NL1007121C2 - Hard PVC, gestabiliseerd met N,N-dimethyl-6-aminouracillen. - Google Patents

Hard PVC, gestabiliseerd met N,N-dimethyl-6-aminouracillen. Download PDF

Info

Publication number: NL1007121C2
Authority: NL; Netherlands
Prior art keywords: tert; butyl; acid; bis; pvc
Prior art date: 1996-09-25

Application number

NL1007121A

Other languages

English (en)

Dutch (nl)

Other versions

NL1007121A1 (nl

Inventor

Rolf Drewes

Wolfgang Wehner

Hans-Helmut Friedrich

Kornelia Malzacher

Original Assignee

Ciba Geigy Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-09-25

Filing date

1997-09-25

Publication date

1998-05-18

1997-09-25 Application filed by Ciba Geigy Ag filed Critical Ciba Geigy Ag

1998-03-31 Publication of NL1007121A1 publication Critical patent/NL1007121A1/xx

1998-05-18 Application granted granted Critical

1998-05-18 Publication of NL1007121C2 publication Critical patent/NL1007121C2/nl

Links

229910052757 nitrogen Inorganic materials 0.000 title description 6
239000000203 mixture Substances 0.000 description 70
-1 polydihydropyridines Chemical class 0.000 description 69
150000001875 compounds Chemical class 0.000 description 34
150000002148 esters Chemical class 0.000 description 17
229920001577 copolymer Polymers 0.000 description 16
239000004014 plasticizer Substances 0.000 description 16
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 15
239000007983 Tris buffer Substances 0.000 description 14
229920000642 polymer Polymers 0.000 description 14
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 13
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
229910052751 metal Inorganic materials 0.000 description 12
239000002184 metal Substances 0.000 description 12
239000003381 stabilizer Substances 0.000 description 12
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 11
229910052725 zinc Inorganic materials 0.000 description 11
239000011701 zinc Substances 0.000 description 11
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 10
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 10
239000002253 acid Substances 0.000 description 10
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 10
235000014113 dietary fatty acids Nutrition 0.000 description 9
239000000194 fatty acid Substances 0.000 description 9
229930195729 fatty acid Natural products 0.000 description 9
239000000049 pigment Substances 0.000 description 9
239000000344 soap Substances 0.000 description 9
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
239000000654 additive Substances 0.000 description 8
239000011575 calcium Substances 0.000 description 8
235000012424 soybean oil Nutrition 0.000 description 8
239000003549 soybean oil Substances 0.000 description 8
JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 7
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 7
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 7
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 7
239000011777 magnesium Substances 0.000 description 7
239000004800 polyvinyl chloride Substances 0.000 description 7
229920000915 polyvinyl chloride Polymers 0.000 description 7
229910052717 sulfur Inorganic materials 0.000 description 7
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 7
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000003963 antioxidant agent Substances 0.000 description 6
235000006708 antioxidants Nutrition 0.000 description 6
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 6
229910052791 calcium Inorganic materials 0.000 description 6
229910052749 magnesium Inorganic materials 0.000 description 6
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 6
230000006641 stabilisation Effects 0.000 description 6
238000011105 stabilization Methods 0.000 description 6
HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 6
239000001993 wax Substances 0.000 description 6
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 5
230000000996 additive effect Effects 0.000 description 5
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 5
150000007942 carboxylates Chemical class 0.000 description 5
150000001735 carboxylic acids Chemical class 0.000 description 5
XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 5
239000000314 lubricant Substances 0.000 description 5
238000000034 method Methods 0.000 description 5
SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 5
BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 5
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 5
229920003023 plastic Polymers 0.000 description 5
239000004033 plastic Substances 0.000 description 5
239000000047 product Substances 0.000 description 5
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 4
ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
239000004803 Di-2ethylhexylphthalate Substances 0.000 description 4
KCXZNSGUUQJJTR-UHFFFAOYSA-N Di-n-hexyl phthalate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC KCXZNSGUUQJJTR-UHFFFAOYSA-N 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
239000006057 Non-nutritive feed additive Substances 0.000 description 4
229910019142 PO4 Inorganic materials 0.000 description 4
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
229910052783 alkali metal Inorganic materials 0.000 description 4
