SK176098A3 - Amino silane and a catalyst - Google Patents

Amino silane and a catalyst Download PDF

Info

Publication number: SK176098A3
Authority: SK; Slovakia
Prior art keywords: alkyl; aminosilane; carbon atoms; linear; cycloalkyl
Prior art date: 1997-12-23

Application number

SK1760-98A

Other languages

English (en)

Slovak (sk)

Inventor

Constantine A Stewart

Eric J Evain

Original Assignee

Montell North America Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-12-23

Filing date

1998-12-18

Publication date

2000-03-13

1998-12-18 Application filed by Montell North America Inc filed Critical Montell North America Inc

2000-03-13 Publication of SK176098A3 publication Critical patent/SK176098A3/sk

Links

FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 title claims abstract description 32
239000003054 catalyst Substances 0.000 title claims abstract description 24
125000000217 alkyl group Chemical group 0.000 claims abstract description 45
239000011777 magnesium Substances 0.000 claims abstract description 29
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 24
229910052749 magnesium Inorganic materials 0.000 claims abstract description 24
229910052736 halogen Inorganic materials 0.000 claims abstract description 19
125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 17
125000001424 substituent group Chemical group 0.000 claims abstract description 17
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 12
150000001336 alkenes Chemical class 0.000 claims abstract description 10
150000002367 halogens Chemical class 0.000 claims abstract description 10
239000007787 solid Substances 0.000 claims abstract description 10
125000005843 halogen group Chemical group 0.000 claims abstract description 8
125000004856 decahydroquinolinyl group Chemical group N1(CCCC2CCCCC12)* 0.000 claims abstract description 7
125000000719 pyrrolidinyl group Chemical group 0.000 claims abstract description 6
125000004607 1,2,3,4-tetrahydroquinolinyl group Chemical group N1(CCCC2=CC=CC=C12)* 0.000 claims abstract description 5
125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims abstract description 5
125000004605 1,2,3,4-tetrahydroisoquinolinyl group Chemical group C1(NCCC2=CC=CC=C12)* 0.000 claims abstract description 4
125000003386 piperidinyl group Chemical group 0.000 claims abstract description 3
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract 2
239000000203 mixture Substances 0.000 claims description 44
-1 amino, substituted pyrrolidinyl Chemical group 0.000 claims description 32
125000004432 carbon atom Chemical group C* 0.000 claims description 22
239000010936 titanium Substances 0.000 claims description 16
229910052719 titanium Inorganic materials 0.000 claims description 16
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 11
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 8
229910052782 aluminium Inorganic materials 0.000 claims description 4
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 4
239000007795 chemical reaction product Substances 0.000 claims description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
239000002685 polymerization catalyst Substances 0.000 claims description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims 2
229910001629 magnesium chloride Inorganic materials 0.000 claims 1
125000000147 tetrahydroquinolinyl group Chemical group N1(CCCC2=CC=CC=C12)* 0.000 claims 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical group Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims 1
PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical group C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 claims 1
238000006116 polymerization reaction Methods 0.000 abstract description 18
125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 abstract description 3
125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 3
150000003609 titanium compounds Chemical class 0.000 abstract 1
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 62
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 52
239000000243 solution Substances 0.000 description 28
