OA13150A - Novel crystalline modification of the anhydrate ofboscalid. - Google Patents

Novel crystalline modification of the anhydrate ofboscalid. Download PDF

Info

Publication number: OA13150A
Authority: OA; OAPI
Prior art keywords: compound; formula; préparation; anhydrate; whereinthe
Prior art date: 2003-02-14

Application number

OA1200500217A

Other languages

English (en)

Inventor

Gerhard Cox

Peter Erk

Karl-Heinrich Schneider

Thomas Krohl

Reinhard Stierl

Winfried Mayer

Hans Ziegler

Horst Mayer

Original Assignee

Basf Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2003-02-14

Filing date

2004-01-28

Publication date

2006-12-13

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=32748027&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=OA13150(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2004-01-28 Application filed by Basf Ag filed Critical Basf Ag

2006-12-13 Publication of OA13150A publication Critical patent/OA13150A/en

Links

238000012986 modification Methods 0.000 title description 28
230000004048 modification Effects 0.000 title description 28
WYEMLYFITZORAB-UHFFFAOYSA-N boscalid Chemical compound C1=CC(Cl)=CC=C1C1=CC=CC=C1NC(=O)C1=CC=CN=C1Cl WYEMLYFITZORAB-UHFFFAOYSA-N 0.000 claims abstract description 20
150000001875 compounds Chemical class 0.000 claims description 30
238000000034 method Methods 0.000 claims description 13
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
239000000203 mixture Substances 0.000 claims description 8
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 7
238000001816 cooling Methods 0.000 claims description 5
239000002904 solvent Substances 0.000 claims description 5
150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 4
150000002148 esters Chemical class 0.000 claims description 4
150000002576 ketones Chemical class 0.000 claims description 4
238000002844 melting Methods 0.000 claims description 4
230000008018 melting Effects 0.000 claims description 4
150000001408 amides Chemical class 0.000 claims description 3
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 3
239000003586 protic polar solvent Substances 0.000 claims 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
241000233866 Fungi Species 0.000 claims 2
230000002363 herbicidal effect Effects 0.000 claims 2
239000004009 herbicide Substances 0.000 claims 2
239000000654 additive Substances 0.000 claims 1
230000000855 fungicidal effect Effects 0.000 claims 1
239000000463 material Substances 0.000 claims 1
239000000155 melt Substances 0.000 abstract description 4
238000004519 manufacturing process Methods 0.000 abstract 1
239000005740 Boscalid Substances 0.000 description 17
229940118790 boscalid Drugs 0.000 description 17
239000004562 water dispersible granule Substances 0.000 description 5
239000013078 crystal Substances 0.000 description 4
239000000725 suspension Substances 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
238000009472 formulation Methods 0.000 description 3
239000007787 solid Substances 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
150000002170 ethers Chemical class 0.000 description 2
150000002334 glycols Chemical class 0.000 description 2
239000008187 granular material Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229960003966 nicotinamide Drugs 0.000 description 2
239000011570 nicotinamide Substances 0.000 description 2
239000007921 spray Substances 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
239000002518 antifoaming agent Substances 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
239000003849 aromatic solvent Substances 0.000 description 1
FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
230000004927 fusion Effects 0.000 description 1
239000005337 ground glass Substances 0.000 description 1
238000011835 investigation Methods 0.000 description 1
239000012669 liquid formulation Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
235000005152 nicotinamide Nutrition 0.000 description 1
238000010899 nucleation Methods 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000003495 polar organic solvent Substances 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000004546 suspension concentrate Substances 0.000 description 1
239000004548 suspo-emulsion Substances 0.000 description 1
239000003021 water soluble solvent Substances 0.000 description 1
239000000080 wetting agent Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/81—Amides; Imides
- C07D213/82—Amides; Imides in position 3
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

Landscapes

Life Sciences & Earth Sciences (AREA)
Organic Chemistry (AREA)
Chemical & Material Sciences (AREA)
Environmental Sciences (AREA)
Agronomy & Crop Science (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
General Health & Medical Sciences (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Plant Pathology (AREA)
Pest Control & Pesticides (AREA)
Health & Medical Sciences (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Pyridine Compounds (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Plural Heterocyclic Compounds (AREA)
Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)
Centrifugal Separators (AREA)
Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

OA1200500217A 2003-02-14 2004-01-28 Novel crystalline modification of the anhydrate ofboscalid. OA13150A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE10307751A DE10307751A1 (de)	2003-02-14	2003-02-14	Neue kristalline Modifikation des Anhydrates von Boscalid

Publications (1)

Publication Number	Publication Date
OA13150A true OA13150A (en)	2006-12-13

Family

ID=32748027

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
OA1200500217A OA13150A (en)	2003-02-14	2004-01-28	Novel crystalline modification of the anhydrate ofboscalid.

