SE458612B - Katalysatorkomposition baserad paa aktiverad silika och en reaktionsprodukt av vanadinpentoxid och ett kloreringsmedel samt saett att framstaella en olefinpolymer haermed - Google Patents

Katalysatorkomposition baserad paa aktiverad silika och en reaktionsprodukt av vanadinpentoxid och ett kloreringsmedel samt saett att framstaella en olefinpolymer haermed

Info

Publication number: SE458612B
Authority: SE; Sweden
Prior art keywords: catalyst; catalyst composition; chlorinated; oxygen; silica
Prior art date: 1987-08-19

Application number

SE8703212A

Other languages

English (en)

Swedish (sv)

Other versions

SE8703212L (sv

SE8703212D0 (sv

Inventor

U Palmqvist

S Johansson

D Lindgren

A Wahlstroem

Original Assignee

Neste Oy

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-08-19

Filing date

1987-08-19

Publication date

1989-04-17

1987-08-19 Application filed by Neste Oy filed Critical Neste Oy

1987-08-19 Priority to SE8703212A priority Critical patent/SE458612B/sv

1987-08-19 Publication of SE8703212D0 publication Critical patent/SE8703212D0/xx

1988-08-15 Priority to PCT/SE1988/000414 priority patent/WO1989001497A1/en

1988-08-15 Priority to DE8888907418T priority patent/DE3867847D1/de

1988-08-15 Priority to EP88907418A priority patent/EP0378556B1/de

1988-08-15 Priority to AT88907418T priority patent/ATE71634T1/de

1988-08-15 Priority to JP63505391A priority patent/JPH03500783A/ja

1988-08-18 Priority to CA000575093A priority patent/CA1314535C/en

1988-08-18 Priority to CN88106704.0A priority patent/CN1016428B/zh

1989-02-20 Publication of SE8703212L publication Critical patent/SE8703212L/xx

1989-04-17 Publication of SE458612B publication Critical patent/SE458612B/sv

1990-02-16 Priority to FI900780A priority patent/FI91969C/fi

1990-02-19 Priority to DK044090A priority patent/DK44090A/da

1990-02-19 Priority to NO900784A priority patent/NO172804C/no

Links

VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 165
239000003054 catalyst Substances 0.000 title claims abstract description 148
239000000203 mixture Substances 0.000 title claims abstract description 67
238000004519 manufacturing process Methods 0.000 title claims description 14
229920000642 polymer Polymers 0.000 title description 8
150000003682 vanadium compounds Chemical class 0.000 claims abstract description 76
-1 SbOCl3 Chemical compound 0.000 claims abstract description 67
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 27
GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims abstract description 18
XEMRAKSQROQPBR-UHFFFAOYSA-N (trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=CC=C1 XEMRAKSQROQPBR-UHFFFAOYSA-N 0.000 claims abstract description 17
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 16
125000000217 alkyl group Chemical group 0.000 claims abstract description 12
239000007788 liquid Substances 0.000 claims abstract description 11
150000002902 organometallic compounds Chemical class 0.000 claims abstract description 11
229910052801 chlorine Inorganic materials 0.000 claims abstract description 10
239000012320 chlorinating reagent Substances 0.000 claims abstract description 9
125000003545 alkoxy group Chemical group 0.000 claims abstract description 8
150000001336 alkenes Chemical class 0.000 claims abstract description 7
239000007795 chemical reaction product Substances 0.000 claims abstract description 7
VFDYKPARTDCDCU-UHFFFAOYSA-N hexachloropropene Chemical group ClC(Cl)=C(Cl)C(Cl)(Cl)Cl VFDYKPARTDCDCU-UHFFFAOYSA-N 0.000 claims abstract description 7
238000000034 method Methods 0.000 claims abstract description 6
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 6
150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 5
239000000047 product Substances 0.000 claims abstract description 5
229910052751 metal Inorganic materials 0.000 claims abstract description 4
239000002184 metal Substances 0.000 claims abstract description 4
239000000178 monomer Substances 0.000 claims abstract description 4
230000000737 periodic effect Effects 0.000 claims abstract description 4
238000006116 polymerization reaction Methods 0.000 claims description 63
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 62
238000006243 chemical reaction Methods 0.000 claims description 38
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 34
BNIXVQGCZULYKV-UHFFFAOYSA-N pentachloroethane Chemical compound ClC(Cl)C(Cl)(Cl)Cl BNIXVQGCZULYKV-UHFFFAOYSA-N 0.000 claims description 29
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 26
239000001257 hydrogen Substances 0.000 claims description 26
239000001301 oxygen Substances 0.000 claims description 26
229910052760 oxygen Inorganic materials 0.000 claims description 26
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 25
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 22
239000005977 Ethylene Substances 0.000 claims description 22
239000000460 chlorine Substances 0.000 claims description 10
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 6
239000007789 gas Substances 0.000 claims description 6
