JPS6132332B2 - - Google Patents

Info

Publication number: JPS6132332B2
Authority: JP; Japan
Prior art keywords: polymer; bpa; bisphenol; pyridine; carbonate
Prior art date: 1976-04-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP3626277A

Other languages

English (en)

Japanese (ja)

Other versions

JPS52128992A (en

Inventor

Shiriru Bureboruseku Deyushan

Kesutan Yari

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Honeywell International Inc

Original Assignee

Allied Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-04-02

Filing date

1977-04-01

Publication date

1986-07-26

1977-02-01 Priority claimed from US05/764,623 external-priority patent/US4156069A/en

1977-04-01 Application filed by Allied Corp filed Critical Allied Corp

1977-10-28 Publication of JPS52128992A publication Critical patent/JPS52128992A/ja

1986-07-26 Publication of JPS6132332B2 publication Critical patent/JPS6132332B2/ja

Status Granted legal-status Critical Current

Links

IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 174
229920000642 polymer Polymers 0.000 claims description 97
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 84
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 82
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 41
LXEJRKJRKIFVNY-UHFFFAOYSA-N terephthaloyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C=C1 LXEJRKJRKIFVNY-UHFFFAOYSA-N 0.000 claims description 40
229920001577 copolymer Polymers 0.000 claims description 39
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 27
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 24
229920000728 polyester Polymers 0.000 claims description 23
YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 claims description 20
238000006243 chemical reaction Methods 0.000 claims description 19
239000011541 reaction mixture Substances 0.000 claims description 18
239000002904 solvent Substances 0.000 claims description 15
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
239000012429 reaction media Substances 0.000 claims description 12
238000012360 testing method Methods 0.000 claims description 12
238000000034 method Methods 0.000 claims description 11
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims description 11
229920000515 polycarbonate Polymers 0.000 claims description 10
239000004417 polycarbonate Substances 0.000 claims description 10
230000015572 biosynthetic process Effects 0.000 claims description 7
239000003795 chemical substances by application Substances 0.000 claims description 7
229910052757 nitrogen Inorganic materials 0.000 claims description 6
238000004260 weight control Methods 0.000 claims description 6
230000009477 glass transition Effects 0.000 claims description 5
238000004519 manufacturing process Methods 0.000 claims description 5
239000003960 organic solvent Substances 0.000 claims description 5
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
-1 bisphenol A diester Chemical class 0.000 claims description 4
230000006835 compression Effects 0.000 claims description 4
238000007906 compression Methods 0.000 claims description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
150000002989 phenols Chemical class 0.000 claims description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 3
238000000113 differential scanning calorimetry Methods 0.000 claims description 3
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 3
229910000041 hydrogen chloride Inorganic materials 0.000 claims description 3
230000008859 change Effects 0.000 claims description 2
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims 2
XGIAHMUOCFHQTI-UHFFFAOYSA-N Cl.Cl.Cl.Cl.CC Chemical compound Cl.Cl.Cl.Cl.CC XGIAHMUOCFHQTI-UHFFFAOYSA-N 0.000 claims 1
229910052786 argon Inorganic materials 0.000 claims 1
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 33
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 26
239000000243 solution Substances 0.000 description 24
