TW462980B - Dye compositions comprising anthraquinones and/or quinophthalones - Google Patents
Dye compositions comprising anthraquinones and/or quinophthalones Download PDFInfo
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- TW462980B TW462980B TW086107742A TW86107742A TW462980B TW 462980 B TW462980 B TW 462980B TW 086107742 A TW086107742 A TW 086107742A TW 86107742 A TW86107742 A TW 86107742A TW 462980 B TW462980 B TW 462980B
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- dye composition
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- 239000000203 mixture Substances 0.000 title claims abstract description 58
- 150000004056 anthraquinones Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000007641 inkjet printing Methods 0.000 claims abstract description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 238000012546 transfer Methods 0.000 claims description 8
- 150000002431 hydrogen Chemical class 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Chemical group 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical group 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 125000004414 alkyl thio group Chemical group 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 125000001033 ether group Chemical group 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 125000000304 alkynyl group Chemical group 0.000 claims 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
- 239000000460 chlorine Chemical group 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 claims 1
- 239000008267 milk Substances 0.000 claims 1
- 210000004080 milk Anatomy 0.000 claims 1
- 235000013336 milk Nutrition 0.000 claims 1
- 238000006467 substitution reaction Methods 0.000 claims 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 claims 1
- 239000000975 dye Substances 0.000 abstract description 51
- 239000000976 ink Substances 0.000 abstract description 18
- 239000002253 acid Substances 0.000 abstract description 12
- 239000002270 dispersing agent Substances 0.000 abstract description 12
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 9
- 239000007859 condensation product Substances 0.000 abstract description 6
- 125000003010 ionic group Chemical group 0.000 abstract description 5
- 238000010023 transfer printing Methods 0.000 abstract 1
- -1 aryl flavonic acid Chemical compound 0.000 description 38
- 125000003118 aryl group Chemical group 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- 230000002079 cooperative effect Effects 0.000 description 8
- 229920001223 polyethylene glycol Polymers 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 5
- 230000032683 aging Effects 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000004043 dyeing Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 3
- 150000001491 aromatic compounds Chemical class 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical compound C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 description 2
- UUGLSEIATNSHRI-UHFFFAOYSA-N 1,3,4,6-tetrakis(hydroxymethyl)-3a,6a-dihydroimidazo[4,5-d]imidazole-2,5-dione Chemical compound OCN1C(=O)N(CO)C2C1N(CO)C(=O)N2CO UUGLSEIATNSHRI-UHFFFAOYSA-N 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- FIPKSKMDTAQBDJ-UHFFFAOYSA-N 1-methyl-2,3-dihydro-1h-indene Chemical compound C1=CC=C2C(C)CCC2=C1 FIPKSKMDTAQBDJ-UHFFFAOYSA-N 0.000 description 2