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 24
238000002390 rotary evaporation Methods 0.000 description 24
IUYHWZFSGMZEOG-UHFFFAOYSA-M magnesium;propane;chloride Chemical compound [Mg+2].[Cl-].C[CH-]C IUYHWZFSGMZEOG-UHFFFAOYSA-M 0.000 description 20
238000006243 chemical reaction Methods 0.000 description 19
238000004821 distillation Methods 0.000 description 18
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 15
239000010410 layer Substances 0.000 description 15
229920000642 polymer Polymers 0.000 description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
238000001816 cooling Methods 0.000 description 14
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 12
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 11
238000000034 method Methods 0.000 description 11
238000010992 reflux Methods 0.000 description 11
238000009835 boiling Methods 0.000 description 10
238000000746 purification Methods 0.000 description 10
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 10
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
238000000926 separation method Methods 0.000 description 9
239000002904 solvent Substances 0.000 description 9
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
238000001914 filtration Methods 0.000 description 8
JLGNHOJUQFHYEZ-UHFFFAOYSA-N trimethoxy(3,3,3-trifluoropropyl)silane Chemical compound CO[Si](OC)(OC)CCC(F)(F)F JLGNHOJUQFHYEZ-UHFFFAOYSA-N 0.000 description 8
239000003795 chemical substances by application Substances 0.000 description 7
229910052739 hydrogen Inorganic materials 0.000 description 7
239000000047 product Substances 0.000 description 7
238000001228 spectrum Methods 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
229910052786 argon Inorganic materials 0.000 description 6
235000019441 ethanol Nutrition 0.000 description 6
239000000178 monomer Substances 0.000 description 6
UUTBSNFHBOVJLI-UHFFFAOYSA-N 2-(3-methylphenyl)pyrrolidine Chemical compound CC1=CC=CC(C2NCCC2)=C1 UUTBSNFHBOVJLI-UHFFFAOYSA-N 0.000 description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 5
239000012267 brine Substances 0.000 description 5
150000004820 halides Chemical group 0.000 description 5
239000001257 hydrogen Substances 0.000 description 5
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 5
229910000041 hydrogen chloride Inorganic materials 0.000 description 5
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 5
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 4
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 4
HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 4
239000007789 gas Substances 0.000 description 4
230000002140 halogenating effect Effects 0.000 description 4
239000007788 liquid Substances 0.000 description 4
239000000843 powder Substances 0.000 description 4
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
229910000077 silane Inorganic materials 0.000 description 4
239000011949 solid catalyst Substances 0.000 description 4
WVFLUUDVJHXQDX-UHFFFAOYSA-N trimethyl(piperidin-2-yl)silane Chemical compound C[Si](C)(C)C1CCCCN1 WVFLUUDVJHXQDX-UHFFFAOYSA-N 0.000 description 4
KQRWBDURMARJQV-UHFFFAOYSA-N trimethyl(pyrrolidin-2-yl)silane Chemical compound C[Si](C)(C)C1CCCN1 KQRWBDURMARJQV-UHFFFAOYSA-N 0.000 description 4
WHRLTFVOCQGAHN-UHFFFAOYSA-N 2,2-diphenylethoxy(diethoxy)silane Chemical compound C1(=CC=CC=C1)C(CO[SiH](OCC)OCC)C1=CC=CC=C1 WHRLTFVOCQGAHN-UHFFFAOYSA-N 0.000 description 3
YKFXSWPGGIAPSM-UHFFFAOYSA-N 2-(3-methylphenyl)piperidine Chemical compound CC1=CC=CC(C2NCCCC2)=C1 YKFXSWPGGIAPSM-UHFFFAOYSA-N 0.000 description 3
MXOPVIHVSGNVNN-UHFFFAOYSA-N 3,4,4a,5,6,7,8,8a-octahydro-2h-quinolin-1-yl-dimethoxy-(3,3,3-trifluoropropyl)silane Chemical compound C1CCCC2N([Si](CCC(F)(F)F)(OC)OC)CCCC21 MXOPVIHVSGNVNN-UHFFFAOYSA-N 0.000 description 3
RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
AGPJNIZHNYOFHN-PHIMTYICSA-N [(2r,6s)-2,6-dimethylpiperidin-1-yl]-dimethoxy-(3,3,3-trifluoropropyl)silane Chemical compound FC(F)(F)CC[Si](OC)(OC)N1[C@@H](C)CCC[C@H]1C AGPJNIZHNYOFHN-PHIMTYICSA-N 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
