JPS61120843A - ポリメチルメタクリレ−トとあるスチレンコポリマ−との透明ブレンド物 - Google Patents

ポリメチルメタクリレ−トとあるスチレンコポリマ−との透明ブレンド物

Info

Publication number: JPS61120843A
Authority: JP; Japan
Prior art keywords: weight; formula; copolymer; styrene; polymethyl methacrylate
Prior art date: 1984-11-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP23870584A

Other languages

English (en)

Japanese (ja)

Other versions

JPS6340822B2 (fr

Inventor

ヘンノ　ケスクラ

キヤサリン　マクカーシイ　マククレデイ

ドナルド　エイ　マス

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Chemical Co

Original Assignee

Dow Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-11-14

Filing date

1984-11-14

Publication date

1986-06-07

1984-11-14 Application filed by Dow Chemical Co filed Critical Dow Chemical Co

1984-11-14 Priority to JP23870584A priority Critical patent/JPS61120843A/ja

1986-06-07 Publication of JPS61120843A publication Critical patent/JPS61120843A/ja

1988-08-12 Publication of JPS6340822B2 publication Critical patent/JPS6340822B2/ja

Status Granted legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims description 87
229920003229 poly(methyl methacrylate) Polymers 0.000 title claims description 44
239000004926 polymethyl methacrylate Substances 0.000 title claims description 43
229920001577 copolymer Polymers 0.000 title claims description 40
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims description 28
229920000642 polymer Polymers 0.000 claims description 25
229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 23
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 21
229920001971 elastomer Polymers 0.000 claims description 21
238000000034 method Methods 0.000 claims description 19
239000005060 rubber Substances 0.000 claims description 19
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 16
239000000178 monomer Substances 0.000 claims description 16
125000003118 aryl group Chemical group 0.000 claims description 9
239000002253 acid Substances 0.000 claims description 8
125000000217 alkyl group Chemical group 0.000 claims description 8
229910052739 hydrogen Inorganic materials 0.000 claims description 8
239000001257 hydrogen Substances 0.000 claims description 8
239000000126 substance Substances 0.000 claims description 8
239000002245 particle Substances 0.000 claims description 7
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 7
125000004432 carbon atom Chemical group C* 0.000 claims description 6
229920002554 vinyl polymer Polymers 0.000 claims description 6
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 5
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 5
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
230000003287 optical effect Effects 0.000 claims description 4
230000031700 light absorption Effects 0.000 claims description 3
239000007787 solid Substances 0.000 claims description 3
229920006352 transparent thermoplastic Polymers 0.000 claims description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
229910052799 carbon Inorganic materials 0.000 claims 2
238000002156 mixing Methods 0.000 description 16
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 15
XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 14
239000004676 acrylonitrile butadiene styrene Substances 0.000 description 14
-1 α-metayarylonitonyl Chemical compound 0.000 description 11
239000011347 resin Substances 0.000 description 10
229920005989 resin Polymers 0.000 description 10
SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 7
229920000638 styrene acrylonitrile Polymers 0.000 description 7
238000010521 absorption reaction Methods 0.000 description 6
KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 5
239000000463 material Substances 0.000 description 5
229920002959 polymer blend Polymers 0.000 description 5
239000005062 Polybutadiene Substances 0.000 description 4
150000001993 dienes Chemical class 0.000 description 4
229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 4
229920002857 polybutadiene Polymers 0.000 description 4
229920002223 polystyrene Polymers 0.000 description 4
FEIQOMCWGDNMHM-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid Chemical compound OC(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-N 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000011156 evaluation Methods 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
239000000155 melt Substances 0.000 description 3
229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 3
125000002348 vinylic group Chemical group 0.000 description 3
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical class C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 2
ZGHFDIIVVIFNPS-UHFFFAOYSA-N 3-Methyl-3-buten-2-one Chemical compound CC(=C)C(C)=O ZGHFDIIVVIFNPS-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
239000004793 Polystyrene Substances 0.000 description 2
239000000654 additive Substances 0.000 description 2
FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
