (fr) * | 1999-10-26 | 2001-05-02 | MERCK PATENT GmbH | Membrane à électrolyte polymère employée dans des batteries au lithium |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH042291B2 (fr) | 1992-01-17 |
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