TW380153B - New (meth)acrylic resin compositions for marine antifouling paints and corresponding paint compositions - Google Patents

New (meth)acrylic resin compositions for marine antifouling paints and corresponding paint compositions Download PDF

Info

Publication number: TW380153B
Authority: TW; Taiwan
Prior art keywords: composition; polymer; patent application; scope; esterified
Prior art date: 1996-08-22

Application number

TW086114536A

Other languages

English (en)

Chinese (zh)

Inventor

Didier Vanhoye

Michel Camail

Andre Margaillan

Jean-Louis Vernet

Marie Humbert

Original Assignee

Atochem Elf Sa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-08-22

Filing date

1997-10-04

Publication date

2000-01-21

1997-10-04 Application filed by Atochem Elf Sa filed Critical Atochem Elf Sa

2000-01-21 Application granted granted Critical

2000-01-21 Publication of TW380153B publication Critical patent/TW380153B/zh

Links

239000000203 mixture Substances 0.000 title claims abstract description 80
239000004925 Acrylic resin Substances 0.000 title claims abstract description 6
239000003973 paint Substances 0.000 title claims description 19
230000003373 anti-fouling effect Effects 0.000 title claims description 10
229920000178 Acrylic resin Polymers 0.000 title abstract description 4
229920000642 polymer Polymers 0.000 claims abstract description 39
239000002904 solvent Substances 0.000 claims abstract description 28
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 17
-1 2-ethylhexyl Chemical group 0.000 claims abstract description 14
238000006243 chemical reaction Methods 0.000 claims abstract description 13
238000005886 esterification reaction Methods 0.000 claims abstract description 9
238000002360 preparation method Methods 0.000 claims abstract description 9
238000007334 copolymerization reaction Methods 0.000 claims abstract description 8
230000032050 esterification Effects 0.000 claims abstract description 8
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims abstract description 8
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims abstract description 6
125000000896 monocarboxylic acid group Chemical group 0.000 claims abstract description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 66
239000011347 resin Substances 0.000 claims description 16
229920005989 resin Polymers 0.000 claims description 16
238000011049 filling Methods 0.000 claims description 15
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 13
239000008096 xylene Substances 0.000 claims description 13
ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 10
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
229920001577 copolymer Polymers 0.000 claims description 9
125000005395 methacrylic acid group Chemical group 0.000 claims description 9
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
239000000047 product Substances 0.000 claims description 8
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 7
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
239000000853 adhesive Substances 0.000 claims description 6
230000001070 adhesive effect Effects 0.000 claims description 6
125000001147 pentyl group Chemical group C(CCCC)* 0.000 claims description 6
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 4
KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims description 4
229940112669 cuprous oxide Drugs 0.000 claims description 4
239000004615 ingredient Substances 0.000 claims description 4
239000011787 zinc oxide Substances 0.000 claims description 4
PZNPLUBHRSSFHT-RRHRGVEJSA-N 1-hexadecanoyl-2-octadecanoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCCCC(=O)O[C@@H](COP([O-])(=O)OCC[N+](C)(C)C)COC(=O)CCCCCCCCCCCCCCC PZNPLUBHRSSFHT-RRHRGVEJSA-N 0.000 claims description 3
240000008564 Boehmeria nivea Species 0.000 claims description 3
239000002253 acid Substances 0.000 claims description 3
125000005907 alkyl ester group Chemical group 0.000 claims description 3
230000002079 cooperative effect Effects 0.000 claims description 3
239000000049 pigment Substances 0.000 claims description 3
150000003254 radicals Chemical group 0.000 claims description 3
239000007787 solid Substances 0.000 claims description 3
239000008347 soybean phospholipid Substances 0.000 claims description 3
239000002671 adjuvant Substances 0.000 claims description 2
239000012043 crude product Substances 0.000 claims description 2
238000012856 packing Methods 0.000 claims description 2
239000003381 stabilizer Substances 0.000 claims description 2
PCTMTFRHKVHKIS-BMFZQQSSSA-N (1s,3r,4e,6e,8e,10e,12e,14e,16e,18s,19r,20r,21s,25r,27r,30r,31r,33s,35r,37s,38r)-3-[(2r,3s,4s,5s,6r)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-19,25,27,30,31,33,35,37-octahydroxy-18,20,21-trimethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10 Chemical compound C1C=C2C[C@@H](OS(O)(=O)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2.O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C=C/C=C/C=C/[C@H](C)[C@@H](O)[C@@H](C)[C@H](C)OC(=O)C[C@H](O)C[C@H](O)CC[C@@H](O)[C@H](O)C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 PCTMTFRHKVHKIS-BMFZQQSSSA-N 0.000 claims 4
RWHRFHQRVDUPIK-UHFFFAOYSA-N 50867-57-7 Chemical group CC(=C)C(O)=O.CC(=C)C(O)=O RWHRFHQRVDUPIK-UHFFFAOYSA-N 0.000 claims 2
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 2
235000013409 condiments Nutrition 0.000 claims 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
229910001952 rubidium oxide Inorganic materials 0.000 claims 1
CWBWCLMMHLCMAM-UHFFFAOYSA-M rubidium(1+);hydroxide Chemical compound [OH-].[Rb+].[Rb+] CWBWCLMMHLCMAM-UHFFFAOYSA-M 0.000 claims 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract description 2
