OA10397A - Gel formulation - Google Patents

Gel formulation Download PDF

Info

Publication number: OA10397A
Authority: OA; OAPI
Prior art keywords: water; added; gel; carbopol; water dispersible
Prior art date: 1994-07-28

Application number

OA60955A

Other languages

English (en)

Inventor

Tharwat Fouad Tadros

Philip Taylor

Original Assignee

Zeneca Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1994-07-28

Filing date

1997-01-28

Publication date

2001-11-03

1997-01-28 Application filed by Zeneca Ltd filed Critical Zeneca Ltd

2001-11-03 Publication of OA10397A publication Critical patent/OA10397A/en

Links

239000000203 mixture Substances 0.000 title claims abstract description 47
238000009472 formulation Methods 0.000 title description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 144
229920002125 Sokalan® Polymers 0.000 claims abstract description 86
239000003905 agrochemical Substances 0.000 claims abstract description 14
239000004584 polyacrylic acid Substances 0.000 claims abstract description 9
239000005562 Glyphosate Substances 0.000 claims description 43
239000002585 base Substances 0.000 claims description 13
FIKAKWIAUPDISJ-UHFFFAOYSA-L paraquat dichloride Chemical compound [Cl-].[Cl-].C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 FIKAKWIAUPDISJ-UHFFFAOYSA-L 0.000 claims description 8
125000003545 alkoxy group Chemical group 0.000 claims description 6
239000005630 Diquat Substances 0.000 claims description 5
125000000217 alkyl group Chemical group 0.000 claims description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 5
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 4
150000001412 amines Chemical class 0.000 claims description 4
ZEKANFGSDXODPD-UHFFFAOYSA-N glyphosate-isopropylammonium Chemical compound CC(C)N.OC(=O)CNCP(O)(O)=O ZEKANFGSDXODPD-UHFFFAOYSA-N 0.000 claims description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
MKUXAQIIEYXACX-UHFFFAOYSA-N aciclovir Chemical compound N1C(N)=NC(=O)C2=C1N(COCCO)C=N2 MKUXAQIIEYXACX-UHFFFAOYSA-N 0.000 claims description 3
239000003513 alkali Substances 0.000 claims description 3
MXZACTZQSGYANA-UHFFFAOYSA-N chembl545463 Chemical compound Cl.C1=CC(OC)=CC=C1C(N=C1)=CN2C1=NC(C)=C2O MXZACTZQSGYANA-UHFFFAOYSA-N 0.000 claims description 3
XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims description 3
229940097068 glyphosate Drugs 0.000 claims description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
SYJFEGQWDCRVNX-UHFFFAOYSA-N diquat Chemical compound C1=CC=[N+]2CC[N+]3=CC=CC=C3C2=C1 SYJFEGQWDCRVNX-UHFFFAOYSA-N 0.000 claims description 2
150000002148 esters Chemical class 0.000 claims description 2
125000004438 haloalkoxy group Chemical group 0.000 claims description 2
229910052736 halogen Inorganic materials 0.000 claims description 2
150000002367 halogens Chemical class 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
125000005113 hydroxyalkoxy group Chemical group 0.000 claims description 2
238000000034 method Methods 0.000 claims description 2
238000004519 manufacturing process Methods 0.000 claims 1
230000000063 preceeding effect Effects 0.000 claims 1
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 87
239000000243 solution Substances 0.000 description 42
RUCAXVJJQQJZGU-UHFFFAOYSA-M hydron;2-(phosphonatomethylamino)acetate;trimethylsulfanium Chemical compound C[S+](C)C.OP(O)(=O)CNCC([O-])=O RUCAXVJJQQJZGU-UHFFFAOYSA-M 0.000 description 40
239000000499 gel Substances 0.000 description 38
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 37
239000007864 aqueous solution Substances 0.000 description 37
239000002253 acid Substances 0.000 description 30
230000008961 swelling Effects 0.000 description 30
235000011121 sodium hydroxide Nutrition 0.000 description 29
229940083608 sodium hydroxide Drugs 0.000 description 29
-1 diquatduromide Chemical compound 0.000 description 9
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 8
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 7
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
229910052708 sodium Inorganic materials 0.000 description 6
239000011734 sodium Substances 0.000 description 6
239000004372 Polyvinyl alcohol Substances 0.000 description 5
239000002671 adjuvant Substances 0.000 description 5
239000003795 chemical substances by application Substances 0.000 description 5
230000000855 fungicidal effect Effects 0.000 description 5
239000000417 fungicide Substances 0.000 description 5
230000002363 herbicidal effect Effects 0.000 description 5
239000004009 herbicide Substances 0.000 description 5
239000002917 insecticide Substances 0.000 description 5
230000000149 penetrating effect Effects 0.000 description 5
229920002451 polyvinyl alcohol Polymers 0.000 description 5
235000019422 polyvinyl alcohol Nutrition 0.000 description 5
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
239000005977 Ethylene Substances 0.000 description 3
239000012872 agrochemical composition Substances 0.000 description 3
239000003792 electrolyte Substances 0.000 description 3
239000008187 granular material Substances 0.000 description 3
239000007788 liquid Substances 0.000 description 3
239000000463 material Substances 0.000 description 3
238000005259 measurement Methods 0.000 description 3
239000000843 powder Substances 0.000 description 3
