PL413612A1 - Ionic liquids with cation N-[2-(2,3,4,6-tetra-O-acetyl β-D-glucopyranosyloxy)ethyl]-N,N,N-alkyl dimethyloammonium cation and (2,4-dichlorophfenoxy)acetate anion and method for obtaining them - Google Patents
Ionic liquids with cation N-[2-(2,3,4,6-tetra-O-acetyl β-D-glucopyranosyloxy)ethyl]-N,N,N-alkyl dimethyloammonium cation and (2,4-dichlorophfenoxy)acetate anion and method for obtaining themInfo
- Publication number
- PL413612A1 PL413612A1 PL413612A PL41361215A PL413612A1 PL 413612 A1 PL413612 A1 PL 413612A1 PL 413612 A PL413612 A PL 413612A PL 41361215 A PL41361215 A PL 41361215A PL 413612 A1 PL413612 A1 PL 413612A1
- Authority
- PL
- Poland
- Prior art keywords
- cation
- glucopyranosyloxy
- tetra
- acetyl
- ethyl
- Prior art date
Links
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 title abstract 4
- 150000001768 cations Chemical class 0.000 title abstract 3
- 239000002608 ionic liquid Substances 0.000 title abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 abstract 3
- OVSKIKFHRZPJSS-UHFFFAOYSA-M (2,4-dichlorophenoxy)acetate Chemical compound [O-]C(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-M 0.000 abstract 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 230000001476 alcoholic effect Effects 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- AQKNQRMIGNOQQF-UHFFFAOYSA-N azane;2-(2,4-dichlorophenoxy)acetic acid Chemical compound [NH4+].[O-]C(=O)COC1=CC=C(Cl)C=C1Cl AQKNQRMIGNOQQF-UHFFFAOYSA-N 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 230000002363 herbicidal effect Effects 0.000 abstract 1
- 239000004009 herbicide Substances 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Saccharide Compounds (AREA)
Abstract
Przedmiotem zgłoszenia są ciecze jonowe z kationem N-[2-(2,3,4,6-tetra-O-acetylo-ß-D-glukopiranozyloksy)etylo]-N,N,N-alkilodimetyloamoniowym i anionem herbicydowym, o wzorze ogólnym 1, w którym R oznacza podstawnik alkilowy o długości łańcucha węglowego od jednego do szesnastu atomów węgla, oraz A oznacza anion (2,4-dichlorofenoksy)octanowy o wzorze ogólnym 2. Zgłoszenie dotyczy także sposobu otrzymywania cieczy jonowych z kationem N-[2-(2,3,4,6-tetra-O-acetylo-ß-D-glukopiranozyloksy)etylo]-N,N,N-alkilodimetyloamoniowym, o wzorze ogólnym 1, określonych zastrzeżeniem 1. Sposób polega na tym, że bromki N-[2-(2,3,4,6-tetra-O-acetylo-ß-D-glukopiranozyloksy)etylo]-N,N,N-alkilodimetyloamoniowe o wzorze ogólnym 3, w którym R oznacza podstawnik alkilowy o długości łańcucha węglowego od jednego do szesnastu atomów węgla rozpuszcza się w alkoholu alifatycznym o długości łańcucha węglowego od 1 do 4 atomów węgla, lub ich mieszaninie, korzystnie w metanolu, miesza się w stosunku molowym od 0,8:1 do 1:1,2, korzystnie 1:1 z alkoholowym roztworem soli sodowej lub potasowej, lub litowej, lub amonowej kwasu (2,4-dichlorofenoksy)octowego, o stężeniu co najmniej 1%, w temperaturze od 20 do 60°C, korzystnie 20°C, w czasie co najmniej 4 minut, następnie odsącza się wytrącony z alkoholu, lub ich mieszaniny nieorganiczny produkt uboczny, po czym rozpuszczalnik lub ich mieszaninę usuwa się.The subject of the application are ionic liquids with the cation N- [2- (2,3,4,6-tetra-O-acetyl-ß-D-glucopyranosyloxy) ethyl] -N, N, N-alkyl dimethylammonium and herbicide anion of general formula The application of claim 1, wherein R is an alkyl substituent with a carbon chain length of one to sixteen carbon atoms, and A is a (2,4-dichlorophenoxy) acetate anion of general formula 2. The application also relates to a method for obtaining ionic liquids with an N- [2- (2,3,4,6-tetra-O-acetyl-ß-D-glucopyranosyloxy) ethyl] -N, N, N-alkyl dimethylammonium, of general formula 1, as defined by claim 1. The method consists in that N- bromides [2- (2,3,4,6-tetra-O-acetyl-ß-D-glucopyranosyloxy) ethyl] -N, N, N-alkyl dimethylammonium of general formula 3, wherein R is an alkyl substituent with a carbon chain length of one to sixteen carbon atoms are dissolved in an aliphatic alcohol with a carbon chain length of 1 to 4 carbon atoms, or a mixture thereof, preferably in methanol, m Is mixed in a molar ratio of 0.8: 1 to 1: 1.2, preferably 1: 1 with an alcoholic solution of sodium, potassium or lithium or ammonium (2,4-dichlorophenoxy) acetic acid, at a concentration of at least 1 %, at a temperature of 20 to 60 ° C, preferably 20 ° C, for at least 4 minutes, then the inorganic by-product precipitated from the alcohol or mixtures thereof is filtered off, after which the solvent or mixture is removed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL413612A PL227335B1 (en) | 2015-08-21 | 2015-08-21 | Ionic liquids with cation N-[2-(2,3,4,6-tetra-O-acetyl β-D-glucopyranosyloxy)ethyl]-N,N,N-alkyl dimethyloammonium cation and (2,4-dichlorophfenoxy)acetate anion and method for obtaining them |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL413612A PL227335B1 (en) | 2015-08-21 | 2015-08-21 | Ionic liquids with cation N-[2-(2,3,4,6-tetra-O-acetyl β-D-glucopyranosyloxy)ethyl]-N,N,N-alkyl dimethyloammonium cation and (2,4-dichlorophfenoxy)acetate anion and method for obtaining them |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL413612A1 true PL413612A1 (en) | 2017-02-27 |
| PL227335B1 PL227335B1 (en) | 2017-11-30 |
Family
ID=58092006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL413612A PL227335B1 (en) | 2015-08-21 | 2015-08-21 | Ionic liquids with cation N-[2-(2,3,4,6-tetra-O-acetyl β-D-glucopyranosyloxy)ethyl]-N,N,N-alkyl dimethyloammonium cation and (2,4-dichlorophfenoxy)acetate anion and method for obtaining them |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL227335B1 (en) |
-
2015
- 2015-08-21 PL PL413612A patent/PL227335B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL227335B1 (en) | 2017-11-30 |
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