TWI338024B - Fire-resistant coating materials - Google Patents

Fire-resistant coating materials Download PDF

Info

Publication number
TWI338024B
TWI338024B TW95148148A TW95148148A TWI338024B TW I338024 B TWI338024 B TW I338024B TW 95148148 A TW95148148 A TW 95148148A TW 95148148 A TW95148148 A TW 95148148A TW I338024 B TWI338024 B TW I338024B
Authority
TW
Taiwan
Prior art keywords
scope
coating
fire
fireproof
organic
Prior art date
Application number
TW95148148A
Other languages
English (en)
Other versions
TW200724619A (en
Inventor
Chih Ming Hu
Yung Hsing Huang
Che I Kao
Original Assignee
Ind Tech Res Inst
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ind Tech Res Inst filed Critical Ind Tech Res Inst
Priority to TW95148148A priority Critical patent/TWI338024B/zh
Priority to FI20070483A priority patent/FI126518B/fi
Publication of TW200724619A publication Critical patent/TW200724619A/zh
Application granted granted Critical
Publication of TWI338024B publication Critical patent/TWI338024B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29—Protection against damage caused by extremes of temperature or by flame
    • H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/02—Acids; Metal salts or ammonium salts thereof, e.g. maleic acid or itaconic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/83—Chemically modified polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/83—Chemically modified polymers
    • C08G18/831—Chemically modified polymers by oxygen-containing compounds inclusive of carbonic acid halogenides, carboxylic acid halogenides and epoxy halides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1405—Polycondensates modified by chemical after-treatment with inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/26—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D135/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least another carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/14—Macromolecular materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B17/00—Insulators or insulating bodies characterised by their form
    • H01B17/56—Insulating bodies
    • H01B17/66—Joining insulating bodies together, e.g. by bonding
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/302—Polyurethanes or polythiourethanes; Polyurea or polythiourea
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/303—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups H01B3/38 or H01B3/302
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/40—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes epoxy resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/447—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from acrylic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29—Protection against damage caused by extremes of temperature or by flame
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/14—Layer or component removable to expose adhesive
    • Y10T428/1405—Capsule or particulate matter containing [e.g., sphere, flake, microballoon, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31547—Of polyisocyanurate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Insulated Conductors (AREA)
  • Laminated Bodies (AREA)
  • Fireproofing Substances (AREA)
  • Inorganic Insulating Materials (AREA)
  • Paper (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Building Environments (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)