UOCJDOLVGGIYIQ-PBFPGSCMSA-N cefatrizine Chemical group S([C@@H]1[C@@H](C(N1C=1C(O)=O)=O)NC(=O)[C@H](N)C=2C=CC(O)=CC=2)CC=1CSC=1C=NNN=1 UOCJDOLVGGIYIQ-PBFPGSCMSA-N 0.000 abstract 1
239000010936 titanium Substances 0.000 description 20
238000009472 formulation Methods 0.000 description 11
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 8
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 7
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 6
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 6
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 6
239000011230 binding agent Substances 0.000 description 6
150000001875 compounds Chemical class 0.000 description 6
238000005498 polishing Methods 0.000 description 6
229910052719 titanium Inorganic materials 0.000 description 6
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 5
239000003921 oil Substances 0.000 description 5
238000000034 method Methods 0.000 description 4
239000000178 monomer Substances 0.000 description 4
238000006116 polymerization reaction Methods 0.000 description 4
XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
238000004364 calculation method Methods 0.000 description 3
239000003085 diluting agent Substances 0.000 description 3
239000004922 lacquer Substances 0.000 description 3
239000007788 liquid Substances 0.000 description 3
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
239000002023 wood Substances 0.000 description 3
VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
241000237502 Ostreidae Species 0.000 description 2
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
239000000919 ceramic Substances 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
230000007423 decrease Effects 0.000 description 2
238000007872 degassing Methods 0.000 description 2
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
230000003628 erosive effect Effects 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
235000003642 hunger Nutrition 0.000 description 2
239000003999 initiator Substances 0.000 description 2
238000011835 investigation Methods 0.000 description 2
238000002156 mixing Methods 0.000 description 2
235000020636 oyster Nutrition 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000013535 sea water Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
238000005303 weighing Methods 0.000 description 2
YIWGJFPJRAEKMK-UHFFFAOYSA-N 1-(2H-benzotriazol-5-yl)-3-methyl-8-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carbonyl]-1,3,8-triazaspiro[4.5]decane-2,4-dione Chemical compound CN1C(=O)N(c2ccc3n[nH]nc3c2)C2(CCN(CC2)C(=O)c2cnc(NCc3cccc(OC(F)(F)F)c3)nc2)C1=O YIWGJFPJRAEKMK-UHFFFAOYSA-N 0.000 description 1
JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 1
KTXWGMUMDPYXNN-UHFFFAOYSA-N 2-ethylhexan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCC(CC)C[O-].CCCCC(CC)C[O-].CCCCC(CC)C[O-].CCCCC(CC)C[O-] KTXWGMUMDPYXNN-UHFFFAOYSA-N 0.000 description 1
101500021165 Aplysia californica Myomodulin-A Proteins 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
244000025254 Cannabis sativa Species 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
102000040712 Kappa family Human genes 0.000 description 1
108091071243 Kappa family Proteins 0.000 description 1
XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 1
VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
238000005481 NMR spectroscopy Methods 0.000 description 1
241000218206 Ranunculus Species 0.000 description 1
230000002159 abnormal effect Effects 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
230000009471 action Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
230000033228 biological regulation Effects 0.000 description 1
YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
239000004359 castor oil Substances 0.000 description 1
235000019438 castor oil Nutrition 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
230000000875 corresponding effect Effects 0.000 description 1
239000006184 cosolvent Substances 0.000 description 1
229920006037 cross link polymer Polymers 0.000 description 1
238000004821 distillation Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
238000001879 gelation Methods 0.000 description 1
ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
239000008240 homogeneous mixture Substances 0.000 description 1
239000012456 homogeneous solution Substances 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
230000009545 invasion Effects 0.000 description 1
KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
238000012886 linear function Methods 0.000 description 1
239000006193 liquid solution Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
231100000956 nontoxicity Toxicity 0.000 description 1
230000000414 obstructive effect Effects 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
230000037361 pathway Effects 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
230000008569 process Effects 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000008439 repair process Effects 0.000 description 1
238000011160 research Methods 0.000 description 1
238000007788 roughening Methods 0.000 description 1
235000015170 shellfish Nutrition 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
229940083466 soybean lecithin Drugs 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
238000012360 testing method Methods 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/04—Acids; Metal salts or ammonium salts thereof
- C08F120/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Wood Science & Technology (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
General Chemical & Material Sciences (AREA)
Paints Or Removers (AREA)
Compositions Of Macromolecular Compounds (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Macromonomer-Based Addition Polymer (AREA)
Silicon Polymers (AREA)