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- RKJHJMAZNPASHY-UHFFFAOYSA-N 2-methyl-9h-fluorene Chemical compound C1=CC=C2C3=CC=C(C)C=C3CC2=C1 RKJHJMAZNPASHY-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 239000001000 anthraquinone dye Substances 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229960004365 benzoic acid Drugs 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
- 125000004744 butyloxycarbonyl group Chemical group 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- LCPDWSOZIOUXRV-UHFFFAOYSA-N phenoxyacetic acid Chemical compound OC(=O)COC1=CC=CC=C1 LCPDWSOZIOUXRV-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 150000004053 quinones Chemical class 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 125000005420 sulfonamido group Chemical group S(=O)(=O)(N*)* 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 1
- HYFLWBNQFMXCPA-UHFFFAOYSA-N 1-ethyl-2-methylbenzene Chemical compound CCC1=CC=CC=C1C HYFLWBNQFMXCPA-UHFFFAOYSA-N 0.000 description 1
- ZWAMZDRREBOHIO-UHFFFAOYSA-N 1-ethylpyrene Chemical compound C1=C2C(CC)=CC=C(C=C3)C2=C2C3=CC=CC2=C1 ZWAMZDRREBOHIO-UHFFFAOYSA-N 0.000 description 1
- LRTOHSLOFCWHRF-UHFFFAOYSA-N 1-methyl-1h-indene Chemical compound C1=CC=C2C(C)C=CC2=C1 LRTOHSLOFCWHRF-UHFFFAOYSA-N 0.000 description 1
- KLIDCXVFHGNTTM-UHFFFAOYSA-N 2,6-dimethoxyphenol Chemical group COC1=CC=CC(OC)=C1O KLIDCXVFHGNTTM-UHFFFAOYSA-N 0.000 description 1
- 125000004198 2-fluorophenyl group Chemical group [H]C1=C([H])C(F)=C(*)C([H])=C1[H] 0.000 description 1
- WRLGCODFDFQLGM-UHFFFAOYSA-N 2-hydroxybenzoic acid;2-phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1.OC(=O)C1=CC=CC=C1O WRLGCODFDFQLGM-UHFFFAOYSA-N 0.000 description 1
- 125000004204 2-methoxyphenyl group Chemical group [H]C1=C([H])C(*)=C(OC([H])([H])[H])C([H])=C1[H] 0.000 description 1
- WLJVXDMOQOGPHL-PPJXEINESA-N 2-phenylacetic acid Chemical compound O[14C](=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-PPJXEINESA-N 0.000 description 1
- 125000005975 2-phenylethyloxy group Chemical group 0.000 description 1
- 125000001241 2-phenylethylthio group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])S* 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- 125000006275 3-bromophenyl group Chemical group [H]C1=C([H])C(Br)=C([H])C(*)=C1[H] 0.000 description 1
- 125000004180 3-fluorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C(F)=C1[H] 0.000 description 1
- 125000004800 4-bromophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Br 0.000 description 1
- 125000004860 4-ethylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001255 4-fluorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1F 0.000 description 1
- 125000004861 4-isopropyl phenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000004172 4-methoxyphenyl group Chemical group [H]C1=C([H])C(OC([H])([H])[H])=C([H])C([H])=C1* 0.000 description 1
- 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- HBZVNWNSRNTWPS-UHFFFAOYSA-N 6-amino-4-hydroxynaphthalene-2-sulfonic acid Chemical compound C1=C(S(O)(=O)=O)C=C(O)C2=CC(N)=CC=C21 HBZVNWNSRNTWPS-UHFFFAOYSA-N 0.000 description 1
- XZOYHFBNQHPJRQ-UHFFFAOYSA-N 7-methyloctanoic acid Chemical compound CC(C)CCCCCC(O)=O XZOYHFBNQHPJRQ-UHFFFAOYSA-N 0.000 description 1
