NO328281B1 - Fremgangsmate for omdannelse av hydrokarbonoljer - Google Patents
Fremgangsmate for omdannelse av hydrokarbonoljer Download PDFInfo
- Publication number
- NO328281B1 NO328281B1 NO19991360A NO991360A NO328281B1 NO 328281 B1 NO328281 B1 NO 328281B1 NO 19991360 A NO19991360 A NO 19991360A NO 991360 A NO991360 A NO 991360A NO 328281 B1 NO328281 B1 NO 328281B1
- Authority
- NO
- Norway
- Prior art keywords
- hydrodemercaptanization
- stated
- catalyst
- cobalt
- weight
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 210
- 239000003921 oil Substances 0.000 title claims description 115
- 238000006243 chemical reaction Methods 0.000 title claims description 79
- 229930195733 hydrocarbon Natural products 0.000 title claims description 18
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 18
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 4
- 239000003054 catalyst Substances 0.000 claims description 144
- 239000001257 hydrogen Substances 0.000 claims description 77
- 229910052739 hydrogen Inorganic materials 0.000 claims description 77
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 67
- 239000002994 raw material Substances 0.000 claims description 52
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 48
- 229910052717 sulfur Inorganic materials 0.000 claims description 47
- 239000011593 sulfur Substances 0.000 claims description 47
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 44
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 38
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 35
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 27
- 239000007864 aqueous solution Substances 0.000 claims description 27
- 239000003350 kerosene Substances 0.000 claims description 26
- 239000002253 acid Substances 0.000 claims description 24
- 238000004523 catalytic cracking Methods 0.000 claims description 24
- 238000004821 distillation Methods 0.000 claims description 21
- 230000000694 effects Effects 0.000 claims description 21
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 20
- 229910052750 molybdenum Inorganic materials 0.000 claims description 20
- 239000011733 molybdenum Substances 0.000 claims description 20
- 229910052759 nickel Inorganic materials 0.000 claims description 18
- 229910017052 cobalt Inorganic materials 0.000 claims description 17
- 239000010941 cobalt Substances 0.000 claims description 17
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 17
- 239000010779 crude oil Substances 0.000 claims description 17
- 238000004227 thermal cracking Methods 0.000 claims description 16
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 16
- 229910052721 tungsten Inorganic materials 0.000 claims description 15
- 239000010937 tungsten Substances 0.000 claims description 15
- 150000001869 cobalt compounds Chemical class 0.000 claims description 13
- 238000001354 calcination Methods 0.000 claims description 12
- 239000003502 gasoline Substances 0.000 claims description 12
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 11
- 239000000295 fuel oil Substances 0.000 claims description 11
- 239000011777 magnesium Substances 0.000 claims description 11
- 229910052749 magnesium Inorganic materials 0.000 claims description 11
- 150000002816 nickel compounds Chemical class 0.000 claims description 11
- 229910052698 phosphorus Inorganic materials 0.000 claims description 11
- 239000011574 phosphorus Substances 0.000 claims description 11
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 10
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 10
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 10
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 10
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 9
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 9