Description

1J JW24 九、發明說明： 【發明所屬之技術領域】 別θ有^1^㈣於有機高分子7無機粉體複合材料，且特 別疋有闕於一種有機高分子/無機粉體複 【先前技術】 层，：::近t來台芎經濟成長快速，帶動營建業亦蓬勃發 部=而㈣是對於建築物消防觀念的提升。根據内政 产宣的，統5卜民國93年台灣地區總共發生6,611起火 :民國92年的8,642起與88年的18,254起均減 二目虽大的幅度’此良性現象與近來國人防火觀念提升 人建樂物防火設施的逐漸普遍使用有關。但就我國因火災 1 造成的損失來看，93年死亡人數高達160人，所造成的 =損失更高達2〇億8千592萬4千元，顯示火災所= 軸失仍相當嚴重。因此’除了建築業者需就防火逃生安 王作更有效之空間規劃外，最重要的防火對策即是防火 築材料與裳修（飾）材料的使用。在材料的選擇上，易辦 性的材料應盡量減少使用’而需使用具有防焰性及耐燃性 防火的室内建築與裝修（飾）材料，以免火源產生後燃燒 ，速擴大’造成災害一發不可收拾。而隨著建築物高度與 密度快速提升’火災產生源以及蔓延因子增加，人員^方 逃生更加不易，故所使用之防火耐燃材料其應用與使用層 面以及防火能力亦需隨之提升，現行防火耐燃材料在^ 必定不敷使用。 以現行耐燃材料而言，主要可分為難燃與防火材料兩 0424-A2l260CIPTWF(N2V.P54950061TW. esmond 1338024 燃材料，主要以難燃性高分子 樹脂、難燃性高分子塑材、難燃 $ 4。難燃性南分子材料組成與製備多以難辦 與易燃之高分子主體進行摻混，以製備具 4…性的向分子材料’例如美國專利6’284,343、 遍，〇8與/，〇34,423 ’以及日本專利2005133027、 0319349等。此種材料以添加之難燃劑來改變高分子材 ^的燃燒現象，是需要加入麵合劑或界面活性劑來增加分 散效果，局分子與無機粉體難_本身是無鍵結的，因此 材料本身雖不易燃燒，但在火焰與熱量的影響下會產生炫 =m㈣等現象’故此難_性並不足以提供防火 此力’亦即無法保護其他易燃物質在有火焰與熱量下不被 引燃並且有效的延緩火焰蔓延。而以防火材料而言，主要 !用，有防火塗料與防火月板(包括防火片、防火板 寻）。目前防火塗料’例如中華名國專利442,549、499，彻 與419,514以及美國專利5,723,5】5、5,356,568、日本專利 綱4315812、8253710等防火塗料，都是使用大量的發泡 ^奴化釗、難燃劑與黏著劑，在燃燒時促進材料碳化與 發泡膨脹，制用此—具#孔洞蓬鬆的破化膨脹層作為主 要防火的機制’阻隔火焰並延緩熱量傳遞至易燃物質。此 種防火機制在火災初期火焰與熱量較小的情況下，能夠提 供二定的防火效能，但火災中期火騎熱量較大時，碳化 層邊易產生龜裂、剝落或裂解的現象，導致防火效能降低。 【發明内容】 0424-A21260CIPTWF(M2);P54950061 TW；esm〇nd 1338024 本發明的目的在於提供一種有機/無機複合防火塗 料，其具備良好的防火與崎燃特性。 