PL414510A1 - Bifunctional difenoconazole ionic liquid, method for obtaining them and application as the compounds with fungicidal and herbicidal actions - Google Patents
Bifunctional difenoconazole ionic liquid, method for obtaining them and application as the compounds with fungicidal and herbicidal actionsInfo
- Publication number
- PL414510A1 PL414510A1 PL414510A PL41451015A PL414510A1 PL 414510 A1 PL414510 A1 PL 414510A1 PL 414510 A PL414510 A PL 414510A PL 41451015 A PL41451015 A PL 41451015A PL 414510 A1 PL414510 A1 PL 414510A1
- Authority
- PL
- Poland
- Prior art keywords
- diphenoconazole
- application
- acetic
- bifunctional
- difenoconazole
- Prior art date
Links
- 239000002608 ionic liquid Substances 0.000 title abstract 4
- 230000001588 bifunctional effect Effects 0.000 title abstract 2
- 230000002363 herbicidal effect Effects 0.000 title abstract 2
- 239000005760 Difenoconazole Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 title 1
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 title 1
- 230000000855 fungicidal effect Effects 0.000 title 1
- -1 4-chloro-2-methylphenoxy Chemical group 0.000 abstract 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 230000001476 alcoholic effect Effects 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Przedmiotem zgłoszenia są dwufunkcyjne ciecze jonowe difenokonazolu oraz sposób ich otrzymywania. Dwufunkcyjne ciecze jonowe difenokonazolu przedstawia wzór ogólny 1, w którym A- oznacza: anion herbicydowy (4-chloro-2-metylofenoksy)octowy lub 2,4-dichlorofenoksy)octowy. Sposób polega na tym, że difenokonazol o wzorze ogólnym 2, rozpuszcza się w alkoholu alifatycznym o długości łańcucha węglowego od jednego do czterech atomów węgla lub ich mieszaninie, korzystnie w metanolu, dalej miesza się z alkoholowym roztworem kwasu (4-chloro-2-metylofenoksy)octowego lub (2,4-dichlorofenoksy)octowego o stężeniu co najmniej 1%, w stosunku molowym difenokonazolu do kwasu organicznego od 1 : 1 do 1 : 1,1, korzystnie 1 : 1, w temperaturze poniżej 100°C, korzystnie w 50°C, w czasie co najmniej 40 minut, po czym rozpuszczalnik usuwa się. Zgłoszenie dotyczy też zastosowania dwufunkcyjnych cieczy jonowych difenokonazolu o wzorze ogólnym 1.The subject of the application are difunctional ionic liquids of diphenoconazole and the method of their preparation. The difunctional ionic liquids of diphenoconazole are represented by general formula 1, in which A- is: herbicidal (4-chloro-2-methylphenoxy) acetic or 2,4-dichlorophenoxy) acetic anion. The method consists in the fact that diphenoconazole of general formula 2 dissolves in an aliphatic alcohol with a carbon chain length of one to four carbon atoms or a mixture thereof, preferably in methanol, further mixed with an alcoholic acid solution (4-chloro-2-methylphenoxy) ) acetic or (2,4-dichlorophenoxy) acetic at a concentration of at least 1%, in a molar ratio of diphenoconazole to organic acid from 1: 1 to 1: 1.1, preferably 1: 1, at a temperature below 100 ° C, preferably at 50 ° C for at least 40 minutes, after which the solvent is removed. The application also relates to the use of bifunctional ionic liquids of diphenoconazole of general formula 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL414510A PL237289B1 (en) | 2015-10-26 | 2015-10-26 | Bifunctional difenoconazole ionic liquid, method for obtaining them and application as the compounds with fungicidal and herbicidal actions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL414510A PL237289B1 (en) | 2015-10-26 | 2015-10-26 | Bifunctional difenoconazole ionic liquid, method for obtaining them and application as the compounds with fungicidal and herbicidal actions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL414510A1 true PL414510A1 (en) | 2017-05-08 |
| PL237289B1 PL237289B1 (en) | 2021-04-06 |
Family
ID=58643690
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL414510A PL237289B1 (en) | 2015-10-26 | 2015-10-26 | Bifunctional difenoconazole ionic liquid, method for obtaining them and application as the compounds with fungicidal and herbicidal actions |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL237289B1 (en) |
-
2015
- 2015-10-26 PL PL414510A patent/PL237289B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL237289B1 (en) | 2021-04-06 |
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