Classifications

• • H—ELECTRICITY
  • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
  • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
  • H05B3/00—Ohmic-resistance heating
  • H05B3/20—Heating elements having extended surface area substantially in a two-dimensional [2D] plane, e.g. plate-heater
  • H05B3/22—Heating elements having extended surface area substantially in a two-dimensional [2D] plane, e.g. plate-heater non-flexible
  • H05B3/28—Heating elements having extended surface area substantially in a two-dimensional [2D] plane, e.g. plate-heater non-flexible heating conductor embedded in insulating material
  • H05B3/30—Heating elements having extended surface area substantially in a two-dimensional [2D] plane, e.g. plate-heater non-flexible heating conductor embedded in insulating material on or between metallic plates
• • H—ELECTRICITY
  • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
  • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
  • H05B3/00—Ohmic-resistance heating
  • H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
  • H05B3/18—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor the conductor being embedded in an insulating material

Definitions

• the present invention relates to heating elements consisting of a composite system of metal substrate, a base layer of electrically insulating glass applied to the substrate, metal conductors and a chemically resistant covering layer of glass.
• Panel heating elements based on enamelled steel sheet are known per se. Electric resistances in the form of heating lacquers or pastes containing metal or metallic conductive strips are applied to the enamelling. Conventional enamelling to serve as electric insulator has the disadvantage that the volume resistance decreases with increasing temperature. In addition, the operational safety of enamelled panels is liable to be adversely affected by blisters, pores or weak points resulting from the manufacturing process.
• the conductive heating tracks are protected against contact, for example by the application of foam plastics or by means of metal grids but such panel heating elements nevertheless fail to conform to safety regulations in some countries. Moreover, the heating power is limited since the surface temperature must be limited to about 100° C. for constructional reasons. These disadvantages may be overcome by using novel heating elements which are resistant to temperature changes.
• the present invention relates to a panel heating element consisting of a metal substrate coated with an insulating glass and metallic resistance tracks applied to the substrate, characterised in that the insulating glass is a calcium-aluminium-boron-silicate glass and that an additional layer consisting of a mixture of zirconium phosphate glass and a boron-titanium enamel is placed above the metallic resistance tracks.
• the insulating glass is a calcium-aluminium-boron-silicate glass and that an additional layer consisting of a mixture of zirconium phosphate glass and a boron-titanium enamel is placed above the metallic resistance tracks.
• the layer of insulating glass consists of an alkali-free calcium-aluminium-boron-silicate glass (29 to 34% by weight CaO, 7 to 10% by weight Al 2 O 3 , 43 to 48% by weight B 2 O 3 , 8 to 15% by weight SiO 2 , 1 to 2% by weight MgO).
• the insulating glass After it has been fired on steel substrates, it can be subjected to temperatures up to 400° C. without suffering any significant loss in electric volume resistance. In contrast to conventional enamelling, which has an irregular bubble structure, which is almost impossible to control, the insulating glass is distinguished in its fired condition by a uniform, fine, statistically distributed bubble structure.
• the insulating glass according to the invention may be applied to a cold rolled sheet coated with conventional base enamel or it may be applied directly to decarbonized steel sheet.
• decarbonized steel steel substrates of decarbonized steel are found to be particularly suitable.
• This decarbonized steel is degreased in the manner normally employed for direct white enamelling and intensively pickled with acid and nickel plated (see, e.g., A. H. Dietzel, Emailltechnik, Springer Verlag 1981, pages 214 et seq).
• a clay-free slip of insulating glass is applied by immersion or spraying to the steel panels which have been treated as described above, and while the layer of slip is still wet the metallic heating conductor is placed on it, care being taken not to include air, and the components are dried together and fired in the usual manner at 820° to 840° C.
• the covering layer of enamel tends to crack and peel off even when the heating elements produced as described above are heated only to about 300° C. and subsequently cooled in air.
• the resistance to temperature changes of the composition of an insulating glass, a heating conductor and a covering layer may be substantially improved by using a combination of a glass which is rich in zirconium phosphate and contains Ba 2 Zr 2 Si 3 O 12 crystals with a titanium white enamel with TiO 2 recrystallization.
• the composite system may be heated to 400° C. and subsequently sprayed with cold water without showing any signs of damage in the form of cracks or peeling.
• Suitable zirconium phosphate glasses may have approximately the following composition:
• a zirconium phosphate glass component having the following oxidic composition was found to be particularly suitable:
• the proportion of zirconium phosphate glass in the mixture with commercial titanium white enamel is about 35 to 55% by weight, preferably more than 45% by weight.
• Titanium white enamels are well known, conventional types of enamel (see, e.g., A. I. Andrews, Porcelain Enamels, page 277).
• the panel heating elements according to the invention may be used for the following purposes: Heating elements for space heating, integrated heating elements for heating water, for cooking utensils and water heaters, and heating elements for toasters and for warming plates.
• the insulating glass slip is applied by spray gun to both sides of steel sheets 1 mm in thickness measuring 100 ⁇ 100 mm, the amount applied being calculated so that the fired layer on one side will have a thickness of 180 ⁇ m and on the other side a thickness of about 70 ⁇ m.
• the application on both sides prevents distortion.
• the metallic heating conductor is applied to the thick coated side, avoiding air bubbles, while the latter is still moist and the whole assembly is dried and stoved at 820° C. for 6 minutes.
• a mixture of 15.6 g of quartz powder, 19.5 g of sodium tripolyphosphate, 1.8 g of potassium carbonate, 7.5 g of titanium dioxide, 20.5 g of zirconium silicate, 18.7 g of monobarium phosphate, 10.9 g of monopotassium phosphate and 9.7 g of potassium silicofluoride was melted at 1400° C. in a fireclay crucible for 25 minutes, the temperature was lowered to 1250° C. for 10 minutes and the mixture was then quenched in water, The resulting granules together with a commercial titanium white enamel were ground to a slip with the following mill formula in a ball mill:

Landscapes

• Glass Compositions (AREA)
• Resistance Heating (AREA)
• Surface Heating Bodies (AREA)

Applications Claiming Priority (2)

Publications (1)

Family

ID=6283330

Family Applications (1)

Country Status (7)

Cited By (22)

Families Citing this family (9)

Citations (11)

Family Cites Families (3)

• 1985
  • 1985-10-11 DE DE19853536268 patent/DE3536268A1/de not_active Withdrawn
• 1986
  • 1986-09-25 MX MX003847A patent/MX168410B/es unknown
  • 1986-09-26 US US06/912,446 patent/US4713530A/en not_active Expired - Fee Related
  • 1986-10-06 JP JP61236366A patent/JPS6293884A/ja active Pending
  • 1986-10-08 AT AT86113934T patent/ATE48057T1/de not_active IP Right Cessation
  • 1986-10-08 DE DE8686113934T patent/DE3667004D1/de not_active Expired
  • 1986-10-08 ES ES86113934T patent/ES2012041B3/es not_active Expired - Lifetime
  • 1986-10-08 EP EP86113934A patent/EP0222162B1/de not_active Expired

Patent Citations (11)

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