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- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 244000291564 Allium cepa Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- FVIGODVHAVLZOO-UHFFFAOYSA-N Dixanthogen Chemical compound CCOC(=S)SSC(=S)OCC FVIGODVHAVLZOO-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
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- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 244000147568 Laurus nobilis Species 0.000 description 1
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- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- ABBQHOQBGMUPJH-UHFFFAOYSA-M Sodium salicylate Chemical compound [Na+].OC1=CC=CC=C1C([O-])=O ABBQHOQBGMUPJH-UHFFFAOYSA-M 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
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- 239000002671 adjuvant Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 125000000319 biphenyl-4-yl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C1=C([H])C([H])=C([*])C([H])=C1[H] 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- NJSUFZNXBBXAAC-UHFFFAOYSA-N ethanol;toluene Chemical compound CCO.CC1=CC=CC=C1 NJSUFZNXBBXAAC-UHFFFAOYSA-N 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 1
- 125000004705 ethylthio group Chemical group C(C)S* 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 239000001019 fluorene dye Substances 0.000 description 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003707 hexyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 239000012771 household material Substances 0.000 description 1
- 150000007857 hydrazones Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000005929 isobutyloxycarbonyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])OC(*)=O 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000005932 isopentyloxycarbonyl group Chemical group 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000005928 isopropyloxycarbonyl group Chemical group [H]C([H])([H])C([H])(OC(*)=O)C([H])([H])[H] 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- GPKUICFDWYEPTK-UHFFFAOYSA-N methoxycyclohexatriene Chemical compound COC1=CC=C=C[CH]1 GPKUICFDWYEPTK-UHFFFAOYSA-N 0.000 description 1
- JIQNWFBLYKVZFY-UHFFFAOYSA-N methoxycyclohexatriene Chemical compound COC1=C[C]=CC=C1 JIQNWFBLYKVZFY-UHFFFAOYSA-N 0.000 description 1
- 239000003658 microfiber Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- VMGAPWLDMVPYIA-HIDZBRGKSA-N n'-amino-n-iminomethanimidamide Chemical compound N\N=C\N=N VMGAPWLDMVPYIA-HIDZBRGKSA-N 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000005933 neopentyloxycarbonyl group Chemical group 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 125000000636 p-nitrophenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)[N+]([O-])=O 0.000 description 1
- 125000001148 pentyloxycarbonyl group Chemical group 0.000 description 1
- IYYMDGDZPDXTGT-UHFFFAOYSA-N perylene-1,2-dione Chemical compound C1=CC(C2=C3C(=CC(C2=O)=O)C=CC=C32)=C3C2=CC=CC3=C1 IYYMDGDZPDXTGT-UHFFFAOYSA-N 0.000 description 1
- 125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000004742 propyloxycarbonyl group Chemical group 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000007347 radical substitution reaction Methods 0.000 description 1
