SK13882001A3 - Spôsob hemihydrogenácie dinitrilov na aminonitrily - Google Patents

Spôsob hemihydrogenácie dinitrilov na aminonitrily Download PDF

Info

Publication number: SK13882001A3
Authority: SK; Slovakia
Prior art keywords: catalyst; process according; range; dinitriles; reaction mixture
Prior art date: 1999-03-30

Application number

SK1388-2001A

Other languages

English (en)

Slovak (sk)

Inventor

Fr�D�Ric Dallemer

Aline Seigneurin

Original Assignee

Rhodia Polyamide Intermediates

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-03-30

Filing date

2000-03-29

Publication date

2002-01-07

2000-03-29 Application filed by Rhodia Polyamide Intermediates filed Critical Rhodia Polyamide Intermediates

2002-01-07 Publication of SK13882001A3 publication Critical patent/SK13882001A3/sk

Links

238000000034 method Methods 0.000 title claims abstract description 34
125000005219 aminonitrile group Chemical group 0.000 title claims abstract description 19
239000003054 catalyst Substances 0.000 claims abstract description 50
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 29
239000001257 hydrogen Substances 0.000 claims abstract description 29
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 27
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 18
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 12
239000006230 acetylene black Substances 0.000 claims abstract description 12
229910052707 ruthenium Inorganic materials 0.000 claims abstract description 12
238000000197 pyrolysis Methods 0.000 claims abstract description 3
239000006229 carbon black Substances 0.000 claims abstract 2
239000003921 oil Substances 0.000 claims abstract 2
239000012188 paraffin wax Substances 0.000 claims abstract 2
239000011541 reaction mixture Substances 0.000 claims description 25
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 22
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 21
238000006243 chemical reaction Methods 0.000 claims description 19
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 17
239000000203 mixture Substances 0.000 claims description 13
229910052742 iron Inorganic materials 0.000 claims description 11
238000005984 hydrogenation reaction Methods 0.000 claims description 10
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
229910021529 ammonia Inorganic materials 0.000 claims description 8
150000007529 inorganic bases Chemical class 0.000 claims description 7
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 6
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
150000004703 alkoxides Chemical class 0.000 claims description 6
150000004985 diamines Chemical class 0.000 claims description 6
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 6
150000004649 carbonic acid derivatives Chemical class 0.000 claims description 5
150000001875 compounds Chemical class 0.000 claims description 5
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
125000002947 alkylene group Chemical group 0.000 claims description 4
125000004432 carbon atom Chemical group C* 0.000 claims description 4
CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 claims description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
125000001931 aliphatic group Chemical group 0.000 claims description 3
229910052782 aluminium Inorganic materials 0.000 claims description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
229910052787 antimony Inorganic materials 0.000 claims description 3
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 3
229910052785 arsenic Inorganic materials 0.000 claims description 3
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 3
229910052797 bismuth Inorganic materials 0.000 claims description 3
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 3
229910052793 cadmium Inorganic materials 0.000 claims description 3
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 3
229910052804 chromium Inorganic materials 0.000 claims description 3
239000011651 chromium Substances 0.000 claims description 3
229910052802 copper Inorganic materials 0.000 claims description 3
239000010949 copper Substances 0.000 claims description 3
150000004679 hydroxides Chemical class 0.000 claims description 3
229910052741 iridium Inorganic materials 0.000 claims description 3
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 3
239000007788 liquid Substances 0.000 claims description 3
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
229910052750 molybdenum Inorganic materials 0.000 claims description 3
239000011733 molybdenum Substances 0.000 claims description 3
229910052762 osmium Inorganic materials 0.000 claims description 3
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 3
229910052763 palladium Inorganic materials 0.000 claims description 3
229910052698 phosphorus Inorganic materials 0.000 claims description 3
239000011574 phosphorus Substances 0.000 claims description 3
229910052697 platinum Inorganic materials 0.000 claims description 3
229910052761 rare earth metal Inorganic materials 0.000 claims description 3
150000002910 rare earth metals Chemical class 0.000 claims description 3
