SK10132000A3 - Homopolyméry a kopolyméry etylénu - Google Patents

Homopolyméry a kopolyméry etylénu Download PDF

Info

Publication number: SK10132000A3
Authority: SK; Slovakia
Prior art keywords: copolymer; ethylene; value; homopolymer; less
Prior art date: 1998-01-07

Application number

SK1013-2000A

Other languages

English (en)

Slovak (sk)

Inventor

Choon Kooi Chai

Original Assignee

Bp Chemicals Limited

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-01-07

Filing date

1999-01-05

Publication date

2001-07-10

1999-01-05 Application filed by Bp Chemicals Limited filed Critical Bp Chemicals Limited

2001-07-10 Publication of SK10132000A3 publication Critical patent/SK10132000A3/sk

Links

229920001577 copolymer Polymers 0.000 title claims description 142
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 56
239000005977 Ethylene Substances 0.000 title claims description 54
229920001519 homopolymer Polymers 0.000 title claims description 48
229920000642 polymer Polymers 0.000 claims abstract description 55
239000012968 metallocene catalyst Substances 0.000 claims abstract description 19
125000004432 carbon atom Chemical group C* 0.000 claims description 35
238000001125 extrusion Methods 0.000 claims description 27
238000000034 method Methods 0.000 claims description 27
239000003054 catalyst Substances 0.000 claims description 26
238000006116 polymerization reaction Methods 0.000 claims description 24
238000005227 gel permeation chromatography Methods 0.000 claims description 22
230000004913 activation Effects 0.000 claims description 20
239000000155 melt Substances 0.000 claims description 20
239000000203 mixture Substances 0.000 claims description 20
-1 germanyl group Chemical group 0.000 claims description 17
238000000518 rheometry Methods 0.000 claims description 14
150000001336 alkenes Chemical class 0.000 claims description 11
239000007789 gas Substances 0.000 claims description 11
125000000217 alkyl group Chemical group 0.000 claims description 9
229910052698 phosphorus Inorganic materials 0.000 claims description 8
150000001993 dienes Chemical class 0.000 claims description 7
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
125000004429 atom Chemical group 0.000 claims description 6
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
239000002245 particle Substances 0.000 claims description 5
229910052726 zirconium Inorganic materials 0.000 claims description 5
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
125000001183 hydrocarbyl group Chemical group 0.000 claims description 4
238000009863 impact test Methods 0.000 claims description 4
229910052751 metal Inorganic materials 0.000 claims description 4
239000002184 metal Substances 0.000 claims description 4
125000001424 substituent group Chemical group 0.000 claims description 4
229910052719 titanium Inorganic materials 0.000 claims description 4
239000010936 titanium Substances 0.000 claims description 4
125000003342 alkenyl group Chemical group 0.000 claims description 3
MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 claims description 3
229920001038 ethylene copolymer Polymers 0.000 claims description 3
239000004711 α-olefin Substances 0.000 claims description 3
229910052799 carbon Inorganic materials 0.000 claims description 2
238000012685 gas phase polymerization Methods 0.000 claims description 2
229910052735 hafnium Inorganic materials 0.000 claims description 2
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 2
230000003647 oxidation Effects 0.000 claims description 2
238000007254 oxidation reaction Methods 0.000 claims description 2
238000004064 recycling Methods 0.000 claims description 2
125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 2
XKWGSXSZRDBDMT-UHFFFAOYSA-N 1-methyl-4-[1-(4-methylphenyl)buta-1,3-dienyl]benzene Chemical compound C1=CC(C)=CC=C1C(=CC=C)C1=CC=C(C)C=C1 XKWGSXSZRDBDMT-UHFFFAOYSA-N 0.000 claims 1
CJSBUWDGPXGFGA-UHFFFAOYSA-N 4-methylpenta-1,3-diene Chemical compound CC(C)=CC=C CJSBUWDGPXGFGA-UHFFFAOYSA-N 0.000 claims 1
125000002947 alkylene group Chemical group 0.000 claims 1
238000007599 discharging Methods 0.000 claims 1
GVOLZAKHRKGRRM-UHFFFAOYSA-N hafnium(4+) Chemical compound [Hf+4] GVOLZAKHRKGRRM-UHFFFAOYSA-N 0.000 claims 1
125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims 1
125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
238000009826 distribution Methods 0.000 abstract description 12
238000006243 chemical reaction Methods 0.000 abstract description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 76
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 69
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 54
239000000377 silicon dioxide Substances 0.000 description 34
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 23
239000000243 solution Substances 0.000 description 23
238000004519 manufacturing process Methods 0.000 description 20
239000000725 suspension Substances 0.000 description 19
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
239000000463 material Substances 0.000 description 18
239000000047 product Substances 0.000 description 18
229910052757 nitrogen Inorganic materials 0.000 description 11
239000000843 powder Substances 0.000 description 11
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 10
229920001684 low density polyethylene Polymers 0.000 description 10
239000004702 low-density polyethylene Substances 0.000 description 10
229920000098 polyolefin Polymers 0.000 description 10
238000013459 approach Methods 0.000 description 9
238000003756 stirring Methods 0.000 description 9
238000002360 preparation method Methods 0.000 description 8
239000012190 activator Substances 0.000 description 7
229910052782 aluminium Inorganic materials 0.000 description 7
239000003446 ligand Substances 0.000 description 7
230000008569 process Effects 0.000 description 7
238000012545 processing Methods 0.000 description 7
239000002904 solvent Substances 0.000 description 7