- BOLDJAUMGUJJKM-LSDHHAIUSA-N renifolin D Natural products CC(=C)[C@@H]1Cc2c(O)c(O)ccc2[C@H]1CC(=O)c3ccc(O)cc3O BOLDJAUMGUJJKM-LSDHHAIUSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- ZLVSYODPTJZFMK-UHFFFAOYSA-M sodium 4-hydroxybenzoate Chemical compound [Na+].OC1=CC=C(C([O-])=O)C=C1 ZLVSYODPTJZFMK-UHFFFAOYSA-M 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229960004025 sodium salicylate Drugs 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000979 synthetic dye Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- ZFXYFBGIUFBOJW-UHFFFAOYSA-N theophylline Chemical group O=C1N(C)C(=O)N(C)C2=C1NC=N2 ZFXYFBGIUFBOJW-UHFFFAOYSA-N 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 229960000401 tranexamic acid Drugs 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/328—Inkjet printing inks characterised by colouring agents characterised by dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
- B41M5/0356—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the inks used for printing the pattern on the temporary support or additives therefor, e.g. dyes, transferable compounds, binders or transfer promoting additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0084—Dispersions of dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/385—Contact thermal transfer or sublimation processes characterised by the transferable dyes or pigments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/385—Contact thermal transfer or sublimation processes characterised by the transferable dyes or pigments
- B41M5/3852—Anthraquinone or naphthoquinone dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/385—Contact thermal transfer or sublimation processes characterised by the transferable dyes or pigments
- B41M5/3858—Mixtures of dyes, at least one being a dye classifiable in one of groups B41M5/385 - B41M5/39
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Description
A7 〇 NH-L1
L3 462980 _____B7 五、發明説明（1 ) 本發明係關於新顆的染料組合物，其含有以组合物之重 重計之0.1至30重量％的一或多種選自包括不帶有離子性 基團的蒽酿或S昆S太的染料、0 · 1至2 0重量％之以芳基$黃酸 和甲遂的縮合產物為基礎的分散劑及視情況所須而使用的 水的染料組合物，亦係關於其於作為噴墨印刷和轉印的墨 水上之使用。 EP-A 65 5,527已經提出一種含有分散性染料和特定分散 劑的調配物。 本發明的目的是要提出一種含有不帶有離子性基團的惠 醌或醌酞染料之新穎的染料組合物。此新穎的染料组合物 非常適合用於喷墨印刷和轉印。 據此，吾等發現上面所定義的染料組合物。 適當之不帶有離子性基團的蒽醌染料符合，如：式工 (I), 其中 L 代表氬' C1_CI0烷氧基；或视情況而經cf-c4烷基 C1-C1烷氧基、鹵素或硝基取代的苯基； L和L 4別代表氫、c 1 - CI ΰ烷基（視情況地經苯基或c】 烷基苯基取代）、Cl-Cw烷基硫代（視情況地經苯 取代）' 函素、氰基、輕基苯基、Ci_c4燒氧 ---------赛------1r------漆· (請先閲讀背面之注意事項再#i本寅) 經濟部中央標準局員工消費合作社印製 本紙張尺度财峨格（21〇 X 297公釐） _______^ 1 4629 8 0 A7 B7
如：式II
X
五、發明説明（ 基、Ci-Cs貌•酿基、CrQ燒氧藏基或如下的基團 G1 O'02 其中 G1代表氩或硫，而 G2代表氫或^:广^ 一烷基磺醯胺基，其烷基鏈被1或2 個在醚官能基中的氧原子所中斷， 而 L4 代表胺基（其視情況地經CrC4烷基、笨基 基苯基取代）、輕基或CrCl。燒基疏代（其視情況: 經苯基取代）。 適當之不帶有離子性基團的自昆自太染料符合， (⑴, ---------奸衣------II------線 <請先閱讀背面之注意事項再本f) . 經濟部中央標準局員工消費合作社印11 其中’X代表氫、氣或溴。 前述式I中所提到之所有的烷基可為直鏈或帶有支鍵 者 若前述式I中有經取代的烷基存在，它 取代基。 們通常具1或2 個 本紙張尺度通用中國國家橾準（CNs〉A4規格（21〇X 297公釐） 4629 8 0 經濟部中央檫準局員工消費合作社印製 A7 ____B7 ___ 五、發明説明（3 ) 若前述式中有經取代的苯基存在，它們通常具1至3個取 代基’以具1或2個取代基為佳。 下面列舉出一些如式I中所定義的基團。 燒基的例子有甲基、乙基、丙基、異丙基、丁基、異丁 基、第二丁基、第三丁基、戊基、異戊基、新戊基、第三 戊基、己基、甲基戊基、庚基、辛基、2 -乙基己基、異 辛基、壬基、異壬基' 癸基或異癸基（所謂的異辛基 '異 壬基和異癸基是通稱，其衍生自醇類，藉氧代合成法製 #于’此方法可參考 Ullmann's Encyclopedia of Industrial