- 150000002431 hydrogen Chemical class 0.000 claims description 9
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 8
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 8
- 150000003658 tungsten compounds Chemical class 0.000 claims description 8
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 7
- 229910052731 fluorine Inorganic materials 0.000 claims description 7
- 239000011737 fluorine Substances 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000004480 active ingredient Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- 229910021536 Zeolite Inorganic materials 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 229910052786 argon Inorganic materials 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 238000005336 cracking Methods 0.000 claims description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 238000011084 recovery Methods 0.000 claims description 2
- 239000000047 product Substances 0.000 description 59
- 239000007795 chemical reaction product Substances 0.000 description 48
- 239000007789 gas Substances 0.000 description 37
- 238000005984 hydrogenation reaction Methods 0.000 description 17
- 239000000243 solution Substances 0.000 description 15
- 238000005194 fractionation Methods 0.000 description 12
- 238000005470 impregnation Methods 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 239000000446 fuel Substances 0.000 description 8
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 6
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 6
- 238000010992 reflux Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 239000003208 petroleum Substances 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 4
- 150000002222 fluorine compounds Chemical class 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052761 rare earth metal Inorganic materials 0.000 description 4
- 150000002910 rare earth metals Chemical class 0.000 description 4
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 3
- 229940010552 ammonium molybdate Drugs 0.000 description 3
- 235000018660 ammonium molybdate Nutrition 0.000 description 3
- 239000011609 ammonium molybdate Substances 0.000 description 3
- 238000004332 deodorization Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 239000010771 distillate fuel oil Substances 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- ADVCGXWUUOVPPB-XLPZGREQSA-N 1-[(2r,4s,5s)-4-amino-5-(hydroxymethyl)oxolan-2-yl]-5-methylpyrimidine-2,4-dione Chemical compound O=C1NC(=O)C(C)=CN1[C@@H]1O[C@H](CO)[C@@H](N)C1 ADVCGXWUUOVPPB-XLPZGREQSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229940011182 cobalt acetate Drugs 0.000 description 1
- MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical class [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 description 1
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910001679 gibbsite Inorganic materials 0.000 description 1
- 239000011874 heated mixture Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 229940078494 nickel acetate Drugs 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- -1 phosphorus compound Chemical class 0.000 description 1
- 238000003918 potentiometric titration Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000004846 x-ray emission Methods 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
- C10G69/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of catalytic cracking in the absence of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
- C10G69/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98100760 | 1998-03-20 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO991360D0 NO991360D0 (no) | 1999-03-19 |
| NO991360L NO991360L (no) | 1999-09-21 |
| NO328281B1 true NO328281B1 (no) | 2010-01-25 |
Family
