ZA200300246B - Heat sealable polyethylene film and method for its preparation. - Google Patents

Heat sealable polyethylene film and method for its preparation. Download PDF

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Publication number
ZA200300246B
ZA200300246B ZA200300246A ZA200300246A ZA200300246B ZA 200300246 B ZA200300246 B ZA 200300246B ZA 200300246 A ZA200300246 A ZA 200300246A ZA 200300246 A ZA200300246 A ZA 200300246A ZA 200300246 B ZA200300246 B ZA 200300246B
Authority
ZA
South Africa
Prior art keywords
copolymer composition
ethylene copolymer
tref
molecular weight
temperature
Prior art date
Application number
ZA200300246A
Other languages
English (en)
Inventor
Kalle Kallio
Jari Aeaerilae
Marete Skar
Arja Lehtinen
Original Assignee
Borealis Tech Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=9894814&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ZA200300246(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Borealis Tech Oy filed Critical Borealis Tech Oy
Publication of ZA200300246B publication Critical patent/ZA200300246B/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/327Layered products comprising a layer of synthetic resin comprising polyolefins comprising polyolefins obtained by a metallocene or single-site catalyst
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • B32B2250/242All polymers belonging to those covered by group B32B27/32
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/31Heat sealable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/412Transparent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558Impact strength, toughness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/72Density
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/70Food packaging
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/80Medical packaging
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00Polymer mixtures characterised by way of preparation
    • C08L2314/06Metallocene or single site catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2813Heat or solvent activated or sealable
    • Y10T428/2817Heat sealable
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852Adhesive compositions
    • Y10T428/2878Adhesive compositions including addition polymer from unsaturated monomer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/31909Next to second addition polymer from unsaturated monomers
    • Y10T428/31913Monoolefin polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/31938Polymer of monoethylenically unsaturated hydrocarbon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Sealing Material Composition (AREA)
  • Glass Compositions (AREA)
  • Iron Core Of Rotating Electric Machines (AREA)
ZA200300246A 2000-06-30 2003-01-09 Heat sealable polyethylene film and method for its preparation. ZA200300246B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB0016153.9A GB0016153D0 (en) 2000-06-30 2000-06-30 Process

Publications (1)

Publication Number Publication Date
ZA200300246B true ZA200300246B (en) 2004-01-21

Family

ID=9894814

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA200300246A ZA200300246B (en) 2000-06-30 2003-01-09 Heat sealable polyethylene film and method for its preparation.

Country Status (11)