Chemistry ’ 第 5 版，A1 卷，290-293 頁及 A10 卷 284-285 頁）。 苯基的例子是苯基，2_、3_或4_甲基苯基、2-、3·或 4 -乙基苯基、2 -、3_或4_丙基苯基、2-、3_或4_異丙基 苯基、2-、3 -或4 - 丁基苯基、2,3-、2,4-或2,6-二甲基苯 基、2_、3 -或4 -甲氧基苯基、2-、3 -或4·乙氧基苯基、 2,3- ' 2,4-或2,6-二甲氧基苯基、2 -、3 -或4 -氟苯基、2-、 3 -或4 -氣苯基、、3_或4 -溴苯基或2-、3 -或4 -硝基苯 基。 基硫代和苯基硫代基團的例子有曱基硫代、乙基硫 代 '丙基硫代、異丙基硫代、丁基硫代、異丁基硫代、戍 基硫代、已基硫代、庚基硫代、辛基硫代、異辛基硫代、 2 -乙基己基硫代、壬基硫代、異壬基硫代、癸基硫代、異 癸基硫代、苄基硫代或1 -或2 -苯基乙基硫代^ 燒氧基的例子有甲氧基、乙氧基、丙氧基、異丙氧基、 -6- 本紙張尺度適用中( CNS ) A4規格（210X297公釐） '~' ---------装------1T------0 (請先閔讀背面之：注意事項再^^.本頁} 五 462980 A7 B7 發明説明（4 丁氧基、異丁氧基'第二丁氧基、戊氧基、異戊氧基、新 戊氧基〃、第三戊氧基、已氧基、2-甲氧基戊氧基、庚氧 基、辛氧基、異辛氧基、2·乙基己氧基、壬氧基、異壬氧 基、癸氧基、異癸氧基 '芊氧基或【_或2苯基乙氧基。 自素的例子是氟、氣或溴。 烷氧羰基的例子有甲氧基羰基、乙氧基羰基、丙氧基羰 ,、異丙氧基羰基、丁氧基羰基、異丁氧基羰基、第二丁 氧基羰基、戊氧基羰基、異戊氧基羰基、新戊氧基羰基或 己氧基羰基。烷醯基的例子有甲醯基、乙醯基、丙醯基、 丁醯基、戊醯基或己醯基。 磺醯胺基的例子有甲磺醯胺基、乙磺醯胺基、丙磺醯胺 基、異丙磺醯胺基、丁磺醯胺基、戊磺醯胺基 '己磺醯胺 基、庚磺醯胺基、辛磺醯胺基、2_乙基磺醯胺基、2_甲氧 基乙基磺醯胺基、2 -乙氧基乙基磺醯胺基、3,6_二氧雜庚 續臨胺基、3,6·二氧雜辛績醯胺基、4,8_二氧雜壬橫醯胺 基、3,7-二氧雜辛磺醯胺基、3,7_二氧雜壬磺醯胺基、4,7_ —氧雜辛磺醯胺基、4,7_二氧雜壬磺醯胺基或4,8-二氧雜癸 磺醯胺基。 吾等偏好組合物中含有一或多種其Li代表氫、Ci_c4烷基 或苯基（視情況而經曱基取代基）而L4代表羥基、胺基、Cl_ C4虎基胺基或苯胺基（視情況而經甲基取代者）之以式j表 示的E S昆染料。 吾等偏好組合物中含有一或多種其L2代表C]_C4烷氧基、 氰基、乙醯基、烷氧羰基或下列基團 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） . ^-- (請先閲讀背面之注意事項再^^本頁) 订 經濟部中央標準局負工消費合作社印製
462980 A7 _______B7___ 五'發明説明（5 ) G1仆2 (其中，G1和G2如前文中所定義者，G1特別是指氧，G2特 別是指氫）之式I表示的蒽醌染料。 含一或多種式I之蔥醌（其中L3表氫）之染料組合物。 吾等亦偏好含有以式IIa表示之醌酞染料的組合物， (Iia). 式I和11的染料是一般知道的染料。式I的蒽酿染料述 於，如.K. Venkataraman "The Chemistry of Synthetic Dyes", Vol. III，391-413 頁，Academic Press, New York，London, 1970 » 式II的酿S太染料述於’如：EP-A 83，5 53或其中所列的文獻 中。 吾等偏好存在於調配物中之99%的染料顆粒小於i微米的 染料組合物。 吾等亦偏好所含的蒽g昆或醌酞系列染料之昇華溫度由 140°C至300°C的染料組合物。 所用的分散劑以芳基磺酸與甲醛的縮合產物為佳，以分 散劑之重量計，其中含3至50重量％一或多種芳族或長鏈 脂族羧酸、其鹽類 '其酐類或該類化合物之混合物。 -8 - 本紙張尺度適用中SSt家料（CNS > A4規格（21GX297公着) " —----- ----------^------1T------0 (請先閱讀背面之項再蟑Ϊ、本頁) 經濟部中央標準局負工消費合作社印製 4 6 2980 A7 ______B7_ 、發明说明（6 ) 用於芳基績酸之初產物之特別的例子是那些可由環烷油 和解離產物餾份熱解反應得到的芳族化合物之混合物者。 輕質汽油裂解（舉例言之）可形成此環烷油。例如，DE A 2,947,005中，將它們稱為高沸點芳族烴油。此環烷油以於 1400t至1700°C的溫度範圍内熱解為佳。然後將解離產物 引至分餾階段。收集於100X：至12〇。(：、標準壓力（1〇丨3毫巴） 下之塔頂餾出物形式的餾份，以芳族化合物形式引至磺化 階段中。這樣的餾份通常是已知的乙炔油驟冷法（ullmann,s Encyclopedia of Industrial Chemistry, VCH Verlagsgesellschaft mbH, Weinheim, 1985, Vol. Al, 107-112頁）中的副產物。 此芳族餾份含括多種芳族物質之混合物，其個別分析幾 乎是不可能的。下列芳族化合物是此芳族餾份中最重要的 代表物： 在芳族餾份中的重量％ -ί A- 奈 30-55 2-甲基莕 5-15 1 -甲基萘 4-10 -Λλ- 印 3-10 聯苯 1-5 甲茚 1-5 厄 1-4 此芳族餾份亦含有0.1至約2重量％之已確定的下列芳族 -9- CNS ) A4規格（2i〇X297公釐） (請先閱讀背面之注意事項再填.ΐ;‘本頁) 裝' 丁 、-0 經濟部中央樣準局員工消費合作社印製 紙 本 462980 經濟部中央標隼局員工消費合作杜印製 Α7 Β7 五、發明説明（7 ) 化合物：苗、氫化茚、甲基苯乙埽、菲、甲基氫化茚、二 甲基萘、乙基莕、二甲苯、四氫茶、苯乙烯、甲基乙基 苯、E、芙、芘、苊和甲苯。 特別佳的芳基橫酸通常含有α和点茬績酸，其中，α異 構物與召異構物之間的比例是2Ch丨至丨：8，特別是1〇:丨至 1:5。 適當的芳族羧酸或其衍生物是，如：莕羧酸、茶酸、對 S太酸、異酞酸、苯甲酸、苯偏三酸、苯基醋酸、苯氧基醋 酸、水楊酸 '對-經基苯曱酸、二苯基醋酸、間·經基苯曱 酸、苯四酸或酐（如：酞酸酐、苯偏三酸酐、苯四 酸二酐）或苯衍生物。 適當的長鏈脂族羧酸特別是飽和或烯類未飽和、直鏈或 帶有支鍵之具8至22個碳原子（以8至18個碳原子為佳）的 脂族單羧酸，其可為天然物或合成品，例如：脂肪酸 (如.辛酸、癸紅、月桂、肉豆證酸、棕檀酸 '硬脂 酸、油酸、亞油酸或亞麻酸）或者是人工合成的幾酸（如： 乙基己版、異壬酸或異十三酸）。 此外，也對奸類混合物、幾酸 >昆合物、相關的禮酸鹽混 合物及複酸和奸之混合物感興趣。該幾酸之適當的鹽類是 鹼金屬鹽、銨鹽或鹼土金屬鹽，其可藉由以氩氧化鈉溶 液、氫氧化鉀溶液、氫氧化鋰、碳酸鈉'碳酸鎂、氧化 妈、氫氧化鈣、氨或烷醇胺（如：乙醇胺、二乙醇胺或三 乙醇胺）中和這些幾酸而製得。 特別佳的情況是在分散劑中使用苯甲酸鈉、笨基乙酸 -10- 本紙乐尺度通用中國國家橾準（CNS ) A4規格（210 X 29*?公釐） (請先閱讀背面之注意事項再頊3本頁} -* Γ 4 6 2 9 8 0
經濟部中央標準局貝工消費合作社印$L A7 _____B7 ____ 五、發明説明（8 ) 鈉、水楊酸鈉、4 -羥基苯甲酸鈉、對自大酸鈉'2 -羥基-3-苯羧酸鈉，莕-1-羧酸、酞酸酐或苯γ酸。 較佳的情況是本發明之組合物中所用的分散劑中含有 A) 50至97重量％(特別是7〇至95重量％)的一或多種芳基 磺酸/甲醛縮合物，和 B ) 3至5 0重量％ (特別是5至3 〇重量％ )的一或多種芳族或 長鏈脂族羧酸，其鹽類或其酐類或該類化合物之混合 物。 考慮用來作為本發明方法中之分散劍之芳基績酸和甲越 的縮合產物是目前已知的產品β它們述於US-A 5,186,846。 吾等偏好含有以組合物之重量計之1至1 5重量％的一或 多種選自包括葸醌或醌酞的染料、〇·5至1 〇重量％之以芳 基續酸和甲越的縮合產物為基礎的分散劑及視情況所須而 使用的水的染料組合物β 吾等亦偏好含有以组合物之重量計之0.1至重量。/。（以 0.1至2 5重量％為佳）的竣水化合物和〇. 1至2 〇重量％ (以〇 · j 至1 5重量％為佳）的聚（乙二醇）的染料組合物。 可存在於本發明之染料組合物中之適當的碳水化合物類 是，如：山梨糖醇或蔗糖。 可存在於本發明之染料組合物中之適當的聚（乙二醇）類 的平均分子量是100至1000，以約4〇〇為佳。本發明之染料 组合物中的其他組份可以是，輔助劑（如：防腐劑、抗氧 化劑 '起泡抑制劑或黏度調節劑）。