ID=5216227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19991360A NO328281B1 (no) | 1998-03-20 | 1999-03-19 | Fremgangsmate for omdannelse av hydrokarbonoljer |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6156190A (fr) |
| EP (1) | EP0949314B1 (fr) |
| JP (1) | JP3927721B2 (fr) |
| CA (1) | CA2266570C (fr) |
| DE (1) | DE69931837T2 (fr) |
| ES (1) | ES2267209T3 (fr) |
| NO (1) | NO328281B1 (fr) |
| SA (1) | SA99200475B1 (fr) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0810664Y2 (ja) | 1989-08-18 | 1996-03-29 | 三菱自動車工業株式会社 | 低温始動時のバルブ制御機構 |
| WO2001074973A1 (fr) * | 2000-03-30 | 2001-10-11 | Japan Energy Corporation | Procede d'hydrodesulfuration d'une fraction d'huile legere |
| US7097761B2 (en) * | 2000-06-27 | 2006-08-29 | Colt Engineering Corporation | Method of removing water and contaminants from crude oil containing same |
| JP4858933B2 (ja) * | 2000-11-17 | 2012-01-18 | 日揮株式会社 | 軽油留分の脱硫方法、脱硫軽油および軽油留分の脱硫装置 |
| CA2455011C (fr) | 2004-01-09 | 2011-04-05 | Suncor Energy Inc. | Traitement de mousse bitumineuse par injection de vapeur en ligne |
| US20070189959A1 (en) * | 2006-02-15 | 2007-08-16 | Steven Allen Carlson | Methods of preparing separators for electrochemical cells |
| US7871399B2 (en) * | 2006-05-17 | 2011-01-18 | Alcon Research, Ltd. | Disposable ophthalmic injection device |
| US20130056391A1 (en) * | 2010-03-17 | 2013-03-07 | Indian Oil Corporation Limited | Catalytical hydrodesulfurization of kerosene in two steps on cobalt-molybdenum catalyst and intermediate stripping |
| DE202011002149U1 (de) | 2011-01-31 | 2011-10-26 | Sartorius Stedim Biotech Gmbh | Filtrationsbehälter |
| CN102634370B (zh) * | 2011-02-10 | 2014-08-06 | 中国石油天然气股份有限公司 | 一种汽油加氢改质的方法 |
| WO2014179355A1 (fr) | 2013-04-29 | 2014-11-06 | Madico, Inc. | Séparateurs composites nanoporeux ayant une conductivité thermique accrue |
| WO2016029401A1 (fr) * | 2014-08-28 | 2016-03-03 | 中国石油大学(北京) | Catalyseur d'élimination des mercaptans pour hydrocarbures légers, un procédé de préparation associé, et des utilisations associées |
| RU2677285C1 (ru) * | 2018-09-20 | 2019-01-16 | Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") | Способ приготовления катализатора гидроочистки нефтяных фракций в сульфидной форме (варианты) |
| RU2691760C1 (ru) * | 2019-02-11 | 2019-06-18 | Открытое акционерное общество "Славнефть-Ярославнефтеоргсинтез" (ОАО "Славнефть-ЯНОС") | Способ демеркаптанизации керосиновых фракций |
| RU2691761C1 (ru) * | 2019-02-11 | 2019-06-18 | Открытое акционерное общество "Славнефть-Ярославнефтеоргсинтез" (ОАО "Славнефть-ЯНОС") | Способ демеркаптанизации керосиновых фракций |
| JP7525334B2 (ja) * | 2020-08-21 | 2024-07-30 | 出光興産株式会社 | ガソリン基材の製造方法 |
| CN114433116B (zh) * | 2020-10-19 | 2023-05-30 | 中国石油化工股份有限公司 | 一种加氢精制催化剂的制备方法 |
| KR20240005710A (ko) | 2021-04-29 | 2024-01-12 | 24엠 테크놀로지즈, 인크. | 다수의 분리막을 갖는 전기화학 셀, 및 이의 생성 방법 |
| CN116445186B (zh) * | 2022-01-06 | 2025-03-04 | 中国石油化工股份有限公司 | 一种劣质柴油深度脱芳的方法 |
| CN115536487B (zh) * | 2022-10-12 | 2024-06-14 | 宁波巨化化工科技有限公司 | 一种高纯低碳烷烃生产工艺及设备 |
| TW202443944A (zh) | 2022-12-16 | 2024-11-01 | 美商24M科技公司 | 用於最小化及預防電化電池中形成枝晶的系統及方法 |
| US12431545B1 (en) | 2024-03-26 | 2025-09-30 | 24M Technologies, Inc. | Systems and methods for minimizing and preventing dendrite formation in electrochemical cells |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| NL256096A (fr) * | 1959-09-21 | |||
| US3852744A (en) * | 1973-01-05 | 1974-12-03 | Singer Co | Single time shared receiver and frequency tracker for a beam-lobed doppler radar system |
| US3876532A (en) * | 1973-02-27 | 1975-04-08 | Gulf Research Development Co | Method for reducing the total acid number of a middle distillate oil |
| US3870626A (en) * | 1973-02-27 | 1975-03-11 | Gulf Research Development Co | Method for reducing the mercaptan content of a middle distillate oil |
| US4010116A (en) * | 1974-10-15 | 1977-03-01 | Filtrol Corporation | Fluid cracking catalysts |
