SK14794A3 - Piperidinetriazine compounds suitable for use as stabilizers of organic matters - Google Patents

Piperidinetriazine compounds suitable for use as stabilizers of organic matters Download PDF

Info

Publication number: SK14794A3
Authority: SK; Slovakia
Prior art keywords: group; carbon atoms; alkylene; alkyl; carbon
Prior art date: 1993-02-11

Application number

SK147-94A

Other languages

English (en)

Slovak (sk)

Inventor

Valerio Borzatta

Graziano Vignali

Original Assignee

Ciba Geigy Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-02-11

Filing date

1994-02-09

Publication date

1995-03-08

1994-02-09 Application filed by Ciba Geigy Ag filed Critical Ciba Geigy Ag

1995-03-08 Publication of SK14794A3 publication Critical patent/SK14794A3/sk

Links

150000001875 compounds Chemical class 0.000 title claims description 48
239000003381 stabilizer Substances 0.000 title description 10
125000002947 alkylene group Chemical group 0.000 claims abstract description 66
-1 hydroxytrimethylene Chemical group 0.000 claims description 176
125000004432 carbon atom Chemical group C* 0.000 claims description 121
125000000217 alkyl group Chemical group 0.000 claims description 42
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 39
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 33
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 26
239000000203 mixture Substances 0.000 claims description 26
229910052799 carbon Inorganic materials 0.000 claims description 25
125000004429 atom Chemical group 0.000 claims description 23
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 23
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 18
239000005977 Ethylene Substances 0.000 claims description 18
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 16
125000004430 oxygen atom Chemical group O* 0.000 claims description 15
239000000126 substance Substances 0.000 claims description 15
239000004743 Polypropylene Substances 0.000 claims description 12
125000002252 acyl group Chemical group 0.000 claims description 12
125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 11
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 11
125000003545 alkoxy group Chemical group 0.000 claims description 10
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 10
125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 claims description 10
125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 9
125000003342 alkenyl group Chemical group 0.000 claims description 9
125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 9
229920001155 polypropylene Polymers 0.000 claims description 9
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 8
125000001118 alkylidene group Chemical group 0.000 claims description 8
239000004698 Polyethylene Substances 0.000 claims description 7
125000004956 cyclohexylene group Chemical group 0.000 claims description 7
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 7
229920000573 polyethylene Polymers 0.000 claims description 7
239000001257 hydrogen Substances 0.000 claims description 6
229910052739 hydrogen Inorganic materials 0.000 claims description 6
229920001059 synthetic polymer Polymers 0.000 claims description 6
239000000654 additive Substances 0.000 claims description 5
229910052801 chlorine Inorganic materials 0.000 claims description 5
125000001309 chloro group Chemical group Cl* 0.000 claims description 5
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 5
125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 claims description 5
125000000000 cycloalkoxy group Chemical group 0.000 claims description 4
125000002993 cycloalkylene group Chemical group 0.000 claims description 4
230000003647 oxidation Effects 0.000 claims description 4
238000007254 oxidation reaction Methods 0.000 claims description 4
229920000098 polyolefin Polymers 0.000 claims description 4
125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 3
230000015556 catabolic process Effects 0.000 claims description 3
125000000753 cycloalkyl group Chemical group 0.000 claims description 3
238000006731 degradation reaction Methods 0.000 claims description 3
125000005065 undecenyl group Chemical group C(=CCCCCCCCCC)* 0.000 claims description 3
125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 2
150000001721 carbon Chemical group 0.000 claims description 2
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 2
230000000087 stabilizing effect Effects 0.000 claims description 2
239000011203 carbon fibre reinforced carbon Substances 0.000 claims 3
125000004214 1-pyrrolidinyl group Chemical group [H]C1([H])N(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 claims 2
CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 claims 2
125000003031 C5-C7 cycloalkylene group Chemical group 0.000 claims 1
IFVTZJHWGZSXFD-UHFFFAOYSA-N biphenylene Chemical group C1=CC=C2C3=CC=CC=C3C2=C1 IFVTZJHWGZSXFD-UHFFFAOYSA-N 0.000 claims 1
125000006165 cyclic alkyl group Chemical group 0.000 claims 1
125000004663 dialkyl amino group Chemical group 0.000 claims 1
125000000587 piperidin-1-yl group Chemical group [H]C1([H])N(*)C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 claims 1
MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 abstract description 8
239000003963 antioxidant agent Substances 0.000 abstract description 4
239000004611 light stabiliser Substances 0.000 abstract description 3
YPSLATCYOGSFDU-UHFFFAOYSA-N piperidine;triazine Chemical class C1CCNCC1.C1=CN=NN=C1 YPSLATCYOGSFDU-UHFFFAOYSA-N 0.000 abstract description 3
JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 abstract description 2
239000004608 Heat Stabiliser Substances 0.000 abstract 1
230000015572 biosynthetic process Effects 0.000 abstract 1