這些物劑已為習知並 了由市面上構仔。這些物劑存在於本發明之染料組合物中 -11 - 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇χ297公釐） ---------^------1Τ------^ (讀先聞讀背面之注意事項再敁\本頁) ?980五、發明説明（9 A7 B7 經濟部中央標準局員工消費合作社印製 時二二總量通常是以组合物重量計心重”。或以下、 右發明《染料組合物中之組份總和低於1〇〇重量％， 餘組份通常是水。 ☆ 、本發明之染料组合物之黏度通常是⑴平方毫米/秒， 以2至3.5平方毫米/秒為佳。 本發明之染料组合物的表面張力通常是3〇至7〇牛頓米/ 米且較佳為40至60牛頓米/米。 本發明之染料組合物的pH通常是5至〖丨，以7至丨〇為 佳。 、此新㈣染料组合物之製備以已知的方式進行。舉例言 在有水存在的情況下，染料可以如加壓片形式與分散 劑及視情況所須而使用的聚（乙二醇）混合在一起，繼而 適Sr的K備中預先分散。然後，所得的混合物在研磨機 處理’以得到所欲的染料顆粒尺寸。最後，添加適當量 水、視情況所須而使用的聚（乙二醇）和/或烴類及視情 而使用的其他輔助劑以進行最終的調整’混合之後，濾 痛網（以孔徑1微米者為佳）s 本發明之染料組合物非常適合作為噴墨印刷和轉印的 水。 喷墨印刷法中’通常使用水性墨水，它們以小液滴形 直接喷在底質上》此方法可歸類成a)連續法，其中，利用 由名乂印出的圖案所駕驭的電場，墨水被追均勻地通過喷嘴 且被引導至底質上，及b)連續或，，滴於所欲處（drop demand)”法，其中，只將墨水噴在須要顏色處。在第 於中 況 經 墨 式 )-on- 種 ---------扑衣------II------0 (請先閲讀背面之注意事項再填ΐ本頁) -12- 本紙張尺度適用中國國家標準（CNS ) A4規格（21 〇 X 297公缝 462980 A7 B7 五、發明説明（ΊΟ ) 經濟部中央標準局員工消費合作社印製 万法中，以高壓晶體或經由受熱的中空針頭對於墨水系統 施壓（泡泳或熱注入法），結果嗜出墨水滴。這樣的程序述 於 Text. Ch亂 Color，V〇1. 19 ⑻，pp 23_29, 1987和 ν〇ι 21， (6)，27·32 頁，1989。 ， 本發明之染料組合物特別適合在噴墨法或使用高壓電晶 體的方法中作為墨水之用。 用於噴墨印刷法之適當的底質不只是紙，也可能是下面 所列的載體材料。 轉印法中，先在轉印介質上形成圖案，然後藉由熱轉 底質上。此染料在轉印操作期間内固著，或者在後續的 著程序中固著，繼而進行整理步驟。此方法已為習知， 於 Ullmann’s Encyclopedia of Industrial chemistry，第 5版 A26卷，499-501頁。 適當的載體特別是織品材料，如：纖維、纖紗、检線、 針織品、聚酯的梭織品或非梭織品、經改質的聚酯（如： 經陰離子修飾的聚酯）、聚酯與纖維素、棉、黏膠纖維或 毛的此紡織品、聚醯胺、聚丙烯腈 '三醋酸酯、醋酸酯、 水碳酸酯、聚丙烯或聚（氣乙烯）、聚酯微纖維及經塑膠纖 維塗覆的載體（如：金屬箔片、玻璃或陶瓷）。 本發明之染料组合物特別適合用於使用喷墨程序而在轉 印介質上形成圖案的轉印法。 一 此新顆的染料組合物的特點在於它們在噴墨程序中不 造成噴嘴的堵塞。其使用不會製造出有斑紋的印製品。 下文中以下面的實例說明本發明。 至 固 述 會 (讀先閱讀背面之注意事項再填i本頁) " -13 本纸張尺度適用中國國家標準（CNS)A4規格（21〇χ 297公釐） 4629 80 at B7 五、發明説明（11 )使用下列染料： 染料1
染料2
〇 nh2 k/>^〇C5H5
0 OH (請先閲讀背面之注意事項再本頁) 染料3
CH 經濟部中央樣準局員工消費合作社印製 染料4
CH, 本紙張尺度適用中固國家標準（CNS > A4規格（210X297公釐） 462980 A7 _____ B7 五、發明说明（12 ) A )染料組合物之製備
1 5克染料、1 5克聚（乙二醇）（平均分子量400)、7.5克分 散劑（以芳基磺酸和甲醛之縮合產物為基礎，另含有笨甲 酸，述於US-A 5,186,846的分散劑3、（0.37克濃度為5 〇重 量％的戊二醛水溶液和〇 75克濃度為4 7重量％的四羥甲基 乙炔二脲水溶液）加水至總重為1 〇〇克並研磨成糊狀。然後 添加濃度為1 0重量％的氫氧化納溶液，將pH調整至8.5 D 然後，此混合物於球磨機中研磨，使得9 9 %的染料顆粒 小於1微米。 最終的調整中，26.7克研磨物與另外4克聚（乙二醇）（如 前述者）、〇，1克濃度為50重量％戊二醛水溶液、〇.3克濃度 為4 7重量％的四羥甲基乙炔二脲水溶液和2 0克濃度為7 0 重量％的山梨糖醇水溶液混合，加水補足1 〇0克’混合’ 遽經孔徑為1微米的篩網。
得到下列染料組合物（所列的百分比以重量計）D ---------^------1r------線 {諸先閑讀背面之注意?項再本頁) 經濟部中央標準局負工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公嫠） 462980 A7 B7 五、發明説明（13 ) 表 1 組合物編號 1 2 3 4 染料1 4% 染料2 4% 染料3 4% 染料4 4% 分散劑 2% 2% 2% 2% 聚(乙二醇） 8% 8% 8% 8% 濃度為70重量％的山梨糖醇水溶液 20% 20% 20% 20% 濃度為50重量％的戊二醛水溶液 0.5% 0.5% 0.5% 0.5% 濃度為4重量％的四羥甲基乙炔水溶液 1.0% 1.0% 1.0°/ 1.0% 去離子水 64.5% 64.5% 64.5°/c 64.5% 總量 100 % 100 % 100 °/( 100 % (請先閲讀背面之注意事項再本頁) 經濟部中央標準局員工消費合作社印裝 B)此染料組合物的物性和印刷性質如下a 表2 組合物編號 1 2 3 4 PH 9.1 7.9 8.9 8.5 表面張力[牛頓米/米] 54.9 58.1 50.8 56.0 黏度[平方毫米/秒] 2.76 2.58 3.22 3.11 粒徑分佈[微米]X 50 0.32 ^ 0.33 0.46 0.42 老化程度a)之後的粒徑分佈[微米]X 50 0.55 0.32 0.45 0,37 老化程度b)之後的粒徑分佈[微米]X 50 0.35 0.36 0.48 0.35 滴落重量(1000萬滴)[毫微克]最小/最大 94/101 93/110 85/95 80/105 分散率 99.4% 100% 99.5% 99.2% -16- 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 經濟部中央標準局員工消費合作社印¾ „ 29 8 0 A7 _______________B7 立、發明説明（μ ) 試驗方法及評估結果 1 )表面張力 使用Kruss销售的數位式張力計K1〇測定表面張力。表2 所列的值是三次測量的平均值。 2) 黏度 以Ubbelohde法測定黏度。
3) pH 使用Knick销售的pH meter 763測定pH。 4) 粒徑分佈 使用Alcatel銷售的CILAS粒徑測定器HR 850測定粒徑分 伟。 5 )老化安定性 以兩個方法檢測組合物（墨水）的老化安定性： a)對墨水進行熱處理（於6 〇 °C下3天的溫和儲存方 式）， b )對墨水進行冷凍/加熱試驗（於2 〇 t /凍結4小時，繼 而於7 0 °C加熱4小時）。此程序共重覆4次。 在每個老化程序之後，粒子大小分佈係以CIL AS方法再 測定。 6)凝結試驗 一 印刷期間内，墨水在喷嘴上的行為特別重要。以下面 的方法測試墨水結塊而造成喷嘴阻塞的趨勢。 試驗用的印表機是改良型的Hewlett-Packard Desk Jet -17- 本紙張尺度遑用中國國家標準（CNS ) M規格（2丨0X297公釐） ---------¾.------II------0 (請先閲讀背面之注項再^本頁) A7 462980 __B7 ____ 五、發明説明（15 )