JVTIXNMXDLQEJE-UHFFFAOYSA-N 2-decanoyloxypropyl decanoate 2-octanoyloxypropyl octanoate Chemical compound C(CCCCCCC)(=O)OCC(C)OC(CCCCCCC)=O.C(=O)(CCCCCCCCC)OCC(C)OC(=O)CCCCCCCCC JVTIXNMXDLQEJE-UHFFFAOYSA-N 0.000 description 2
XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
150000001450 anions Chemical class 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000011591 potassium Substances 0.000 description 2
FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
235000017557 sodium bicarbonate Nutrition 0.000 description 2
229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
229910000029 sodium carbonate Inorganic materials 0.000 description 2
235000002639 sodium chloride Nutrition 0.000 description 2
239000011780 sodium chloride Substances 0.000 description 2
229960002668 sodium chloride Drugs 0.000 description 2
229910021653 sulphate ion Inorganic materials 0.000 description 2
LSPHULWDVZXLIL-UHFFFAOYSA-N (+/-)-Camphoric acid Chemical compound CC1(C)C(C(O)=O)CCC1(C)C(O)=O LSPHULWDVZXLIL-UHFFFAOYSA-N 0.000 description 1
WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical compound C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
241000287196 Asthenes Species 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
239000001166 ammonium sulphate Substances 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
NGPGDYLVALNKEG-UHFFFAOYSA-N azanium;azane;2,3,4-trihydroxy-4-oxobutanoate Chemical compound [NH4+].[NH4+].[O-]C(=O)C(O)C(O)C([O-])=O NGPGDYLVALNKEG-UHFFFAOYSA-N 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-M bisulphate group Chemical group S([O-])(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 1
239000000872 buffer Substances 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
229910001919 chlorite Inorganic materials 0.000 description 1
229910052619 chlorite group Inorganic materials 0.000 description 1
QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
229940114081 cinnamate Drugs 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
229940075933 dithionate Drugs 0.000 description 1
POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
239000002895 emetic Substances 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
KIWBPDUYBMNFTB-UHFFFAOYSA-M ethyl sulfate Chemical compound CCOS([O-])(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-M 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
YAGKRVSRTSUGEY-UHFFFAOYSA-N ferricyanide Chemical compound [Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YAGKRVSRTSUGEY-UHFFFAOYSA-N 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
NFMHSPWHNQRFNR-UHFFFAOYSA-N hyponitrous acid Chemical compound ON=NO NFMHSPWHNQRFNR-UHFFFAOYSA-N 0.000 description 1
ICIWUVCWSCSTAQ-UHFFFAOYSA-M iodate Chemical compound [O-]I(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-M 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
229940070765 laurate Drugs 0.000 description 1
JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
229940049964 oleate Drugs 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
230000010355 oscillation Effects 0.000 description 1
230000003534 oscillatory effect Effects 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
239000002304 perfume Substances 0.000 description 1
230000010363 phase shift Effects 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
229920001021 polysulfide Polymers 0.000 description 1
229940075065 polyvinyl acetate Drugs 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
235000007686 potassium Nutrition 0.000 description 1
235000010333 potassium nitrate Nutrition 0.000 description 1
239000004323 potassium nitrate Substances 0.000 description 1
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
229910052939 potassium sulfate Inorganic materials 0.000 description 1
239000001120 potassium sulphate Substances 0.000 description 1
235000011151 potassium sulphates Nutrition 0.000 description 1
239000003755 preservative agent Substances 0.000 description 1
230000002335 preservative effect Effects 0.000 description 1
YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
229960001860 salicylate Drugs 0.000 description 1
238000007789 sealing Methods 0.000 description 1
239000002904 solvent Substances 0.000 description 1
229940075554 sorbate Drugs 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
229940071182 stannate Drugs 0.000 description 1
125000005402 stannate group Chemical group 0.000 description 1
239000000126 substance Substances 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
229940095064 tartrate Drugs 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
238000003856 thermoforming Methods 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
WBYWAXJHAXSJNI-VOTSOKGWSA-M trans-cinnamate Chemical compound [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
ICESBGJHRQHALQ-UHFFFAOYSA-K trisodium;(carboxymethylamino)methyl-hydroxyphosphinate;2-[[hydroxy(oxido)phosphoryl]methylamino]acetate Chemical compound [Na+].[Na+].[Na+].OC(=O)CNCP(O)([O-])=O.OC(=O)CNCP([O-])([O-])=O ICESBGJHRQHALQ-UHFFFAOYSA-K 0.000 description 1
229940070710 valerate Drugs 0.000 description 1
NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
239000000080 wetting agent Substances 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals

Landscapes

Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Agronomy & Crop Science (AREA)
Pest Control & Pesticides (AREA)
Plant Pathology (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Toxicology (AREA)
Chemical & Material Sciences (AREA)
Dispersion Chemistry (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Medicinal Preparation (AREA)
Packages (AREA)
Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
Wrappers (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Compositions Of Macromolecular Compounds (AREA)
Thermotherapy And Cooling Therapy Devices (AREA)
Paper (AREA)
Glass Compositions (AREA)
Colloid Chemistry (AREA)

OA60955A 1994-07-28 1997-01-28 Gel formulation OA10397A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB9415290A GB9415290D0 (en)	1994-07-28	1994-07-28	Gel formation

Publications (1)

Publication Number	Publication Date
OA10397A true OA10397A (en)	2001-11-03

Family

ID=10759052

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
OA60955A OA10397A (en)	1994-07-28	1997-01-28	Gel formulation

Country Status (23)

Country	Link
US (1)	US6649190B1 (de)
EP (1)	EP0772392B1 (de)
JP (1)	JP3880620B2 (de)
KR (1)	KR970704336A (de)
CN (1)	CN1104193C (de)
AT (1)	ATE171040T1 (de)
AU (1)	AU696669B2 (de)
BR (1)	BR9508440A (de)
CA (1)	CA2194408A1 (de)
CZ (1)	CZ23297A3 (de)
DE (1)	DE69504851T2 (de)
DK (1)	DK0772392T3 (de)
ES (1)	ES2120756T3 (de)
GB (1)	GB9415290D0 (de)
HU (1)	HU215788B (de)
MX (1)	MX9700380A (de)
NZ (1)	NZ288725A (de)
OA (1)	OA10397A (de)
PL (1)	PL318359A1 (de)
SK (1)	SK11997A3 (de)
TW (1)	TW377272B (de)
WO (1)	WO1996003038A1 (de)
ZA (1)	ZA955848B (de)