為達上述與其他目的，本發明係選用較易於加工處理 . 的有機成分，包括有機高分子、單體、寡聚合物、預聚合 , 物或共聚合物作為主體材料，將無機粉體材料均勻地分散 於有機成分中並進行反應，形成有機/無機複合材料，以無 機粉體材料補強並改變其有機高分子之機械性質與燃燒特 性，使其在火焰或熱量的作用下，有機/無機複合材料除了 φ 具有難燃性質之外亦能維持埘燃、防焰與阻燃等防火能 力，能夠有效的保護其他易燃材料。本發明之防火塗料主 要包括一有機/無機複合材料，其包含一有機成分，具有第 一反應性官能基，該有機成分包括：有機高分子、單體、 寡聚合物、預聚合物或共聚合物；及一無機粉體，具有第 二反應性官能基；其中該有機成分與該無機粉體經由該第 一與第二反應性官能基形成化學鍵結。 為讓本發明之上述和其他目的、特徵、和優點能更明 • 顯易懂，下文特舉出較佳實施例，並配合所附圖式，作詳 細說明如下： 【實施方式】 本發明利用本身具有反應性官能基，或能夠經由表面 處理、改質後具備表面官能基的無機粉體材料與添加物， 與有機高分子、單體、募聚合物、預聚合物或共聚合物之 反應性官能基產生反應，並且使其均勻地分散於有機成分 系統中，並依照所使用有機成分系統的不同搭配適當的連 0424-A21260CIPTWF(N2)；P5495005lTW：esmond 8 1338024 續相，形成有機/無機複合防火塗料。一般而言，有機成分 之含量可在10-90wt%之間，無機粉體之含量可在90-10wt% 之間；在較佳實施例中，有機成分含量為30-70wt%，無機 • 粉體含量為70-30wt% ;在更佳實施例中，有機成分含量為 40-60wt%，無機粉體含量為60-40wto/〇。 本發明之防火塗料為漿料形態（slurry form)，其中之有 機成分可為有機高分子、單體、寡聚合物、預聚合物或共 聚合物，而固化後的塗膜，其有機成分可能為寡聚合物 φ (oligomer)、共聚合物(copolymer)或有機高分子(polymer)。 本發明中所稱之”寡聚合物”係指數量平均分子量約200至 1499 Daltons之化合物，而”共聚合物”與”有機高分子”係指 數量平均分子量約1500至大於〗，00,000 Daltons之化合物。 有機成分與無機粉體之反應性官能基包括，但不限 於：-OH、-COOH、-NCO、-NH3、-NH2、-NH、環氧基等。 舉例而言，可選擇具有-COOH或-NCO官能基之有機成分 (如有機酸系化合物或反應型聚氨酯）與具有-Ο Η官能基之 • 無機粉體（如金屬氫氧化物）反應。亦可選擇具有環氧基 (epoxy)之有機成分與表面具有-ΝΗ2官能基之無機粉體反 應。反之，亦可選擇具有-ΟΗ官能基之有機成分（如聚乙烯 醇)與具有-COOH或-NCO官能基之無機粉體反應，或者選 擇具有-ΝΗ2官能基之有機成分與具有環氧基（epoxy)之無 機粉體反應。 本發明之有機成分包括任何具有上述反應性官能基之 募聚物、單聚合物、或共聚合物，且反應性官能基可位於 0424-A21260CIPTWF(N2)：P54950061TW；esmond 9