229910052702 rhenium Inorganic materials 0.000 claims description 3
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 3
229910052709 silver Inorganic materials 0.000 claims description 3
239000004332 silver Substances 0.000 claims description 3
229910052718 tin Inorganic materials 0.000 claims description 3
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
229910052721 tungsten Inorganic materials 0.000 claims description 3
239000010937 tungsten Substances 0.000 claims description 3
229910052725 zinc Inorganic materials 0.000 claims description 3
239000011701 zinc Substances 0.000 claims description 3
MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 claims description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims description 2
125000004450 alkenylene group Chemical group 0.000 claims description 2
HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 claims description 2
229910052710 silicon Inorganic materials 0.000 claims description 2
239000010703 silicon Substances 0.000 claims description 2
229910052719 titanium Inorganic materials 0.000 claims description 2
239000010936 titanium Substances 0.000 claims description 2
229910052726 zirconium Inorganic materials 0.000 claims description 2
229910000288 alkali metal carbonate Inorganic materials 0.000 claims 1
150000008041 alkali metal carbonates Chemical class 0.000 claims 1
229910000272 alkali metal oxide Inorganic materials 0.000 claims 1
150000001340 alkali metals Chemical class 0.000 claims 1
125000001453 quaternary ammonium group Chemical group 0.000 claims 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 26
FHKPTEOFUHYQFY-UHFFFAOYSA-N 2-aminohexanenitrile Chemical compound CCCCC(N)C#N FHKPTEOFUHYQFY-UHFFFAOYSA-N 0.000 description 12
BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 description 12
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
238000004817 gas chromatography Methods 0.000 description 9
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
238000004458 analytical method Methods 0.000 description 5
238000011010 flushing procedure Methods 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 5
230000035484 reaction time Effects 0.000 description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
229920002292 Nylon 6 Polymers 0.000 description 3
229910000564 Raney nickel Inorganic materials 0.000 description 3
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 3
125000005677 ethinylene group Chemical group [*:2]C#C[*:1] 0.000 description 3
229940044631 ferric chloride hexahydrate Drugs 0.000 description 3
238000001914 filtration Methods 0.000 description 3
NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 description 3
BIXNGBXQRRXPLM-UHFFFAOYSA-K ruthenium(3+);trichloride;hydrate Chemical compound O.Cl[Ru](Cl)Cl BIXNGBXQRRXPLM-UHFFFAOYSA-K 0.000 description 3
229910000029 sodium carbonate Inorganic materials 0.000 description 3
238000003756 stirring Methods 0.000 description 3
239000000725 suspension Substances 0.000 description 3
GDCJAPJJFZWILF-UHFFFAOYSA-N 2-ethylbutanedinitrile Chemical compound CCC(C#N)CC#N GDCJAPJJFZWILF-UHFFFAOYSA-N 0.000 description 2
FPPLREPCQJZDAQ-UHFFFAOYSA-N 2-methylpentanedinitrile Chemical compound N#CC(C)CCC#N FPPLREPCQJZDAQ-UHFFFAOYSA-N 0.000 description 2
NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 2
239000003513 alkali Substances 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
239000003245 coal Substances 0.000 description 2
239000010941 cobalt Substances 0.000 description 2
229910017052 cobalt Inorganic materials 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
239000000178 monomer Substances 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
239000005662 Paraffin oil Substances 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
239000007868 Raney catalyst Substances 0.000 description 1
229910001854 alkali hydroxide Inorganic materials 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
239000000010 aprotic solvent Substances 0.000 description 1
239000002585 base Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
239000012050 conventional carrier Substances 0.000 description 1
125000004966 cyanoalkyl group Chemical group 0.000 description 1
ZTOMUSMDRMJOTH-UHFFFAOYSA-N glutaronitrile Chemical compound N#CCCCC#N ZTOMUSMDRMJOTH-UHFFFAOYSA-N 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
239000010931 gold Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
CUONGYYJJVDODC-UHFFFAOYSA-N malononitrile Chemical compound N#CCC#N CUONGYYJJVDODC-UHFFFAOYSA-N 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
150000002825 nitriles Chemical group 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
239000002243 precursor Substances 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1
IAHFWCOBPZCAEA-UHFFFAOYSA-N succinonitrile Chemical compound N#CCCC#N IAHFWCOBPZCAEA-UHFFFAOYSA-N 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/24—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the same saturated acyclic carbon skeleton
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)