Country Link
US (1) US7018710B2 (de)
EP (2) EP1623825A3 (de)
KR (1) KR100717654B1 (de)
CN (1) CN1210148C (de)
AT (1) ATE314931T1 (de)
AU (2) AU6622001A (de)
DE (1) DE60116490T2 (de)
ES (1) ES2256259T3 (de)
GB (1) GB0016153D0 (de)
WO (1) WO2002002323A1 (de)
ZA (1) ZA200300246B (de)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0217520D0 (en) 2002-07-29 2002-09-04 Borealis Tech Oy Product
EP1566265A1 (de) * 2004-02-20 2005-08-24 Flexopack S.A. Plastics Industry Styrolpolymer oder eine Mischung von Styrolpolymeren enthaltende mehrschichtige wärmeschrumpfbare Folie
EP1674490A1 (de) * 2004-12-23 2006-06-28 Borealis Technology Oy Copolymer
CN101087824B (zh) * 2005-01-12 2011-02-16 波利亚里斯技术有限公司 挤出涂覆聚乙烯
EP1902837A1 (de) * 2006-09-22 2008-03-26 Borealis Technology OY Mehrschichtfolie
DE602006009412D1 (de) * 2006-12-21 2009-11-05 Borealis Tech Oy Film
EP1961558A1 (de) * 2007-02-26 2008-08-27 Borealis Technology OY Mehrschichtige Verbundfolien
ES2624542T3 (es) * 2007-02-26 2017-07-14 Borealis Technology Oy Estructura de película multicapa
ES2354383T5 (es) 2007-08-10 2021-06-21 Borealis Tech Oy Artículo que comprende una composición de polipropileno
EP2067799A1 (de) 2007-12-05 2009-06-10 Borealis Technology OY Polymer
US8114946B2 (en) 2008-12-18 2012-02-14 Chevron Phillips Chemical Company Lp Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches
EP2354183B1 (de) 2010-01-29 2012-08-22 Borealis AG Formungszusammensetzung
PL2354184T3 (pl) 2010-01-29 2013-01-31 Borealis Ag Tłoczywo polietylenowe o ulepszonym stosunku odporność na pękanie /sztywność i ulepszone udarności
ES2581568T3 (es) 2010-09-29 2016-09-06 Dow Global Technologies Llc Un interpolímero de etileno/alfa-olefina apropiado para su uso en aplicaciones de película retráctil, y artículos formados a partir de la misma
US8907030B2 (en) 2010-09-29 2014-12-09 Dow Global Technologies Llc Ethylene/alpha-olefin interpolymer suitable for use in fiber applications, and fibers made therefrom
EP2554375B1 (de) * 2011-08-03 2014-04-09 Borealis AG Film
US9115233B2 (en) 2012-06-21 2015-08-25 Nova Chemicals (International) S.A. Ethylene copolymer compositions, film and polymerization processes
CA2798855C (en) 2012-06-21 2021-01-26 Nova Chemicals Corporation Ethylene copolymers having reverse comonomer incorporation
SG10201703271QA (en) 2012-10-09 2017-07-28 Dow Global Technologies Llc Sealant Composition
CA2800056A1 (en) 2012-12-24 2014-06-24 Nova Chemicals Corporation Polyethylene blend compositions
US9181369B2 (en) 2013-03-11 2015-11-10 Chevron Phillips Chemical Company Lp Polymer films having improved heat sealing properties
CN104703994B (zh) * 2013-09-26 2017-05-10 Lg化学株式会社 过渡金属化合物、含有所述化合物的催化剂组合物及利用所述组合物的聚合物的制备方法
CN103707595A (zh) * 2013-12-17 2014-04-09 海宁市粤海彩印有限公司 超低温热封包装复合膜制造方法
EP3286233B1 (de) 2015-04-23 2022-09-14 Univation Technologies, LLC Polyethylencopolymere mit einer bestimmten co-monomer-verteilung
JP2019517938A (ja) 2016-06-03 2019-06-27 ボレアリス エージー 多層構造体
PL3630449T3 (pl) * 2017-05-23 2025-04-28 Jfe Innovation Center Srl Metalizowane, orientowane i cienkie folie lldpe
CN111902467B (zh) 2018-02-05 2022-11-11 埃克森美孚化学专利公司 通过添加超高分子量高密度聚乙烯增强的lldpe的加工性
KR102831044B1 (ko) * 2022-05-27 2025-07-04 롯데케미칼 주식회사 이축배향 필름용 폴리에틸렌 수지 조성물
CN119613598A (zh) * 2023-09-14 2025-03-14 Dl化学株式会社 聚烯烃聚合物,聚烯烃的聚合系统和聚合方法

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CA2113627A1 (en) 1991-07-18 1993-02-18 Prasadarao Meka Heat sealed article
US5464905A (en) 1992-11-19 1995-11-07 Mitsui Petrochemical Industries, Ltd. Ethylene/α-olefin copolymer composition, graft modified ethylene/α-olefin copolymer composition, ethylene copolymer composition, and multi-stage olefin polymerization process
DE69317862T2 (de) * 1992-12-03 1998-09-17 Mitsubishi Chem Corp Harzzusammensetzung für Laminate
US5792534A (en) 1994-10-21 1998-08-11 The Dow Chemical Company Polyolefin film exhibiting heat resistivity, low hexane extractives and controlled modulus
US5770318A (en) 1995-01-13 1998-06-23 Norton Performance Plastics Corporation Thermoplastic seal and wrapping film
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Also Published As

Publication number Publication date
EP1623825A3 (de) 2008-12-03
AU2001266220B2 (en) 2004-07-22
DE60116490D1 (de) 2006-03-30
US7018710B2 (en) 2006-03-28
US20030171501A1 (en) 2003-09-11
CN1440330A (zh) 2003-09-03
DE60116490T2 (de) 2006-08-31
EP1294564A1 (de) 2003-03-26
EP1623825A2 (de) 2006-02-08
GB0016153D0 (en) 2000-08-23
KR20030034114A (ko) 2003-05-01
WO2002002323A1 (en) 2002-01-10
ATE314931T1 (de) 2006-02-15
EP1294564B1 (de) 2006-01-04
ES2256259T3 (es) 2006-07-16
CN1210148C (zh) 2005-07-13
AU6622001A (en) 2002-01-14
KR100717654B1 (ko) 2007-05-15

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