229910052784 alkaline earth metal Inorganic materials 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 4
239000012964 benzotriazole Substances 0.000 description 4
FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 4
239000011888 foil Substances 0.000 description 4
239000000463 material Substances 0.000 description 4
DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
150000002815 nickel Chemical class 0.000 description 4
235000021317 phosphate Nutrition 0.000 description 4
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
235000013772 propylene glycol Nutrition 0.000 description 4
150000005846 sugar alcohols Polymers 0.000 description 4
YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 4
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
125000005591 trimellitate group Chemical group 0.000 description 4
ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 4
GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 3
ZPIRWAHWDCHWLM-UHFFFAOYSA-N 2-dodecylsulfanylethanol Chemical compound CCCCCCCCCCCCSCCO ZPIRWAHWDCHWLM-UHFFFAOYSA-N 0.000 description 3
CKPKHTKLLYPGFM-UHFFFAOYSA-N 6,6-dimethylheptane-1,1-diol Chemical compound CC(CCCCC(O)O)(C)C CKPKHTKLLYPGFM-UHFFFAOYSA-N 0.000 description 3
WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
239000004604 Blowing Agent Substances 0.000 description 3
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 3
WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
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239000001361 adipic acid Substances 0.000 description 3
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150000001340 alkali metals Chemical class 0.000 description 3
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POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 3
229920001971 elastomer Polymers 0.000 description 3
239000003623 enhancer Substances 0.000 description 3
239000000945 filler Substances 0.000 description 3
239000006260 foam Substances 0.000 description 3
229910001385 heavy metal Inorganic materials 0.000 description 3
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 3
229910052746 lanthanum Inorganic materials 0.000 description 3
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 3
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
238000002156 mixing Methods 0.000 description 3
FPQJEXTVQZHURJ-UHFFFAOYSA-N n,n'-bis(2-hydroxyethyl)oxamide Chemical compound OCCNC(=O)C(=O)NCCO FPQJEXTVQZHURJ-UHFFFAOYSA-N 0.000 description 3
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
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239000010452 phosphate Substances 0.000 description 3
229920005862 polyol Polymers 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
235000019260 propionic acid Nutrition 0.000 description 3
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150000002909 rare earth metal compounds Chemical class 0.000 description 3
239000005060 rubber Substances 0.000 description 3
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XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 3
ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
BVUXDWXKPROUDO-UHFFFAOYSA-N 2,6-di-tert-butyl-4-ethylphenol Chemical compound CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BVUXDWXKPROUDO-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
UQZPGHOJMQTOHB-UHFFFAOYSA-N 2-chloro-n-(2-chloroethyl)-n-ethylethanamine Chemical compound ClCCN(CC)CCCl UQZPGHOJMQTOHB-UHFFFAOYSA-N 0.000 description 2
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FXUXBBWNHJZXPH-UHFFFAOYSA-N 3-methyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octan-4-ol Chemical compound O1CC2(O)C(C)OP1OC2 FXUXBBWNHJZXPH-UHFFFAOYSA-N 0.000 description 2
SIXWIUJQBBANGK-UHFFFAOYSA-N 4-(4-fluorophenyl)-1h-pyrazol-5-amine Chemical compound N1N=CC(C=2C=CC(F)=CC=2)=C1N SIXWIUJQBBANGK-UHFFFAOYSA-N 0.000 description 2
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VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
229910052684 Cerium Inorganic materials 0.000 description 2
235000008733 Citrus aurantifolia Nutrition 0.000 description 2
NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
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235000021122 unsaturated fatty acids Nutrition 0.000 description 1
238000001291 vacuum drying Methods 0.000 description 1
229940005605 valeric acid Drugs 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
235000019165 vitamin E Nutrition 0.000 description 1
239000011709 vitamin E Substances 0.000 description 1
229940046009 vitamin E Drugs 0.000 description 1
239000002351 wastewater Substances 0.000 description 1
239000002023 wood Substances 0.000 description 1
NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
229910052727 yttrium Inorganic materials 0.000 description 1
VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
239000010457 zeolite Substances 0.000 description 1
150000003751 zinc Chemical class 0.000 description 1
150000003752 zinc compounds Chemical class 0.000 description 1
BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
- C08K5/3462—Six-membered rings
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/378—Thiols containing heterocyclic rings
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