Plus (喷墨印表機）。 首先，測定在喷嘴上的施用量與平均滴落重量之間的 關係。然後，使用一定的施用量（每個喷嘴供墨一百萬 次之後，再度測定一定滴落次數之後的平均滴落量。 此程序共重覆1 0次。 理想上，在此試驗期間内，墨水的平均滴落量應維持 不變。 各種墨水之滴落量的改變列於表2。 7)分散率 1 00毫升試驗用的墨水於室溫下儲存於有刻度的量筒中 達7天。10毫升分散液由量筒底部引入，另10毫升分 散液由表面引入，以光測量方式測定這些樣品中的每 一者的染色強度。 分散率是分散液頂層的染色強度除以分散液底層的染 色強度乘以100所得的值。 C )於各種紙上形成喷墨印品： a) 影印紙 b) Claire Fontaine紙 c) Premium光澤紙（Hewlett-Packard) d) 噴墨紙（Zweckform) e) 經特別塗覆的紙（Epson) 亦於以下列方式塗覆的紙上印行印刷試驗： 使用1 2微米塗佈刀，影印紙經聚（乙缔醇）在體積比為 20:45 :20的甲苯/ 丁酮/環己酮混合物中形成之濃度為1 〇重 -18- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ---------神各------II----- (請先閱讀背面之注意事項再f本頁) 經濟部中央標準局員工消費合作社印策 462980 A7 I__________B7 五、發明説明（π ) 量/。的洛液塗覆，然後，使用丨2微米塗佈刀，以乙基羥基 乙基纖維素於體積比為8:2的曱苯乙醇混合物中形成之濃 度為D重量％的溶液塗覆，最後再使用2 *微米塗佈刀以濃 度為5重量％的羧甲基纖維素水溶液塗覆。 此處组合物1至4以水稀釋至兩倍體積之後，形成印 品。乾燥24小時之後，所得的印品顯現良好的耐磨損性、 良好的耐水性和良好的光牢度。 /此印品經熱處理⑴，3〇秒），其染色強度顯著提 咼，會顯現明亮感。此外，耐磨損性和 且染色均句度較佳。在紙上，這些結 ---------^------ir------▲ ·* (諳先閱讀背面之注意事項再填本頁) 經濟部中央標準局I工消費合作社印掣 本紙浪尺度適用中國國家標準（<：?'!5)八4規格（210/297公楚）
Claims (1)
- 462980A8 B8 C8 D8 462980 六、申請專利範圍 基、Ci-C4烷氧基、鹵素或硝基取代的苯基；. L2和L3分別代表氫、CrCw燒基（未經取代或經笨基或 C|-C4^基表基取代）、C|-C1G燒基硫（未經取代或 經苯基取代）、鹵素 '氰基、羥基苯基、Ci_C4^ 戰基冬基、Ci-Cg〗元酿基、Ci_C6燒乳幾基或如下 的基團 G1其中 G1代表氧或硫，而 G2代表氫或Ci-C2—燒基項酿胺基，其燒基鍵 被1或2個在醚官能基中的氧原子所中斷， L4代表胺基（其未經取代或經C「C4烷基、苯基或C| (：4 燒基苯基取代）、經基或C ] - C i 〇挽基硫（其未經取代或 經苯基取代）。 6‘根據申請專利範圍第1項之染料組合物，其中含有式j ί 表示的@昆§大染料本紙張又度適用中國國家標準(CNS) Α4規格(210 X 297公釐) 46298 0 A8 B8 C8 D8六、申請專利範圍 其中，x代表氫、氯或溴。 7. 根據申請專利範圍第1項之染料組合物，其係作為喷墨 印刷法中之墨水。 8. 根據申請專利範圍第1項之染料組合物，其係作為轉印 法中之墨水。 9. 根據申請專利範圍第1或2項之染料組合物，其進而包括 水0 -3- 本纸張尺度適用中國國家標竿(CNS) Α4規格（210X297公#) 裝 η 線 462980
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19622485A DE19622485A1 (de) | 1996-06-05 | 1996-06-05 | Farbstoffzubereitungen |
| DE19647600A DE19647600A1 (de) | 1996-11-18 | 1996-11-18 | Farbstoffzubereitungen |
| DE19650251A DE19650251A1 (de) | 1996-12-04 | 1996-12-04 | Farbstoffzubereitungen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW462980B true TW462980B (en) | 2001-11-11 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW086107742A TW462980B (en) | 1996-06-05 | 1997-06-05 | Dye compositions comprising anthraquinones and/or quinophthalones |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6117224A (zh) |
| EP (1) | EP0912638B1 (zh) |
| JP (1) | JP3986561B2 (zh) |
| AU (1) | AU3168597A (zh) |
| DE (1) | DE59707873D1 (zh) |
| TW (1) | TW462980B (zh) |
| WO (1) | WO1997046623A1 (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8053493B2 (en) | 2005-03-16 | 2011-11-08 | Lg Chem, Ltd. | Pixel-to-barrier-unevenness-controllable ink |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5972082A (en) * | 1996-04-30 | 1999-10-26 | Ricoh Company, Ltd. | Aqueous ink composition and ink-jet printing method using the same |
| DE19752333A1 (de) * | 1997-11-26 | 1999-05-27 | Basf Ag | Farbstoffzubereitungen |
| JP4118563B2 (ja) | 1999-08-13 | 2008-07-16 | ビーエーエスエフ ソシエタス・ヨーロピア | 着色剤調製物 |
| WO2001059019A1 (en) * | 2000-02-10 | 2001-08-16 | Mitsui Chemicals, Inc. | Anthraquinone compound and water-based ink-jet recording ink containing the compound |
| DE10030780A1 (de) * | 2000-06-29 | 2002-01-10 | Basf Ag | Kristallisationsmodifikation auf der Basis von Chinophthalonderivaten |
| US6844276B2 (en) * | 2001-03-22 | 2005-01-18 | Milliken & Company | Dyed microfiber textiles |