239000012159 carrier gas Substances 0.000 description 3
239000003426 co-catalyst Substances 0.000 description 3
OUKBKRSAARYGFA-UHFFFAOYSA-N dimethoxy-(3,3,3-trifluoropropyl)-(2-trimethylsilylpyrrolidin-1-yl)silane Chemical compound FC(F)(F)CC[Si](OC)(OC)N1CCCC1[Si](C)(C)C OUKBKRSAARYGFA-UHFFFAOYSA-N 0.000 description 3
YQGOWXYZDLJBFL-UHFFFAOYSA-N dimethoxysilane Chemical compound CO[SiH2]OC YQGOWXYZDLJBFL-UHFFFAOYSA-N 0.000 description 3
239000000835 fiber Substances 0.000 description 3
238000009472 formulation Methods 0.000 description 3
239000001307 helium Substances 0.000 description 3
229910052734 helium Inorganic materials 0.000 description 3
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 3
238000002347 injection Methods 0.000 description 3
239000007924 injection Substances 0.000 description 3
WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000012044 organic layer Substances 0.000 description 3
SDGKUVSVPIIUCF-KNVOCYPGSA-N (2r,6s)-2,6-dimethylpiperidine Chemical compound C[C@H]1CCC[C@@H](C)N1 SDGKUVSVPIIUCF-KNVOCYPGSA-N 0.000 description 2
UWYZHKAOTLEWKK-UHFFFAOYSA-N 1,2,3,4-tetrahydroisoquinoline Chemical compound C1=CC=C2CNCCC2=C1 UWYZHKAOTLEWKK-UHFFFAOYSA-N 0.000 description 2
LBUJPTNKIBCYBY-UHFFFAOYSA-N 1,2,3,4-tetrahydroquinoline Chemical compound C1=CC=C2CCCNC2=C1 LBUJPTNKIBCYBY-UHFFFAOYSA-N 0.000 description 2
RINOYHWVBUKAQE-UHFFFAOYSA-N 1-iodo-2-methylbenzene Chemical compound CC1=CC=CC=C1I RINOYHWVBUKAQE-UHFFFAOYSA-N 0.000 description 2
VLCPISYURGTGLP-UHFFFAOYSA-N 1-iodo-3-methylbenzene Chemical compound CC1=CC=CC(I)=C1 VLCPISYURGTGLP-UHFFFAOYSA-N 0.000 description 2
OISVCGZHLKNMSJ-UHFFFAOYSA-N 2,6-dimethylpyridine Chemical compound CC1=CC=CC(C)=N1 OISVCGZHLKNMSJ-UHFFFAOYSA-N 0.000 description 2
101150041968 CDC13 gene Proteins 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
102100035861 Cytosolic 5'-nucleotidase 1A Human genes 0.000 description 2
101000802744 Homo sapiens Cytosolic 5'-nucleotidase 1A Proteins 0.000 description 2
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical class [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
150000001450 anions Chemical class 0.000 description 2
239000012223 aqueous fraction Substances 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical compound CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
AZFVLHQDIIJLJG-UHFFFAOYSA-N chloromethylsilane Chemical compound [SiH3]CCl AZFVLHQDIIJLJG-UHFFFAOYSA-N 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000000576 coating method Methods 0.000 description 2
DOBRDRYODQBAMW-UHFFFAOYSA-N copper(i) cyanide Chemical compound [Cu+].N#[C-] DOBRDRYODQBAMW-UHFFFAOYSA-N 0.000 description 2
NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical group CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
KNABVAMDEMFWLV-UHFFFAOYSA-N dimethoxy-(1,2,3,4-tetrahydroisoquinolin-1-yl)-(3,3,3-trifluoropropyl)silane Chemical compound C1=CC=C2C([Si](CCC(F)(F)F)(OC)OC)NCCC2=C1 KNABVAMDEMFWLV-UHFFFAOYSA-N 0.000 description 2
XRWJXNPHWIIFPP-UHFFFAOYSA-N dimethoxy-(3,3,3-trifluoropropyl)-(2-trimethylsilylpiperidin-1-yl)silane Chemical compound FC(F)(F)CC[Si](OC)(OC)N1CCCCC1[Si](C)(C)C XRWJXNPHWIIFPP-UHFFFAOYSA-N 0.000 description 2
RAYBZPINKIHRAG-UHFFFAOYSA-N dimethoxy-(4-methylpiperidin-1-yl)-(3,3,3-trifluoropropyl)silane Chemical compound FC(F)(F)CC[Si](OC)(OC)N1CCC(C)CC1 RAYBZPINKIHRAG-UHFFFAOYSA-N 0.000 description 2
BDZLBTVSWMLOPQ-UHFFFAOYSA-N dimethoxy-[2-(3-methylphenyl)piperidin-1-yl]-(3,3,3-trifluoropropyl)silane Chemical compound FC(F)(F)CC[Si](OC)(OC)N1CCCCC1C1=CC=CC(C)=C1 BDZLBTVSWMLOPQ-UHFFFAOYSA-N 0.000 description 2
MPUXYTVBUPCGLW-UHFFFAOYSA-N dimethoxy-[2-(3-methylphenyl)pyrrolidin-1-yl]-(3,3,3-trifluoropropyl)silane Chemical compound FC(F)(F)CC[Si](OC)(OC)N1CCCC1C1=CC=CC(C)=C1 MPUXYTVBUPCGLW-UHFFFAOYSA-N 0.000 description 2
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
239000012065 filter cake Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
238000011065 in-situ storage Methods 0.000 description 2