238000013329 compounding Methods 0.000 description 2
230000006835 compression Effects 0.000 description 2
238000007906 compression Methods 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
238000010586 diagram Methods 0.000 description 2
239000000806 elastomer Substances 0.000 description 2
238000007429 general method Methods 0.000 description 2
239000008187 granular material Substances 0.000 description 2
125000005843 halogen group Chemical group 0.000 description 2
229920000126 latex Polymers 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
238000010587 phase diagram Methods 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
239000004033 plastic Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
238000000197 pyrolysis Methods 0.000 description 2
239000011145 styrene acrylonitrile resin Substances 0.000 description 2
229920003051 synthetic elastomer Polymers 0.000 description 2
239000005061 synthetic rubber Substances 0.000 description 2
239000012780 transparent material Substances 0.000 description 2
PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical class ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
BTOVVHWKPVSLBI-UHFFFAOYSA-N 2-methylprop-1-enylbenzene Chemical compound CC(C)=CC1=CC=CC=C1 BTOVVHWKPVSLBI-UHFFFAOYSA-N 0.000 description 1
DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
UFERIGCCDYCZLN-UHFFFAOYSA-N 3a,4,7,7a-tetrahydro-1h-indene Chemical compound C1C=CCC2CC=CC21 UFERIGCCDYCZLN-UHFFFAOYSA-N 0.000 description 1
VJOWMORERYNYON-UHFFFAOYSA-N 5-ethenyl-2-methylpyridine Chemical compound CC1=CC=C(C=C)C=N1 VJOWMORERYNYON-UHFFFAOYSA-N 0.000 description 1
229920002126 Acrylic acid copolymer Polymers 0.000 description 1
239000004604 Blowing Agent Substances 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
244000178870 Lavandula angustifolia Species 0.000 description 1
235000010663 Lavandula angustifolia Nutrition 0.000 description 1
229920000459 Nitrile rubber Polymers 0.000 description 1
229920001890 Novodur Polymers 0.000 description 1
YMOONIIMQBGTDU-VOTSOKGWSA-N [(e)-2-bromoethenyl]benzene Chemical compound Br\C=C\C1=CC=CC=C1 YMOONIIMQBGTDU-VOTSOKGWSA-N 0.000 description 1
ATMLPEJAVWINOF-UHFFFAOYSA-N acrylic acid acrylic acid Chemical compound OC(=O)C=C.OC(=O)C=C ATMLPEJAVWINOF-UHFFFAOYSA-N 0.000 description 1
229920001893 acrylonitrile styrene Polymers 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
238000000149 argon plasma sintering Methods 0.000 description 1
NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
125000003963 dichloro group Chemical group Cl* 0.000 description 1
239000000975 dye Substances 0.000 description 1
229920001198 elastomeric copolymer Polymers 0.000 description 1
238000004945 emulsification Methods 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000012765 fibrous filler Substances 0.000 description 1
239000000945 filler Substances 0.000 description 1
NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
238000005227 gel permeation chromatography Methods 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
239000004816 latex Substances 0.000 description 1
239000001102 lavandula vera Substances 0.000 description 1
235000018219 lavender Nutrition 0.000 description 1
238000005259 measurement Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate group Chemical group C(C(=C)C)(=O)[O-] CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
238000003801 milling Methods 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
235000010446 mineral oil Nutrition 0.000 description 1
229920003052 natural elastomer Polymers 0.000 description 1
229920001194 natural rubber Polymers 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920005553 polystyrene-acrylate Polymers 0.000 description 1
239000005077 polysulfide Substances 0.000 description 1
229920001021 polysulfide Polymers 0.000 description 1
150000008117 polysulfides Polymers 0.000 description 1
229920002379 silicone rubber Polymers 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
229920001909 styrene-acrylic polymer Polymers 0.000 description 1
229920005792 styrene-acrylic resin Polymers 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229920003002 synthetic resin Polymers 0.000 description 1
239000000057 synthetic resin Substances 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
238000012360 testing method Methods 0.000 description 1
230000007704 transition Effects 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1

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Compositions Of Macromolecular Compounds (AREA)

JP23870584A 1984-11-14 1984-11-14 ポリメチルメタクリレ−トとあるスチレンコポリマ−との透明ブレンド物 Granted JPS61120843A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP23870584A JPS61120843A (ja)	1984-11-14	1984-11-14	ポリメチルメタクリレ−トとあるスチレンコポリマ−との透明ブレンド物

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP23870584A JPS61120843A (ja)	1984-11-14	1984-11-14	ポリメチルメタクリレ−トとあるスチレンコポリマ−との透明ブレンド物

Publications (2)