229920000098 polyolefin Polymers 0.000 claims description 3
PDWVXNLUDMQFCH-UHFFFAOYSA-N oxoantimony;hydrochloride Chemical compound Cl.[Sb]=O PDWVXNLUDMQFCH-UHFFFAOYSA-N 0.000 claims description 2
150000002926 oxygen Chemical class 0.000 abstract description 35
FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 abstract description 16
229910052794 bromium Inorganic materials 0.000 abstract description 4
XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 abstract description 4
CTSLXHKWHWQRSH-UHFFFAOYSA-N oxalyl chloride Chemical compound ClC(=O)C(Cl)=O CTSLXHKWHWQRSH-UHFFFAOYSA-N 0.000 abstract description 3
229910019213 POCl3 Inorganic materials 0.000 abstract description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 2
YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 abstract 1
229910005948 SO2Cl Inorganic materials 0.000 abstract 1
229910006124 SOCl2 Inorganic materials 0.000 abstract 1
229910003074 TiCl4 Inorganic materials 0.000 abstract 1
229910021627 Tin(IV) chloride Inorganic materials 0.000 abstract 1
229910007932 ZrCl4 Inorganic materials 0.000 abstract 1
VMPVEPPRYRXYNP-UHFFFAOYSA-I antimony(5+);pentachloride Chemical compound Cl[Sb](Cl)(Cl)(Cl)Cl VMPVEPPRYRXYNP-UHFFFAOYSA-I 0.000 abstract 1
UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 abstract 1
HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 abstract 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 1
DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 abstract 1
239000000377 silicon dioxide Substances 0.000 description 75
229920000573 polyethylene Polymers 0.000 description 58
239000004698 Polyethylene Substances 0.000 description 57
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 35
229910052720 vanadium Inorganic materials 0.000 description 35
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 33
239000002002 slurry Substances 0.000 description 31
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 30
239000012299 nitrogen atmosphere Substances 0.000 description 30
238000010992 reflux Methods 0.000 description 21
238000002474 experimental method Methods 0.000 description 20
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 18
229910052782 aluminium Inorganic materials 0.000 description 18
238000009826 distribution Methods 0.000 description 17
229910052757 nitrogen Inorganic materials 0.000 description 16
229910052809 inorganic oxide Inorganic materials 0.000 description 14
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 11
150000001875 compounds Chemical class 0.000 description 11
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 11
229910000831 Steel Inorganic materials 0.000 description 9
239000010959 steel Substances 0.000 description 9
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 8
229930195733 hydrocarbon Natural products 0.000 description 8
150000002430 hydrocarbons Chemical class 0.000 description 8
125000002887 hydroxy group Chemical group [H]O* 0.000 description 8
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 7
239000004215 Carbon black (E152) Substances 0.000 description 7
239000002245 particle Substances 0.000 description 7
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
238000009835 boiling Methods 0.000 description 6
239000012071 phase Substances 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
239000011541 reaction mixture Substances 0.000 description 6
230000035945 sensitivity Effects 0.000 description 6
229910000029 sodium carbonate Inorganic materials 0.000 description 6
239000002904 solvent Substances 0.000 description 6
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 5
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 5
238000012685 gas phase polymerization Methods 0.000 description 5
VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 description 5
150000001350 alkyl halides Chemical class 0.000 description 4
230000000694 effects Effects 0.000 description 4
239000000463 material Substances 0.000 description 4
239000011148 porous material Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 4
YFIIENAGGCUHIQ-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptachloropropane Chemical compound ClC(Cl)C(Cl)(Cl)C(Cl)(Cl)Cl YFIIENAGGCUHIQ-UHFFFAOYSA-N 0.000 description 3
QVLAWKAXOMEXPM-UHFFFAOYSA-N 1,1,1,2-tetrachloroethane Chemical compound ClCC(Cl)(Cl)Cl QVLAWKAXOMEXPM-UHFFFAOYSA-N 0.000 description 3
230000004913 activation Effects 0.000 description 3
HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 description 3
238000005660 chlorination reaction Methods 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
230000007797 corrosion Effects 0.000 description 3
238000005260 corrosion Methods 0.000 description 3
229910001873 dinitrogen Inorganic materials 0.000 description 3
JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 description 3
229920001903 high density polyethylene Polymers 0.000 description 3
239000004700 high-density polyethylene Substances 0.000 description 3
150000002431 hydrogen Chemical class 0.000 description 3
