JPS6043631B2 - 二次電池用の複合負極構造体 - Google Patents

二次電池用の複合負極構造体

Info

Publication number: JPS6043631B2
Authority: JP; Japan
Prior art keywords: lithium; electrode; alloy; electrolyte; matrix
Prior art date: 1974-10-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP50119851A

Other languages

English (en)

Japanese (ja)

Other versions

JPS5163432A (en

Inventor

チエンライサン

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Boeing North American Inc

Original Assignee

Rockwell International Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-10-07

Filing date

1975-10-06

Publication date

1985-09-28

1975-10-06 Application filed by Rockwell International Corp filed Critical Rockwell International Corp

1976-06-01 Publication of JPS5163432A publication Critical patent/JPS5163432A/ja

1985-09-28 Publication of JPS6043631B2 publication Critical patent/JPS6043631B2/ja

Status Expired legal-status Critical Current

Links

239000002131 composite material Substances 0.000 title claims description 4
229910052744 lithium Inorganic materials 0.000 claims description 90
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 81
229910045601 alloy Inorganic materials 0.000 claims description 42
239000000956 alloy Substances 0.000 claims description 42
239000003792 electrolyte Substances 0.000 claims description 31
239000011159 matrix material Substances 0.000 claims description 31
229910000676 Si alloy Inorganic materials 0.000 claims description 14
239000010703 silicon Substances 0.000 claims description 14
229910000733 Li alloy Inorganic materials 0.000 claims description 11
229910052710 silicon Inorganic materials 0.000 claims description 11
239000000758 substrate Substances 0.000 description 29
235000002639 sodium chloride Nutrition 0.000 description 28
150000003839 salts Chemical class 0.000 description 25
229910052751 metal Inorganic materials 0.000 description 24
239000002184 metal Substances 0.000 description 24
238000004146 energy storage Methods 0.000 description 21
-1 lithium halide Chemical class 0.000 description 21
239000007788 liquid Substances 0.000 description 20
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 18
JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 17
239000000463 material Substances 0.000 description 16
ZVLDJSZFKQJMKD-UHFFFAOYSA-N [Li].[Si] Chemical compound [Li].[Si] ZVLDJSZFKQJMKD-UHFFFAOYSA-N 0.000 description 14
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 14
239000000835 fiber Substances 0.000 description 13
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 12
238000000034 method Methods 0.000 description 11
239000002904 solvent Substances 0.000 description 10
HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 9
229910052742 iron Inorganic materials 0.000 description 9
229910001416 lithium ion Inorganic materials 0.000 description 9
239000000203 mixture Substances 0.000 description 9
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 8
AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 8
238000002844 melting Methods 0.000 description 8
230000008018 melting Effects 0.000 description 8
150000002739 metals Chemical class 0.000 description 8
239000000374 eutectic mixture Substances 0.000 description 7
239000001989 lithium alloy Substances 0.000 description 7
239000002609 medium Substances 0.000 description 7
239000007784 solid electrolyte Substances 0.000 description 7
238000012360 testing method Methods 0.000 description 7
229910000838 Al alloy Inorganic materials 0.000 description 6
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
239000011149 active material Substances 0.000 description 6
HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Chemical compound [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 description 6
239000005486 organic electrolyte Substances 0.000 description 6
229910052719 titanium Inorganic materials 0.000 description 6
239000010936 titanium Substances 0.000 description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
229910052782 aluminium Inorganic materials 0.000 description 5
150000002500 ions Chemical class 0.000 description 5
239000003960 organic solvent Substances 0.000 description 5
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
238000007599 discharging Methods 0.000 description 4
230000005496 eutectics Effects 0.000 description 4
229910002804 graphite Inorganic materials 0.000 description 4
239000010439 graphite Substances 0.000 description 4
PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 4
229910052759 nickel Inorganic materials 0.000 description 4
239000011255 nonaqueous electrolyte Substances 0.000 description 4
239000001103 potassium chloride Substances 0.000 description 4
235000011164 potassium chloride Nutrition 0.000 description 4
239000007787 solid Substances 0.000 description 4
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
230000008901 benefit Effects 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
229910052802 copper Inorganic materials 0.000 description 3
239000010949 copper Substances 0.000 description 3
230000001351 cycling effect Effects 0.000 description 3
150000004820 halides Chemical class 0.000 description 3
239000011133 lead Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
229910052709 silver Inorganic materials 0.000 description 3
239000004332 silver Substances 0.000 description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000011575 calcium Substances 0.000 description 2
230000008859 change Effects 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000010276 construction Methods 0.000 description 2
230000008021 deposition Effects 0.000 description 2
230000005611 electricity Effects 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 2
229910001486 lithium perchlorate Inorganic materials 0.000 description 2
INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 2
230000007246 mechanism Effects 0.000 description 2
239000000155 melt Substances 0.000 description 2
229910001507 metal halide Inorganic materials 0.000 description 2
150000005309 metal halides Chemical class 0.000 description 2
RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
JAAGVIUFBAHDMA-UHFFFAOYSA-M rubidium bromide Chemical compound [Br-].[Rb+] JAAGVIUFBAHDMA-UHFFFAOYSA-M 0.000 description 2
PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
239000000126 substance Substances 0.000 description 2
229910052717 sulfur Inorganic materials 0.000 description 2
229910052715 tantalum Inorganic materials 0.000 description 2
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 2
239000011135 tin Substances 0.000 description 2
229910052718 tin Inorganic materials 0.000 description 2
WHXSMMKQMYFTQS-BJUDXGSMSA-N (6Li)Lithium Chemical compound [6Li] WHXSMMKQMYFTQS-BJUDXGSMSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
FWLUTJHBRZTAMP-UHFFFAOYSA-N B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+] Chemical compound B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.B([O-])([O-])F.[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+] FWLUTJHBRZTAMP-UHFFFAOYSA-N 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
229910012019 Li4Si Inorganic materials 0.000 description 1
229910001209 Low-carbon steel Inorganic materials 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
LISVNGUOWUKZQY-UHFFFAOYSA-N Methyl benzyl sulfoxide Chemical compound CS(=O)CC1=CC=CC=C1 LISVNGUOWUKZQY-UHFFFAOYSA-N 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
FRRFXFCSMTUEMZ-UHFFFAOYSA-K [Cl-].[K+].[Cl-].[Li+].[Cl-].[Ca+2] Chemical compound [Cl-].[K+].[Cl-].[Li+].[Cl-].[Ca+2] FRRFXFCSMTUEMZ-UHFFFAOYSA-K 0.000 description 1
CIHHRNQZUFCQRG-UHFFFAOYSA-L [Li+].[K+].[Br-].[Br-] Chemical compound [Li+].[K+].[Br-].[Br-] CIHHRNQZUFCQRG-UHFFFAOYSA-L 0.000 description 1
230000009471 action Effects 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910001508 alkali metal halide Inorganic materials 0.000 description 1
229910001413 alkali metal ion Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910001615 alkaline earth metal halide Inorganic materials 0.000 description 1
229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
229910002056 binary alloy Inorganic materials 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
229910052792 caesium Inorganic materials 0.000 description 1
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
LEJQKNPYBCFVSU-UHFFFAOYSA-K calcium lithium barium(2+) trichloride Chemical compound [Cl-].[Ba+2].[Cl-].[Li+].[Cl-].[Ca+2] LEJQKNPYBCFVSU-UHFFFAOYSA-K 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
239000010406 cathode material Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
230000008602 contraction Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical class [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
230000006378 damage Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
238000010586 diagram Methods 0.000 description 1
125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
239000007772 electrode material Substances 0.000 description 1
239000002001 electrolyte material Substances 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
239000012535 impurity Substances 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
239000012212 insulator Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000011872 intimate mixture Substances 0.000 description 1
239000011630 iodine Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
229910001500 lithium hexafluoroborate Inorganic materials 0.000 description 1
PBQJJAGPOOEKMU-UHFFFAOYSA-K lithium potassium barium(2+) trichloride Chemical compound [Cl-].[Ba+2].[Cl-].[K+].[Cl-].[Li+] PBQJJAGPOOEKMU-UHFFFAOYSA-K 0.000 description 1
LBEWFUFVQRYRPT-UHFFFAOYSA-L lithium rubidium(1+) difluoride Chemical compound [F-].[Rb+].[F-].[Li+] LBEWFUFVQRYRPT-UHFFFAOYSA-L 0.000 description 1
229910003002 lithium salt Inorganic materials 0.000 description 1
159000000002 lithium salts Chemical class 0.000 description 1
229910001537 lithium tetrachloroaluminate Inorganic materials 0.000 description 1
229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 1
QNRUKMBLUVIEBO-UHFFFAOYSA-L lithium;magnesium;dichloride Chemical compound [Li+].[Mg+2].[Cl-].[Cl-] QNRUKMBLUVIEBO-UHFFFAOYSA-L 0.000 description 1
HCQWRNRRURULEY-UHFFFAOYSA-L lithium;potassium;dichloride Chemical compound [Li+].[Cl-].[Cl-].[K+] HCQWRNRRURULEY-UHFFFAOYSA-L 0.000 description 1
IEGSXYJGFBDOLI-UHFFFAOYSA-L lithium;potassium;diiodide Chemical compound [Li+].[K+].[I-].[I-] IEGSXYJGFBDOLI-UHFFFAOYSA-L 0.000 description 1
WTFCBWXBJBYVOS-UHFFFAOYSA-L lithium;sodium;dichloride Chemical compound [Li+].[Na+].[Cl-].[Cl-] WTFCBWXBJBYVOS-UHFFFAOYSA-L 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052976 metal sulfide Inorganic materials 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
MPDOUGUGIVBSGZ-UHFFFAOYSA-N n-(cyclobutylmethyl)-3-(trifluoromethyl)aniline Chemical compound FC(F)(F)C1=CC=CC(NCC2CCC2)=C1 MPDOUGUGIVBSGZ-UHFFFAOYSA-N 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
238000012856 packing Methods 0.000 description 1
238000010587 phase diagram Methods 0.000 description 1
239000011148 porous material Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
KVMLCRQYXDYXDX-UHFFFAOYSA-M potassium;chloride;hydrochloride Chemical compound Cl.[Cl-].[K+] KVMLCRQYXDYXDX-UHFFFAOYSA-M 0.000 description 1
150000004040 pyrrolidinones Chemical class 0.000 description 1
229910052701 rubidium Inorganic materials 0.000 description 1
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
239000011833 salt mixture Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
150000003346 selenoethers Chemical class 0.000 description 1
238000005245 sintering Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000011775 sodium fluoride Substances 0.000 description 1
235000013024 sodium fluoride Nutrition 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
239000006104 solid solution Substances 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010959 steel Substances 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
150000003462 sulfoxides Chemical class 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
239000013589 supplement Substances 0.000 description 1
239000006163 transport media Substances 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
238000009736 wetting Methods 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/40—Alloys based on alkali metals
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
General Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Secondary Cells (AREA)
Battery Electrode And Active Subsutance (AREA)