239000000047 product Substances 0.000 description 23
239000000376 reactant Substances 0.000 description 13
239000000203 mixture Substances 0.000 description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
230000000052 comparative effect Effects 0.000 description 9
150000002148 esters Chemical class 0.000 description 8
238000000465 moulding Methods 0.000 description 8
239000007787 solid Substances 0.000 description 7
238000010521 absorption reaction Methods 0.000 description 6
238000005299 abrasion Methods 0.000 description 5
238000004458 analytical method Methods 0.000 description 5
238000005119 centrifugation Methods 0.000 description 5
150000005690 diesters Chemical class 0.000 description 5
239000000178 monomer Substances 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
238000003756 stirring Methods 0.000 description 5
238000005406 washing Methods 0.000 description 5
QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 4
239000002253 acid Substances 0.000 description 4
229920005603 alternating copolymer Polymers 0.000 description 4
238000011088 calibration curve Methods 0.000 description 4
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
239000007788 liquid Substances 0.000 description 4
238000005259 measurement Methods 0.000 description 4
238000001556 precipitation Methods 0.000 description 4
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
238000013019 agitation Methods 0.000 description 3
AOGYCOYQMAVAFD-UHFFFAOYSA-N chlorocarbonic acid Chemical group OC(Cl)=O AOGYCOYQMAVAFD-UHFFFAOYSA-N 0.000 description 3
238000001816 cooling Methods 0.000 description 3
238000010586 diagram Methods 0.000 description 3
238000001125 extrusion Methods 0.000 description 3
239000011521 glass Substances 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
239000002245 particle Substances 0.000 description 3
238000000746 purification Methods 0.000 description 3
239000002994 raw material Substances 0.000 description 3
238000000926 separation method Methods 0.000 description 3
239000000126 substance Substances 0.000 description 3
WEHZNZTWKUYVIY-UHFFFAOYSA-N 3-oxabicyclo[3.2.2]nona-1(7),5,8-triene-2,4-dione Chemical compound O=C1OC(=O)C2=CC=C1C=C2 WEHZNZTWKUYVIY-UHFFFAOYSA-N 0.000 description 2
OCKGFTQIICXDQW-ZEQRLZLVSA-N 5-[(1r)-1-hydroxy-2-[4-[(2r)-2-hydroxy-2-(4-methyl-1-oxo-3h-2-benzofuran-5-yl)ethyl]piperazin-1-yl]ethyl]-4-methyl-3h-2-benzofuran-1-one Chemical compound C1=C2C(=O)OCC2=C(C)C([C@@H](O)CN2CCN(CC2)C[C@H](O)C2=CC=C3C(=O)OCC3=C2C)=C1 OCKGFTQIICXDQW-ZEQRLZLVSA-N 0.000 description 2
XVMSFILGAMDHEY-UHFFFAOYSA-N 6-(4-aminophenyl)sulfonylpyridin-3-amine Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=N1 XVMSFILGAMDHEY-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical compound ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
230000009471 action Effects 0.000 description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
150000008064 anhydrides Chemical class 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
150000007942 carboxylates Chemical class 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
238000006731 degradation reaction Methods 0.000 description 2
238000004821 distillation Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
230000001747 exhibiting effect Effects 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
239000012535 impurity Substances 0.000 description 2
239000011261 inert gas Substances 0.000 description 2
238000002329 infrared spectrum Methods 0.000 description 2
238000001746 injection moulding Methods 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
239000000843 powder Substances 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
239000002243 precursor Substances 0.000 description 2
AOJFQRQNPXYVLM-UHFFFAOYSA-N pyridin-1-ium;chloride Chemical compound [Cl-].C1=CC=[NH+]C=C1 AOJFQRQNPXYVLM-UHFFFAOYSA-N 0.000 description 2
239000011877 solvent mixture Substances 0.000 description 2
238000001228 spectrum Methods 0.000 description 2
