NO314696B1 - Fremgangsmåte for fremstilling og anvendelse av homogen forpolymer - Google Patents

Fremgangsmåte for fremstilling og anvendelse av homogen forpolymer Download PDF

Info

Publication number: NO314696B1
Authority: NO; Norway
Prior art keywords: prepolymer; catalyst component; polymerization; prepolymerization; polymer
Prior art date: 1995-09-19

Application number

NO19963885A

Other languages

English (en)

Norwegian (no)

Other versions

NO963885L (no

NO963885D0 (no

Inventor

Jean Malinge

Original Assignee

Atochem Elf Sa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-09-19

Filing date

1996-09-17

Publication date

2003-05-05

1996-09-17 Application filed by Atochem Elf Sa filed Critical Atochem Elf Sa

1996-09-17 Publication of NO963885D0 publication Critical patent/NO963885D0/no

1997-03-20 Publication of NO963885L publication Critical patent/NO963885L/no

2003-05-05 Publication of NO314696B1 publication Critical patent/NO314696B1/no

Links

238000000034 method Methods 0.000 title claims description 21
238000002360 preparation method Methods 0.000 title description 5
238000006116 polymerization reaction Methods 0.000 claims description 62
229910052723 transition metal Inorganic materials 0.000 claims description 39
150000003624 transition metals Chemical class 0.000 claims description 39
150000001336 alkenes Chemical class 0.000 claims description 29
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 20
239000011949 solid catalyst Substances 0.000 claims description 19
239000000725 suspension Substances 0.000 claims description 14
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 9
239000007788 liquid Substances 0.000 claims description 7
150000003609 titanium compounds Chemical class 0.000 claims description 4
239000000178 monomer Substances 0.000 claims description 2
239000003054 catalyst Substances 0.000 description 82
229920000642 polymer Polymers 0.000 description 47
230000003197 catalytic effect Effects 0.000 description 21
238000009826 distribution Methods 0.000 description 16
238000012685 gas phase polymerization Methods 0.000 description 16
239000010936 titanium Substances 0.000 description 16
238000010557 suspension polymerization reaction Methods 0.000 description 15
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
239000002245 particle Substances 0.000 description 14
239000000203 mixture Substances 0.000 description 13
229910052719 titanium Inorganic materials 0.000 description 13
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 12
-1 aluminum compound Chemical class 0.000 description 12
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 11
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 9
239000005977 Ethylene Substances 0.000 description 9
150000001875 compounds Chemical class 0.000 description 8
125000004432 carbon atom Chemical group C* 0.000 description 7
239000010419 fine particle Substances 0.000 description 7
239000001257 hydrogen Substances 0.000 description 7
229910052739 hydrogen Inorganic materials 0.000 description 7
229910052757 nitrogen Inorganic materials 0.000 description 7
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
230000004913 activation Effects 0.000 description 6
229910052782 aluminium Inorganic materials 0.000 description 6
239000011777 magnesium Substances 0.000 description 6
239000007787 solid Substances 0.000 description 6
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 5
239000000460 chlorine Substances 0.000 description 5
229910052801 chlorine Inorganic materials 0.000 description 5
229910052749 magnesium Inorganic materials 0.000 description 5
ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
238000003756 stirring Methods 0.000 description 4
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
230000003213 activating effect Effects 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
229910052794 bromium Inorganic materials 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000012299 nitrogen atmosphere Substances 0.000 description 3
239000000243 solution Substances 0.000 description 3
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 3
239000004711 α-olefin Substances 0.000 description 3
AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
239000004411 aluminium Substances 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
125000002029 aromatic hydrocarbon group Chemical group 0.000 description 2
229910052796 boron Inorganic materials 0.000 description 2
WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