Claims (1)

1338024 第 95148148 號 、申請專利範圍： 修正日，期:99.9.16 修正本 1·一種防火塗料，包括： 有機/無機複合材料，其包含： 有機成分，具有異氰酸g旨基包括·聚氨酉旨 (polyurethane)系高分子、共聚合物、單體、寡聚合物或預 聚合物；及 一金屬氫氧化物粉體，具有羥基； 其中該有機成分之異氰酸酯基與該金屬氫氧化物粉體 之經基反應形成共價鍵。 2,如申請專利範圍第1項所述之防火塗料，其中該有 機/無機複合材料中該有機成分含量為1〇·90重量％ ，該無 機粉體含量為9〇_ι〇重量％。 3·如申請專利範圍帛1項所述之防火塗料’其中該有 合材料巾該有機成分含㈣3()·70重量％，該無 機叔體含量為7〇_3〇 .重量％。 4,，申5月專利範圍第！項所述之防火塗料’其中該金 物包括氫氧化㉝（ai(〇h)3)或氫氧化鎂 或有5機t容申^專利範圍1^1項所述之防火塗料，更包括水 水二申項所述之防火塗料’更包括: 7.如申請專：圍：劑、界面活性劑、或前述之組合。 機溶劑、顏料項所述之时塗料，更包括有 、曰机平劑、硬化劑、或前述之組合。 22 1338024 第 93] 48148 號 修JL 日期:99,9.16 8. 如申請專利範圍第〗項所述之防火塗料 阻燃劑、矽烷、矽氧烷、玻璃砂、或玻璃纖維t 9. 如申請專利範圍第丨項所述之防火塗料 室内用防火塗料。 1〇‘如申請專利範圍第1項所述之防火塗料 鋼構用防火塗料。 π·如申請專利範圍第丨項所述之防火塗料： 電線電纜用防火塗料。 12.如申請專利範圍第】項所述之防火塗料， 發泡材料用防火塗料。 ^ 13·如申請專利範圍第丨項所述之防火塗料， 父通工具内易燃材料用防火塗料。 14.如申請專利範圍第丨項所述之防火塗料， 1〇〇(M20〇°C之高溫超過3分鐘。 修正本 更包括： 其係作為 其係作為 其係作為 其係作為 其係作為 其可承受
23
TW95148148A 2005-12-26 2006-12-21 Fire-resistant coating materials TWI338024B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
TW95148148A TWI338024B (en) 2005-12-26 2006-12-21 Fire-resistant coating materials
FI20070483A FI126518B (fi) 2006-12-21 2007-06-18 Palonkestoinen päällystysmateriaali

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TW94146503 2005-12-26
TW95148148A TWI338024B (en) 2005-12-26 2006-12-21 Fire-resistant coating materials

Publications (2)

Publication Number Publication Date
TW200724619A TW200724619A (en) 2007-07-01
TWI338024B true TWI338024B (en) 2011-03-01

Family

ID=37759006

Family Applications (3)

