JPS6237660B2 - - Google Patents

Info

Publication number: JPS6237660B2
Authority: JP; Japan
Prior art keywords: silane; crosslinking; polyolefin; group; molded product
Prior art date: 1977-06-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP7609977A

Other languages

English (en)

Japanese (ja)

Other versions

JPS5411154A (en

Inventor

Hiroshi Hirukawa

Kenichi Ootani

Eisuke Saito

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Furukawa Electric Co Ltd

Original Assignee

Furukawa Electric Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-06-28

Filing date

1977-06-28

Publication date

1987-08-13

1977-06-28 Application filed by Furukawa Electric Co Ltd filed Critical Furukawa Electric Co Ltd

1977-06-28 Priority to JP7609977A priority Critical patent/JPS5411154A/ja

1979-01-27 Publication of JPS5411154A publication Critical patent/JPS5411154A/ja

1987-08-13 Publication of JPS6237660B2 publication Critical patent/JPS6237660B2/ja

Status Granted legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 claims description 24
229920000098 polyolefin Polymers 0.000 claims description 24
-1 silane compound Chemical class 0.000 claims description 19
229920000642 polymer Polymers 0.000 claims description 13
239000002904 solvent Substances 0.000 claims description 13
229910000077 silane Inorganic materials 0.000 claims description 12
SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims description 12
238000009833 condensation Methods 0.000 claims description 11
230000005494 condensation Effects 0.000 claims description 11
229920001112 grafted polyolefin Polymers 0.000 claims description 11
238000004519 manufacturing process Methods 0.000 claims description 7
239000011259 mixed solution Substances 0.000 claims description 7
150000002430 hydrocarbons Chemical group 0.000 claims description 4
150000003254 radicals Chemical class 0.000 claims description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
150000001875 compounds Chemical class 0.000 claims description 3
239000001257 hydrogen Substances 0.000 claims description 3
229910052739 hydrogen Inorganic materials 0.000 claims description 3
125000000962 organic group Chemical group 0.000 claims description 3
229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 3
238000004132 cross linking Methods 0.000 description 30
239000000047 product Substances 0.000 description 30
238000000034 method Methods 0.000 description 14
239000004698 Polyethylene Substances 0.000 description 13
239000000203 mixture Substances 0.000 description 13
229920000573 polyethylene Polymers 0.000 description 13
AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 11
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 9
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
230000000052 comparative effect Effects 0.000 description 6
XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 5
239000004594 Masterbatch (MB) Substances 0.000 description 5
238000001125 extrusion Methods 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 4
239000011248 coating agent Substances 0.000 description 4
238000000576 coating method Methods 0.000 description 4
NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 4
238000000465 moulding Methods 0.000 description 4
230000008569 process Effects 0.000 description 4
239000008096 xylene Substances 0.000 description 4
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
239000006260 foam Substances 0.000 description 3
238000007654 immersion Methods 0.000 description 3
239000011877 solvent mixture Substances 0.000 description 3
CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000004927 clay Substances 0.000 description 2
239000012141 concentrate Substances 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
238000009792 diffusion process Methods 0.000 description 2
FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical group CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 2
230000004807 localization Effects 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
BOOBDAVNHSOIDB-UHFFFAOYSA-N (2,3-dichlorobenzoyl) 2,3-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC=CC(C(=O)OOC(=O)C=2C(=C(Cl)C=CC=2)Cl)=C1Cl BOOBDAVNHSOIDB-UHFFFAOYSA-N 0.000 description 1
239000004156 Azodicarbonamide Substances 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
239000004604 Blowing Agent Substances 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
239000004709 Chlorinated polyethylene Substances 0.000 description 1
239000004606 Fillers/Extenders Substances 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
239000005062 Polybutadiene Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
229920003182 Surlyn® Polymers 0.000 description 1
239000012963 UV stabilizer Substances 0.000 description 1
230000009471 action Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
235000019399 azodicarbonamide Nutrition 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
229920005549 butyl rubber Polymers 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000010382 chemical cross-linking Methods 0.000 description 1
239000011247 coating layer Substances 0.000 description 1
239000003086 colorant Substances 0.000 description 1
239000004020 conductor Substances 0.000 description 1
229920003020 cross-linked polyethylene Polymers 0.000 description 1
239000004703 cross-linked polyethylene Substances 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
PNOXNTGLSKTMQO-UHFFFAOYSA-L diacetyloxytin Chemical compound CC(=O)O[Sn]OC(C)=O PNOXNTGLSKTMQO-UHFFFAOYSA-L 0.000 description 1
238000007323 disproportionation reaction Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
238000010894 electron beam technology Methods 0.000 description 1
239000005038 ethylene vinyl acetate Substances 0.000 description 1
229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
238000005187 foaming Methods 0.000 description 1
239000004088 foaming agent Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
229920002681 hypalon Polymers 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
229920000554 ionomer Polymers 0.000 description 1
239000010410 layer Substances 0.000 description 1
GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
239000012046 mixed solvent Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229920003052 natural elastomer Polymers 0.000 description 1
229920001194 natural rubber Polymers 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
239000008188 pellet Substances 0.000 description 1
239000012466 permeate Substances 0.000 description 1
229920001084 poly(chloroprene) Polymers 0.000 description 1
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
229920002857 polybutadiene Polymers 0.000 description 1
229920001748 polybutylene Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
239000005060 rubber Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1