Publication Number	Publication Date
JPS61120843A true JPS61120843A (ja)	1986-06-07
JPS6340822B2 JPS6340822B2 (fr)	1988-08-12

Family

ID=17034055

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP23870584A Granted JPS61120843A (ja)	1984-11-14	1984-11-14	ポリメチルメタクリレ−トとあるスチレンコポリマ−との透明ブレンド物

Country Status (1)

Country	Link
JP (1)	JPS61120843A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2022140406A (ja) *	2021-03-10	2022-09-26	Ｐｓジャパン株式会社	スチレン系樹脂組成物、押出シート及び容器

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6143642A (ja) *	1984-08-08	1986-03-03	Dainippon Ink & Chem Inc	熱可塑性樹脂組成物

1984
- 1984-11-14 JP JP23870584A patent/JPS61120843A/ja active Granted

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6143642A (ja) *	1984-08-08	1986-03-03	Dainippon Ink & Chem Inc	熱可塑性樹脂組成物

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2022140406A (ja) *	2021-03-10	2022-09-26	Ｐｓジャパン株式会社	スチレン系樹脂組成物、押出シート及び容器

Also Published As

Publication number	Publication date
JPS6340822B2 (fr)	1988-08-12

Publication	Publication Date	Title
JP3784660B2 (ja)	2006-06-14	難燃性熱可塑性樹脂組成物
JPS5913539B2 (ja)	1984-03-30	セイケイセイジユウテンザイガンユウポリスチレンセイヒンノセイホウ
JPH09104811A (ja)	1997-04-22	ポリカーボネートとモノビニリデン芳香族コンパウンドとの耐燃性組成物
US4366289A (en)	1982-12-28	Acrylate-grafted elastomers as polymer modifiers
JPH09104795A (ja)	1997-04-22	耐衝撃性改良シンジオタクチックポリスチレン
JPH0333744B2 (fr)	1991-05-20
JPS62143957A (ja)	1987-06-27	スチレン系樹脂組成物
JPS5846269B2 (ja)	1983-10-15	成形用組成物
JPS6237671B2 (fr)	1987-08-13
KR19980026163A (ko)	1998-07-15	열가소성 수지 조성물
JPH02272050A (ja)	1990-11-06	透明性の熱可塑性樹脂組成物
US3592878A (en)	1971-07-13	Compositions comprising a high cis graft copolymer and a high trans graft copolymer
JPS5827738A (ja)	1983-02-18	熱可塑性成形材料
JPS61120843A (ja)	1986-06-07	ポリメチルメタクリレ−トとあるスチレンコポリマ−との透明ブレンド物
US4508871A (en)	1985-04-02	Transparent blends of polymethylmethacrylate and certain styrene copolymers
US5053456A (en)	1991-10-01	Transparent polyblends
EP0269027B1 (fr)	1994-01-19	Mélange à base de polymères vinylaromatiques ayant une bonne fluidité à l'état fondu et une bonne thermostabilité
KR860001118B1 (ko)	1986-08-13	폴리메틸 메트 아크릴레이트 및 스티렌 공중합체의 투명블랜드
JPH04505628A (ja)	1992-10-01	カーボネートポリマーとゴム改質ビニル芳香族ニトリルグラフトコポリマーとメチル（メタ）アクリレート―ブタジエン―スチレングラフトコポリマーとを含む成形用組成物及びこのような組成物を用いたブロー成形法と熱成形法
JP3135408B2 (ja)	2001-02-13	ポリアセタール樹脂組成物
CA1267743A (fr)	1990-04-10	Melanges transparents de polymethylmethacrylate et de certains copolymeres de styrene
JP3115438B2 (ja)	2000-12-04	ポリアセタール樹脂組成物
KR100372568B1 (ko)	2003-02-19	열가소성 수지조성물
JP2001072797A (ja)	2001-03-21	難燃剤含有組成物、及び難燃性熱可塑性樹脂組成物
US5256722A (en)	1993-10-26	Blends based on vinyl aromatic polymers having high molding fluidity and high thermo resistance

JPS61120843A - ポリメチルメタクリレ−トとあるスチレンコポリマ−との透明ブレンド物 - Google Patents

Info

Links

Landscapes

Priority Applications (1)

Applications Claiming Priority (1)

Publications (2)

Family

ID=17034055

Family Applications (1)

Country Status (1)

Cited By (1)

Citations (1)

Patent Citations (1)

Cited By (1)

Also Published As

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