Country Status (33)

Country	Link
US (1)	US7501384B2 (es)
EP (1)	EP1597232B1 (es)
JP (1)	JP4642743B2 (es)
KR (2)	KR101146446B1 (es)
CN (1)	CN100494179C (es)
AP (1)	AP1955A (es)
AR (2)	AR043175A1 (es)
AT (1)	ATE339405T1 (es)
AU (1)	AU2004212039B2 (es)
BR (1)	BRPI0407358B1 (es)
CA (1)	CA2515725C (es)
CL (1)	CL2004000256A1 (es)
CR (1)	CR7939A (es)
CY (1)	CY1107513T1 (es)
DE (2)	DE10307751A1 (es)
DK (1)	DK1597232T3 (es)
EA (1)	EA008004B1 (es)
EC (1)	ECSP055948A (es)
ES (1)	ES2273211T3 (es)
HR (1)	HRP20050803B1 (es)
MA (1)	MA27619A1 (es)
ME (1)	ME00061B (es)
MX (1)	MXPA05007962A (es)
NO (1)	NO329988B1 (es)
NZ (1)	NZ542308A (es)
OA (1)	OA13150A (es)
PL (1)	PL219123B1 (es)
PT (1)	PT1597232E (es)
RS (1)	RS51685B (es)
SI (1)	SI1597232T1 (es)
UA (1)	UA81659C2 (es)
WO (1)	WO2004072039A1 (es)
ZA (1)	ZA200507344B (es)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
UA90035C2 (ru) *	2005-11-10	2010-03-25	Басф Се	Фунгицидная смесь, которая содержит боскалид и пириметанил и способ борьбы с фитопатогенными грибами
CN101778569A (zh) *	2007-08-09	2010-07-14	巴斯夫欧洲公司	杀真菌混合物
BR112012010597B8 (pt)	2009-11-06	2022-07-19	Basf Se	Complexo cristalino, processo para preparar o complexo cristalino, formulação agrícola, método para controlar fungos fitopatogênicos, método para melhorar a saúde de plantas, método para a proteção de material de propagação de planta contra pragas, método para regular o crescimento de plantas e material de propagação de planta revestido
US9226504B2 (en)	2010-09-09	2016-01-05	Suncor Energy Inc.	Synergistic paraffinic oil and boscalid fungicides
CN102217604B (zh) *	2011-04-16	2013-11-06	陕西汤普森生物科技有限公司	一种含啶酰菌胺与三唑类化合物的杀菌组合物
CN102860307B (zh) *	2012-09-13	2014-04-02	倪烈	一种含井冈霉素与啶酰菌胺的复配农药及其应用
CN103348982B (zh)	2013-07-15	2016-06-15	江苏龙灯化学有限公司	一种杀真菌混合物
CN103980192B (zh) *	2014-01-20	2016-02-17	泰州百力化学股份有限公司	一种选择性合成不同晶型啶酰菌胺的方法
CN104016915B (zh) *	2014-06-27	2016-03-30	重庆工商大学	一种啶酰菌胺的制备方法
CN104920366A (zh) *	2015-05-14	2015-09-23	京博农化科技股份有限公司	一种啶酰菌胺制剂的加工方法
GB2536979B (en) *	2015-06-04	2019-03-13	Rotam Agrochem Int Co Ltd	Process for preparing boscalid
GB2539022B (en) *	2015-06-04	2018-02-07	Rotam Agrochem Int Co Ltd	Process for preparing boscalid
GB2550138B (en)	2016-05-09	2019-06-12	Rotam Agrochem Int Co Ltd	Process for preparing boscalid
GB2552696B (en) *	2016-08-04	2020-03-04	Rotam Agrochem Int Co Ltd	Process for preparing boscalid
GB2552697B (en) *	2016-08-04	2021-03-10	Rotam Agrochem Int Co Ltd	Process for the preparation of boscalid
GB2552694B (en) *	2016-08-04	2020-03-04	Rotam Agrochem Int Co Ltd	A Synergistic fungicidal composition and use thereof
GB2552695B (en) *	2016-08-04	2020-03-04	Rotam Agrochem Int Co Ltd	A synergistic fungicidal composition
GB2552699B (en) *	2016-08-04	2021-03-10	Rotam Agrochem Int Co Ltd	Process for preparing boscalid
CN109790124B (zh) *	2016-09-28	2022-09-13	Upl 有限公司	用于制备形式i的无水啶酰菌胺和形式ii的无水啶酰菌胺的方法
CN115536581A (zh) *	2022-10-08	2022-12-30	河北兰升生物科技有限公司	高纯度啶酰菌胺晶型i的制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CH657129A5 (en)	1983-12-20	1986-08-15	Sandoz Ag	Process for preparing N-thienylchloroacetamides
CA2081935C (en) *	1991-11-22	2004-05-25	Karl Eicken	Anilide derivatives and their use for combating botrytis
TW431861B (en)	1997-12-18	2001-05-01	Basf Ag	Fungicidal mixtures based on amide compounds and azoles
US7087239B2 (en)	2001-09-25	2006-08-08	Basf Aktiengesellschaft	Crystalline hydrates of anilide derivatives
PT2080433E (pt) *	2002-03-21	2011-10-03	Basf Se	Misturas fungicidas