NL1007121A 1996-09-25 1997-09-25 Hard PVC, gestabiliseerd met N,N-dimethyl-6-aminouracillen. NL1007121C2 (nl)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
CH234496		1996-09-25
CH234496		1996-09-25

Publications (2)

Publication Number	Publication Date
NL1007121A1 NL1007121A1 (nl)	1998-03-31
NL1007121C2 true NL1007121C2 (nl)	1998-05-18

Family

ID=4231613

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL1007121A NL1007121C2 (nl)	1996-09-25	1997-09-25	Hard PVC, gestabiliseerd met N,N-dimethyl-6-aminouracillen.

Country Status (21)

Country	Link
US (1)	US5859100A (de)
JP (1)	JPH10158454A (de)
KR (1)	KR19980024864A (de)
AT (1)	AT407395B (de)
AU (1)	AU715135B2 (de)
BE (1)	BE1011371A3 (de)
BR (1)	BR9704856A (de)
CA (1)	CA2216141A1 (de)
DE (1)	DE19741778A1 (de)
DK (1)	DK106297A (de)
ES (1)	ES2131017B1 (de)
FI (1)	FI973734A7 (de)
FR (1)	FR2753709B1 (de)
GB (1)	GB2318118B (de)
IT (1)	IT1295058B1 (de)
MY (1)	MY114466A (de)
NL (1)	NL1007121C2 (de)
NO (1)	NO315165B1 (de)
SE (1)	SE9703423L (de)
TW (1)	TW404964B (de)
ZA (1)	ZA978531B (de)