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
238000012937 correction Methods 0.000 description 5
238000012360 testing method Methods 0.000 description 5
OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 5
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
230000003213 activating effect Effects 0.000 description 4
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
229910052739 hydrogen Inorganic materials 0.000 description 4
239000001257 hydrogen Substances 0.000 description 4
238000005259 measurement Methods 0.000 description 4
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 3
BAVYZALUXZFZLV-UHFFFAOYSA-O Methylammonium ion Chemical compound [NH3+]C BAVYZALUXZFZLV-UHFFFAOYSA-O 0.000 description 3
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
230000008859 change Effects 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
238000006073 displacement reaction Methods 0.000 description 3
125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 3
239000011888 foil Substances 0.000 description 3
229910052809 inorganic oxide Inorganic materials 0.000 description 3
239000000178 monomer Substances 0.000 description 3
239000003760 tallow Substances 0.000 description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
239000002879 Lewis base Substances 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
BEIOEBMXPVYLRY-UHFFFAOYSA-N [4-[4-bis(2,4-ditert-butylphenoxy)phosphanylphenyl]phenyl]-bis(2,4-ditert-butylphenoxy)phosphane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(C=1C=CC(=CC=1)C=1C=CC(=CC=1)P(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C BEIOEBMXPVYLRY-UHFFFAOYSA-N 0.000 description 2
150000001450 anions Chemical class 0.000 description 2
239000012876 carrier material Substances 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
238000012512 characterization method Methods 0.000 description 2
238000004587 chromatography analysis Methods 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 2
ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
125000000524 functional group Chemical group 0.000 description 2
238000004898 kneading Methods 0.000 description 2
150000007527 lewis bases Chemical class 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
101100058320 Arabidopsis thaliana BHLH12 gene Proteins 0.000 description 1
239000007848 Bronsted acid Substances 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
241001467982 Mermessus index Species 0.000 description 1
239000006057 Non-nutritive feed additive Substances 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
101150115932 Tep1 gene Proteins 0.000 description 1
239000007983 Tris buffer Substances 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
FHKPLLOSJHHKNU-INIZCTEOSA-N [(3S)-3-[8-(1-ethyl-5-methylpyrazol-4-yl)-9-methylpurin-6-yl]oxypyrrolidin-1-yl]-(oxan-4-yl)methanone Chemical compound C(C)N1N=CC(=C1C)C=1N(C2=NC=NC(=C2N=1)O[C@@H]1CN(CC1)C(=O)C1CCOCC1)C FHKPLLOSJHHKNU-INIZCTEOSA-N 0.000 description 1
YTPUOJUPWBJFCE-UHFFFAOYSA-N [Zr+] Chemical compound [Zr+] YTPUOJUPWBJFCE-UHFFFAOYSA-N 0.000 description 1
230000001133 acceleration Effects 0.000 description 1
HDYRYUINDGQKMC-UHFFFAOYSA-M acetyloxyaluminum;dihydrate Chemical compound O.O.CC(=O)O[Al] HDYRYUINDGQKMC-UHFFFAOYSA-M 0.000 description 1
125000005210 alkyl ammonium group Chemical group 0.000 description 1
229940009827 aluminum acetate Drugs 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
230000003466 anti-cipated effect Effects 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
230000002902 bimodal effect Effects 0.000 description 1
239000004305 biphenyl Substances 0.000 description 1
UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical class B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 1
229910000085 borane Inorganic materials 0.000 description 1
150000001639 boron compounds Chemical class 0.000 description 1
KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
239000000969 carrier Substances 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
125000002897 diene group Chemical group 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000005265 energy consumption Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000000835 fiber Substances 0.000 description 1
238000001595 flow curve Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
238000010102 injection blow moulding Methods 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
150000008040 ionic compounds Chemical class 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000004811 liquid chromatography Methods 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
229910052752 metalloid Inorganic materials 0.000 description 1
150000002737 metalloid compounds Chemical class 0.000 description 1
150000002738 metalloids Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
238000000465 moulding Methods 0.000 description 1
229920005615 natural polymer Polymers 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
FVZVCSNXTFCBQU-UHFFFAOYSA-N phosphanyl Chemical group [PH2] FVZVCSNXTFCBQU-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
238000010094 polymer processing Methods 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
239000002243 precursor Substances 0.000 description 1
238000004886 process control Methods 0.000 description 1
239000002516 radical scavenger Substances 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
239000013557 residual solvent Substances 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
238000001374 small-angle light scattering Methods 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
125000005270 trialkylamine group Chemical group 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000003643 water by type Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Materials Engineering (AREA)
Crystallography & Structural Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)
Artificial Filaments (AREA)
Polymerisation Methods In General (AREA)