2003
- 2003-02-14 DE DE10307751A patent/DE10307751A1/de not_active Withdrawn
2004
- 2004-01-28 HR HRP20050803AA patent/HRP20050803B1/hr not_active IP Right Cessation
- 2004-01-28 JP JP2006501625A patent/JP4642743B2/ja not_active Expired - Fee Related
- 2004-01-28 NZ NZ542308A patent/NZ542308A/en not_active IP Right Cessation
- 2004-01-28 KR KR1020127003369A patent/KR101146446B1/ko not_active Expired - Lifetime
- 2004-01-28 DK DK04705809T patent/DK1597232T3/da active
- 2004-01-28 ES ES04705809T patent/ES2273211T3/es not_active Expired - Lifetime
- 2004-01-28 SI SI200430069T patent/SI1597232T1/sl unknown
- 2004-01-28 PT PT04705809T patent/PT1597232E/pt unknown
- 2004-01-28 EP EP04705809A patent/EP1597232B1/de not_active Expired - Lifetime
- 2004-01-28 AP AP2005003370A patent/AP1955A/xx active
- 2004-01-28 DE DE502004001477T patent/DE502004001477D1/de not_active Expired - Lifetime
- 2004-01-28 RS YU20050621A patent/RS51685B/sr unknown
- 2004-01-28 EA EA200501226A patent/EA008004B1/ru not_active IP Right Cessation
- 2004-01-28 CA CA2515725A patent/CA2515725C/en not_active Expired - Lifetime
- 2004-01-28 AT AT04705809T patent/ATE339405T1/de active
- 2004-01-28 BR BRPI0407358-4A patent/BRPI0407358B1/pt not_active IP Right Cessation
- 2004-01-28 ME MEP-2008-70A patent/ME00061B/me unknown
- 2004-01-28 MX MXPA05007962A patent/MXPA05007962A/es active IP Right Grant
- 2004-01-28 AU AU2004212039A patent/AU2004212039B2/en not_active Expired
- 2004-01-28 WO PCT/EP2004/000703 patent/WO2004072039A1/de not_active Ceased
- 2004-01-28 CN CNB2004800041805A patent/CN100494179C/zh not_active Expired - Lifetime
- 2004-01-28 US US10/544,627 patent/US7501384B2/en not_active Expired - Lifetime
- 2004-01-28 UA UAA200508696A patent/UA81659C2/ru unknown
- 2004-01-28 KR KR1020057014876A patent/KR101146432B1/ko not_active Expired - Lifetime
- 2004-01-28 OA OA1200500217A patent/OA13150A/en unknown
- 2004-01-28 PL PL378403A patent/PL219123B1/pl unknown
- 2004-02-12 CL CL200400256A patent/CL2004000256A1/es unknown
- 2004-02-13 AR ARP040100449A patent/AR043175A1/es not_active Application Discontinuation
2005
- 2005-08-04 EC EC2005005948A patent/ECSP055948A/es unknown
- 2005-08-08 NO NO20053767A patent/NO329988B1/no not_active IP Right Cessation
- 2005-08-09 CR CR7939A patent/CR7939A/es unknown
- 2005-08-11 MA MA28432A patent/MA27619A1/fr unknown
- 2005-09-13 ZA ZA200507344A patent/ZA200507344B/xx unknown
2006
- 2006-12-11 CY CY20061101782T patent/CY1107513T1/el unknown
2014
- 2014-01-08 AR ARP140100072A patent/AR094395A2/es unknown