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DE19915388A1 (de)	1999-04-06	2000-10-12	Witco Vinyl Additives Gmbh	4-Aminopyrimidinone und Oxazolidino-4-amino-pyrimidinone, Verfahren zu deren Herstellung und ihre Verwendung zum Stabilisieren von halogenhaltigen Polymeren
US6498240B1 (en)	1999-09-17	2002-12-24	Millipore Corporation	Method for sequencing reaction cleanup by constant pressure diffential ultrafiltration
JP4516650B2 (ja) *	2000-01-21	2010-08-04	水澤化学工業株式会社	塩素含有重合体用安定剤組成物
MXPA01008705A (es)	2000-09-03	2004-08-12	Rohm & Haas	Sistemas de aditivos polimericos multiples: composiciones, procesos y productos derivados.
MXPA01008706A (es)	2000-09-03	2004-08-12	Rohm & Haas	Sistemas aditivos polimericos altos en solidos: composiciones, procesos y productos de los mismos.
ATE283896T1 (de) *	2001-02-16	2004-12-15	Crompton Vinyl Additives Gmbh	Chlorathaltiges stabilisatorsystem mit stickstoffhaltigen synergisten zur stabilisierung von halogenhaltigen polymeren
DE10132836A1 (de) *	2001-07-06	2003-01-16	Cognis Deutschland Gmbh	Verwendung von Aminouracilen zur Stabilisierung von antistatisch ausgerüsteten halogenhaltigen organischen Kunststoffen
DE10159344A1 (de)	2001-12-04	2003-06-12	Crompton Vinyl Additives Gmbh	Prestabilisierung von halogenhaltigen Polymeren
MXPA02011789A (es)	2001-12-06	2005-08-26	Rohm & Haas	Composicion estabilizada de polimero, que contiene halogeno.
TW200303887A (en)	2002-03-07	2003-09-16	Rohm & Haas	Organic based thermal stabilizers and heat stabilized polymer compositions
DE60304568T2 (de) *	2002-03-28	2006-08-24	Equipolymers Gmbh	Verbindungen zur reduzierung des acetaldehydgehalts von polyethylenterephthalat , ihre verwendung und daraus erhaltene produkte
ITVA20020058A1 (it) *	2002-11-15	2004-05-16	Lamberti Spa	Composizioni di pvc stabili al calore.
DE10301675A1 (de) *	2003-01-17	2004-07-29	Crompton Vinyl Additives Gmbh	Stabilisatorsystem zur PVC-Stabilisierung
DE10317870A1 (de) *	2003-04-17	2004-11-04	Crompton Vinyl Additives Gmbh	Neues Stabilisatorsystem zur Stabilisierung von halogenhaltigen Polymeren
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JP2007529606A (ja) *	2004-03-15	2007-10-25	ハネウェル・インターナショナル・インコーポレーテッド	セルロース強化樹脂組成物
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EP2013279B1 (de) *	2006-05-02	2010-03-31	Basf Se	Derivate von pyrimidinen als flammschutzmittel
CN101437886B (zh) *	2006-05-02	2011-11-09	西巴控股有限公司	作为阻燃剂的嘧啶衍生物
WO2009005693A1 (en) *	2007-06-29	2009-01-08	Gilead Sciences, Inc.	Novel hiv reverse transcriptase inhibitors
ES2533863T3 (es) *	2007-06-29	2015-04-15	Korea Research Institute Of Chemical Technology	Inhibidores novedosos de la transcriptasa inversa de VIH
DE102007037795A1 (de)	2007-08-10	2009-02-12	Nabaltec Ag	Stabilisatorsysteme für halogenhaltige Polymere
DE202007017631U1 (de) *	2007-12-14	2008-04-10	Baukulit Handelsgesellschaft Mbh	Kunststoffextrusionsteile für den Innen- und Außenausbau von Gebäuden
US8119800B2 (en) *	2007-12-21	2012-02-21	Korea Research Institute Of Chemical Technology	Processes for preparing HIV reverse transcriptase inhibitors
DE102008018872A1 (de)	2008-04-14	2009-10-15	Ika Innovative Kunststoffaufbereitung Gmbh & Co. Kg	Stabilisatorsystem für halogenhaltige Polymere
DE102008020203A1 (de)	2008-04-22	2009-10-29	Catena Additives Gmbh & Co. Kg	Lösemittelfreie High Solids (One-Pack)-Stabilisatoren für halogenhaltige Polymere
US8012539B2 (en)	2008-05-09	2011-09-06	Kraton Polymers U.S. Llc	Method for making sulfonated block copolymers, method for making membranes from such block copolymers and membrane structures
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US8263713B2 (en)	2009-10-13	2012-09-11	Kraton Polymers U.S. Llc	Amine neutralized sulfonated block copolymers and method for making same
US8337987B2 (en) *	2009-12-29	2012-12-25	Nesbitt Jeffrey E	Exterior UV-cured coatings and coating systems and methods of forming exterior UV-cured coating systems
DE102010020486A1 (de)	2010-05-14	2011-11-17	Catena Additives Gmbh & Co. Kg	Flammgeschützte halogenhaltige Polymere mit verbesserter Thermostabilität
US9429366B2 (en)	2010-09-29	2016-08-30	Kraton Polymers U.S. Llc	Energy recovery ventilation sulfonated block copolymer laminate membrane
US9394414B2 (en)	2010-09-29	2016-07-19	Kraton Polymers U.S. Llc	Elastic, moisture-vapor permeable films, their preparation and their use
BR112013007705A2 (pt)	2010-10-18	2016-08-09	Kraton Polymers Us Llc	solução tendo uma composição de copolímero em bloco sulfonado, película ou membrana, dispersão aquosa, compósito, composição de copolímeto em bloco sulfonado, processo, método para formar uma composição de copolímero em bloco sulfonado, e, célula eletrodialítica
WO2012143794A1 (en)	2011-04-18	2012-10-26	Galata Chemicals Gmbh	Polymer stabilizer system for polymers containing halogen
US9861941B2 (en)	2011-07-12	2018-01-09	Kraton Polymers U.S. Llc	Modified sulfonated block copolymers and the preparation thereof
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WO2016085785A1 (en) *	2014-11-24	2016-06-02	Lubrizol Advanced Materials, Inc.	Novel coupled uracil compound for vinyl chloride polymer resins
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EP4129611A4 (de)	2020-03-24	2024-04-17	Zeon Corporation	Vinylchloridharzzusammensetzung, vinylchloridharzformartikel und laminat
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Citations (4)