| GB0130316D0 (en) * | 2001-12-19 | 2002-02-06 | Clariant Int Ltd | Composition for printing recording materials |
| DE10246209A1 (de) * | 2002-10-04 | 2004-04-15 | Basf Ag | Farbstoffzubereitungen |
| DE10338142A1 (de) * | 2003-08-15 | 2005-03-17 | Basf Ag | Farbmittelzubereitungen |
| GB0517750D0 (en) * | 2005-09-01 | 2005-10-12 | Proteckta Steel Ltd | Marking application method |
| JP2009057416A (ja) * | 2007-08-30 | 2009-03-19 | Konica Minolta Ij Technologies Inc | ダイレクト昇華型インクジェット用インク組成物およびその記録方法 |
| WO2016144782A1 (en) * | 2015-03-10 | 2016-09-15 | Cargill, Incorporated | Stable and homogenous anthraquinone compositions and preparations thereof |
| US20230115193A1 (en) * | 2020-03-18 | 2023-04-13 | Dai Nippon Printing Co., Ltd. | Thermal transfer sheet and method for producing printed matter |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3660008A (en) * | 1968-04-25 | 1972-05-02 | Du Pont | Dyeing sulfonated anionic polymeric fibers with an aqueous dispersion of a salt of a cationic dye and an arylsulfonate |
| US3765835A (en) * | 1968-04-25 | 1973-10-16 | Du Pont | Anionic dispersion of a salt of a cationic dye and a selected arylsulfonate |
| US4110073A (en) * | 1971-09-10 | 1978-08-29 | Ciba-Geigy Ag | Fluid and stable dispersions of anionic dyestuffs |
| GB1527396A (en) * | 1975-07-25 | 1978-10-04 | Sublistatic Holding Sa | Transfer print carriers and their manufacture |
| DE2947005C2 (de) * | 1979-11-22 | 1983-08-04 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Acetylen aus Kohlenwasserstoffen |
| US4427413A (en) * | 1981-12-24 | 1984-01-24 | Ciba-Geigy A.G. | Dye mixture, and its use in transfer printing |
| JPS61148275A (ja) * | 1984-12-20 | 1986-07-05 | Mitsubishi Chem Ind Ltd | インクジエツト捺染用インク |
| JPS6211780A (ja) * | 1985-07-09 | 1987-01-20 | Mitsubishi Chem Ind Ltd | インクジエツト捺染用インク |
| DE4018873A1 (de) * | 1990-06-13 | 1991-12-19 | Basf Ag | Verwendung von kondensaten auf basis von arylsulfonsaeuren und formaldehyd als dispergiermittel |
| JPH05255626A (ja) * | 1992-03-11 | 1993-10-05 | Kanebo Ltd | インクジェット捺染用インク |
| DE69427068T2 (de) * | 1993-11-30 | 2001-10-25 | Seiren Co. Ltd., Fukui | Tinte für Tintenstrahlfärbung und Verfahren zur Herstellung von Mischfarben |
-
1997
- 1997-05-28 EP EP97927058A patent/EP0912638B1/de not_active Expired - Lifetime
- 1997-05-28 WO PCT/EP1997/002759 patent/WO1997046623A1/de not_active Ceased
- 1997-05-28 US US09/147,329 patent/US6117224A/en not_active Expired - Fee Related
- 1997-05-28 DE DE59707873T patent/DE59707873D1/de not_active Expired - Fee Related
- 1997-05-28 AU AU31685/97A patent/AU3168597A/en not_active Abandoned
- 1997-05-28 JP JP50019498A patent/JP3986561B2/ja not_active Expired - Lifetime
- 1997-06-05 TW TW086107742A patent/TW462980B/zh not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8053493B2 (en) | 2005-03-16 | 2011-11-08 | Lg Chem, Ltd. | Pixel-to-barrier-unevenness-controllable ink |
Also Published As
| Publication number | Publication date |
|---|---|
| US6117224A (en) | 2000-09-12 |
| AU3168597A (en) | 1998-01-05 |
| DE59707873D1 (de) | 2002-09-05 |
| EP0912638A1 (de) | 1999-05-06 |
| EP0912638B1 (de) | 2002-07-31 |
| JP2000511954A (ja) | 2000-09-12 |
| JP3986561B2 (ja) | 2007-10-03 |
| WO1997046623A1 (de) | 1997-12-11 |
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