Also Published As

Publication number	Publication date
BRPI0407358B1 (pt)	2014-11-18
NO329988B1 (no)	2011-01-31
RS20050621A (sr)	2007-09-21
RS51685B (sr)	2011-10-31
AR043175A1 (es)	2005-07-20
ECSP055948A (es)	2006-04-19
MXPA05007962A (es)	2005-09-20
CN1751026A (zh)	2006-03-22
US20060154825A1 (en)	2006-07-13
HRP20050803B1 (hr)	2014-03-28
CR7939A (es)	2006-02-07
NO20053767L (no)	2005-08-08
AU2004212039A1 (en)	2004-08-26
BRPI0407358A (pt)	2006-01-10
DK1597232T3 (da)	2007-01-29
ZA200507344B (en)	2007-02-28
JP2006517548A (ja)	2006-07-27
EP1597232B1 (de)	2006-09-13
KR20120018384A (ko)	2012-03-02
KR101146432B1 (ko)	2012-05-21
CY1107513T1 (el)	2013-03-13
ATE339405T1 (de)	2006-10-15
AU2004212039B2 (en)	2010-07-22
EA200501226A1 (ru)	2006-02-24
SI1597232T1 (sl)	2006-12-31
KR101146446B1 (ko)	2012-05-18
WO2004072039A1 (de)	2004-08-26
PT1597232E (pt)	2006-12-29
US7501384B2 (en)	2009-03-10
EP1597232A1 (de)	2005-11-23
AP1955A (en)	2009-02-13
MEP7008A (en)	2010-06-10
HRP20050803A2 (en)	2005-10-31
UA81659C2 (ru)	2008-01-25
DE10307751A1 (de)	2004-08-26
MA27619A1 (fr)	2005-11-01
EA008004B1 (ru)	2007-02-27
DE502004001477D1 (de)	2006-10-26
JP4642743B2 (ja)	2011-03-02
AR094395A2 (es)	2015-07-29
PL378403A1 (pl)	2006-04-03
ES2273211T3 (es)	2007-05-01
KR20050101211A (ko)	2005-10-20
AP2005003370A0 (en)	2005-09-30
CA2515725C (en)	2011-01-04
PL219123B1 (pl)	2015-03-31
NZ542308A (en)	2008-07-31
ME00061B (me)	2010-10-10
CN100494179C (zh)	2009-06-03
CL2004000256A1 (es)	2005-02-04
CA2515725A1 (en)	2004-08-26

Publication	Publication Date	Title
OA13150A (en)	2006-12-13	Novel crystalline modification of the anhydrate ofboscalid.
US12162843B2 (en)	2024-12-10	High-purity thermostable crystal form of substituted 3-isoxazolidinone compound, preparation method therefor and application thereof
CN114478506B (zh)	2025-11-18	吡啶噁唑类化合物及其应用
CN112409263B (zh)	2024-04-05	取代的苯甲酰类化合物及其应用
CN114437056B (zh)	2025-11-18	吡啶噁二唑酮类化合物及其应用
CA1085857A (en)	1980-09-16	1-aryl-5-carboxy-2 pyridones and derivatives thereof
CA1127167A (en)	1982-07-06	Substituted thiosemicarbazides, their manufacture and use as plant growth regulants
EP0089137B1 (en)	1986-11-12	Substituted pyridazines, their use as plant growth regulators, and plant growth regulating compositions containing them
CN114163400B (zh)	2025-03-14	环己二酮-苯并噻二嗪类化合物及其应用
JPS59176288A (ja)	1984-10-05	新規な２−シアノイミダゾピリジン誘導体、その製造方法および殺菌剤としてのその使用
US5494887A (en)	1996-02-27	Ring annulated 5-alkoxy-n-aryl[1,2,4]triazolo[1,5-C]-pyrimidine-2-sulfonamide herbicides
JPS5838241A (ja)	1983-03-05	安息香酸アミド誘導体およびそれらを含有する除草剤
JPS63218674A (ja)	1988-09-12	２−イミダゾリノンニコチン酸の複素環式アルキルエステル、その製造方法並びに除草及び植物生長調節用組成物