229950011008 tetrachloroethylene Drugs 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
230000004580 weight loss Effects 0.000 description 2
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
ZNJRONVKWRHYBF-UHFFFAOYSA-N 2-[2-[2-(1-azatricyclo[7.3.1.05,13]trideca-5,7,9(13)-trien-7-yl)ethenyl]-6-methylpyran-4-ylidene]propanedinitrile Chemical group O1C(C)=CC(=C(C#N)C#N)C=C1C=CC1=CC(CCCN2CCC3)=C2C3=C1 ZNJRONVKWRHYBF-UHFFFAOYSA-N 0.000 description 1
WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
229910000619 316 stainless steel Inorganic materials 0.000 description 1
QCQCHGYLTSGIGX-GHXANHINSA-N 4-[[(3ar,5ar,5br,7ar,9s,11ar,11br,13as)-5a,5b,8,8,11a-pentamethyl-3a-[(5-methylpyridine-3-carbonyl)amino]-2-oxo-1-propan-2-yl-4,5,6,7,7a,9,10,11,11b,12,13,13a-dodecahydro-3h-cyclopenta[a]chrysen-9-yl]oxy]-2,2-dimethyl-4-oxobutanoic acid Chemical compound N([C@@]12CC[C@@]3(C)[C@]4(C)CC[C@H]5C(C)(C)[C@@H](OC(=O)CC(C)(C)C(O)=O)CC[C@]5(C)[C@H]4CC[C@@H]3C1=C(C(C2)=O)C(C)C)C(=O)C1=CN=CC(C)=C1 QCQCHGYLTSGIGX-GHXANHINSA-N 0.000 description 1
101710134784 Agnoprotein Proteins 0.000 description 1
DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
229910002808 Si–O–Si Inorganic materials 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
PWAXUOGZOSVGBO-UHFFFAOYSA-N adipoyl chloride Chemical compound ClC(=O)CCCCC(Cl)=O PWAXUOGZOSVGBO-UHFFFAOYSA-N 0.000 description 1
230000002411 adverse Effects 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
238000013459 approach Methods 0.000 description 1
239000012300 argon atmosphere Substances 0.000 description 1
230000005540 biological transmission Effects 0.000 description 1
229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000005587 carbonate group Chemical group 0.000 description 1
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000000748 compression moulding Methods 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
239000003502 gasoline Substances 0.000 description 1
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
DKAGJZJALZXOOV-UHFFFAOYSA-N hydrate;hydrochloride Chemical compound O.Cl DKAGJZJALZXOOV-UHFFFAOYSA-N 0.000 description 1
230000002779 inactivation Effects 0.000 description 1
239000012442 inert solvent Substances 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
238000011835 investigation Methods 0.000 description 1
238000002955 isolation Methods 0.000 description 1
238000011005 laboratory method Methods 0.000 description 1
238000002789 length control Methods 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
238000011068 loading method Methods 0.000 description 1
238000000691 measurement method Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
NZZGQZMNFCTNAM-UHFFFAOYSA-N naphthalene-2,6-dicarbonyl chloride Chemical compound C1=C(C(Cl)=O)C=CC2=CC(C(=O)Cl)=CC=C21 NZZGQZMNFCTNAM-UHFFFAOYSA-N 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
239000012074 organic phase Substances 0.000 description 1
QBDSZLJBMIMQRS-UHFFFAOYSA-N p-Cumylphenol Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=CC=C1 QBDSZLJBMIMQRS-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
230000008569 process Effects 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
238000010926 purge Methods 0.000 description 1
238000010791 quenching Methods 0.000 description 1
230000000171 quenching effect Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000003303 reheating Methods 0.000 description 1
238000011160 research Methods 0.000 description 1
238000006748 scratching Methods 0.000 description 1
230000002393 scratching effect Effects 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
238000009864 tensile test Methods 0.000 description 1
238000012546 transfer Methods 0.000 description 1
238000001721 transfer moulding Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/64—Polyesters containing both carboxylic ester groups and carbonate groups
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polyesters Or Polycarbonates (AREA)