Application Number Title Priority Date Filing Date
TW95148148A TWI338024B (en) 2005-12-26 2006-12-21 Fire-resistant coating materials
TW95148153A TWI333496B (en) 2005-12-26 2006-12-21 Organic/inorganic composite and fire-resistant plate containing the same
TW95148155A TWI343060B (en) 2005-12-26 2006-12-21 Fire-resistant wire/cable

Family Applications After (2)

Application Number Title Priority Date Filing Date
TW95148153A TWI333496B (en) 2005-12-26 2006-12-21 Organic/inorganic composite and fire-resistant plate containing the same
TW95148155A TWI343060B (en) 2005-12-26 2006-12-21 Fire-resistant wire/cable

Country Status (5)

Country Link
US (3) US20070149675A1 (zh)
JP (3) JP4810418B2 (zh)
DE (3) DE102006062147A1 (zh)
GB (3) GB2433742B (zh)
TW (3) TWI338024B (zh)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI331625B (en) 2007-12-04 2010-10-11 Ind Tech Res Inst Fire resistant material and formulation thereof
US8330045B2 (en) * 2005-12-26 2012-12-11 Industrial Technology Research Institute Fire-resistant wire/cable
US20070149675A1 (en) * 2005-12-26 2007-06-28 Industrial Technology Research Institute Organic polymer/inorganic particles composite materials
TWI357436B (en) * 2007-08-31 2012-02-01 Ind Tech Res Inst Multilayer fire-resistant material
JP5371777B2 (ja) * 2007-01-24 2013-12-18 ビーエーエスエフ ソシエタス・ヨーロピア 研磨表面を有するフレキシブルな平面状基材
TWI330651B (en) * 2007-12-04 2010-09-21 Ind Tech Res Inst Modified inorganic particles and methods of preparing the same
US20110130080A1 (en) * 2008-07-24 2011-06-02 Basf Se Flexible, flat substrate with an abrasive surface
JP5507561B2 (ja) 2008-08-15 2014-05-28 オーチス エレベータ カンパニー ポリマジャケット材料中に難燃剤を有するコードおよびポリマジャケットアセンブリ
DE102008059770A1 (de) 2008-12-01 2010-06-02 Felix Schoeller Jr. Foto- Und Spezialpapiere Gmbh & Co. Kg Verbundwerkstoff, Verfahren zur Herstellung eines Formkörpers und Verwendung des Verbundwerkstoffs
US9217731B2 (en) 2010-05-21 2015-12-22 Kabushiki Kaisha Toshiba Welding inspection method and apparatus thereof
US20110284508A1 (en) * 2010-05-21 2011-11-24 Kabushiki Kaisha Toshiba Welding system and welding method
TW201210145A (en) * 2010-08-25 2012-03-01 zhi-yang Xu Flame retardant and fire extinguishing structure of objects
TWI401345B (zh) * 2010-08-31 2013-07-11 San Wu Textile Co Ltd 芯線製造方法
TW201226363A (en) * 2010-12-28 2012-07-01 Sunward Refractories Co Ltd Silicon sol guniting material for main runner of blast furnace
DE102011006731A1 (de) * 2011-04-04 2012-10-04 Endress + Hauser Flowtec Ag Verfahren zur Herstellung eines Kunststoffs für eine Auskleidung eines Messrohrs eines Durchflussmessgeräts
TWI499648B (zh) * 2012-11-08 2015-09-11 阻燃塗料及阻燃基材
CN103864156B (zh) * 2012-12-13 2015-08-05 北京市太阳能研究所集团有限公司 一种氧化镍复合薄膜的制备方法及制备得到的薄膜
CN103911866B (zh) * 2013-01-08 2016-03-09 聚森股份有限公司 阻燃涂料及阻燃织物
TWI504734B (zh) 2013-12-31 2015-10-21 Ind Tech Res Inst 防火耐燃複合材料、板材與塗層
US9710496B2 (en) 2014-01-09 2017-07-18 International Business Machines Corporation Determining the schema of a graph dataset
TWI506085B (zh) 2014-12-31 2015-11-01 Ind Tech Res Inst 樹脂組合物與應用其之塗料
CN104762009B (zh) * 2015-04-08 2017-03-01 浙江大学 纳米改性聚氨酯阻燃防水涂料及其制备方法
CN108586796B (zh) * 2018-04-10 2021-05-11 李光俊 一种二维材料增强eps的a2级防火保温板的制备方法
CN108659694B (zh) * 2018-06-15 2020-10-23 惠州学院 一种聚氨酯木器漆
CN109112881A (zh) * 2018-09-03 2019-01-01 安庆市航海印务有限公司 一种纸质制品印刷用阻燃涂料
CN109504240B (zh) * 2018-12-01 2021-04-13 杭州赛宝化工有限公司 一种高附着薄涂溶剂型环氧树脂漆以及制备方法
CN111347157B (zh) * 2018-12-21 2023-04-28 松下知识产权经营株式会社 激光焊接装置以及激光焊接方法
CN109705702A (zh) * 2018-12-29 2019-05-03 武汉博奇玉宇环保股份有限公司 一种阻燃性玻璃鳞片的制备工艺
TWI736989B (zh) * 2019-09-26 2021-08-21 國立勤益科技大學 防火隔熱材料的製造方法
KR102335042B1 (ko) * 2019-12-27 2021-12-03 (주)비엠피이 내화학성 고온용 단열도료 조성물
US11361964B2 (en) * 2020-05-14 2022-06-14 The Boeing Company Fabricating a silicon carbide and nitride structures on a carrier substrate
CN111572140A (zh) * 2020-06-18 2020-08-25 苏州法思特新材料有限公司 一种防火耐火结构
JP7420013B2 (ja) * 2020-08-25 2024-01-23 株式会社プロテリアル 多心ケーブル
CN111961377A (zh) * 2020-08-26 2020-11-20 三棵树涂料股份有限公司 一种水性高抗裂仿石艺术涂料及其制备方法
CN114057977B (zh) * 2021-12-14 2023-02-24 安徽誉林新材料科技有限公司 一种叉车用低升热高强度聚氨酯轮胎
CN119371627B (zh) * 2024-11-19 2025-07-04 广州声博士声学技术有限公司 一种基于二氧化硅的吸声材料、制备方法及其应用
CN119320552B (zh) * 2024-12-13 2025-04-04 浙江光大普特通讯科技股份有限公司 一种采用自修复性聚氨酯材料的机器人关节动态线缆及其制备方法