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Publication number	Priority date	Publication date	Assignee	Title
BE687294A (de) *	1966-02-12	1967-03-01
FR2010134A1 (de) *	1968-06-04	1970-02-13	Asahi Chemical Ind
EP0041479A1 (de) *	1980-06-02	1981-12-09	Ciba-Geigy Ag	Mit Amino-thiouracilen stabilisierte chlorhaltige Thermoplasten
EP0065934A1 (de) *	1981-05-26	1982-12-01	Ciba-Geigy Ag	Mit Aminouracilen stabilisierte chlorhaltige Thermoplaste

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US4656209A (en) *	1982-05-26	1987-04-07	Ciba-Geigy Corporation	Chlorinated thermoplastics stabilized with aminouracils
DE58908208D1 (de) *	1988-07-29	1994-09-22	Ciba Geigy Ag	Thiouracile als Stabilisatoren für chlorhaltige Polymerisate.
ATE302816T1 (de) *	1995-10-13	2005-09-15	Crompton Vinyl Additives Gmbh	Stabilisatorkombinationen für chlorhaltige polymere

1997
- 1997-09-12 MY MYPI97004236A patent/MY114466A/en unknown
- 1997-09-16 DK DK106297A patent/DK106297A/da not_active Application Discontinuation
- 1997-09-18 AU AU38345/97A patent/AU715135B2/en not_active Ceased
- 1997-09-19 FI FI973734A patent/FI973734A7/fi unknown
- 1997-09-22 US US08/934,986 patent/US5859100A/en not_active Expired - Fee Related
- 1997-09-22 DE DE19741778A patent/DE19741778A1/de not_active Ceased
- 1997-09-22 ES ES009701977A patent/ES2131017B1/es not_active Expired - Lifetime
- 1997-09-23 KR KR1019970048183A patent/KR19980024864A/ko not_active Ceased
- 1997-09-23 ZA ZA9708531A patent/ZA978531B/xx unknown
- 1997-09-23 BE BE9700771A patent/BE1011371A3/fr not_active IP Right Cessation
- 1997-09-23 FR FR9711792A patent/FR2753709B1/fr not_active Expired - Fee Related
- 1997-09-23 GB GB9720124A patent/GB2318118B/en not_active Expired - Fee Related
- 1997-09-23 SE SE9703423A patent/SE9703423L/xx unknown
- 1997-09-23 CA CA002216141A patent/CA2216141A1/en not_active Abandoned
- 1997-09-23 TW TW086113802A patent/TW404964B/zh not_active IP Right Cessation
- 1997-09-24 IT IT97MI002161A patent/IT1295058B1/it active IP Right Grant
- 1997-09-24 NO NO19974416A patent/NO315165B1/no unknown
- 1997-09-24 BR BR9704856A patent/BR9704856A/pt not_active Application Discontinuation
- 1997-09-24 AT AT0162497A patent/AT407395B/de not_active IP Right Cessation
- 1997-09-25 NL NL1007121A patent/NL1007121C2/nl not_active IP Right Cessation
- 1997-09-25 JP JP9299289A patent/JPH10158454A/ja active Pending

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BE687294A (de) *	1966-02-12	1967-03-01
FR2010134A1 (de) *	1968-06-04	1970-02-13	Asahi Chemical Ind
EP0041479A1 (de) *	1980-06-02	1981-12-09	Ciba-Geigy Ag	Mit Amino-thiouracilen stabilisierte chlorhaltige Thermoplasten
EP0065934A1 (de) *	1981-05-26	1982-12-01	Ciba-Geigy Ag	Mit Aminouracilen stabilisierte chlorhaltige Thermoplaste