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FR2790642A1 (fr) *	1999-03-08	2000-09-15	Aventis Cropscience Sa	Nouvelles compositions pesticides et/ou regulatrices de croissance
WO2000054586A1 (en) *	1999-03-17	2000-09-21	Aventis Environmental Science Usa Lp	Insecticide formulation
DE10022986A1 (de) *	2000-05-11	2001-11-22	Aventis Cropscience Gmbh	Kombinationen von Pflanzenschutzmitteln mit anionischen Polymeren
GB0107651D0 (en) *	2001-03-27	2001-05-16	Syngenta Ltd	Composition
DE10138456A1 (de) *	2001-08-04	2003-02-13	Bode Chemie Gmbh & Co	Alkoholische Gele
JP2005132781A (ja) *	2003-10-31	2005-05-26	Sanyo Chem Ind Ltd	誘引剤
BRPI0504779A (pt) *	2004-11-08	2006-06-27	Rohm & Haas	composição aquosa, método de preparação da mesma, e, formulação aquosa
EP1655351B1 (de) *	2004-11-08	2020-01-01	Rohm and Haas Company	Wässrige Zusammensetzungen mit schwerwasserlöslichen Verbindungen
GB0803026D0 (en) *	2008-02-20	2008-03-26	Enviroquest Group Ltd	External surface treatment system
US20110045979A1 (en) *	2008-03-28	2011-02-24	Rhodia Operations	Agriculturally active composition comprising a polycarboxylate
PL2544532T3 (pl)	2010-03-12	2017-08-31	Monsanto Technology Llc	Agrochemiczne kompozycje żelowe
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CN102293204A (zh) *	2011-09-26	2011-12-28	中化化工科学技术研究总院	百草枯可溶胶剂及其制备方法
CN102657153A (zh) *	2011-12-30	2012-09-12	广西田园生化股份有限公司	百草枯膏剂及其制备方法
JP2013180977A (ja) *	2012-03-01	2013-09-12	Daikyogumi:Kk	除草用材及び除草方法
JP2015512378A (ja) *	2012-03-21	2015-04-27	ビーエーエスエフソシエタス・ヨーロピアＢａｓｆＳｅ	炭酸塩及び炭酸水素塩の混合物から選択される塩基を含む液体又は粒子タンクミックス用アジュバント
JP2015510912A (ja) *	2012-03-21	2015-04-13	ビーエーエスエフソシエタス・ヨーロピアＢａｓｆＳｅ	炭酸塩及び／又はリン酸塩から選択される塩基を含む固体粒子状タンクミックス用アジュバント
US20160302408A1 (en) *	2015-04-14	2016-10-20	Rhodia Operations	Liquid ammonium-free adjuvants and agricultural compositions for drift reduction and water conditioning
WO2016168313A1 (en) *	2015-04-14	2016-10-20	Rhodia Operations	Dry ammonium-free adjuvant for drift reduction and water conditioning
CN110583655A (zh) *	2019-09-25	2019-12-20	四川省农业科学院生物技术核技术研究所	一种用于柑橘的防病型保水剂及其制备方法
CN114190396A (zh) *	2021-12-28	2022-03-18	陕西麦可罗生物科技有限公司	一种多抗霉素可溶胶剂及其制备方法

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1994
- 1994-07-28 GB GB9415290A patent/GB9415290D0/en active Pending
1995
- 1995-07-06 EP EP95923517A patent/EP0772392B1/de not_active Expired - Lifetime
- 1995-07-06 SK SK119-97A patent/SK11997A3/sk unknown
- 1995-07-06 CN CN95194386A patent/CN1104193C/zh not_active Expired - Fee Related
- 1995-07-06 BR BR9508440A patent/BR9508440A/pt not_active Application Discontinuation
- 1995-07-06 HU HU9700214A patent/HU215788B/hu not_active IP Right Cessation
- 1995-07-06 AU AU28054/95A patent/AU696669B2/en not_active Ceased
- 1995-07-06 NZ NZ288725A patent/NZ288725A/en unknown
- 1995-07-06 MX MX9700380A patent/MX9700380A/es unknown
- 1995-07-06 DE DE69504851T patent/DE69504851T2/de not_active Expired - Lifetime
- 1995-07-06 DK DK95923517T patent/DK0772392T3/da active
- 1995-07-06 CA CA002194408A patent/CA2194408A1/en not_active Abandoned
- 1995-07-06 JP JP50555096A patent/JP3880620B2/ja not_active Expired - Fee Related
- 1995-07-06 WO PCT/GB1995/001605 patent/WO1996003038A1/en not_active Ceased
- 1995-07-06 KR KR1019970700539A patent/KR970704336A/ko not_active Withdrawn
- 1995-07-06 ES ES95923517T patent/ES2120756T3/es not_active Expired - Lifetime
- 1995-07-06 AT AT95923517T patent/ATE171040T1/de not_active IP Right Cessation
- 1995-07-06 PL PL95318359A patent/PL318359A1/xx unknown
- 1995-07-06 CZ CZ97232A patent/CZ23297A3/cs unknown
- 1995-07-11 TW TW084107161A patent/TW377272B/zh not_active IP Right Cessation
- 1995-07-13 ZA ZA955848A patent/ZA955848B/xx unknown
1997
- 1997-01-28 OA OA60955A patent/OA10397A/en unknown
- 1997-07-22 US US08/898,627 patent/US6649190B1/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA2194408A1 (en)	1996-02-08
JPH10503193A (ja)	1998-03-24
DK0772392T3 (da)	1999-06-14
EP0772392A1 (de)	1997-05-14
DE69504851D1 (de)	1998-10-22
CZ23297A3 (en)	1997-04-16
HUT77237A (hu)	1998-03-02
AU2805495A (en)	1996-02-22
ATE171040T1 (de)	1998-10-15
AU696669B2 (en)	1998-09-17
ZA955848B (en)	1996-01-29
EP0772392B1 (de)	1998-09-16
TW377272B (en)	1999-12-21
KR970704336A (ko)	1997-09-06
US6649190B1 (en)	2003-11-18
PL318359A1 (en)	1997-06-09
GB9415290D0 (en)	1994-09-21
HU215788B (hu)	1999-02-01
JP3880620B2 (ja)	2007-02-14
WO1996003038A1 (en)	1996-02-08
MX9700380A (es)	1998-05-31
SK11997A3 (en)	1997-07-09
DE69504851T2 (de)	1999-02-11
CN1104193C (zh)	2003-04-02
NZ288725A (en)	1998-07-28
CN1154059A (zh)	1997-07-09
BR9508440A (pt)	1997-12-30
ES2120756T3 (es)	1998-11-01