JP3626277A 1976-04-02 1977-04-01 Melt processing copolymer of bisphenol aatelephthalateecarbonate and preparation thereof Granted JPS52128992A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US67294576A	1976-04-02	1976-04-02
US05/764,623 US4156069A (en)	1976-04-02	1977-02-01	Bisphenol-A/terephthalate/carbonate melt processable copolymers

Publications (2)

Publication Number	Publication Date
JPS52128992A JPS52128992A (en)	1977-10-28
JPS6132332B2 true JPS6132332B2 (fr)	1986-07-26

Family

ID=27100852

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP3626277A Granted JPS52128992A (en)	1976-04-02	1977-04-01	Melt processing copolymer of bisphenol aatelephthalateecarbonate and preparation thereof

Country Status (6)

Country	Link
JP (1)	JPS52128992A (fr)
CA (1)	CA1100681A (fr)
DE (1)	DE2714544A1 (fr)
FR (1)	FR2346386A1 (fr)
GB (1)	GB1552558A (fr)
IT (1)	IT1116721B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0610458U (ja) *	1992-07-10	1994-02-10	ナショナル住宅産業株式会社	手摺りの取り付け構造

Families Citing this family (187)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0006965A1 (fr) *	1978-03-31	1980-01-23	Allied Corporation	Polyester-carbonates contenant des parties de bisphénol A et d'acide trans-1,4-cyclohexanedicarboxylique et leur procédé de préparation
JPS5525427A (en) *	1978-08-10	1980-02-23	Mitsubishi Chem Ind Ltd	Preparation of aromatic polyester-polycarbonate
JPS5532183U (fr) *	1978-08-25	1980-03-01
JPS5543159A (en) *	1978-09-22	1980-03-26	Mitsubishi Chem Ind Ltd	Aromatic polyester polycarbonate
JPS5543137A (en) *	1978-09-21	1980-03-26	Mitsubishi Chem Ind Ltd	Aromatic polyestercarbonate resin composition
JPS5550059A (en) *	1978-10-04	1980-04-11	Mitsubishi Chem Ind Ltd	Resin composition
JPS5550061A (en) *	1978-10-06	1980-04-11	Mitsubishi Chem Ind Ltd	Resin composition
JPS5552345A (en) *	1978-10-13	1980-04-16	Mitsubishi Chem Ind Ltd	Resin composition
JPS5556152A (en) *	1978-10-23	1980-04-24	Mitsubishi Chem Ind Ltd	Aromatic polyester polycarbomate resin composition
JPS5558250A (en) *	1978-10-26	1980-04-30	Mitsubishi Chem Ind Ltd	Aromatic polyester-polycarbonate resin composition
EP0012203B1 (fr) *	1978-11-30	1983-05-11	Allied Corporation	Polycarbonates à résistance améliorée au vieillissement
JPS5590550A (en) *	1978-12-28	1980-07-09	Mitsubishi Chem Ind Ltd	Resin composition
US4194038A (en) *	1979-01-25	1980-03-18	Allied Chemical Corporation	Poly(ester-carbonates) from dicarboxylic acid chlorides
JPS55110153A (en) *	1979-02-16	1980-08-25	Mitsubishi Chem Ind Ltd	Resin composition
US4238596A (en) *	1979-04-26	1980-12-09	General Electric Company	Process for obtaining copolyester-carbonates
US4238597A (en)	1979-04-26	1980-12-09	General Electric Company	Process for producing copolyester-carbonates
GB2060664B (en) *	1979-07-25	1983-10-26	Secr Defence	Polyester carbonates
JPS5661429A (en) *	1979-10-24	1981-05-26	Mitsubishi Chem Ind Ltd	Production of aromatic polyester-polycarbonate
DE3007934A1 (de) *	1980-03-01	1981-09-17	Bayer Ag, 5090 Leverkusen	Aromatische polyestercarbonate, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von spritzgussartikeln, folien und ueberzuegen
JPS57174343A (en) *	1981-04-21	1982-10-27	Mitsubishi Chem Ind Ltd	Aromatic polyester polycarbonate resin composition
JPS5859255A (ja) *	1982-08-13	1983-04-08	Mitsubishi Chem Ind Ltd	芳香族ポリエステルポリカ−ボネ−ト樹脂組成物
DE3346946A1 (de) *	1983-12-24	1985-07-04	Bayer Ag, 5090 Leverkusen	Verfahren zur herstellung von farblosen aromatischen polyestern und polyestercarbonaten
DE3726189A1 (de) *	1987-08-06	1989-02-16	Eyemetrics Systems Ag	Brillengestelle und teile davon
EP0695785B1 (fr)	1994-08-01	1998-05-20	Bayer Ag	Mélanges de polycarbonate, de polyesters d'acides gras dimériques ramifiés à fonctions hydroxyles phénoliques et éventuellement des copolymères greffés
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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3030331A (en) *	1957-08-22	1962-04-17	Gen Electric	Process for preparing copolyesters comprising reacting a carbonyl halide with a dicarboxylic acid and a dihydroxy compound in the presence of a tertiary amine
IT595468A (fr) *	1957-08-22
US3177179A (en) *	1960-05-31	1965-04-06	Dow Chemical Co	Chain terminated polycarbonates
DE1447674A1 (de) *	1962-04-10	1968-12-05	Gen Electric	Schleierfreie fotografische Filme
DE2435507C3 (de) *	1974-07-24	1980-04-30	Bayer Ag, 5090 Leverkusen	Carbonatmodifizierte Copolyester, Verfahren zu ihrer Herstellung und ihre Verwendung