SK1013-2000A 1998-01-07 1999-01-05 Homopolyméry a kopolyméry etylénu SK10132000A3 (sk)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GBGB9800245.4A GB9800245D0 (en)	1998-01-07	1998-01-07	Novel polymers
PCT/GB1999/000021 WO1999035174A1 (en)	1998-01-07	1999-01-05	Homopolymers and copolymers of ethylene

Publications (1)

Publication Number	Publication Date
SK10132000A3 true SK10132000A3 (sk)	2001-07-10

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ID=10824911

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK1013-2000A SK10132000A3 (sk)	1998-01-07	1999-01-05	Homopolyméry a kopolyméry etylénu

Country Status (31)

Country	Link
US (2)	US6518385B1 (de)
EP (2)	EP1045868B1 (de)
JP (2)	JP2002500249A (de)
KR (1)	KR100645271B1 (de)
CN (1)	CN1134463C (de)
AR (1)	AR014252A1 (de)
AT (1)	ATE269873T1 (de)
AU (1)	AU760130B2 (de)
BR (1)	BR9906811A (de)
CA (1)	CA2316165C (de)
CO (1)	CO4830472A1 (de)
CZ (1)	CZ302705B6 (de)
DE (1)	DE69918263T2 (de)
DK (1)	DK1045868T3 (de)
DZ (1)	DZ2704A1 (de)
EG (1)	EG22389A (de)
ES (2)	ES2486842T3 (de)
GB (1)	GB9800245D0 (de)
HU (1)	HU224167B1 (de)
MY (1)	MY122063A (de)
NO (1)	NO20003488L (de)
PL (1)	PL198209B1 (de)
PT (1)	PT1045868E (de)
RU (1)	RU2223283C2 (de)
SA (1)	SA99191234B1 (de)
SK (1)	SK10132000A3 (de)
TR (1)	TR200001955T2 (de)
TW (1)	TW557303B (de)
UA (1)	UA66375C2 (de)
WO (1)	WO1999035174A1 (de)
ZA (1)	ZA9811886B (de)