Family Cites Families (72)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE237758C (de) * 1909-07-31 1911-09-05 Gesellschaft Fuer Elektrisches Licht Mbh Elektische bogenlampe mit nebeneinander angeordneten elektroden
BE758347A (fr) * 1970-03-17 1971-05-03 Universal Propulsion Cy Materiau thermo-isolant
JPS5122799A (zh) * 1974-08-16 1976-02-23 Toyo Rubber Chemical Ind Co
DE2646763C2 (de) 1976-10-16 1983-03-31 Krone Gmbh, 1000 Berlin Verfahren zum Herstellen einer gieß- oder preßbaren Kunststoff-Formmasse
US4150207A (en) * 1977-06-13 1979-04-17 Basf Wyandotte Corporation Alumina trihydrate as flame retardant agent for urethane-modified carbodiimide-isocyanurate foams
US4376840A (en) * 1979-10-24 1983-03-15 Mitsubishi Denki Kabushiki Kaisha Flame retardant liquid rubber composition
JPS5792037A (en) 1980-11-29 1982-06-08 Fujikura Ltd Flame-retardant composition
DD237758A3 (de) 1982-05-13 1986-07-30 Adw Ddr Verfahren zur herstellung von polyurethanen
JPS5942779A (ja) 1982-08-31 1984-03-09 Toshiba Battery Co Ltd アルカリ電池の製造方法
DE3501762A1 (de) 1985-01-21 1986-07-24 Elastogran GmbH, 2844 Lemförde Flammwidrige, thermoplastische polyurethan-elastomere, verfahren zu deren herstellung und deren verwendung
JPS61272222A (ja) 1985-05-28 1986-12-02 Mitsubishi Electric Corp 液状ゴム組成物
JPH0768353B2 (ja) 1986-02-28 1995-07-26 株式会社中戸研究所内 複合材料の製造方法
GB8806497D0 (en) * 1988-03-18 1988-04-20 Mortile Acoustic Ind Ltd Non-toxic fire retardant thermoplastic material
US4876291A (en) * 1988-08-24 1989-10-24 J.M. Huber Corporation Mineral filler fire retardant composition and method
JPH02202907A (ja) * 1989-02-02 1990-08-13 Nippon Zeon Co Ltd ウレタン組成物
JPH02210717A (ja) 1989-02-09 1990-08-22 Nissei Denki Kk 難燃性ケーブル
JPH0455454A (ja) 1990-06-25 1992-02-24 Mitsubishi Petrochem Co Ltd 熱硬化性ポリアクリル酸組成物
JPH04202587A (ja) * 1990-11-30 1992-07-23 Taoka Chem Co Ltd 強化プラスチック用接着剤組成物
US5418272A (en) * 1991-12-10 1995-05-23 Nippon Petrochemicals Company, Limited Abrasion-resistant flame-retardant composition
JP3280099B2 (ja) 1991-12-10 2002-04-30 日本石油化学株式会社 耐摩耗性難燃組成物
FR2713565B1 (fr) 1993-12-13 1996-01-19 Gec Alsthom Transport Sa Système d'alimentation multicourant à haute disponibilité pour engin de locomotive ferroviaire.
JPH08113682A (ja) 1994-10-14 1996-05-07 Sumitomo Bakelite Co Ltd 難燃ポリプロピレンシート
US5670748A (en) 1995-02-15 1997-09-23 Alphagary Corporation Flame retardant and smoke suppressant composite electrical insulation, insulated electrical conductors and jacketed plenum cable formed therefrom
JP3261016B2 (ja) * 1995-08-25 2002-02-25 三菱電線工業株式会社 ポリウレタン樹脂組成物及びそれを用いてなる耐火性シーリング材
US5723515A (en) * 1995-12-29 1998-03-03 No Fire Technologies, Inc. Intumescent fire-retardant composition for high temperature and long duration protection
JPH09204824A (ja) 1996-01-29 1997-08-05 Hitachi Cable Ltd 耐火ケーブル
ES2132980T3 (es) * 1996-02-14 1999-08-16 Sika Ag Sistemas de poliuretano pirorretardantes.
JPH1029278A (ja) 1996-07-16 1998-02-03 Chisso Corp 難燃性積層体及びその製造方法
US5853809A (en) * 1996-09-30 1998-12-29 Basf Corporation Scratch resistant clearcoats containing suface reactive microparticles and method therefore
ATE240370T1 (de) 1996-09-30 2003-05-15 Basf Corp Kratzfeste klarlacke enthaltend oberflächig reaktive mikroteilchen und verfahren zu deren herstellung
JPH10147707A (ja) * 1996-11-18 1998-06-02 Meisei Kagaku Kogyo Kk 難燃性ポリウレタン弾性体の製造方法
JP3344918B2 (ja) 1997-03-06 2002-11-18 昭和電線電纜株式会社 難燃性ポリオレフィン組成物及び該組成物を使用した電力ケーブル
US6262161B1 (en) * 1997-06-26 2001-07-17 The Dow Chemical Company Compositions having improved ignition resistance
US6599631B2 (en) * 2001-01-26 2003-07-29 Nanogram Corporation Polymer-inorganic particle composites
JPH1180538A (ja) * 1997-09-09 1999-03-26 Sadao Kumasaka 無機不燃性エラストマー