SK1388-2001A 1999-03-30 2000-03-29 Spôsob hemihydrogenácie dinitrilov na aminonitrily SK13882001A3 (sk)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR9904206A FR2791672B1 (fr)	1999-03-30	1999-03-30	Procede d'hemihydrogenation de dinitriles en aminonitriles
PCT/FR2000/000787 WO2000059870A1 (fr)	1999-03-30	2000-03-29	Procede d'hemihydrogenation de dinitriles en aminonitriles

Publications (1)

Publication Number	Publication Date
SK13882001A3 true SK13882001A3 (sk)	2002-01-07

Family

ID=9544007

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK1388-2001A SK13882001A3 (sk)	1999-03-30	2000-03-29	Spôsob hemihydrogenácie dinitrilov na aminonitrily

Country Status (18)

Country	Link
US (1)	US6635781B1 (de)
EP (1)	EP1165498B1 (de)
JP (1)	JP2002541135A (de)
KR (1)	KR20020010597A (de)
CN (1)	CN1348440A (de)
AT (1)	ATE247633T1 (de)
BR (1)	BR0009409A (de)
CA (1)	CA2368238A1 (de)
CZ (1)	CZ20013484A3 (de)
DE (1)	DE60004653T2 (de)
ES (1)	ES2199801T3 (de)
FR (1)	FR2791672B1 (de)
MX (1)	MXPA01009782A (de)
PL (1)	PL350802A1 (de)
RU (1)	RU2230732C2 (de)
SK (1)	SK13882001A3 (de)
TW (1)	TW574189B (de)
WO (1)	WO2000059870A1 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ES2294075T3 (es)	2001-12-07	2008-04-01	Basf Se	Procedimiento para la obtencion de catalizadores de rutenio/hierro sobre soportes de carbono.
FR2892118B1 (fr)	2005-10-18	2010-12-10	Rhodia Recherches & Tech	Procede de fabrication d'hexamethylene diamine et d'aminocapronitrile.

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3127356A (en) *		1964-03-31		Process for the preparation of hydro-
US2967200A (en) *	1959-01-28	1961-01-03	Du Pont	Preparation of ketoximes
US3898286A (en) *	1973-11-19	1975-08-05	Phillips Petroleum Co	Catalytic hydrogenation of unsaturated dinitriles employing palladium and ruthenium as catalyst
US4259262A (en) *	1979-08-23	1981-03-31	Phillips Petroleum Company	Catalytic hydrogenation of unsaturated dinitriles
US4302604A (en) *	1980-07-24	1981-11-24	Phillips Petroleum Company	Increasing the life of a supported ruthenium catalyst in the hydrogenation of an olefinically unsaturated dinitrile
DE3130805A1 (de) *	1981-08-04	1983-02-24	Basf Ag, 6700 Ludwigshafen	Neue ruthenium/kohle-hydrierkatalysatoren, deren herstellung und verwendung zur selektiven hydrierung von ungesaettigten carbonylverbindungen
US4389348A (en) *	1981-10-26	1983-06-21	Allied Corporation	Selective hydrogenation of dinitrile to omega-aminonitrile and supported rhodium-containing catalyst therefor
DE4446894A1 (de) *	1994-12-27	1996-07-04	Basf Ag	Verfahren zur Herstellung von aliphatischen alpha,omega-Aminonitrilen
US5756808A (en) *	1994-12-27	1998-05-26	Basf Aktiengesellschaft	Preparation of aliphatic, alpha omega-aminonitriles