TW086114536A 1996-08-22 1997-10-04 New (meth)acrylic resin compositions for marine antifouling paints and corresponding paint compositions TW380153B (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR9610374A FR2752581B1 (fr)	1996-08-22	1996-08-22	Nouvelles compositions de resines (meth)acryliques pour peintures marines antisalissures, et compositions de peintures correspondantes

Publications (1)

Publication Number	Publication Date
TW380153B true TW380153B (en)	2000-01-21

Family

ID=9495168

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW086114536A TW380153B (en)	1996-08-22	1997-10-04	New (meth)acrylic resin compositions for marine antifouling paints and corresponding paint compositions

Country Status (14)

Country	Link
US (1)	US5919840A (id)
EP (1)	EP0825203B1 (id)
JP (1)	JP3265240B2 (id)
KR (1)	KR100215527B1 (id)
CN (1)	CN1105746C (id)
AT (1)	ATE213501T1 (id)
CA (1)	CA2215572C (id)
CZ (1)	CZ260397A3 (id)
DE (1)	DE69710537T2 (id)
ES (1)	ES2171857T3 (id)
FR (1)	FR2752581B1 (id)
ID (1)	ID18057A (id)
SG (1)	SG71038A1 (id)
TW (1)	TW380153B (id)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IL142130A0 (en) *	1998-09-23	2002-03-10	Phycogen Inc	Safe and effective biofilm inhibitory compounds and health-related uses thereof
FR2787800B1 (fr)	1998-12-23	2001-01-26	Atochem Elf Sa	Procede de fabrication d'une composition organosoluble de resine (meth)acrylique, et utilisation de cette composition comme liant des peintures marines antisalissures
FR2816314A1 (fr) *	2000-11-08	2002-05-10	Atofina	Composition de resines (meth) acryliques en milieu solvant organique, leur procede de fabrication, et leur utilisation comme liants des peintures marines antisalissures
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1996
- 1996-08-22 FR FR9610374A patent/FR2752581B1/fr not_active Expired - Fee Related
1997
- 1997-08-08 ES ES97401909T patent/ES2171857T3/es not_active Expired - Lifetime
- 1997-08-08 EP EP97401909A patent/EP0825203B1/fr not_active Expired - Lifetime
- 1997-08-08 DE DE69710537T patent/DE69710537T2/de not_active Expired - Fee Related
- 1997-08-08 AT AT97401909T patent/ATE213501T1/de not_active IP Right Cessation
- 1997-08-15 CZ CZ972603A patent/CZ260397A3/cs unknown
- 1997-08-15 SG SG1997002946A patent/SG71038A1/en unknown
- 1997-08-20 ID IDP972907A patent/ID18057A/id unknown
- 1997-08-21 US US08/915,799 patent/US5919840A/en not_active Expired - Fee Related
- 1997-08-22 JP JP24191097A patent/JP3265240B2/ja not_active Expired - Fee Related
- 1997-08-22 CA CA002215572A patent/CA2215572C/fr not_active Expired - Fee Related
- 1997-08-22 KR KR1019970040338A patent/KR100215527B1/ko not_active Expired - Fee Related
- 1997-08-22 CN CN97121368A patent/CN1105746C/zh not_active Expired - Fee Related
- 1997-10-04 TW TW086114536A patent/TW380153B/zh not_active IP Right Cessation

Also Published As

Publication number	Publication date
FR2752581A1 (fr)	1998-02-27
DE69710537T2 (de)	2002-09-12
KR100215527B1 (ko)	1999-08-16
JPH1087676A (ja)	1998-04-07
CN1178229A (zh)	1998-04-08
DE69710537D1 (de)	2002-03-28
CA2215572A1 (fr)	1998-02-22
ID18057A (id)	1998-02-26
SG71038A1 (en)	2000-03-21
FR2752581B1 (fr)	1998-10-30
EP0825203B1 (fr)	2002-02-20
CZ260397A3 (cs)	1998-03-18
KR19980018934A (ko)	1998-06-05
US5919840A (en)	1999-07-06
ATE213501T1 (de)	2002-03-15
CA2215572C (fr)	2002-10-15
ES2171857T3 (es)	2002-09-16
CN1105746C (zh)	2003-04-16
JP3265240B2 (ja)	2002-03-11
EP0825203A1 (fr)	1998-02-25

Legal Events

Date	Code	Title	Description
2000-05-29	GD4A	Issue of patent certificate for granted invention patent
2006-03-01	MM4A	Annulment or lapse of patent due to non-payment of fees

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