JPS6071042A - クラツキング触媒上の金属汚染物の不動態化方法 - Google Patents
クラツキング触媒上の金属汚染物の不動態化方法Info
- Publication number
- JPS6071042A JPS6071042A JP59162770A JP16277084A JPS6071042A JP S6071042 A JPS6071042 A JP S6071042A JP 59162770 A JP59162770 A JP 59162770A JP 16277084 A JP16277084 A JP 16277084A JP S6071042 A JPS6071042 A JP S6071042A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- cracking
- zone
- contacting
- cranking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title claims description 83
- 238000005336 cracking Methods 0.000 title claims description 25
- 229910052751 metal Inorganic materials 0.000 title claims description 24
- 239000002184 metal Substances 0.000 title claims description 24
- 239000000356 contaminant Substances 0.000 title claims description 13
- 238000000034 method Methods 0.000 claims description 27
- 239000007789 gas Substances 0.000 claims description 20
- 229910052787 antimony Inorganic materials 0.000 claims description 19
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 19
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical group [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 16
- 229930195733 hydrocarbon Natural products 0.000 claims description 15
- 150000002430 hydrocarbons Chemical class 0.000 claims description 15
- 238000002161 passivation Methods 0.000 claims description 15
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 10
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- 229910052720 vanadium Inorganic materials 0.000 claims description 9
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 230000009467 reduction Effects 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000002485 combustion reaction Methods 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 4
- 230000008929 regeneration Effects 0.000 claims description 4
- 238000011069 regeneration method Methods 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 description 10
- 239000003921 oil Substances 0.000 description 8
- 238000004523 catalytic cracking Methods 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 239000003607 modifier Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000000571 coke Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 239000003502 gasoline Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000009849 deactivation Effects 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 238000004847 absorption spectroscopy Methods 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000011959 amorphous silica alumina Substances 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 238000011021 bench scale process Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/90—Regeneration or reactivation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
- C10G2300/705—Passivation
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US53682083A | 1983-09-28 | 1983-09-28 | |
| US536820 | 1983-09-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6071042A true JPS6071042A (ja) | 1985-04-22 |
Family
ID=24140061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59162770A Pending JPS6071042A (ja) | 1983-09-28 | 1984-08-01 | クラツキング触媒上の金属汚染物の不動態化方法 |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0141988B1 (de) |
| JP (1) | JPS6071042A (de) |
| AT (1) | ATE34404T1 (de) |
| CA (1) | CA1223856A (de) |
| DE (1) | DE3471320D1 (de) |
| ES (1) | ES8606519A1 (de) |
| NO (1) | NO160333C (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62232485A (ja) * | 1986-03-24 | 1987-10-12 | シエブロン リサ−チ カンパニ− | 流動接触分解触媒のナトリウム被毒の抑制法 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1333381C (en) | 1986-02-20 | 1994-12-06 | Eric D. Nyberg | Method and articles employing ion exchange material |
| US5401384A (en) * | 1993-12-17 | 1995-03-28 | Inteven, S.A. | Antimony and tin containing compound, use of such a compound as a passivating agent, and process for preparing such a compound |
| JP4238803B2 (ja) * | 2004-09-08 | 2009-03-18 | ソニー株式会社 | 液体吐出ヘッド及び液体吐出装置 |
| JP2011016036A (ja) | 2007-11-26 | 2011-01-27 | Asahi Kasei Chemicals Corp | タンパク吸着材料およびその製造方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4321129A (en) * | 1978-09-12 | 1982-03-23 | Phillips Petroleum Company | Cracking process employing catalyst having combination of antimony and tin |
| US4280895A (en) * | 1979-12-31 | 1981-07-28 | Exxon Research & Engineering Co. | Passivation of cracking catalysts |
| US5358630A (en) * | 1980-11-17 | 1994-10-25 | Phillips Petroleum Company | Regenerating zeolitic cracking catalyst |
-
1984
- 1984-05-18 CA CA000454706A patent/CA1223856A/en not_active Expired
- 1984-08-01 JP JP59162770A patent/JPS6071042A/ja active Pending
- 1984-09-21 NO NO843811A patent/NO160333C/no unknown
- 1984-09-27 AT AT84111536T patent/ATE34404T1/de not_active IP Right Cessation
- 1984-09-27 ES ES536300A patent/ES8606519A1/es not_active Expired
- 1984-09-27 DE DE8484111536T patent/DE3471320D1/de not_active Expired
- 1984-09-27 EP EP84111536A patent/EP0141988B1/de not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62232485A (ja) * | 1986-03-24 | 1987-10-12 | シエブロン リサ−チ カンパニ− | 流動接触分解触媒のナトリウム被毒の抑制法 |
Also Published As
| Publication number | Publication date |
|---|---|
| NO160333C (no) | 1989-04-12 |
| NO843811L (no) | 1985-03-29 |
| ATE34404T1 (de) | 1988-06-15 |
| EP0141988B1 (de) | 1988-05-18 |
| ES8606519A1 (es) | 1986-04-01 |
| NO160333B (no) | 1989-01-02 |
| CA1223856A (en) | 1987-07-07 |
| DE3471320D1 (en) | 1988-06-23 |
| ES536300A0 (es) | 1986-04-01 |
| EP0141988A1 (de) | 1985-05-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0072653B1 (de) | Endotherme Entfernung von Koks, der bei der Umwandlung von Koksvorläufer und Schwermetalle enthaltenden Ölen an adsorbierten Materialien abgelagert worden ist | |
| US2560433A (en) | Desulfurization of hydrocarbon oils | |
| JPH057436B2 (de) | ||
| US3839187A (en) | Removing metal contaminants from petroleum residual oil | |
| US5358630A (en) | Regenerating zeolitic cracking catalyst | |
| US3983030A (en) | Combination process for residua demetalation, desulfurization and resulting coke gasification | |
| US4256564A (en) | Cracking process and catalyst for same containing indium to passivate contaminating metals | |
| CA1127619A (en) | Passivation of metals on cracking catalyst with thallium | |
| US4935121A (en) | Reactivation of metal-contaminated cracking catalysts | |
| JPS5837087A (ja) | 重質供給原料の接触分解におけるコ−クス生成の減少法 | |
| US4364848A (en) | Passivation of metal contaminants on cracking catalyst | |
| US4361496A (en) | Passivation of metal contaminants on cracking catalyst | |
| US4169042A (en) | Cracking process and catalyst for same containing tellurium | |
| US4447552A (en) | Passivation of metal contaminants on cracking catalyst | |
| US4404090A (en) | Passivation of metal contaminants on cracking catalyst | |
| US4218337A (en) | Passivating metals on cracking catalysts with tellurium | |
| US4915820A (en) | Removal of coke and metals from carbo-metallic oils | |
| JPS6071042A (ja) | クラツキング触媒上の金属汚染物の不動態化方法 | |
| US4382015A (en) | Passivation of metal contaminants on cracking catalyst | |
| US2791540A (en) | Hydrocarbon desulfurization process wherein the sulfur compounds are adsorbed by metallic silver | |
| US4384949A (en) | Pretreating hydrocarbon feed stocks using deactivated FCC catalyst | |
| US4292288A (en) | Catalyst for CO removal from flue gas | |
| US4257876A (en) | Passivation of metals contaminating a cracking catalyst with trihydrocarbylantimony oxide and process for converting hydrocarbons | |
| US4283274A (en) | Process for cracking hydrocarbons with a cracking catalyst passivated with thallium | |
| US3242067A (en) | Fluid hydrogenative cracking process with the use of unsulfided metallic nickel on a cracking catalyst support |