1999
- 1999-03-30 FR FR9904206A patent/FR2791672B1/fr not_active Expired - Fee Related
2000
- 2000-03-29 AT AT00915244T patent/ATE247633T1/de not_active IP Right Cessation
- 2000-03-29 RU RU2001129175/04A patent/RU2230732C2/ru not_active IP Right Cessation
- 2000-03-29 MX MXPA01009782A patent/MXPA01009782A/es not_active Application Discontinuation
- 2000-03-29 US US09/937,761 patent/US6635781B1/en not_active Expired - Fee Related
- 2000-03-29 DE DE60004653T patent/DE60004653T2/de not_active Expired - Fee Related
- 2000-03-29 JP JP2000609383A patent/JP2002541135A/ja not_active Abandoned
- 2000-03-29 PL PL00350802A patent/PL350802A1/xx not_active IP Right Cessation
- 2000-03-29 SK SK1388-2001A patent/SK13882001A3/sk unknown
- 2000-03-29 EP EP00915244A patent/EP1165498B1/de not_active Expired - Lifetime
- 2000-03-29 WO PCT/FR2000/000787 patent/WO2000059870A1/fr not_active Ceased
- 2000-03-29 CA CA002368238A patent/CA2368238A1/fr not_active Abandoned
- 2000-03-29 CN CN00806671A patent/CN1348440A/zh active Pending
- 2000-03-29 ES ES00915244T patent/ES2199801T3/es not_active Expired - Lifetime
- 2000-03-29 BR BR0009409-9A patent/BR0009409A/pt not_active IP Right Cessation
- 2000-03-29 KR KR1020017012563A patent/KR20020010597A/ko not_active Ceased
- 2000-03-29 TW TW89105806A patent/TW574189B/zh active
- 2000-03-29 CZ CZ20013484A patent/CZ20013484A3/cs unknown

Also Published As

Publication number	Publication date
RU2230732C2 (ru)	2004-06-20
DE60004653T2 (de)	2004-06-24
PL350802A1 (en)	2003-02-10
EP1165498A1 (de)	2002-01-02
FR2791672A1 (fr)	2000-10-06
WO2000059870A1 (fr)	2000-10-12
CA2368238A1 (fr)	2000-10-12
BR0009409A (pt)	2002-01-08
CZ20013484A3 (cs)	2002-01-16
DE60004653D1 (de)	2003-09-25
EP1165498B1 (de)	2003-08-20
ATE247633T1 (de)	2003-09-15
JP2002541135A (ja)	2002-12-03
ES2199801T3 (es)	2004-03-01
MXPA01009782A (es)	2002-03-27
CN1348440A (zh)	2002-05-08
TW574189B (en)	2004-02-01
KR20020010597A (ko)	2002-02-04
US6635781B1 (en)	2003-10-21
FR2791672B1 (fr)	2001-05-04

Publication	Publication Date	Title
JP2938975B2 (ja)	1999-08-25	ジニトリルをアミノニトリルに半水素化する方法
KR100502606B1 (ko)	2005-07-22	지방족 디니트릴의 부분 수소화에 의한 지방족 알파-, 오메가-아미노니트릴의 제조에 적합한 촉매
KR100586668B1 (ko)	2006-06-07	니트릴 관능기의 아민 관능기로의 수소화 방법
RU2220133C2 (ru)	2003-12-27	Способ полугидрирования динитрилов
KR100402525B1 (ko)	2004-03-30	지방족알파,오메가-아미노니트릴의제조방법
CZ79599A3 (cs)	1999-11-17	Způsob přípravy alifatických alfa, omega-aminonitrilů
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