229960002809 lindane Drugs 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
238000003756 stirring Methods 0.000 description 3
ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 3
LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 3
QQAHAGNPDBPSJP-UHFFFAOYSA-N 1,1,1,2,2,3,3,3-octachloropropane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)C(Cl)(Cl)Cl QQAHAGNPDBPSJP-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
239000012298 atmosphere Substances 0.000 description 2
150000001805 chlorine compounds Chemical class 0.000 description 2
229910000423 chromium oxide Inorganic materials 0.000 description 2
238000005336 cracking Methods 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
238000001035 drying Methods 0.000 description 2
229910052731 fluorine Inorganic materials 0.000 description 2
150000008282 halocarbons Chemical class 0.000 description 2
125000005843 halogen group Chemical group 0.000 description 2
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
238000010926 purge Methods 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000000725 suspension Substances 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 2
150000003681 vanadium Chemical class 0.000 description 2
UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
APQIUTYORBAGEZ-UHFFFAOYSA-N 1,1-dibromoethane Chemical compound CC(Br)Br APQIUTYORBAGEZ-UHFFFAOYSA-N 0.000 description 1
PAAZPARNPHGIKF-UHFFFAOYSA-N 1,2-dibromoethane Chemical compound BrCCBr PAAZPARNPHGIKF-UHFFFAOYSA-N 0.000 description 1
WPWHSFAFEBZWBB-UHFFFAOYSA-N 1-butyl radical Chemical compound [CH2]CCC WPWHSFAFEBZWBB-UHFFFAOYSA-N 0.000 description 1
AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 1
125000005916 2-methylpentyl group Chemical group 0.000 description 1
AIBRSVLEQRWAEG-UHFFFAOYSA-N 3,9-bis(2,4-ditert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP1OCC2(COP(OC=3C(=CC(=CC=3)C(C)(C)C)C(C)(C)C)OC2)CO1 AIBRSVLEQRWAEG-UHFFFAOYSA-N 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
241000132028 Bellis Species 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
229910021551 Vanadium(III) chloride Inorganic materials 0.000 description 1
229910021552 Vanadium(IV) chloride Inorganic materials 0.000 description 1
229910007926 ZrCl Inorganic materials 0.000 description 1
CYJVMBNEKOYAAI-UHFFFAOYSA-N [AlH2]C(C)=C Chemical compound [AlH2]C(C)=C CYJVMBNEKOYAAI-UHFFFAOYSA-N 0.000 description 1
WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 description 1
239000012346 acetyl chloride Substances 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
125000005234 alkyl aluminium group Chemical group 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
DLRHRQTUCJTIIV-UHFFFAOYSA-N diethoxy(ethyl)alumane Chemical compound CC[O-].CC[O-].CC[Al+2] DLRHRQTUCJTIIV-UHFFFAOYSA-N 0.000 description 1
125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
LDYLHMQUPCBROZ-UHFFFAOYSA-N diethyl(methoxy)alumane Chemical compound [O-]C.CC[Al+]CC LDYLHMQUPCBROZ-UHFFFAOYSA-N 0.000 description 1
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
XPURMEXEEOGCNE-UHFFFAOYSA-N ethyl-di(propan-2-yloxy)alumane Chemical compound CC[Al+2].CC(C)[O-].CC(C)[O-] XPURMEXEEOGCNE-UHFFFAOYSA-N 0.000 description 1
MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
239000011521 glass Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
150000004678 hydrides Chemical class 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
239000003317 industrial substance Substances 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
239000011872 intimate mixture Substances 0.000 description 1
239000001282 iso-butane Substances 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
239000000155 melt Substances 0.000 description 1
230000003340 mental effect Effects 0.000 description 1
229910001510 metal chloride Inorganic materials 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
UNFUYWDGSFDHCW-UHFFFAOYSA-N monochlorocyclohexane Chemical compound ClC1CCCCC1 UNFUYWDGSFDHCW-UHFFFAOYSA-N 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
150000002899 organoaluminium compounds Chemical class 0.000 description 1
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
RLOWWWKZYUNIDI-UHFFFAOYSA-N phosphinic chloride Chemical compound ClP=O RLOWWWKZYUNIDI-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000004575 stone Substances 0.000 description 1
125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
YGRHYJIWZFEDBT-UHFFFAOYSA-N tridecylaluminum Chemical compound CCCCCCCCCCCCC[Al] YGRHYJIWZFEDBT-UHFFFAOYSA-N 0.000 description 1
XBEXIHMRFRFRAM-UHFFFAOYSA-N tridodecylalumane Chemical compound CCCCCCCCCCCC[Al](CCCCCCCCCCCC)CCCCCCCCCCCC XBEXIHMRFRFRAM-UHFFFAOYSA-N 0.000 description 1
CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
JBIQAPKSNFTACH-UHFFFAOYSA-K vanadium oxytrichloride Chemical compound Cl[V](Cl)(Cl)=O JBIQAPKSNFTACH-UHFFFAOYSA-K 0.000 description 1
JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 1
HQYCOEXWFMFWLR-UHFFFAOYSA-K vanadium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Silicon Compounds (AREA)
Catalysts (AREA)