1977
- 1977-03-28 IT IT6766377A patent/IT1116721B/it active
- 1977-04-01 JP JP3626277A patent/JPS52128992A/ja active Granted
- 1977-04-01 CA CA275,320A patent/CA1100681A/fr not_active Expired
- 1977-04-01 GB GB1393477A patent/GB1552558A/en not_active Expired
- 1977-04-01 DE DE19772714544 patent/DE2714544A1/de active Granted
- 1977-04-01 FR FR7709993A patent/FR2346386A1/fr active Granted

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0610458U (ja) *	1992-07-10	1994-02-10	ナショナル住宅産業株式会社	手摺りの取り付け構造

Also Published As

Publication number	Publication date
DE2714544C2 (fr)	1990-01-04
JPS52128992A (en)	1977-10-28
IT1116721B (it)	1986-02-10
DE2714544A1 (de)	1977-10-06
CA1100681A (fr)	1981-05-05
GB1552558A (en)	1979-09-12
FR2346386A1 (fr)	1977-10-28
FR2346386B1 (fr)	1984-02-10

Publication	Publication Date	Title
US4156069A (en)	1979-05-22	Bisphenol-A/terephthalate/carbonate melt processable copolymers
CA1100681A (fr)	1981-05-05	Traduction non-disponible
EP0000832B1 (fr)	1984-02-01	Procédé de préparation de phthalates de polyrésorcinol se prêtant au façonnage à l'état fondu
US4194038A (en)	1980-03-18	Poly(ester-carbonates) from dicarboxylic acid chlorides
EP0888414B1 (fr)	2001-05-16	Procede ameliore pour fabriquer des polymeres a cristaux liquides thermotropiques contenant de l'hydroquinone
JP2002512279A (ja)	2002-04-23	イソソルビドをコモノマーとして含有させたポリエステルおよびそれの製造方法
JPS638142B2 (fr)	1988-02-20
JPH0156089B2 (fr)	1989-11-28
JPS6326129B2 (fr)	1988-05-28
JPH0565340A (ja)	1993-03-19	液晶性ポリエステルアミド
JPH0356527A (ja)	1991-03-12	芳香族ポリエステル及びその製造方法
JPH0131497B2 (fr)	1989-06-26
JPH0345092B2 (fr)	1991-07-10
JPH0645677B2 (ja)	1994-06-15	熱互変性芳香族コポリエステル及びその製造法
EP0117556B1 (fr)	1991-04-24	Polyestersulfones aromatiques résistant aux températures élevées et procédé pour leur préparation
JP3136771B2 (ja)	2001-02-19	芳香族共重合ポリエステルの製造方法
EP0578846A1 (fr)	1994-01-19	Polyesters aromatiques thermotropes et cristallines liquides
EP0399349A2 (fr)	1990-11-28	Copolyesters thermotropes aromatiques façonnables à l'état fondu et leur procédé de préparation
US4937319A (en)	1990-06-26	Process for producing aromatic polyesters
KR960006300B1 (ko)	1996-05-13	방향족 코폴리에스테르와 그의 제조방법
JPH0364320A (ja)	1991-03-19	芳香族ポリエステルの製法
JP3132853B2 (ja)	2001-02-05	芳香族ポリエステルアミド及びその製造方法
KR840001927B1 (ko)	1984-10-25	교호 코폴리에스테르 카보네이트 수지의 제조방법
US4645820A (en)	1987-02-24	Partially crystalline poly(sulfone ester) resin
JP2608151B2 (ja)	1997-05-07	耐加水分解性の改善されたポリアリレート樹脂およびその製造方法

JPS6132332B2 - - Google Patents

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Cited By (1)

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