Landscapes

Processes Of Treating Macromolecular Substances (AREA)
Compositions Of Macromolecular Compounds (AREA)

JP7609977A 1977-06-28 1977-06-28 Production of crosslinked polyolefin molded product Granted JPS5411154A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP7609977A JPS5411154A (en)	1977-06-28	1977-06-28	Production of crosslinked polyolefin molded product

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP7609977A JPS5411154A (en)	1977-06-28	1977-06-28	Production of crosslinked polyolefin molded product

Publications (2)

Publication Number	Publication Date
JPS5411154A JPS5411154A (en)	1979-01-27
JPS6237660B2 true JPS6237660B2 (fr)	1987-08-13

Family

ID=13595407

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP7609977A Granted JPS5411154A (en)	1977-06-28	1977-06-28	Production of crosslinked polyolefin molded product

Country Status (1)

Country	Link
JP (1)	JPS5411154A (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5759724A (en) *	1980-09-29	1982-04-10	Mitsui Petrochem Ind Ltd	Method for crosslinking polyethylene pipe grafted with silane compound
JPS5935125U (ja) *	1982-08-30	1984-03-05	トヨタ自動車株式会社	車両用クラツチブ−スタ装置の管路
JPS6013804A (ja) *	1983-07-04	1985-01-24	Toa Nenryo Kogyo Kk	架橋性樹脂組成物
DE3327149A1 (de) *	1983-07-28	1985-04-04	Dynamit Nobel Ag, 5210 Troisdorf	Verfahren zum herstellen von halbzeugen bzw. formteilen aus polypropylen

1977
- 1977-06-28 JP JP7609977A patent/JPS5411154A/ja active Granted

Also Published As

Publication number	Publication date
JPS5411154A (en)	1979-01-27

Publication	Publication Date	Title
DE2740709C3 (de)	1981-07-02	Verfahren zur Herstellung eines geformten, geschäumten und vernetzten Gegenstandes aus Äthylenpolymerisatharzen
US5492760A (en)	1996-02-20	Water tree resistant, moisture curable insulation composition for power cables
JPS5861129A (ja)	1983-04-12	発泡体の製造法
US20080281009A1 (en)	2008-11-13	Cross-linked polyolefin foam
JPH0995590A (ja)	1997-04-08	シラン架橋ポリオレフィンの製造方法
US4680319A (en)	1987-07-14	Accelerated crosslinking of polyolefins grafted with silanes
JP2002146150A (ja)	2002-05-22	シラン架橋ポリオレフィン成型物
JPH07238220A (ja)	1995-09-12	ポリウレタン樹脂組成物及び電線
US4289860A (en)	1981-09-15	Grafting of silane on thermoplastics or elastomers for purposes of cross linking
JP2012256527A (ja)	2012-12-27	シラン架橋ポリオレフィン絶縁電線
JP3959575B2 (ja)	2007-08-15	シラン変性直鎖状ポリエチレンを被覆し、水架橋させてなる電力ケーブルの製造方法
JPS5845942B2 (ja)	1983-10-13	シラン架橋ポリオレフイン系樹脂組成物成形体の製造方法
JPH02107643A (ja)	1990-04-19	耐熱性連続気泡型架橋エチレン系樹脂発泡体組成物
JPS6160727A (ja)	1986-03-28	架橋ポリオレフイン系樹脂組成物及びその製造方法
FR2783830A1 (fr)	2000-03-31	Procede de fabrication d'une mousse de polyolefine reticulee
JP2012149162A (ja)	2012-08-09	シラン架橋樹脂成形体の製造方法及びそれを用いた成形体
JP3090695B2 (ja)	2000-09-25	オレフィン系樹脂架橋発泡体の製造方法
JP4608802B2 (ja)	2011-01-12	シラン架橋ポリオレフィンを用いた成形物及び電線・ケーブル
JP3858511B2 (ja)	2006-12-13	電線・ケーブル
JPH08134147A (ja)	1996-05-28	水架橋性不飽和アルコキシシラングラフト直鎖状低密度エチレン−α−オレフィン共重合体の製造方法および水架橋成形物
JPS6042808B2 (ja)	1985-09-25	ポリエチレン樹脂の改良された架橋方法
JP3692410B2 (ja)	2005-09-07	水架橋ポリプロピレン系樹脂発泡体の製造方法
JP3352631B2 (ja)	2002-12-03	シラン架橋ポリオレフィン樹脂組成物及び絶縁ケーブル
JP2000294037A (ja)	2000-10-20	電気絶縁組成物及び電線・ケーブル
JPS58134133A (ja)	1983-08-10	架橋発泡性プロピレン系樹脂組成物