SE8703212A 1987-08-19 1987-08-19 Katalysatorkomposition baserad paa aktiverad silika och en reaktionsprodukt av vanadinpentoxid och ett kloreringsmedel samt saett att framstaella en olefinpolymer haermed SE458612B (sv)

Priority Applications (11)

Application Number	Priority Date	Filing Date	Title
SE8703212A SE458612B (sv)	1987-08-19	1987-08-19	Katalysatorkomposition baserad paa aktiverad silika och en reaktionsprodukt av vanadinpentoxid och ett kloreringsmedel samt saett att framstaella en olefinpolymer haermed
JP63505391A JPH03500783A (ja)	1987-08-19	1988-08-15	触媒組成物
AT88907418T ATE71634T1 (de)	1987-08-19	1988-08-15	Katalysatorzusammensetzung.
DE8888907418T DE3867847D1 (de)	1987-08-19	1988-08-15	Katalysatorzusammensetzung.
EP88907418A EP0378556B1 (de)	1987-08-19	1988-08-15	Katalysatorzusammensetzung
PCT/SE1988/000414 WO1989001497A1 (en)	1987-08-19	1988-08-15	Catalyst composition
CA000575093A CA1314535C (en)	1987-08-19	1988-08-18	Catalyst composition
CN88106704.0A CN1016428B (zh)	1987-08-19	1988-08-18	催化剂组合物
FI900780A FI91969C (fi)	1987-08-19	1990-02-16	Katalysaattorikoostumus
DK044090A DK44090A (da)	1987-08-19	1990-02-19	Katalysatormateriale, samt fremgangsmaade til fremstilling af en olefinpolymer under anvendelse af katalysatormaterialet
NO900784A NO172804C (no)	1987-08-19	1990-02-19	Katalysatorpreparat, samt fremgangsmaate for polymerisering

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
SE8703212A SE458612B (sv)	1987-08-19	1987-08-19	Katalysatorkomposition baserad paa aktiverad silika och en reaktionsprodukt av vanadinpentoxid och ett kloreringsmedel samt saett att framstaella en olefinpolymer haermed

Publications (3)

Publication Number	Publication Date
SE8703212D0 SE8703212D0 (sv)	1987-08-19
SE8703212L SE8703212L (sv)	1989-02-20
SE458612B true SE458612B (sv)	1989-04-17