Also Published As

Publication number	Publication date
DE19741778A1 (de)	1998-03-26
BR9704856A (pt)	1998-12-29
NO315165B1 (no)	2003-07-21
GB2318118B (en)	2000-12-27
BE1011371A3 (fr)	1999-08-03
SE9703423L (sv)	1998-03-26
DK106297A (da)	1998-03-26
FR2753709A1 (fr)	1998-03-27
FR2753709B1 (fr)	1998-11-27
GB2318118A (en)	1998-04-15
GB9720124D0 (en)	1997-11-19
ES2131017B1 (es)	2000-03-01
SE9703423D0 (sv)	1997-09-23
NO974416D0 (no)	1997-09-24
ATA162497A (de)	2000-07-15
TW404964B (en)	2000-09-11
AU3834597A (en)	1998-04-02
NO974416L (no)	1998-03-26
ES2131017A1 (es)	1999-07-01
CA2216141A1 (en)	1998-03-25
FI973734A0 (fi)	1997-09-19
FI973734A7 (fi)	1998-03-26
US5859100A (en)	1999-01-12
NL1007121A1 (nl)	1998-03-31
MX9707314A (es)	1998-08-30
IT1295058B1 (it)	1999-04-27
MY114466A (en)	2002-10-31
AU715135B2 (en)	2000-01-20
KR19980024864A (ko)	1998-07-06
AT407395B (de)	2001-02-26
JPH10158454A (ja)	1998-06-16
ITMI972161A1 (it)	1999-03-24
ZA978531B (en)	1998-03-25

Legal Events

Date	Code	Title	Description
1998-06-02	AD1B	A search report has been drawn up
1998-07-01	PD2B	A search report has been drawn up
1999-02-01	SD	Assignments of patents	Owner name: WILCO VINYL ADDITIVES GMBH
2001-08-01	TD	Modifications of names of proprietors of patents	Owner name: CROMPTON VINYL ADDITIVES GMBH Owner name: CK WITCO VINYL ADDITIVES GMBH
2004-06-01	VD1	Lapsed due to non-payment of the annual fee	Effective date: 20040401

Publication	Publication Date	Title
NL1007121C2 (nl)	1998-05-18	Hard PVC, gestabiliseerd met N,N-dimethyl-6-aminouracillen.
ES2238064T3 (es)	2005-08-16	Combinaciones de estabilizantes para polimeros clorados.
KR100735594B1 (ko)	2007-07-04	염소-함유 중합체용 안정화 조성물
NO309942B1 (no)	2001-04-23	Stabilisert polyvinylklorid-blanding, fremgangsmÕte for fremstilling av stabilisert PVC, anvendelse av denne PVC samt anvendelse av et perklorat for stabilisering av PVC
US6013703A (en)	2000-01-11	Stabilizer combination for chlorine-containing polymers
US6274654B1 (en)	2001-08-14	1,3-Disubstituted 6-aminouracils for stabilizing halogenated polymers
JP2000026433A (ja)	2000-01-25	Ｎｈ２変性６―アミノウラシル、それを含有する塩素含有ポリマ―組成物、塩素含有ポリマ―の安定化法及び６―アミノウラシル化合物の使用
US6156830A (en)	2000-12-05	5-substituted 6-aminouracils as stabilizers for halogenated polymers
JP2000026680A (ja)	2000-01-25	塩素含有ポリマ―と少なくとも１種のシアノアセチル尿素とを含有する組成物、塩素含有組成物の安定化方法およびシアノアセチル尿素の使用
WO2006058789A1 (en)	2006-06-08	Stabilizing compositions for chlorine-containing polymers and resins
JPH1045983A (ja)	1998-02-17	塩素含有ポリマーのための安定剤の組合せにおける４−アシルアミド−ピペリジン化合物
JPH1060155A (ja)	1998-03-03	塩素含有ポリマーのための安定剤としてのモノマー状ｎ−ピペリジニルメラミン
JPH1053571A (ja)	1998-02-24	塩素含有ポリマーのための安定剤
MXPA97007314A (es)	1998-11-12	Pvc rigido estabilizado con n,n-dimetil-6-aminouracilos
MXPA99005989A (en)	2000-12-06	6-aminouraciles replaced in position 5 as stabilizers for halogenic polymers