JP50119851A 1974-10-07 1975-10-06 二次電池用の複合負極構造体 Expired JPS6043631B2 (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US51263574A	1974-10-07	1974-10-07
US512635		1974-10-07

Publications (2)

Publication Number	Publication Date
JPS5163432A JPS5163432A (en)	1976-06-01
JPS6043631B2 true JPS6043631B2 (ja)	1985-09-28

Family

ID=24039923

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP50119851A Expired JPS6043631B2 (ja)	1974-10-07	1975-10-06	二次電池用の複合負極構造体

Country Status (7)

Country	Link
JP (1)	JPS6043631B2 (it)
BE (1)	BE834008A (it)
CA (1)	CA1045680A (it)
DE (1)	DE2544882A1 (it)
FR (1)	FR2287781A1 (it)
GB (1)	GB1482335A (it)
IT (1)	IT1047560B (it)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US7616282B2 (en)	1995-11-17	2009-11-10	Semiconductor Energy Laboratory Co., Ltd.	Liquid crystal display and method of driving same

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4048395A (en) *	1976-08-18	1977-09-13	Rockwell International Corporation	Lithium electrode for electrical energy storage device
CA1093633A (en) *	1977-04-25	1981-01-13	Charles C. Liang	Cathodes for electrolyte cells
US4076905A (en) *	1977-05-05	1978-02-28	Rockwell International Corporation	Electrode for electrical energy storage device
JPS5564378A (en) *	1978-11-06	1980-05-15	Sanyo Electric Co Ltd	No-water electrolyte cell
US4221849A (en) *	1979-04-27	1980-09-09	Catalyst Research Corporation	Iron-lithium anode for thermal batteries and thermal batteries made therefrom
DE3222675A1 (de) *	1981-06-26	1983-01-13	Mine Safety Appliances Co., Ltd., Glasgow, Schottland	Thermozelle und elektrische batterie aus thermozellen
JPH0644485B2 (ja) *	1984-07-25	1994-06-08	日本電信電話株式会社	リチウム電池用負極
JPS62103968A (ja) *	1985-10-30	1987-05-14	Fuji Elelctrochem Co Ltd	非水電解液二次電池
JPS62110258A (ja) *	1985-11-08	1987-05-21	Matsushita Electric Ind Co Ltd	非水電解質二次電池
DE3838329A1 (de) *	1987-11-11	1989-05-24	Ricoh Kk	Negative elektrode fuer sekundaerbatterie
GB9418475D0 (en) *	1994-09-14	1994-11-02	Secr Defence	Battery
JP2008016329A (ja) *	2006-07-06	2008-01-24	Sumitomo Electric Ind Ltd	リチウム二次電池用負極材
CN114730916A (zh) *	2020-04-14	2022-07-08	圣戈本陶瓷及塑料股份有限公司	电解质材料及其形成方法
CN115433214B (zh) *	2022-08-29	2024-09-17	上海工程技术大学	一种金属卤化物熔融盐及其制备方法和应用