239000011368 organic material Substances 0.000 abstract 1
125000001424 substituent group Chemical group 0.000 abstract 1
229920001577 copolymer Polymers 0.000 description 34
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 28
229920000642 polymer Polymers 0.000 description 22
229910052757 nitrogen Inorganic materials 0.000 description 15
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
238000000034 method Methods 0.000 description 13
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
239000004952 Polyamide Substances 0.000 description 12
239000003054 catalyst Substances 0.000 description 12
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 12
229920002647 polyamide Polymers 0.000 description 12
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 11
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 9
150000002148 esters Chemical class 0.000 description 9
229920001684 low density polyethylene Polymers 0.000 description 9
239000004702 low-density polyethylene Substances 0.000 description 9
229910052751 metal Inorganic materials 0.000 description 8
239000002184 metal Substances 0.000 description 8
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
239000002253 acid Substances 0.000 description 7
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 7
239000000835 fiber Substances 0.000 description 7
229920002857 polybutadiene Polymers 0.000 description 7
229920006324 polyoxymethylene Polymers 0.000 description 7
239000004800 polyvinyl chloride Substances 0.000 description 7
229920000915 polyvinyl chloride Polymers 0.000 description 7
239000000047 product Substances 0.000 description 7
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
239000005062 Polybutadiene Substances 0.000 description 6
239000004721 Polyphenylene oxide Substances 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
150000001412 amines Chemical class 0.000 description 6
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 6
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 6
239000004417 polycarbonate Substances 0.000 description 6
229920000728 polyester Polymers 0.000 description 6
229920002554 vinyl polymer Polymers 0.000 description 6
239000007859 condensation product Substances 0.000 description 5
150000001993 dienes Chemical class 0.000 description 5
238000006116 polymerization reaction Methods 0.000 description 5
150000005846 sugar alcohols Polymers 0.000 description 5
ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
229920002943 EPDM rubber Polymers 0.000 description 4
229920000877 Melamine resin Polymers 0.000 description 4
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 4
229920001903 high density polyethylene Polymers 0.000 description 4
239000004700 high-density polyethylene Substances 0.000 description 4
HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 4
239000011572 manganese Substances 0.000 description 4
239000000463 material Substances 0.000 description 4
238000002844 melting Methods 0.000 description 4
230000008018 melting Effects 0.000 description 4
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 4
150000002815 nickel Chemical class 0.000 description 4
239000003921 oil Substances 0.000 description 4
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 4
229920000570 polyether Polymers 0.000 description 4
229920006380 polyphenylene oxide Polymers 0.000 description 4
229920005606 polypropylene copolymer Polymers 0.000 description 4
239000004814 polyurethane Substances 0.000 description 4
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
150000003254 radicals Chemical class 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
239000000243 solution Substances 0.000 description 4
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 4
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
YEXOWHQZWLCHHD-UHFFFAOYSA-N 3,5-ditert-butyl-4-hydroxybenzoic acid Chemical compound CC(C)(C)C1=CC(C(O)=O)=CC(C(C)(C)C)=C1O YEXOWHQZWLCHHD-UHFFFAOYSA-N 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
229920002396 Polyurea Polymers 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
150000001252 acrylic acid derivatives Chemical class 0.000 description 3
239000001361 adipic acid Substances 0.000 description 3
235000011037 adipic acid Nutrition 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
239000012964 benzotriazole Substances 0.000 description 3
238000004132 cross linking Methods 0.000 description 3
150000001991 dicarboxylic acids Chemical class 0.000 description 3
229920001971 elastomer Polymers 0.000 description 3
239000003446 ligand Substances 0.000 description 3
150000005673 monoalkenes Chemical class 0.000 description 3
239000000178 monomer Substances 0.000 description 3
229920003052 natural elastomer Polymers 0.000 description 3
229920001194 natural rubber Polymers 0.000 description 3
SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 3
229940117969 neopentyl glycol Drugs 0.000 description 3
235000019198 oils Nutrition 0.000 description 3
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 3
229920001281 polyalkylene Polymers 0.000 description 3
229920000647 polyepoxide Polymers 0.000 description 3
239000000843 powder Substances 0.000 description 3
238000010992 reflux Methods 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
239000001993 wax Substances 0.000 description 3
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 2
PJLHTVIBELQURV-UHFFFAOYSA-N 1-pentadecene Chemical compound CCCCCCCCCCCCCC=C PJLHTVIBELQURV-UHFFFAOYSA-N 0.000 description 2
KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 2
BVUXDWXKPROUDO-UHFFFAOYSA-N 2,6-di-tert-butyl-4-ethylphenol Chemical compound CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BVUXDWXKPROUDO-UHFFFAOYSA-N 0.000 description 2
XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 description 2
RXFCIXRFAJRBSG-UHFFFAOYSA-N 3,2,3-tetramine Chemical compound NCCCNCCNCCCN RXFCIXRFAJRBSG-UHFFFAOYSA-N 0.000 description 2
WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 description 2
CKPKHTKLLYPGFM-UHFFFAOYSA-N 6,6-dimethylheptane-1,1-diol Chemical compound CC(CCCCC(O)O)(C)C CKPKHTKLLYPGFM-UHFFFAOYSA-N 0.000 description 2
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
229920000178 Acrylic resin Polymers 0.000 description 2
239000004925 Acrylic resin Substances 0.000 description 2
FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 2
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
239000004716 Ethylene/acrylic acid copolymer Substances 0.000 description 2
244000043261 Hevea brasiliensis Species 0.000 description 2
229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 2
229920002292 Nylon 6 Polymers 0.000 description 2
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
229920002367 Polyisobutene Polymers 0.000 description 2
KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
JWUXJYZVKZKLTJ-UHFFFAOYSA-N Triacetonamine Chemical compound CC1(C)CC(=O)CC(C)(C)N1 JWUXJYZVKZKLTJ-UHFFFAOYSA-N 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
239000006096 absorbing agent Substances 0.000 description 2
239000012190 activator Substances 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
229920000180 alkyd Polymers 0.000 description 2
125000005250 alkyl acrylate group Chemical group 0.000 description 2
125000003282 alkyl amino group Chemical group 0.000 description 2
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
239000002216 antistatic agent Substances 0.000 description 2
TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 2
229920001400 block copolymer Polymers 0.000 description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
229910002091 carbon monoxide Inorganic materials 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
125000004122 cyclic group Chemical group 0.000 description 2
ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
150000004985 diamines Chemical class 0.000 description 2
238000001035 drying Methods 0.000 description 2
239000000806 elastomer Substances 0.000 description 2
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150000002170 ethers Chemical class 0.000 description 2
239000000945 filler Substances 0.000 description 2
239000008187 granular material Substances 0.000 description 2
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
229920000554 ionomer Polymers 0.000 description 2
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
239000004816 latex Substances 0.000 description 2
229920000126 latex Polymers 0.000 description 2
229920000092 linear low density polyethylene Polymers 0.000 description 2
239000004707 linear low-density polyethylene Substances 0.000 description 2
239000000314 lubricant Substances 0.000 description 2
IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
235000019359 magnesium stearate Nutrition 0.000 description 2
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
239000000155 melt Substances 0.000 description 2
239000006078 metal deactivator Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
UJRDRFZCRQNLJM-UHFFFAOYSA-N methyl 3-[3-(benzotriazol-2-yl)-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=CC=CC3=N2)=C1O UJRDRFZCRQNLJM-UHFFFAOYSA-N 0.000 description 2
ZGEGCLOFRBLKSE-UHFFFAOYSA-N methylene hexane Natural products CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
239000002480 mineral oil Substances 0.000 description 2
238000002156 mixing Methods 0.000 description 2
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229920003048 styrene butadiene rubber Polymers 0.000 description 1
229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
CSABAZBYIWDIDE-UHFFFAOYSA-N sulfino hydrogen sulfite Chemical compound OS(=O)OS(O)=O CSABAZBYIWDIDE-UHFFFAOYSA-N 0.000 description 1
229920003051 synthetic elastomer Polymers 0.000 description 1
239000005061 synthetic rubber Substances 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
150000003505 terpenes Chemical class 0.000 description 1
235000007586 terpenes Nutrition 0.000 description 1
229920002803 thermoplastic polyurethane Polymers 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
150000003918 triazines Chemical class 0.000 description 1
125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000005591 trimellitate group Chemical group 0.000 description 1
CNUJLMSKURPSHE-UHFFFAOYSA-N trioctadecyl phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC CNUJLMSKURPSHE-UHFFFAOYSA-N 0.000 description 1
WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229920006337 unsaturated polyester resin Polymers 0.000 description 1
150000003672 ureas Chemical class 0.000 description 1
125000003774 valeryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
235000019871 vegetable fat Nutrition 0.000 description 1
229920001866 very low density polyethylene Polymers 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0627—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only one nitrogen atom in the ring
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0633—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only two nitrogen atoms in the ring
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0638—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with at least three nitrogen atoms in the ring
- C08G73/0644—Poly(1,3,5)triazines
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Compositions Of Macromolecular Compounds (AREA)
Plural Heterocyclic Compounds (AREA)
Hydrogenated Pyridines (AREA)
Polyethers (AREA)
Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)