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JP5392015B2 (ja) *	2008-11-11	2014-01-22	住友化学株式会社	エチレン−α−オレフィン共重合体及び成形体
WO2010080871A1 (en)	2009-01-08	2010-07-15	Univation Technologies, Llc	Additive for gas phase polymerization processes
JP2010276128A (ja) *	2009-05-29	2010-12-09	Sumitomo Chemical Co Ltd	チューブ
DE112010002188T5 (de) *	2009-05-29	2012-08-30	Sumitomo Chemical Company, Ltd.	Ethylen-α-Olefin-Copolymer und Formgegenstand
EP2348057A1 (de)	2010-01-21	2011-07-27	INEOS Manufacturing Belgium NV	Neuartige Polymere
CN103087240B (zh) *	2011-10-31	2015-07-22	中国石油化工股份有限公司	一种制备乙烯聚合物的方法
US9096700B2 (en)	2012-12-10	2015-08-04	Exxonmobil Chemical Patents Inc.	Polymerization process for production of polymer
US9266977B2 (en)	2012-12-21	2016-02-23	Exxonmobil Chemical Patents Inc.	Bridged metallocene compounds, catalyst systems and processes for polymerization therewith
WO2014099307A1 (en) *	2012-12-21	2014-06-26	Exxonmobil Chemical Patents Inc.	Branched polyethylene with improved processing and high tear films made therefrom
KR101924198B1 (ko)	2015-12-23	2018-11-30	주식회사 엘지화학	필름 가공성 및 투명도가 우수한 저밀도 폴리에틸렌 공중합체
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1998
- 1998-01-07 GB GBGB9800245.4A patent/GB9800245D0/en not_active Ceased
- 1998-12-28 ZA ZA9811886A patent/ZA9811886B/xx unknown
1999
- 1999-01-04 EG EG599A patent/EG22389A/xx active
- 1999-01-05 ES ES04076235.3T patent/ES2486842T3/es not_active Expired - Lifetime
- 1999-01-05 CA CA002316165A patent/CA2316165C/en not_active Expired - Lifetime
- 1999-01-05 CZ CZ20002454A patent/CZ302705B6/cs not_active IP Right Cessation
- 1999-01-05 AT AT99901004T patent/ATE269873T1/de active
- 1999-01-05 BR BR9906811-7A patent/BR9906811A/pt not_active IP Right Cessation
- 1999-01-05 RU RU2000120681/04A patent/RU2223283C2/ru active
- 1999-01-05 EP EP99901004A patent/EP1045868B1/de not_active Expired - Lifetime
- 1999-01-05 AU AU20640/99A patent/AU760130B2/en not_active Ceased
- 1999-01-05 CN CNB99803648XA patent/CN1134463C/zh not_active Expired - Lifetime
- 1999-01-05 EP EP04076235.3A patent/EP1443062B1/de not_active Expired - Lifetime
- 1999-01-05 ES ES99901004T patent/ES2224598T3/es not_active Expired - Lifetime
- 1999-01-05 TR TR2000/01955T patent/TR200001955T2/xx unknown
- 1999-01-05 PT PT99901004T patent/PT1045868E/pt unknown
- 1999-01-05 PL PL341677A patent/PL198209B1/pl unknown
- 1999-01-05 DK DK99901004T patent/DK1045868T3/da active
- 1999-01-05 DE DE69918263T patent/DE69918263T2/de not_active Expired - Lifetime
- 1999-01-05 AR ARP990100016A patent/AR014252A1/es unknown
- 1999-01-05 WO PCT/GB1999/000021 patent/WO1999035174A1/en not_active Ceased
- 1999-01-05 HU HU0100366A patent/HU224167B1/hu not_active IP Right Cessation
- 1999-01-05 KR KR1020007007551A patent/KR100645271B1/ko not_active Expired - Lifetime
- 1999-01-05 SK SK1013-2000A patent/SK10132000A3/sk unknown
- 1999-01-05 JP JP2000527569A patent/JP2002500249A/ja active Pending
- 1999-01-06 TW TW088100144A patent/TW557303B/zh not_active IP Right Cessation
- 1999-01-06 DZ DZ990005A patent/DZ2704A1/xx active
- 1999-01-06 MY MYPI99000031A patent/MY122063A/en unknown
- 1999-01-07 CO CO99000708A patent/CO4830472A1/es unknown
- 1999-04-03 SA SA99191234A patent/SA99191234B1/ar unknown
- 1999-05-01 UA UA2000084713A patent/UA66375C2/uk unknown
2000
- 2000-07-06 US US09/600,107 patent/US6518385B1/en not_active Expired - Lifetime
- 2000-07-06 NO NO20003488A patent/NO20003488L/no not_active Application Discontinuation
2002
- 2002-12-09 US US10/314,367 patent/US20030139551A1/en not_active Abandoned
2009
- 2009-12-03 JP JP2009275833A patent/JP5804485B2/ja not_active Expired - Lifetime