1975
- 1975-09-02 CA CA234,748A patent/CA1045680A/en not_active Expired
- 1975-09-23 IT IT51472/75A patent/IT1047560B/it active
- 1975-09-29 GB GB39812/75A patent/GB1482335A/en not_active Expired
- 1975-09-30 BE BE160535A patent/BE834008A/xx unknown
- 1975-10-01 FR FR7530124A patent/FR2287781A1/fr active Granted
- 1975-10-06 JP JP50119851A patent/JPS6043631B2/ja not_active Expired
- 1975-10-07 DE DE19752544882 patent/DE2544882A1/de not_active Withdrawn

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US7616282B2 (en)	1995-11-17	2009-11-10	Semiconductor Energy Laboratory Co., Ltd.	Liquid crystal display and method of driving same

Also Published As

Publication number	Publication date
BE834008A (fr)	1976-03-30
FR2287781A1 (fr)	1976-05-07
GB1482335A (en)	1977-08-10
IT1047560B (it)	1980-10-20
DE2544882A1 (de)	1976-04-15
JPS5163432A (en)	1976-06-01
CA1045680A (en)	1979-01-02
FR2287781B1 (it)	1979-06-29

Publication	Publication Date	Title
US3969139A (en)	1976-07-13	Lithium electrode and an electrical energy storage device containing the same
US4048395A (en)	1977-09-13	Lithium electrode for electrical energy storage device
US4076905A (en)	1978-02-28	Electrode for electrical energy storage device
US4287268A (en)	1981-09-01	Electrode for an electrochemical cell, and an electrochemical cell
US4764437A (en)	1988-08-16	Lithium disulfide battery
US4877695A (en)	1989-10-31	Non-aqueous electrochemical cell
US4011372A (en)	1977-03-08	Method of preparing a negative electrode including lithium alloy for use within a secondary electrochemical cell
US3980495A (en)	1976-09-14	Calcium alloy as active material in secondary electrochemical cell
JPS6043631B2 (ja)	1985-09-28	二次電池用の複合負極構造体
JPS6057188B2 (ja)	1985-12-13	再充電可能なリチウム−アルミニウム負極を有する化学電池
JP2011192474A (ja)	2011-09-29	電池用負極材料、電池用負極前駆体材料、及び電池
WO2013069597A1 (ja)	2013-05-16	ナトリウム電池用の負極活物質、負極及びナトリウム電池
US4003753A (en)	1977-01-18	Electrode structure for electrical energy storage device
US5085955A (en)	1992-02-04	Non-aqueous electrochemical cell
US3881951A (en)	1975-05-06	Lithium electrode and method of producing the same
US4145806A (en)	1979-03-27	Method of assembling an electrochemical cell
JP2021174774A (ja)	2021-11-01	フッ化物イオン電池用負極およびフッ化物イオン電池
US20240339665A1 (en)	2024-10-10	Non-aqueous aluminium ion secondary battery with a quasi-solid electrolyte and electrochemically activated cathode material with high specific capacity
US9786955B1 (en)	2017-10-10	Assembly methods for liquid metal battery with bimetallic electrode
US3484296A (en)	1969-12-16	Low temperature battery
KR102302404B1 (ko)	2021-09-15	중온 나트륨-금속 할라이드 배터리
US20170324072A1 (en)	2017-11-09	Electrochemical Cell with Bipolar Faradaic Membrane
CN111244560B (zh)	2023-07-11	双金属电极二次电池
KR20160028748A (ko)	2016-03-14	나트륨 이차전지
US3907590A (en)	1975-09-23	Aluminum electrode

JPS6043631B2 - 二次電池用の複合負極構造体 - Google Patents

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