RSCMBROUXFLLOX-UHFFFAOYSA-N n-[dimethoxy(3,3,3-trifluoropropyl)silyl]-2-ethyl-n-(2-ethylhexyl)hexan-1-amine Chemical compound CCCCC(CC)CN([Si](CCC(F)(F)F)(OC)OC)CC(CC)CCCC RSCMBROUXFLLOX-UHFFFAOYSA-N 0.000 description 2
150000001282 organosilanes Chemical class 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
229920001384 propylene homopolymer Polymers 0.000 description 2
125000006239 protecting group Chemical group 0.000 description 2
FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 2
DYHSDKLCOJIUFX-UHFFFAOYSA-N tert-butoxycarbonyl anhydride Chemical compound CC(C)(C)OC(=O)OC(=O)OC(C)(C)C DYHSDKLCOJIUFX-UHFFFAOYSA-N 0.000 description 2
HODIIHKVZSUTGR-UHFFFAOYSA-N tert-butyl(piperidin-1-yl)carbamic acid Chemical compound CC(C)(C)N(C(O)=O)N1CCCCC1 HODIIHKVZSUTGR-UHFFFAOYSA-N 0.000 description 2
ATAKCZSQWBOMHH-UHFFFAOYSA-N tert-butyl(pyrrolidin-1-yl)carbamic acid Chemical compound CC(C)(C)N(C(O)=O)N1CCCC1 ATAKCZSQWBOMHH-UHFFFAOYSA-N 0.000 description 2
IPFFIGLTTCGSDM-UHFFFAOYSA-N tert-butyl-(2-trimethylsilylpiperidin-1-yl)carbamic acid Chemical compound CC(C)(C)N(C(O)=O)N1CCCCC1[Si](C)(C)C IPFFIGLTTCGSDM-UHFFFAOYSA-N 0.000 description 2
238000012360 testing method Methods 0.000 description 2
ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 2
239000005052 trichlorosilane Substances 0.000 description 2
125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 2
239000008096 xylene Substances 0.000 description 2
125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
POTIYWUALSJREP-UHFFFAOYSA-N 1,2,3,4,4a,5,6,7,8,8a-decahydroquinoline Chemical compound N1CCCC2CCCCC21 POTIYWUALSJREP-UHFFFAOYSA-N 0.000 description 1
FWKITFSPALLPLM-UHFFFAOYSA-N 1-(3-methylphenyl)piperidine Chemical compound CC1=CC=CC(N2CCCCC2)=C1 FWKITFSPALLPLM-UHFFFAOYSA-N 0.000 description 1
SDGKUVSVPIIUCF-UHFFFAOYSA-N 2,6-dimethylpiperidine Chemical compound CC1CCCC(C)N1 SDGKUVSVPIIUCF-UHFFFAOYSA-N 0.000 description 1
GEHHTRHRKITQSU-UHFFFAOYSA-N 3,4-dihydro-2h-quinolin-1-yl-dimethoxy-(3,3,3-trifluoropropyl)silane Chemical compound C1=CC=C2N([Si](CCC(F)(F)F)(OC)OC)CCCC2=C1 GEHHTRHRKITQSU-UHFFFAOYSA-N 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
SAIKULLUBZKPDA-UHFFFAOYSA-N Bis(2-ethylhexyl) amine Chemical compound CCCCC(CC)CNCC(CC)CCCC SAIKULLUBZKPDA-UHFFFAOYSA-N 0.000 description 1
AUAMCSFFJBTDFG-UHFFFAOYSA-N C[Si](C)(C)OC(N(C(C)(C)C)N1CCCC1)=O Chemical compound C[Si](C)(C)OC(N(C(C)(C)C)N1CCCC1)=O AUAMCSFFJBTDFG-UHFFFAOYSA-N 0.000 description 1
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
241000282326 Felis catus Species 0.000 description 1
239000007818 Grignard reagent Substances 0.000 description 1
OWTJYTHMUALIDS-UHFFFAOYSA-N N-dimethoxysilyl-2-ethyl-N-(2-ethylhexyl)hexan-1-amine Chemical compound C(C)C(CN(CC(CCCC)CC)[SiH](OC)OC)CCCC OWTJYTHMUALIDS-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
239000007868 Raney catalyst Substances 0.000 description 1
229910000564 Raney nickel Inorganic materials 0.000 description 1
229910003902 SiCl 4 Inorganic materials 0.000 description 1
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical class [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
150000004703 alkoxides Chemical class 0.000 description 1
125000005234 alkyl aluminium group Chemical group 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
159000000032 aromatic acids Chemical class 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
HYGWNUKOUCZBND-UHFFFAOYSA-N azanide Chemical compound [NH2-] HYGWNUKOUCZBND-UHFFFAOYSA-N 0.000 description 1
LJWBIAMZBJWAOW-UHFFFAOYSA-N benzhydryloxysilane Chemical compound C=1C=CC=CC=1C(O[SiH3])C1=CC=CC=C1 LJWBIAMZBJWAOW-UHFFFAOYSA-N 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
230000005540 biological transmission Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
239000012986 chain transfer agent Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
SLLGVCUQYRMELA-UHFFFAOYSA-N chlorosilicon Chemical compound Cl[Si] SLLGVCUQYRMELA-UHFFFAOYSA-N 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000012043 crude product Substances 0.000 description 1
238000001514 detection method Methods 0.000 description 1