SK147-94A 1993-02-11 1994-02-09 Piperidinetriazine compounds suitable for use as stabilizers of organic matters SK14794A3 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
ITMI930247A IT1263892B (it)	1993-02-11	1993-02-11	Composti piperidin-triazinici atti all'impiego come stabilizzanti per materiali organici

Publications (1)

Publication Number	Publication Date
SK14794A3 true SK14794A3 (en)	1995-03-08

Family

ID=11364967

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK147-94A SK14794A3 (en)	1993-02-11	1994-02-09	Piperidinetriazine compounds suitable for use as stabilizers of organic matters

Country Status (11)

Country	Link
US (1)	US5466803A (fr)
JP (1)	JPH06298933A (fr)
BE (1)	BE1007065A3 (fr)
CA (1)	CA2115301A1 (fr)
DE (1)	DE4404144A1 (fr)
FR (1)	FR2701482B1 (fr)
GB (1)	GB2276378A (fr)
IT (1)	IT1263892B (fr)
MX (1)	MX9401052A (fr)
NL (1)	NL9400213A (fr)
SK (1)	SK14794A3 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE10004158A1 (de)	2000-02-01	2001-08-02	Basf Ag	Stabilisatorzusammensetzung
US8557950B2 (en)	2005-06-16	2013-10-15	Grupo Petrotemex, S.A. De C.V.	High intrinsic viscosity melt phase polyester polymers with acceptable acetaldehyde generation rates
US7655746B2 (en) *	2005-09-16	2010-02-02	Eastman Chemical Company	Phosphorus containing compounds for reducing acetaldehyde in polyesters polymers
US9267007B2 (en)	2005-09-16	2016-02-23	Grupo Petrotemex, S.A. De C.V.	Method for addition of additives into a polymer melt
US7838596B2 (en)	2005-09-16	2010-11-23	Eastman Chemical Company	Late addition to effect compositional modifications in condensation polymers
DE102008061137A1 (de) *	2008-12-09	2010-06-10	Borealis Agrolinz Melamine Gmbh	Neue Triazinpolymere, Verfahren zu deren Herstellung und deren Verwendung