ATE246716T1 (de) 1997-09-11 2003-08-15 Clariant Gmbh Tropenfeste intumeszenz-beschichtung
AU5134998A (en) 1997-11-21 1999-06-15 Commer S.P.A. A process of producing fire resistant thermoplastic compositions and compositions thus obtained
DE19811790A1 (de) * 1998-03-18 1999-09-23 Bayer Ag Nanopartikel enthaltende transparente Lackbindemittel mit verbesserter Verkratzungsbeständigkeit, ein Verfahren zur Herstellung sowie deren Verwendung
JP3784538B2 (ja) 1998-03-23 2006-06-14 株式会社クラレ 難燃性樹脂組成物
JPH11306873A (ja) 1998-04-22 1999-11-05 Sumitomo Electric Ind Ltd 耐火電線・ケーブル
JP4022639B2 (ja) 1998-04-28 2007-12-19 東ソー株式会社 有機・無機ハイブリッド材料及びその製造方法
US7053145B1 (en) * 1998-08-31 2006-05-30 Riken Technos Corporation Fire-retardant resin composition and molded part using the same
TW419514B (en) 1998-12-01 2001-01-21 Internat Carbide Technology Co Flame-retarding coating formulation
DE19909387C2 (de) 1999-03-04 2001-01-25 Clariant Gmbh Brandschutzbeschichtung
JP2001002840A (ja) 1999-06-21 2001-01-09 Fujikura Ltd ノンハロゲン難燃性樹脂組成物ならびにこれを用いた介在物および難燃性電線・ケーブル
WO2001004050A1 (en) * 1999-07-13 2001-01-18 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Nanocomposite coatings
TW397885B (en) 1999-07-14 2000-07-11 Lin Deng Ke The colorful fireproof heat-insulation board material and its manufacturing method
EP1100093A3 (en) 1999-11-12 2001-07-18 Mitsubishi Cable Industries, Ltd. Flame-resistant resin composition and electric wire having a layer thereof
DE60033373T2 (de) 1999-12-23 2007-10-31 Basell Poliolefine Italia S.R.L. Flammgeschützte polyolefinzusammensetzungen
EP1215238B1 (en) 2000-12-12 2005-07-06 Sumitomo Wiring Systems, Ltd. Fire resistant resin composition and electrical wire having a covering formed of the composition
JP3669920B2 (ja) 2000-12-12 2005-07-13 住友電装株式会社 被覆電線
EP1215685A1 (en) 2000-12-12 2002-06-19 Sumitomo Wiring Systems, Ltd. Electrical wire having a covering of a resin composition
US20020108772A1 (en) * 2000-12-12 2002-08-15 Sumitomo Wiring Systems, Ltd. Electrical wire having resin composition covering
JP4050480B2 (ja) 2001-04-10 2008-02-20 矢崎総業株式会社 絶縁電線
JP3821213B2 (ja) 2001-04-26 2006-09-13 日立電線株式会社 ノンハロゲン難燃電線・ケーブル
EP1457523B1 (en) 2001-05-16 2008-09-17 Shin-Etsu Chemical Co., Ltd. Flame-retardant resin composition free from halogen
TW583078B (en) 2001-06-21 2004-04-11 R-Dung Huang Fireproof material and its manufacturing method
JP2003096306A (ja) 2001-09-20 2003-04-03 Fujikura Ltd 難燃性樹脂組成物
US6960388B2 (en) 2002-09-13 2005-11-01 Gerald Hallissy Electrical distribution system components with fire resistant insulative coating
TWI322176B (en) 2002-10-17 2010-03-21 Polymers Australia Pty Ltd Fire resistant compositions
GB0229810D0 (en) 2002-12-20 2003-01-29 Vantico Ag Flame retardant polymer compositions
JP2004254407A (ja) * 2003-02-19 2004-09-09 Asahi Fiber Glass Co Ltd 防炎保護シートおよびその製造方法
US7456235B2 (en) * 2003-04-30 2008-11-25 Henkel Corporation Flame-retardant composition for coating powders
JP4744108B2 (ja) 2003-07-30 2011-08-10 セラスター塗料株式会社 無機粒子を含むコーティング組成物
JP4311727B2 (ja) 2003-12-04 2009-08-12 株式会社オートネットワーク技術研究所 非架橋型難燃性樹脂組成物ならびにこれを用いた絶縁電線およびワイヤーハーネス
JP2005213480A (ja) 2004-02-02 2005-08-11 Nippon Polyethylene Kk 難燃性樹脂組成物及びそれを用いた電線・ケーブル
JP2005232264A (ja) 2004-02-18 2005-09-02 Nippon Zeon Co Ltd 樹脂組成物及び樹脂組成物の製造方法
US20060014880A1 (en) * 2004-07-14 2006-01-19 Qiping Zhong Nano-talc polymer composites
TWI263628B (en) 2004-10-20 2006-10-11 Ind Tech Res Inst Synthesis of polyurethane/clay nanocomposites
US20070149675A1 (en) * 2005-12-26 2007-06-28 Industrial Technology Research Institute Organic polymer/inorganic particles composite materials
US8330045B2 (en) * 2005-12-26 2012-12-11 Industrial Technology Research Institute Fire-resistant wire/cable
JP4744351B2 (ja) 2006-04-28 2011-08-10 富士通株式会社 無線送信局及び無線受信局