YMWUJEATGCHHMB-UHFFFAOYSA-N dichloromethane Substances ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 1
YNHIGQDRGKUECZ-UHFFFAOYSA-N dichloropalladium;triphenylphosphanium Chemical compound Cl[Pd]Cl.C1=CC=CC=C1[PH+](C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1[PH+](C=1C=CC=CC=1)C1=CC=CC=C1 YNHIGQDRGKUECZ-UHFFFAOYSA-N 0.000 description 1
DOODELBMKSEMGZ-UHFFFAOYSA-N dimethoxy-pyrrolidin-1-yl-(3,3,3-trifluoropropyl)silane Chemical compound FC(F)(F)CC[Si](OC)(OC)N1CCCC1 DOODELBMKSEMGZ-UHFFFAOYSA-N 0.000 description 1
HPYNZHMRTTWQTB-UHFFFAOYSA-N dimethylpyridine Natural products CC1=CC=CN=C1C HPYNZHMRTTWQTB-UHFFFAOYSA-N 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
HHFAWKCIHAUFRX-UHFFFAOYSA-N ethoxide Chemical compound CC[O-] HHFAWKCIHAUFRX-UHFFFAOYSA-N 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
150000004795 grignard reagents Chemical class 0.000 description 1
150000004678 hydrides Chemical class 0.000 description 1
125000001183 hydrocarbyl group Chemical group 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000002329 infrared spectrum Methods 0.000 description 1
230000010354 integration Effects 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 1
150000002680 magnesium Chemical class 0.000 description 1
229910052943 magnesium sulfate Inorganic materials 0.000 description 1
235000019341 magnesium sulphate Nutrition 0.000 description 1
239000000463 material Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000000155 melt Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
NBTOZLQBSIZIKS-UHFFFAOYSA-N methoxide Chemical compound [O-]C NBTOZLQBSIZIKS-UHFFFAOYSA-N 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000007040 multi-step synthesis reaction Methods 0.000 description 1
XBXCNNQPRYLIDE-UHFFFAOYSA-M n-tert-butylcarbamate Chemical compound CC(C)(C)NC([O-])=O XBXCNNQPRYLIDE-UHFFFAOYSA-M 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical compound [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
LPNBBFKOUUSUDB-UHFFFAOYSA-M p-toluate Chemical compound CC1=CC=C(C([O-])=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-M 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000008039 phosphoramides Chemical class 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
150000003021 phthalic acid derivatives Chemical class 0.000 description 1
229910003446 platinum oxide Inorganic materials 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
OTLBJFIVOWJWMM-UHFFFAOYSA-N pyrrolidin-1-yl n-tert-butylcarbamate Chemical compound CC(C)(C)NC(=O)ON1CCCC1 OTLBJFIVOWJWMM-UHFFFAOYSA-N 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
150000004756 silanes Chemical group 0.000 description 1
239000002002 slurry Substances 0.000 description 1
238000002798 spectrophotometry method Methods 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
JQGKNBQEZJSAND-UHFFFAOYSA-N tert-butyl-(2-trimethylsilylpyrrolidin-1-yl)carbamic acid Chemical compound CC(C)(C)N(C(O)=O)N1CCCC1[Si](C)(C)C JQGKNBQEZJSAND-UHFFFAOYSA-N 0.000 description 1
TZSGADJMSDBLTC-UHFFFAOYSA-N tert-butyl-(2-trimethylsilylpyrrolidin-1-yl)carbamic acid;dimethoxy-(3,3,3-trifluoropropyl)-(2-trimethylsilylpyrrolidin-1-yl)silane Chemical compound CC(C)(C)N(C(O)=O)N1CCCC1[Si](C)(C)C.FC(F)(F)CC[Si](OC)(OC)N1CCCC1[Si](C)(C)C TZSGADJMSDBLTC-UHFFFAOYSA-N 0.000 description 1
HZALRIXDEBEFQV-UHFFFAOYSA-N tert-butyl-[2-(3-methylphenyl)pyrrolidin-1-yl]carbamic acid dimethoxy-[2-(3-methylphenyl)pyrrolidin-1-yl]-(3,3,3-trifluoropropyl)silane Chemical compound CC=1C=C(C=CC1)C1N(CCC1)N(C(O)=O)C(C)(C)C.FC(CC[Si](OC)(OC)N1C(CCC1)C1=CC(=CC=C1)C)(F)F HZALRIXDEBEFQV-UHFFFAOYSA-N 0.000 description 1
CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 1
238000012546 transfer Methods 0.000 description 1
230000007704 transition Effects 0.000 description 1
JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
AVCVDUDESCZFHJ-UHFFFAOYSA-N triphenylphosphane;hydrochloride Chemical compound [Cl-].C1=CC=CC=C1[PH+](C=1C=CC=CC=1)C1=CC=CC=C1 AVCVDUDESCZFHJ-UHFFFAOYSA-N 0.000 description 1
PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
- C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