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IT1052501B (it) *	1975-12-04	1981-07-20	Chimosa Chimica Organica Spa	Composti politriazinici utilizzabili per la stabilizzazione di polimeri sintetici e procedimento per la loro preparazione
US4315859A (en) *	1979-01-15	1982-02-16	Ciba-Geigy Corporation	1,3,5-Triazines containing at least one piperidine radical
DE2933078A1 (de) *	1979-08-16	1981-03-26	Hoechst Ag, 65929 Frankfurt	Neue triazinderivate, ihre herstellung und ihre verwendung als stabilisatoren fuer synthetische polymere
IT1151035B (it) *	1980-07-31	1986-12-17	Chimosa Chimica Organica Spa	Piperidil-derivati di copolimeri triazinici,processi per la loro preparazione e composizioni stabilizzate che li comprendono
US4412020A (en) *	1981-07-20	1983-10-25	American Cyanamid Company	Novel light stabilizers for polymers
US4331586A (en) *	1981-07-20	1982-05-25	American Cyanamid Company	Novel light stabilizers for polymers
IT1152192B (it) *	1982-05-19	1986-12-31	Apital Prod Ind	Composti per stabilizzare i polimeri
IT1193659B (it) *	1983-02-04	1988-07-21	Chimosa Chimica Organica Spa	Composti piperidinil-triazinici utili come stabilizzanti per polimeri sintetici
IT1163814B (it) *	1983-07-19	1987-04-08	Chimosa Chimica Organica Spa	Composti polimerici contenenti radicali piperidinici e triazinici,processo per la loro preparazione e loro impiego quali stabilizzanti per polimeri sintetici
IT1169843B (it) *	1983-09-23	1987-06-03	Chimosa Chimica Organica Spa	Composti polimerici contenenti radicali piperidinici, processo per la loro preparazione e loro impiego quali stabilizzanti per polimeri sintetici
JPS6250342A (ja) *	1985-08-30	1987-03-05	Adeka Argus Chem Co Ltd	安定化された高分子材料組成物
JPS63196654A (ja) *	1987-02-09	1988-08-15	Adeka Argus Chem Co Ltd	安定化高分子材料組成物
IT1227334B (it) *	1988-08-04	1991-04-08	Ciba Geigy Spa	Composti piperidin triazinici atti all'impiego come stabilizzanti per materiali organici.
US4889882A (en) *	1988-12-15	1989-12-26	Ici Americas Inc.	Tetramethyl piperidyl terminated triazine oligomeric esters and amides
IT1237541B (it) *	1989-12-28	1993-06-08	Ciba Geigy	Composti piperidin-triazinici atti all'impiego come stabilizzanti per materiali organici
IT1248839B (it) *	1990-06-13	1995-01-30	Ciba Geigy Spa	Nuovi cooligomeri piperidin-triazinici atti all'impiego come stabilizzanti per materiali organici
IT1243374B (it) *	1990-07-27	1994-06-10	Ciba Geigy Spa	Composti piperidin-triazinici contenenti gruppi tetraidrofuranici o tetraidropiranici atti all'impiego come stabilizzanti per materiali organici
IT1243433B (it) *	1990-10-03	1994-06-10	Ciba Geigy Spa	Composti piperidin-triazinici atti all'impiego come stabilizzanti per materiali organici
IT1252227B (it) *	1991-12-17	1995-06-05	Ciba Geigy Spa	Composti tetrametilpiperidinici atti all'impiego come stabilizzanti per materiali organici

1993
- 1993-02-11 IT ITMI930247A patent/IT1263892B/it active IP Right Grant
1994
- 1994-02-03 US US08/191,575 patent/US5466803A/en not_active Expired - Fee Related
- 1994-02-07 GB GB9402324A patent/GB2276378A/en not_active Withdrawn
- 1994-02-09 SK SK147-94A patent/SK14794A3/sk unknown
- 1994-02-09 CA CA002115301A patent/CA2115301A1/fr not_active Abandoned
- 1994-02-09 DE DE4404144A patent/DE4404144A1/de not_active Withdrawn
- 1994-02-10 BE BE9400157A patent/BE1007065A3/fr not_active IP Right Cessation
- 1994-02-10 JP JP6037700A patent/JPH06298933A/ja active Pending
- 1994-02-10 FR FR9401494A patent/FR2701482B1/fr not_active Expired - Fee Related
- 1994-02-10 MX MX9401052A patent/MX9401052A/es unknown
- 1994-02-10 NL NL9400213A patent/NL9400213A/nl not_active Application Discontinuation