Also Published As

Publication number	Publication date
JP2002500249A (ja)	2002-01-08
CA2316165C (en)	2008-12-30
PL198209B1 (pl)	2008-06-30
EP1443062A3 (de)	2004-10-20
AU760130B2 (en)	2003-05-08
KR100645271B1 (ko)	2006-11-13
CO4830472A1 (es)	1999-08-30
NO20003488L (no)	2000-09-07
ES2224598T3 (es)	2005-03-01
EP1045868A1 (de)	2000-10-25
MY122063A (en)	2006-03-31
SA99191234B1 (ar)	2006-11-14
KR20010033966A (ko)	2001-04-25
PL341677A1 (en)	2001-04-23
DZ2704A1 (fr)	2003-09-01
US20030139551A1 (en)	2003-07-24
CN1134463C (zh)	2004-01-14
HU224167B1 (hu)	2005-06-28
ES2486842T3 (es)	2014-08-19
CN1292802A (zh)	2001-04-25
DE69918263T2 (de)	2005-07-21
JP5804485B2 (ja)	2015-11-04
CZ302705B6 (cs)	2011-09-14
UA66375C2 (uk)	2004-05-17
EP1443062B1 (de)	2014-05-07
NO20003488D0 (no)	2000-07-06
ATE269873T1 (de)	2004-07-15
US6518385B1 (en)	2003-02-11
ZA9811886B (en)	2000-06-28
HUP0100366A3 (en)	2002-03-28
EP1443062A2 (de)	2004-08-04
PT1045868E (pt)	2004-10-29
CZ20002454A3 (cs)	2001-04-11
GB9800245D0 (en)	1998-03-04
EG22389A (en)	2003-01-29
RU2223283C2 (ru)	2004-02-10
AU2064099A (en)	1999-07-26
TR200001955T2 (tr)	2000-11-21
TW557303B (en)	2003-10-11
BR9906811A (pt)	2000-10-10
EP1045868B1 (de)	2004-06-23
HUP0100366A2 (hu)	2001-06-28
CA2316165A1 (en)	1999-07-15
DK1045868T3 (da)	2004-10-25
DE69918263D1 (de)	2004-07-29
JP2010047776A (ja)	2010-03-04
AR014252A1 (es)	2001-02-07
WO1999035174A1 (en)	1999-07-15

Legal Events

Date	Code	Title	Description
2012-12-03	FD9A	Suspended procedure due to non-payment of fee

Publication	Publication Date	Title
SK10132000A3 (sk)	2001-07-10	Homopolyméry a kopolyméry etylénu
US6300437B1 (en)	2001-10-09	Polymerization process
US8153734B2 (en)	2012-04-10	Process for preparing a polyethylene resin in a double loop reactor with a mixture of bis-indenyl and bis-tetrahydroindenyl
ES2475944T3 (es)	2014-07-11	Copol�meros y películas de los mismos
HU223951B1 (hu)	2005-03-29	Poliolefinkészítmény az összetétel legnagyobb komonomertartalmú részére eső molekulatömeg maximummal
JP2001523288A (ja)	2001-11-20	高性能パイプ樹脂
KR20140009164A (ko)	2014-01-22	저밀도 폴리에틸렌을 제조하는 중합 방법
EP2129697A1 (de)	2009-12-09	Homo- oder copolymere von ethylen mit kombination von verarbeitbarkeits- und zähigkeitseigenschaften
JP2006508212A (ja)	2006-03-09	ポリエチレン組成物の使用
CA2400662A1 (en)	2001-08-30	Process for producing a polyethylene coating on a substrate
BRPI0611231A2 (pt)	2010-08-24	copolÍmero de etileno e uma alfa-olefina, mÉtodo para a preparaÇço de copolÍmeros, artigo rotomodulado e uso de um copolÍmero preparado pelo uso de um componente de catalisador de monociclopentadienil metaloceno
JP2012528905A (ja)	2012-11-15	ポリエチレン組成物及びそれから構成される最終生成物
US11208504B2 (en)	2021-12-28	Injection-molded articles comprising metallocene-catalyzed polyethylene resin
US7335710B2 (en)	2008-02-26	Polymerization process
RU2772703C2 (ru)	2022-05-24	Изделия, полученные литьем под давлением, содержащие полиэтиленовую смолу, полученную полимеризацией, катализируемой металлоценом
MXPA00006772A (en)	2001-06-26	Homopolymers and copolymers of ethylene