SK1760-98A 1997-12-23 1998-12-18 Amino silane and a catalyst SK176098A3 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US08/996,854 US6130180A (en)	1997-12-23	1997-12-23	Catalyst for the polymerization of alpha-olefins containing substituted amino silane compounds

Publications (1)

Publication Number	Publication Date
SK176098A3 true SK176098A3 (en)	2000-03-13

Family

ID=25543375

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK1760-98A SK176098A3 (en)	1997-12-23	1998-12-18	Amino silane and a catalyst

Country Status (19)

Country	Link
US (1)	US6130180A (de)
EP (1)	EP0926164B1 (de)
JP (1)	JP4174114B2 (de)
KR (1)	KR19990063295A (de)
AR (1)	AR017947A1 (de)
AU (1)	AU739416B2 (de)
BR (1)	BR9805616A (de)
CA (1)	CA2255892A1 (de)
CZ (1)	CZ395598A3 (de)
DE (1)	DE69821890T2 (de)
ES (1)	ES2212206T3 (de)
HU (1)	HUP9802980A3 (de)
ID (1)	ID21553A (de)
IL (1)	IL127322A (de)
NO (1)	NO986047L (de)
PL (1)	PL330462A1 (de)
SK (1)	SK176098A3 (de)
TW (1)	TW499442B (de)
ZA (1)	ZA9811789B (de)

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KR101150579B1 (ko) *	2010-01-22	2012-05-30	삼성토탈 주식회사	프로필렌 중합 및 공중합 방법
CN106632758B (zh) *	2015-10-29	2019-09-27	中国石油化工股份有限公司	乙烯聚合用固体催化剂组分及其制备与应用
CN111295399B (zh)	2017-11-06	2022-09-06	埃克森美孚化学专利公司	基于丙烯的抗冲共聚物及生产方法和设备

