JPS6474202A - Catalyst system for olefin polymerization and olefin copolymerization - Google Patents

Catalyst system for olefin polymerization and olefin copolymerization

Info

Publication number
JPS6474202A
JPS6474202A JP62259836A JP25983687A JPS6474202A JP S6474202 A JPS6474202 A JP S6474202A JP 62259836 A JP62259836 A JP 62259836A JP 25983687 A JP25983687 A JP 25983687A JP S6474202 A JPS6474202 A JP S6474202A
Authority
JP
Japan
Prior art keywords
olefin
polymerization
catalyst system
copolymerization
catalyst systems
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62259836A
Other languages
English (en)
Other versions
JP2669833B2 (ja
Inventor
Ei Yuuen Jiyon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cosden Technology Inc
Original Assignee
Cosden Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cosden Technology Inc filed Critical Cosden Technology Inc
Publication of JPS6474202A publication Critical patent/JPS6474202A/ja
Application granted granted Critical
Publication of JP2669833B2 publication Critical patent/JP2669833B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63904—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with another component of C08F4/62
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP62259836A 1987-09-11 1987-10-16 オレフインの重合及びオレフインの共重合のための触媒系 Expired - Fee Related JP2669833B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US9575587A 1987-09-11 1987-09-11
US95755 1987-09-11

Publications (2)

Publication Number Publication Date
JPS6474202A true JPS6474202A (en) 1989-03-20
JP2669833B2 JP2669833B2 (ja) 1997-10-29

Family

ID=22253445

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62259836A Expired - Fee Related JP2669833B2 (ja) 1987-09-11 1987-10-16 オレフインの重合及びオレフインの共重合のための触媒系

Country Status (7)

Country Link
EP (1) EP0310734B1 (ja)
JP (1) JP2669833B2 (ja)
KR (1) KR950008152B1 (ja)
AT (1) ATE114323T1 (ja)
CA (1) CA1323621C (ja)
DE (1) DE3750776T2 (ja)
ES (1) ES2064322T3 (ja)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01203404A (ja) * 1987-12-21 1989-08-16 Hoechst Ag 1―オレフインポリマーワックス、およびその製造方法並びにその製造に使用するメタロセン/アルミノキサン触媒及びそのメタロセン
JPH01301704A (ja) * 1987-11-09 1989-12-05 Chisso Corp 立体規則性オレフィン重合体製造用触媒
JPH0222307A (ja) * 1988-07-12 1990-01-25 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびオレフィンの重合方法
JPH06179776A (ja) * 1992-09-12 1994-06-28 Hoechst Ag 広範な融点範囲を有するポリオレフィン成形組成物とその調製方法及びその利用
JPH07309910A (ja) * 1994-05-19 1995-11-28 Chisso Corp 改質ポリプロピレンの製造方法および成形品
JP2005504148A (ja) * 2001-09-27 2005-02-10 アトフイナ・リサーチ・ソシエテ・アノニム ポリオレフィン配合物を製造するための触媒成分混合物を含んで成る触媒系
JP2008518069A (ja) * 2004-10-25 2008-05-29 トータル・ペトロケミカルズ・リサーチ・フエリユイ 異なる環を有するビスインデニル−ベースのリガンドを有するldpeのようなポリマー
JPWO2020189676A1 (ja) * 2019-03-19 2020-09-24
JP2022158974A (ja) * 2021-03-31 2022-10-17 三井化学株式会社 オレフィン重合体の製造方法

