PL428878A1 - Sposób wytwarzania proszkowego kesterytu typu Cu₂SnZnS₄ - Google Patents
Sposób wytwarzania proszkowego kesterytu typu Cu₂SnZnS₄Info
- Publication number
- PL428878A1 PL428878A1 PL428878A PL42887819A PL428878A1 PL 428878 A1 PL428878 A1 PL 428878A1 PL 428878 A PL428878 A PL 428878A PL 42887819 A PL42887819 A PL 42887819A PL 428878 A1 PL428878 A1 PL 428878A1
- Authority
- PL
- Poland
- Prior art keywords
- kesterite
- cu2snzns4
- type
- hours
- powder
- Prior art date
Links
- 239000000843 powder Substances 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 238000005303 weighing Methods 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/541—CuInSe2 material PV cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Luminescent Compositions (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Przedmiotem zgłoszenia jest sposób wytwarzania proszkowego kesterytu typu Cu2SnZnS4, który polega na tym, że odważa się proszki metali Cu, Sn i Zn w proporcji molowej Cu:Sn:Zn = 2:1:1 i miesza w wysokoenergetycznym młynie kulowym z dodatkiem cieczy dyspergującej w postaci wysokowrzących ciekłych węglowodorów alifatycznych lub aromatycznych wybranych z grupy obejmującej heksan, toluen i ksylen przez okres od 30 minut do 100 godzin, przy prędkości obrotowej młyna od 200 do 1100 obr/min, po czym do mieszaniny dodaje się siarkę elementarną w ilości od stechiometrycznej do 100% nadmiaru w stosunku do ilości teoretycznej siarki występującej w kesterycie typu Cu2SnZnS4 i dalej mieli przez okres od 30 minut do 100 godzin przy prędkości obrotowej młyna kulowego od 200 do 1100 obr/min, następnie odparowuje się ciecz dyspergującą, a uzyskaną mieszaninę ogrzewa się w atmosferze gazu obojętnego w temperaturze od 400 do 700°C przez okres od 0,5 do 36 godzin, uzyskując proszkowy czysty kesteryt o średniej wielkości krystalitów w zakresie od 10 do 200 nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL428878A PL241410B1 (pl) | 2019-02-11 | 2019-02-11 | Sposób wytwarzania proszkowego kesterytu typu Cu<sub>₂</sub>SnZnS<sub>₄</sub> |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL428878A PL241410B1 (pl) | 2019-02-11 | 2019-02-11 | Sposób wytwarzania proszkowego kesterytu typu Cu<sub>₂</sub>SnZnS<sub>₄</sub> |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL428878A1 true PL428878A1 (pl) | 2019-10-21 |
| PL241410B1 PL241410B1 (pl) | 2022-09-26 |
Family
ID=68238701
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL428878A PL241410B1 (pl) | 2019-02-11 | 2019-02-11 | Sposób wytwarzania proszkowego kesterytu typu Cu<sub>₂</sub>SnZnS<sub>₄</sub> |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL241410B1 (pl) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL441793A1 (pl) * | 2022-07-20 | 2023-07-03 | Akademia Górniczo-Hutnicza Im.Stanisława Staszica W Krakowie | Sposób wytwarzania spieków z nanoproszków półprzewodnika typu kesterytu Cu2ZnSnS4 |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010135622A1 (en) * | 2009-05-21 | 2010-11-25 | E. I. Du Pont De Nemours And Company | Copper zinc tin chalcogenide nanoparticles |
| US20120055554A1 (en) * | 2009-05-21 | 2012-03-08 | E.I. Du Pont De Nemours And Company | Copper zinc tin chalcogenide nanoparticles |
| US20120100664A1 (en) * | 2010-10-26 | 2012-04-26 | International Business Machines Corporation | Fabricating kesterite solar cells and parts thereof |
| US8366975B2 (en) * | 2010-05-21 | 2013-02-05 | E I Du Pont De Nemours And Company | Atypical kesterite compositions |
| US20130037111A1 (en) * | 2011-08-10 | 2013-02-14 | International Business Machines Corporation | Process for Preparation of Elemental Chalcogen Solutions and Method of Employing Said Solutions in Preparation of Kesterite Films |
| PL406175A1 (pl) * | 2013-11-21 | 2015-05-25 | Stanley Aleksander Rokicki | Kompozyt nośny ogniw fotowoltaicznych |
| US20180069146A1 (en) * | 2016-09-02 | 2018-03-08 | International Business Machines Corporation | Minimizing Tin Loss During Thermal Processing of Kesterite Films |
| WO2018065156A1 (en) * | 2016-10-07 | 2018-04-12 | Haldor Topsøe A/S | KESTERITE MATERIAL OF CZTS, CZTSe OR CZTSSe TYPE |
| PL229752B1 (pl) * | 2014-10-27 | 2018-08-31 | Politechnika Slaska | Barwnikowe ogniwo fotowoltaiczne i sposób jego wytwarzania |
-
2019
- 2019-02-11 PL PL428878A patent/PL241410B1/pl unknown
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010135622A1 (en) * | 2009-05-21 | 2010-11-25 | E. I. Du Pont De Nemours And Company | Copper zinc tin chalcogenide nanoparticles |
| US20120055554A1 (en) * | 2009-05-21 | 2012-03-08 | E.I. Du Pont De Nemours And Company | Copper zinc tin chalcogenide nanoparticles |
| US8366975B2 (en) * | 2010-05-21 | 2013-02-05 | E I Du Pont De Nemours And Company | Atypical kesterite compositions |
| US20120100664A1 (en) * | 2010-10-26 | 2012-04-26 | International Business Machines Corporation | Fabricating kesterite solar cells and parts thereof |
| US20130037111A1 (en) * | 2011-08-10 | 2013-02-14 | International Business Machines Corporation | Process for Preparation of Elemental Chalcogen Solutions and Method of Employing Said Solutions in Preparation of Kesterite Films |
| PL406175A1 (pl) * | 2013-11-21 | 2015-05-25 | Stanley Aleksander Rokicki | Kompozyt nośny ogniw fotowoltaicznych |
| PL229752B1 (pl) * | 2014-10-27 | 2018-08-31 | Politechnika Slaska | Barwnikowe ogniwo fotowoltaiczne i sposób jego wytwarzania |
| US20180069146A1 (en) * | 2016-09-02 | 2018-03-08 | International Business Machines Corporation | Minimizing Tin Loss During Thermal Processing of Kesterite Films |
| WO2018065156A1 (en) * | 2016-10-07 | 2018-04-12 | Haldor Topsøe A/S | KESTERITE MATERIAL OF CZTS, CZTSe OR CZTSSe TYPE |
Non-Patent Citations (1)
| Title |
|---|
| WOJSKOWA AKADEMIA TECHNICZNA IM. A ZASTRZEŻENIE JAROSŁAWA DĄBROWSKIEGO, ADVANCES IN CZTS THIN FILMS AND NANOSTRUCTURED, 201S * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL441793A1 (pl) * | 2022-07-20 | 2023-07-03 | Akademia Górniczo-Hutnicza Im.Stanisława Staszica W Krakowie | Sposób wytwarzania spieków z nanoproszków półprzewodnika typu kesterytu Cu2ZnSnS4 |
Also Published As
| Publication number | Publication date |
|---|---|
| PL241410B1 (pl) | 2022-09-26 |
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