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1997
- 1997-12-23 US US08/996,854 patent/US6130180A/en not_active Expired - Fee Related
1998
- 1998-11-30 IL IL12732298A patent/IL127322A/en active IP Right Grant
- 1998-12-02 CZ CZ983955A patent/CZ395598A3/cs unknown
- 1998-12-07 CA CA002255892A patent/CA2255892A1/en not_active Abandoned
- 1998-12-18 SK SK1760-98A patent/SK176098A3/sk unknown
- 1998-12-19 EP EP98124145A patent/EP0926164B1/de not_active Expired - Lifetime
- 1998-12-19 DE DE69821890T patent/DE69821890T2/de not_active Expired - Lifetime
- 1998-12-19 ES ES98124145T patent/ES2212206T3/es not_active Expired - Lifetime
- 1998-12-21 HU HU9802980A patent/HUP9802980A3/hu unknown
- 1998-12-21 PL PL98330462A patent/PL330462A1/xx unknown
- 1998-12-22 AR ARP980106587A patent/AR017947A1/es unknown
- 1998-12-22 KR KR1019980057008A patent/KR19990063295A/ko not_active Withdrawn
- 1998-12-22 AU AU98122/98A patent/AU739416B2/en not_active Ceased
- 1998-12-22 TW TW087121445A patent/TW499442B/zh active
- 1998-12-22 BR BR9805616-6A patent/BR9805616A/pt not_active Application Discontinuation
- 1998-12-22 ZA ZA9811789A patent/ZA9811789B/xx unknown
- 1998-12-22 NO NO986047A patent/NO986047L/no not_active Application Discontinuation
- 1998-12-23 ID IDP981684A patent/ID21553A/id unknown
- 1998-12-24 JP JP36744998A patent/JP4174114B2/ja not_active Expired - Fee Related

Also Published As

Publication number	Publication date
JPH11246618A (ja)	1999-09-14
EP0926164A3 (de)	2001-02-28
HU9802980D0 (en)	1999-02-01
US6130180A (en)	2000-10-10
BR9805616A (pt)	1999-12-21
HUP9802980A2 (hu)	1999-10-28
IL127322A0 (en)	1999-09-22
ID21553A (id)	1999-06-24
IL127322A (en)	2001-04-30
CZ395598A3 (cs)	1999-08-11
AU9812298A (en)	1999-07-15
DE69821890T2 (de)	2004-12-16
EP0926164B1 (de)	2004-02-25
AR017947A1 (es)	2001-10-24
AU739416B2 (en)	2001-10-11
NO986047L (no)	1999-06-24
KR19990063295A (ko)	1999-07-26
HUP9802980A3 (en)	2001-06-28
DE69821890D1 (de)	2004-04-01
JP4174114B2 (ja)	2008-10-29
NO986047D0 (no)	1998-12-22
PL330462A1 (en)	1999-07-05
CA2255892A1 (en)	1999-06-23
TW499442B (en)	2002-08-21
ZA9811789B (en)	1999-06-29
ES2212206T3 (es)	2004-07-16
EP0926164A2 (de)	1999-06-30

Publication	Publication Date	Title
US7009015B2 (en)	2006-03-07	Alpha-olefin polymerization catalyst system which contains an aromatic silane compound
EP0891988A2 (de)	1999-01-20	Katalysatorbestandteile und Katalysatoren für die Olefinpolymerisation
BRPI0615149B1 (pt)	2017-06-27	Component of a catalyst for polymerization of olefin, catalyst for polymerization of olefins, and process for production in polymer of olefin
RU2039062C1 (ru)	1995-07-09	ЭЛЕКТРОНОДОНОРНЫЕ КРЕМНИЙОРГАНИЧЕСКИЕ СОЕДИНЕНИЯ И КАТАЛИЗАТОР ПОЛИМЕРИЗАЦИИ α -ОЛЕФИНОВ
PT773241E (pt)	2002-02-28	Componente de um catalisador solido para a polimerizacao de olefinas e catalisador para a polimerizacao de olefinas
JP3167380B2 (ja)	2001-05-21	トリフルオロプロピル置換シラン化合物を含むα−オレフィンの重合用触媒
SK176098A3 (en)	2000-03-13	Amino silane and a catalyst
EP2666790B1 (de)	2015-03-04	Feststoffkatalysatorbestandteil und katalysator für olefinpolymerisation
EP0849291B1 (de)	2002-02-13	Katalysator zur Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymeren
JP2007530747A (ja)	2007-11-01	塩化マグネシウムに基づく付加物およびそれから得られる触媒成分
MXPA98010497A (en)	1999-06-01	Catalyst for the polymerization of alpha-olefins containing aminosilan substitute compounds
KR930001065B1 (ko)	1993-02-15	α-올레핀의 단독 중합체 또는 공중합체의 제조방법
NO301281B1 (no)	1997-10-06	Katalysatorer for polymerisasjon av <alfa>-olefiner