239000012986 chain transfer agent Substances 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000003426 co-catalyst Substances 0.000 description 2
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
150000004678 hydrides Chemical class 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
238000002347 injection Methods 0.000 description 2
239000007924 injection Substances 0.000 description 2
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
150000002681 magnesium compounds Chemical class 0.000 description 2
229920000728 polyester Polymers 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
150000004756 silanes Chemical class 0.000 description 2
229910052726 zirconium Inorganic materials 0.000 description 2
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 1
NMVXHZSPDTXJSJ-UHFFFAOYSA-L 2-methylpropylaluminum(2+);dichloride Chemical compound CC(C)C[Al](Cl)Cl NMVXHZSPDTXJSJ-UHFFFAOYSA-L 0.000 description 1
229910015900 BF3 Inorganic materials 0.000 description 1
DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
TUSUWHFYKZZRIG-JQWMYKLHSA-N C([C@@H](NC(=O)[C@@H](C(C)C)NC(=O)[C@@H](CC(C)C)NC)C(=O)N[C@H](CC=1C=CC=CC=1)C(=O)N[C@H](CC(C)C)C(N)=O)C1=CC=CC=C1 Chemical compound C([C@@H](NC(=O)[C@@H](C(C)C)NC(=O)[C@@H](CC(C)C)NC)C(=O)N[C@H](CC=1C=CC=CC=1)C(=O)N[C@H](CC(C)C)C(N)=O)C1=CC=CC=C1 TUSUWHFYKZZRIG-JQWMYKLHSA-N 0.000 description 1
YVJWVOSSVAIOFJ-UHFFFAOYSA-N CCOO[Si](C1=CC=CC=C1)(OOCC)OOCC Chemical compound CCOO[Si](C1=CC=CC=C1)(OOCC)OOCC YVJWVOSSVAIOFJ-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
FHUODBDRWMIBQP-UHFFFAOYSA-N Ethyl p-anisate Chemical compound CCOC(=O)C1=CC=C(OC)C=C1 FHUODBDRWMIBQP-UHFFFAOYSA-N 0.000 description 1
239000002841 Lewis acid Substances 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
229910003074 TiCl4 Inorganic materials 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
229910052768 actinide Inorganic materials 0.000 description 1
150000001255 actinides Chemical class 0.000 description 1
125000002723 alicyclic group Chemical group 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
125000005250 alkyl acrylate group Chemical group 0.000 description 1
125000005234 alkyl aluminium group Chemical group 0.000 description 1
125000005907 alkyl ester group Chemical group 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
159000000032 aromatic acids Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000002902 bimodal effect Effects 0.000 description 1
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 description 1
239000012320 chlorinating reagent Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
150000004292 cyclic ethers Chemical class 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
238000001514 detection method Methods 0.000 description 1
JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
ZMXPNWBFRPIZFV-UHFFFAOYSA-M dipropylalumanylium;chloride Chemical compound [Cl-].CCC[Al+]CCC ZMXPNWBFRPIZFV-UHFFFAOYSA-M 0.000 description 1
238000001035 drying Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
238000002270 exclusion chromatography Methods 0.000 description 1
238000011010 flushing procedure Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000003292 glue Substances 0.000 description 1
238000000227 grinding Methods 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002431 hydrogen Chemical group 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
239000001282 iso-butane Substances 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
229910052747 lanthanoid Inorganic materials 0.000 description 1
150000002602 lanthanoids Chemical class 0.000 description 1
150000007517 lewis acids Chemical group 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
239000003446 ligand Substances 0.000 description 1
150000002680 magnesium Chemical class 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
239000000155 melt Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000012071 phase Substances 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical group 0.000 description 1
125000002743 phosphorus functional group Chemical group 0.000 description 1
229920000570 polyether Chemical class 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920001296 polysiloxane Chemical class 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000010926 purge Methods 0.000 description 1
238000007873 sieving Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1
UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
150000003754 zirconium Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Polyesters Or Polycarbonates (AREA)
Reinforced Plastic Materials (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