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE132168T1 (de) * 1991-05-27 1996-01-15 Hoechst Ag Verfahren zur herstellung von syndiotaktischen polyolefinen mit breiter molmassenverteilung
EP0702030B1 (de) * 1991-05-27 2001-03-21 TARGOR GmbH Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung
EP0611377B1 (en) * 1991-11-07 2001-08-01 ExxonMobil Chemical Patents Inc. Process for producing polyolefin
US6143854A (en) * 1993-08-06 2000-11-07 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
EP0854212A1 (en) * 1993-05-25 1998-07-22 Exxon Chemical Patents Inc. Novel polyolefin fibers and their fabrics
DE69422410T2 (de) * 1993-08-06 2000-07-06 Exxon Chemical Patents, Inc. Polymerisationskataylsatoren, ihre herstellung und verwendung
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
ES2116188B1 (es) 1994-12-30 1999-04-01 Repsol Quimica Sa Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.
US5516848A (en) * 1995-01-31 1996-05-14 Exxon Chemical Patents Inc. Process to produce thermoplastic elastomers
US5539056A (en) * 1995-01-31 1996-07-23 Exxon Chemical Patents Inc. Thermoplastic elastomers
US5786291A (en) * 1996-02-23 1998-07-28 Exxon Chemical Patents, Inc. Engineered catalyst systems and methods for their production and use
EP1083188A1 (en) 1999-09-10 2001-03-14 Fina Research S.A. Catalyst and process for the preparation of syndiotactic / atactic block polyolefins
US6576306B2 (en) 1996-09-04 2003-06-10 Exxonmobil Chemical Patents Inc. Propylene polymers for films
KR20000068428A (ko) 1996-09-04 2000-11-25 엑손 케미칼 패턴츠 인코포레이티드 배향 필름용의 개선된 프로필렌 중합체
US6583227B2 (en) 1996-09-04 2003-06-24 Exxonmobil Chemical Patents Inc. Propylene polymers for films
EP1059332A1 (en) * 1999-06-10 2000-12-13 Fina Research S.A. Polypropylene with high melt strength and drawability
CN1260257C (zh) 2001-06-29 2006-06-21 日本聚丙烯公司 烯烃聚合用催化剂及烯烃的聚合方法
JP4020862B2 (ja) * 2001-07-19 2007-12-12 ユニベーション・テクノロジーズ・エルエルシー コモノマー少量組込み触媒とコモノマー多量組込み触媒を含有する混合メタロセン触媒系
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
WO2005108442A1 (en) 2002-10-15 2005-11-17 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
WO2011087520A1 (en) 2009-12-22 2011-07-21 Univation Technologies, Llc Catalyst systems having a tailored hydrogen response
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
WO2010021304A1 (ja) 2008-08-19 2010-02-25 三井化学株式会社 混合触媒によるオレフィン重合体の製造方法
BRPI1010927A2 (pt) 2009-05-14 2016-04-05 Univation Tech Llc sistemas catalisadores de metal misturados que têm uma resposta de hidrogênio sob medida.

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6035008A (ja) * 1983-06-06 1985-02-22 エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− 幅広い分子量分布を有するポリエチレンの製造方法及びその触媒
JPS6035006A (ja) * 1983-06-06 1985-02-22 エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− 反応器ブレンドポリオレフインの製造方法及びその触媒

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
US4522982A (en) * 1983-06-06 1985-06-11 Exxon Research & Engineering Co. Isotactic-stereoblock polymers of alpha-olefins and process for producing the same
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
DE3508887A1 (de) * 1985-03-13 1986-09-25 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von optisch aktiven polyolefinen

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6035008A (ja) * 1983-06-06 1985-02-22 エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− 幅広い分子量分布を有するポリエチレンの製造方法及びその触媒
JPS6035006A (ja) * 1983-06-06 1985-02-22 エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− 反応器ブレンドポリオレフインの製造方法及びその触媒

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01301704A (ja) * 1987-11-09 1989-12-05 Chisso Corp 立体規則性オレフィン重合体製造用触媒
JPH01203404A (ja) * 1987-12-21 1989-08-16 Hoechst Ag 1―オレフインポリマーワックス、およびその製造方法並びにその製造に使用するメタロセン/アルミノキサン触媒及びそのメタロセン
JPH0222307A (ja) * 1988-07-12 1990-01-25 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびオレフィンの重合方法
JPH06179776A (ja) * 1992-09-12 1994-06-28 Hoechst Ag 広範な融点範囲を有するポリオレフィン成形組成物とその調製方法及びその利用
JPH07309910A (ja) * 1994-05-19 1995-11-28 Chisso Corp 改質ポリプロピレンの製造方法および成形品
JP2005504148A (ja) * 2001-09-27 2005-02-10 アトフイナ・リサーチ・ソシエテ・アノニム ポリオレフィン配合物を製造するための触媒成分混合物を含んで成る触媒系
JP2008518069A (ja) * 2004-10-25 2008-05-29 トータル・ペトロケミカルズ・リサーチ・フエリユイ 異なる環を有するビスインデニル−ベースのリガンドを有するldpeのようなポリマー
JPWO2020189676A1 (ja) * 2019-03-19 2020-09-24
JP2022158974A (ja) * 2021-03-31 2022-10-17 三井化学株式会社 オレフィン重合体の製造方法

Also Published As

Publication number Publication date
JP2669833B2 (ja) 1997-10-29
CA1323621C (en) 1993-10-26
EP0310734B1 (en) 1994-11-23
DE3750776D1 (de) 1995-01-05
DE3750776T2 (de) 1995-04-27
ES2064322T3 (es) 1995-02-01
ATE114323T1 (de) 1994-12-15
KR890005155A (ko) 1989-05-13
EP0310734A1 (en) 1989-04-12
KR950008152B1 (ko) 1995-07-25

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