Family

ID=20369322

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SE8703212A SE458612B (sv)	1987-08-19	1987-08-19	Katalysatorkomposition baserad paa aktiverad silika och en reaktionsprodukt av vanadinpentoxid och ett kloreringsmedel samt saett att framstaella en olefinpolymer haermed

Country Status (11)

Country	Link
EP (1)	EP0378556B1 (de)
JP (1)	JPH03500783A (de)
CN (1)	CN1016428B (de)
AT (1)	ATE71634T1 (de)
CA (1)	CA1314535C (de)
DE (1)	DE3867847D1 (de)
DK (1)	DK44090A (de)
FI (1)	FI91969C (de)
NO (1)	NO172804C (de)
SE (1)	SE458612B (de)
WO (1)	WO1989001497A1 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5204304A (en) *	1991-06-04	1993-04-20	Quantum Chemical Corporation	Vanadium-containing polymerization catalyst
US5155079A (en) *	1991-06-07	1992-10-13	Quantum Chemical Corporation	Multiple site olefin polymerization catalysts
US5399540A (en) *	1993-02-12	1995-03-21	Quantum Chemical Corporation	ZR/V multi-site olefin polymerization catalyst
US5405817A (en) *	1993-02-12	1995-04-11	Quantum Chemical Corporation	V/TI multi-site olefin polymerization catalyst
KR100428496B1 (ko) *	2001-07-13	2004-04-28	한국에너지기술연구원	티탄산바륨의 제조방법

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1145318A (en) *	1979-07-17	1983-04-26	John G. Speakman	Olefin polymerisation catalyst, process and polyolefin product
US4435520A (en) *	1982-11-24	1984-03-06	Cities Service Co.	Catalyst composition
US4426317A (en) *	1982-11-24	1984-01-17	Cities Service Company	Process for making olefin polymerization catalyst
US4579835A (en) *	1984-12-12	1986-04-01	Exxon Research & Engineering Co.	Polymerization catalyst, production and use
US4607019A (en) *	1984-12-12	1986-08-19	Exxon Research & Engineering Co.	Polymerization catalyst, production and use

1987
- 1987-08-19 SE SE8703212A patent/SE458612B/sv not_active IP Right Cessation
1988
- 1988-08-15 DE DE8888907418T patent/DE3867847D1/de not_active Expired - Fee Related
- 1988-08-15 EP EP88907418A patent/EP0378556B1/de not_active Expired
- 1988-08-15 AT AT88907418T patent/ATE71634T1/de not_active IP Right Cessation
- 1988-08-15 WO PCT/SE1988/000414 patent/WO1989001497A1/en not_active Ceased
- 1988-08-15 JP JP63505391A patent/JPH03500783A/ja active Pending
- 1988-08-18 CA CA000575093A patent/CA1314535C/en not_active Expired - Fee Related
- 1988-08-18 CN CN88106704.0A patent/CN1016428B/zh not_active Expired
1990
- 1990-02-16 FI FI900780A patent/FI91969C/fi not_active IP Right Cessation
- 1990-02-19 NO NO900784A patent/NO172804C/no unknown
- 1990-02-19 DK DK044090A patent/DK44090A/da not_active Application Discontinuation

Also Published As

Publication number	Publication date
NO900784L (no)	1990-02-19
NO900784D0 (no)	1990-02-19
DK44090D0 (da)	1990-02-19
DE3867847D1 (de)	1992-02-27
EP0378556A1 (de)	1990-07-25
CN1016428B (zh)	1992-04-29
CN1032800A (zh)	1989-05-10
CA1314535C (en)	1993-03-16
FI91969B (fi)	1994-05-31
SE8703212L (sv)	1989-02-20
NO172804B (no)	1993-06-01
WO1989001497A1 (en)	1989-02-23
SE8703212D0 (sv)	1987-08-19
EP0378556B1 (de)	1992-01-15
FI900780A0 (fi)	1990-02-16
NO172804C (no)	1993-09-08
JPH03500783A (ja)	1991-02-21
DK44090A (da)	1990-02-19
ATE71634T1 (de)	1992-02-15
FI91969C (fi)	1994-09-12

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1995-01-31

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