NO19963885A 1995-09-19 1996-09-17 Fremgangsmåte for fremstilling og anvendelse av homogen forpolymer NO314696B1 (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR9510942A FR2738829B1 (fr)	1995-09-19	1995-09-19	Prepolymere pour la polymerisation des olefines, associant plusieurs composantes catalytiques solides

Publications (3)

Publication Number	Publication Date
NO963885D0 NO963885D0 (no)	1996-09-17
NO963885L NO963885L (no)	1997-03-20
NO314696B1 true NO314696B1 (no)	2003-05-05

Family

ID=9482676

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO19963885A NO314696B1 (no)	1995-09-19	1996-09-17	Fremgangsmåte for fremstilling og anvendelse av homogen forpolymer

Country Status (10)

Country	Link
US (1)	US5852141A (de)
EP (1)	EP0771821B1 (de)
JP (1)	JPH09110921A (de)
CN (1)	CN1120181C (de)
AT (1)	ATE213255T1 (de)
CA (1)	CA2183674A1 (de)
DE (1)	DE69619194T2 (de)
ES (1)	ES2170823T3 (de)
FR (1)	FR2738829B1 (de)
NO (1)	NO314696B1 (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN100406476C (zh) *	1998-03-23	2008-07-30	蒙特尔技术有限公司	用于烯烃聚合的预聚合催化剂组分
JP4993865B2 (ja) *	2004-03-01	2012-08-08	東邦チタニウム株式会社	オレフィン類重合用固体触媒成分の製造方法及び触媒
CN101274968B (zh) *	2007-03-28	2012-11-21	中国石油化工股份有限公司	一种用于生产宽分子量分布的聚乙烯的复合催化剂
BRPI0914831A2 (pt) *	2008-06-26	2015-10-27	Basf Corp	processo para a produção de um polímero de alfa-olefina

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4543400A (en) *	1978-09-26	1985-09-24	Exxon Research & Engineering Co.	Titanium trichloride catalyst component and the process for the production thereof
DE3366573D1 (en) *	1982-06-24	1986-11-06	Bp Chimie Sa	Process for the polymerization and copolymerization of alpha-olefins in a fluidized bed
US4478951A (en) *	1983-01-03	1984-10-23	Exxon Research & Engineering Co.	Titanium trichloride catalyst component and the process for the production thereof
FR2541683B1 (fr) *	1983-02-28	1986-05-09	Ato Chimie	Procede pour la preparation d'un solide hydrocarbone actif utilisable pour polymeriser des olefines, et procede de synthese d'un polymere ou copolymere olefinique faisant appel audit solide hydrocarbone actif comme systeme
KR900016267A (ko) *	1989-04-25	1990-11-13	노기 사다오	올레핀 중합체 제조용 삼염화티탄 조성물 및 이의 제조방법
US5032562A (en)	1989-12-27	1991-07-16	Mobil Oil Corporation	Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
TW198726B (de)	1989-12-29	1993-01-21	Mitsui Petroleum Chemicals Ind
FR2659337B1 (fr)	1990-03-12	1992-06-05	Bp Chemicals Snc	Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
FR2689133A1 (fr) *	1992-03-27	1993-10-01	Atochem Elf Sa	Catalyseur de polymérisation des oléfines, son procédé d'obtention.
FR2717816B1 (fr) *	1994-03-23	1996-04-26	Atochem Elf Sa	Composante catalytique pour la polymérisation des oléfines obtenue par impregnation d'un prépolymère par une solution d'une composante catalytique. Prépolymère et polymère obtenus à partir de ladite composante catalytique.

1995
- 1995-09-19 FR FR9510942A patent/FR2738829B1/fr not_active Expired - Fee Related
1996
- 1996-07-31 ES ES96112322T patent/ES2170823T3/es not_active Expired - Lifetime
- 1996-07-31 DE DE69619194T patent/DE69619194T2/de not_active Expired - Fee Related
- 1996-07-31 AT AT96112322T patent/ATE213255T1/de not_active IP Right Cessation
- 1996-07-31 EP EP96112322A patent/EP0771821B1/de not_active Expired - Lifetime
- 1996-08-19 CA CA002183674A patent/CA2183674A1/fr not_active Abandoned
- 1996-09-17 NO NO19963885A patent/NO314696B1/no not_active IP Right Cessation
- 1996-09-17 US US08/710,438 patent/US5852141A/en not_active Expired - Fee Related
- 1996-09-19 CN CN96111303A patent/CN1120181C/zh not_active Expired - Fee Related
- 1996-09-19 JP JP8247487A patent/JPH09110921A/ja active Pending

Also Published As

Publication number	Publication date
ES2170823T3 (es)	2002-08-16
DE69619194D1 (de)	2002-03-21
ATE213255T1 (de)	2002-02-15
FR2738829A1 (fr)	1997-03-21
NO963885L (no)	1997-03-20
EP0771821B1 (de)	2002-02-13
CA2183674A1 (fr)	1997-03-20
NO963885D0 (no)	1996-09-17
JPH09110921A (ja)	1997-04-28
US5852141A (en)	1998-12-22
EP0771821A1 (de)	1997-05-07
CN1120181C (zh)	2003-09-03
DE69619194T2 (de)	2002-07-18
CN1148048A (zh)	1997-04-23
FR2738829B1 (fr)	1997-10-17

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Date	Code	Title	Description
2005-06-20	MM1K	Lapsed by not paying the annual fees

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