Also Published As

Publication number Publication date
GB2433742A (en) 2007-07-04
JP2007191711A (ja) 2007-08-02
JP2007197704A (ja) 2007-08-09
JP4440915B2 (ja) 2010-03-24
GB2433742B (en) 2010-09-08
GB2433741B (en) 2010-08-18
TW200725649A (en) 2007-07-01
TWI343060B (en) 2011-06-01
US20070149675A1 (en) 2007-06-28
GB2433741A (en) 2007-07-04
JP4810418B2 (ja) 2011-11-09
DE102006062148A1 (de) 2007-08-16
GB0625852D0 (en) 2007-02-07
TW200724552A (en) 2007-07-01
US8329819B2 (en) 2012-12-11
US20070149676A1 (en) 2007-06-28
US20070179235A1 (en) 2007-08-02
US8329820B2 (en) 2012-12-11
JP5199570B2 (ja) 2013-05-15
DE102006062147A1 (de) 2007-11-15
GB0625855D0 (en) 2007-02-07
DE102006062148B4 (de) 2011-09-29
GB2433831A (en) 2007-07-04
TW200724619A (en) 2007-07-01
TWI333496B (en) 2010-11-21
DE102006062146B4 (de) 2017-03-30
GB0625854D0 (en) 2007-02-07
DE102006062146A1 (de) 2008-04-03
GB2433831B (en) 2010-09-08
JP2007214113A (ja) 2007-08-23

Similar Documents

Publication Publication Date Title
TWI338024B (en) Fire-resistant coating materials
CN101248124B (zh) 具有阻燃和疏油/疏水性能的开孔泡沫及其生产方法
Zhang et al. A self-healing, recyclable, and degradable fire-retardant gelatin-based biogel coating for green buildings
JPH0242785B2 (zh)
JP2735201B2 (ja) 軽量防音、断熱、耐火材料およびその製造方法
Mastalska-Popławska et al. Applications of hydrogels with fire retardant properties—a review
US7828995B2 (en) Composition for a fire-protection agent for materials and fire-protection method
CN105694648B (zh) 耐烃类防火防爆涂料
CN107216693A (zh) 无机膨胀防火涂料及制备方法
KR20090116042A (ko) 발포성 내화도료 조성물 및 이를 이용한 건축물에 내화성부여 방법
CN104692758A (zh) 一种抑烟型室外阻燃钢结构防火涂料
JP3218359B2 (ja) 発泡耐火性積層体とその形成方法
WO2020077334A1 (en) Intumescent polyacrylic acid compositions
TW201400548A (zh) 防火聚胺酯材料及防火結構
KR101437636B1 (ko) 수성 세라믹 불연도료 조성물의 제조방법
KR20230071263A (ko) 불연성 내화 도료 조성물 및 그 조성물 키트
KR20230090651A (ko) 소화전 및 소방 안전구역용 1000도 불연내화기능을 갖는 기능성 접착 코팅제의 제조 방법
CN101519563B (zh) 溴碳丙烯酸隧道防火涂料及其制备方法
KR101769145B1 (ko) 난연 코팅제 조성물 및 이를 이용한 가연성 소재의 난연 처리방법
CN101397500B (zh) 多层结构防火材料
TW201335344A (zh) 無機防火組合物、防火材料及其形成方法
Xiang et al. Multi-scale synergistic flame-retardant composite aerogel with low thermal conductivity and mechanical robustness for passive fire protection in high-rise buildings
Wang et al. Preparation and study of fireproof materials with high‐waterproof performance
FI86738C (fi) Aktivbrandskyddsmedel
WO2017184023A1 (ru) Автономное средство пожаротушения