| US4218307A (en) * | 1975-04-24 | 1980-08-19 | W. R. Grace & Co. | Hydrocarbon cracking catalyst |
| US4206085A (en) * | 1979-01-15 | 1980-06-03 | Filtrol Corporation | Balanced alumina matrix in zeolite containing catalyst |
| US4325845A (en) * | 1979-11-09 | 1982-04-20 | Filtrol Corporation | Zeolite catalysts and method of producing the same |
| US4325847A (en) * | 1980-06-19 | 1982-04-20 | Filtrol Corporation | Use of additional alumina for extra zeolite stability in FCC catalyst |
| FR2486094B1 (fr) * | 1980-07-02 | 1985-03-22 | Catalyse Soc Prod Francais | |
| US4454241A (en) * | 1982-05-24 | 1984-06-12 | Exxon Research And Engineering Co. | Phosphorus-containing catalyst |
| US4504382A (en) * | 1982-10-14 | 1985-03-12 | Exxon Research And Engineering Co. | Phosphorus-containing catalyst and catalytic cracking process utilizing the same |
| US4465780A (en) * | 1982-10-14 | 1984-08-14 | Exxon Research & Engineering Co. | Phosphorus-containing catalyst |
| US4542118A (en) * | 1984-02-02 | 1985-09-17 | W. R. Grace & Co. | Catalyst manufacture |
| US4584091A (en) * | 1984-12-13 | 1986-04-22 | Exxon Research And Engineering Co. | Cracking with co-matrixed zeolite and p/alumina |
| US4567152A (en) * | 1984-12-13 | 1986-01-28 | Exxon Research And Engineering Co. | Co-matrixed zeolite and p/alumina |
| US4657663A (en) * | 1985-04-24 | 1987-04-14 | Phillips Petroleum Company | Hydrotreating process employing a three-stage catalyst system wherein a titanium compound is employed in the second stage |
| US4839319A (en) * | 1986-07-11 | 1989-06-13 | Exxon Research And Engineering Company | Hydrocarbon cracking catalysts and processes for utilizing the same |
| CA1297861C (fr) * | 1986-07-11 | 1992-03-24 | William L. Schuette | Catalyseurs de craquage d'hydrocarbures et procede utilisant ceux-ci |
| JPS63270545A (ja) * | 1987-04-28 | 1988-11-08 | Nippon Oil Co Ltd | 炭化水素転化触媒 |
| JPS63278553A (ja) * | 1987-05-08 | 1988-11-16 | Nippon Oil Co Ltd | 炭化水素転化触媒 |
| US4839375A (en) * | 1987-07-28 | 1989-06-13 | Merrell Dow Pharmaceuticals Inc. | (Aryl or heteroaromatic methyl)-2,2'-bi-1H-imidazoles and their use as anti-hypertensive agents |
| DE3807910A1 (de) * | 1988-03-10 | 1989-09-21 | Merck Patent Gmbh | Verfahren zur herstellung von 2,3-difluorbenzolen |
| EP0358261B1 (fr) * | 1988-09-06 | 1994-04-13 | Petroleo Brasileiro S.A. - Petrobras | Catalyseur de craquage contenant du kaolin |
| CA2015335A1 (fr) * | 1989-05-12 | 1990-11-12 | Terry G. Roberie | Composes catalytiques |
| US4977622A (en) * | 1989-07-25 | 1990-12-18 | Schley Marlene J | Medical garment |
-
1999
- 1999-03-19 DE DE69931837T patent/DE69931837T2/de not_active Expired - Lifetime
- 1999-03-19 ES ES99105010T patent/ES2267209T3/es not_active Expired - Lifetime
- 1999-03-19 EP EP99105010A patent/EP0949314B1/fr not_active Expired - Lifetime
- 1999-03-19 NO NO19991360A patent/NO328281B1/no not_active IP Right Cessation
- 1999-03-19 US US09/272,246 patent/US6156190A/en not_active Expired - Lifetime
- 1999-03-22 CA CA002266570A patent/CA2266570C/fr not_active Expired - Lifetime
- 1999-03-23 JP JP07872299A patent/JP3927721B2/ja not_active Expired - Lifetime
- 1999-08-17 SA SA99200475A patent/SA99200475B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO991360D0 (no) | 1999-03-19 |
| CA2266570C (fr) | 2007-07-31 |
| ES2267209T3 (es) | 2007-03-01 |
| EP0949314A2 (fr) | 1999-10-13 |
| DE69931837D1 (de) | 2006-07-27 |
| JPH11323354A (ja) | 1999-11-26 |
| CA2266570A1 (fr) | 1999-09-20 |
| DE69931837T2 (de) | 2006-11-09 |
| EP0949314A3 (fr) | 1999-12-22 |
| JP3927721B2 (ja) | 2007-06-13 |
| US6156190A (en) | 2000-12-05 |
| EP0949314B1 (fr) | 2006-06-14 |
| SA99200475B1 (ar) | 2006-08-21 |
| NO991360L (no) | 1999-09-21 |
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