Publication	Publication Date	Title
EP0772392B1 (de)	1998-09-16	Verpackungssystem, das ein wasserdispergierbares gel enthält
US5272191A (en)	1993-12-21	Cold water soluble films and film forming compositions
TWI548655B (zh)	2016-09-11	用於嚴苛化學品包裝的聚乙烯吡咯啶酮（ｐｖｐ）共聚物
JP4118951B2 (ja)	2008-07-16	農芸化学用パッケージ組成物
DE69801547T2 (de)	2002-04-18	Wasserlöslicher Folie
US20090137667A1 (en)	2009-05-28	Pesticide Delivery System
JP2009535484A (ja)	2009-10-01	酸化剤に対して改良された抵抗性を有するポリビニルアルコールフィルム
AU2013215229A1 (en)	2014-07-10	Insecticidal hydrogel feeding spheres
EA017295B1 (ru)	2012-11-30	Жидкие гербицидные препараты на основе сульфонилмочевины
WO1989003176A1 (en)	1989-04-20	Latex-based agricultural compositions
CN1154646A (zh)	1997-07-16	凝胶制剂
JPH11507971A (ja)	1999-07-13	水溶性フィルム
US9796870B2 (en)	2017-10-24	Stabilizer for aggressive chemicals packaging
EP0611163A1 (de)	1994-08-17	Polymere biozide Zusammensetzung und Verfahren zu ihrer Herstellung
CA1107908A (en)	1981-09-01	Stabilized aqueous antimicrobial composition
BRPI0615648B1 (pt)	2016-07-12	'uso de lactato de 2-etil-hexila, e processo para melhorar a retenção e penetrações para proteger plantas na aplicação de caldos de pulverização aquosos'.
CN105120666A (zh)	2015-12-02	种子处理制剂
JP2018510792A (ja)	2018-04-19	オーバーコーティングされた水溶性フィルム
EP0942875B1 (de)	2002-12-11	Löslicher beutel für wasserhaltige substanzen
RU2165699C2 (ru)	2001-04-27	Упаковочная система, включающая водорастворимый или диспергируемый в воде мешок, в котором находится гелевый состав
CA3052327A1 (en)	2018-08-09	Ams-free adjuvants for water conditioning and agricultural formulations
TW202026319A (zh)	2020-07-16	用於嚴苛化學品包裝的聚乙烯吡咯啶酮(pvp)共聚物
JPS63185908A (ja)	1988-08-01	殺虫くん煙剤
JP2001009991A (ja)	2001-01-16	積層体
MXPA97000659A (en)	1999-01-11	Formulation of