Also Published As

Publication number	Publication date
GB9402324D0 (en)	1994-03-30
GB2276378A (en)	1994-09-28
FR2701482B1 (fr)	1995-06-23
IT1263892B (it)	1996-09-05
CA2115301A1 (fr)	1994-08-12
JPH06298933A (ja)	1994-10-25
US5466803A (en)	1995-11-14
NL9400213A (nl)	1994-09-01
BE1007065A3 (fr)	1995-03-07
DE4404144A1 (de)	1994-08-18
FR2701482A1 (fr)	1994-08-19
ITMI930247A0 (it)	1993-02-11
ITMI930247A1 (it)	1994-08-11
MX9401052A (es)	1994-08-31

Publication	Publication Date	Title
KR100248537B1 (ko)	2000-04-01	유기물질에 대한 안정화제로서 유용한 테트라메틸피페리딘 화합물
SK284174B6 (sk)	2004-10-05	Synergická zmes stabilizátorov, kompozícia obsahujúca túto zmes a organický materiál a použitie tejto zmesi
JPS6379886A (ja)	1988-04-09	１，２，２，６，６―ペンタメチル―４―ピリジルアミノトリアジン誘導体及び該誘導体からなる合成ポリマー用安定剤
SK281600B6 (sk)	2001-05-10	Synergické zmesi stabilizátorov, prostriedky, ktoré ich obsahujú a ich použitie na stabilizáciu organických materiálov
JP3314211B2 (ja)	2002-08-12	シリル化２−（２−ヒドロキシフェニル）−４，６−ジアリール−１，３，５−トリアジン
CZ280211B6 (cs)	1995-12-13	Nové piperidinové sloučeniny obsahující silanové skupiny, vhodné k použití jako stabilizátory organických materiálů
KR100346061B1 (ko)	2002-12-06	유기물질용안정화제로서유용한,실란기를함유하는1-히드로카르빌옥시-피페리딘화합물및이를함유하는조성물
BE1007156A5 (fr)	1995-04-11	Nouveaux composes de type polymethyl-piperidine contenant des groupes silane et appropries en tant que stabilisants de matieres organiques.
KR19980087355A (ko)	1998-12-05	2,2,6,6-테트라메틸-4-피페리딜기를 함유하는 트리아진 유도체
KR100306201B1 (ko)	2001-11-30	유기물질에대한광안정화제,열안정화제및산화안정화제로서사용하기위한2,2,6,6-테트라메틸-4-피페리디놀의유도체
SK65494A3 (en)	1995-02-08	Piperidinetriazine compounds and their use as stabilizers of organic matters againts degradation by light, heat or oxidation
ES2560957T3 (es)	2016-02-23	Nuevas aminas poliméricas estéricamente impedidas y su uso como estabilizantes de polímeros
JPH07258228A (ja)	1995-10-09	紫外線吸収剤としての二量体のベンゾトリアゾール類
JPH0770064A (ja)	1995-03-14	有機材料用の安定剤としての用途のための新規ポリアルキル−４−ピペリジノール誘導体
SK14794A3 (en)	1995-03-08	Piperidinetriazine compounds suitable for use as stabilizers of organic matters
JPH08245619A (ja)	1996-09-24	光、熱および酸化に対する有機材料の安定剤としての２，２，６，６−テトラメチルピペリジン誘導体の使用方法
SK83894A3 (en)	1995-03-08	Stabilizers of organic matters on piperidine compounds base
CS301791A3 (en)	1992-04-15	Piperidino-triazine derivatives used for organic compounds stabilization
CS122791A2 (en)	1991-12-17	Piperidine-triazinoic mixtures suitable as stabilizers of organic materials
CZ284132B6 (cs)	1998-08-12	Stabilizace polymerních organických materiálů za použití synergických směsí obsahujících stericky bráněné cyklické aminy a deriváty 3-pyrazolidinonu nebo 1,2,4-triazolin-3,5-dionu
US5489683A (en)	1996-02-06	Piperidine-triazine compounds suitable for use as stabilisers for organic materials
JPH08225650A (ja)	1996-09-03	有機材料のための安定剤としての、シラン基を含有するピペリジントリアジン化合物
JPH08259536A (ja)	1996-10-08	ブチン結合された立体障害アミンの縮合物
SK138593A3 (en)	1994-12-07	Method of preparation 2,2,6,6-tetramethyl-4-piperidyloxy- -1,3,5-triazines with two or more triazines cycles
GB2377450A (en)	2003-01-15	1,3,5-Triazine-Piperazinone derivatives