ZA200307380B - Storage stable aqueous organic peroxide emulsions. - Google Patents

Storage stable aqueous organic peroxide emulsions. Download PDF

Info

Publication number: ZA200307380B
Authority: ZA; South Africa
Prior art keywords: emulsion; organic peroxide; plasticiser; phthalate; emulsion according
Prior art date: 2001-03-23

Application number

ZA200307380A

Other languages

English (en)

Inventor

Ho O Boen

Original Assignee

Akzo Nobel Nv

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2001-03-23

Filing date

2003-09-22

Publication date

2004-07-06

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8180066&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ZA200307380(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2003-09-22 Application filed by Akzo Nobel Nv filed Critical Akzo Nobel Nv

2004-07-06 Publication of ZA200307380B publication Critical patent/ZA200307380B/en

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239000000839 emulsion Substances 0.000 title claims description 73
150000001451 organic peroxides Chemical class 0.000 title claims description 45
238000003860 storage Methods 0.000 title description 11
239000004014 plasticizer Substances 0.000 claims description 29
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 21
239000000203 mixture Substances 0.000 claims description 13
239000000084 colloidal system Substances 0.000 claims description 12
150000002148 esters Chemical class 0.000 claims description 12
229920002689 polyvinyl acetate Polymers 0.000 claims description 11
230000001681 protective effect Effects 0.000 claims description 11
239000011118 polyvinyl acetate Substances 0.000 claims description 10
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
239000007798 antifreeze agent Substances 0.000 claims description 7
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 claims description 5
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 4
239000003995 emulsifying agent Substances 0.000 claims description 4
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 4
ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 claims description 3
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 3
LGBAGUMSAPUZPU-UHFFFAOYSA-N bis(9-methyldecyl) benzene-1,2-dicarboxylate Chemical compound CC(C)CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC(C)C LGBAGUMSAPUZPU-UHFFFAOYSA-N 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
125000004185 ester group Chemical group 0.000 claims description 3
239000002736 nonionic surfactant Substances 0.000 claims description 3
125000005498 phthalate group Chemical group 0.000 claims description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 2
HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical group CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 claims description 2
239000000178 monomer Substances 0.000 claims description 2
ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 13
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
238000000034 method Methods 0.000 description 9
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
DROMNWUQASBTFM-UHFFFAOYSA-N dinonyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC DROMNWUQASBTFM-UHFFFAOYSA-N 0.000 description 6
150000002978 peroxides Chemical class 0.000 description 6
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 6
YKGYQYOQRGPFTO-UHFFFAOYSA-N bis(8-methylnonyl) hexanedioate Chemical compound CC(C)CCCCCCCOC(=O)CCCCC(=O)OCCCCCCCC(C)C YKGYQYOQRGPFTO-UHFFFAOYSA-N 0.000 description 5
238000000354 decomposition reaction Methods 0.000 description 5
238000009826 distribution Methods 0.000 description 5
230000007062 hydrolysis Effects 0.000 description 5
238000006460 hydrolysis reaction Methods 0.000 description 5
239000007788 liquid Substances 0.000 description 5
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 5
239000001913 cellulose Substances 0.000 description 4
229920002678 cellulose Polymers 0.000 description 4
-1 fatty acid esters Chemical class 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 3
239000002904 solvent Substances 0.000 description 3
239000003381 stabilizer Substances 0.000 description 3
VNJISVYSDHJQFR-UHFFFAOYSA-N tert-butyl 4,4-dimethylpentaneperoxoate Chemical compound CC(C)(C)CCC(=O)OOC(C)(C)C VNJISVYSDHJQFR-UHFFFAOYSA-N 0.000 description 3
HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 description 2
BKUSIKGSPSFQAC-RRKCRQDMSA-N 2'-deoxyinosine-5'-diphosphate Chemical compound O1[C@H](CO[P@@](O)(=O)OP(O)(O)=O)[C@@H](O)C[C@@H]1N1C(NC=NC2=O)=C2N=C1 BKUSIKGSPSFQAC-RRKCRQDMSA-N 0.000 description 2
RAWISQFSQWIXCW-UHFFFAOYSA-N 2-methylbutan-2-yl 2,2-dimethyloctaneperoxoate Chemical compound CCCCCCC(C)(C)C(=O)OOC(C)(C)CC RAWISQFSQWIXCW-UHFFFAOYSA-N 0.000 description 2
AQKYLAIZOGOPAW-UHFFFAOYSA-N 2-methylbutan-2-yl 2,2-dimethylpropaneperoxoate Chemical compound CCC(C)(C)OOC(=O)C(C)(C)C AQKYLAIZOGOPAW-UHFFFAOYSA-N 0.000 description 2
RPBWMJBZQXCSFW-UHFFFAOYSA-N 2-methylpropanoyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(=O)C(C)C RPBWMJBZQXCSFW-UHFFFAOYSA-N 0.000 description 2
KFGFVPMRLOQXNB-UHFFFAOYSA-N 3,5,5-trimethylhexanoyl 3,5,5-trimethylhexaneperoxoate Chemical compound CC(C)(C)CC(C)CC(=O)OOC(=O)CC(C)CC(C)(C)C KFGFVPMRLOQXNB-UHFFFAOYSA-N 0.000 description 2
ALKCLFLTXBBMMP-UHFFFAOYSA-N 3,7-dimethylocta-1,6-dien-3-yl hexanoate Chemical compound CCCCCC(=O)OC(C)(C=C)CCC=C(C)C ALKCLFLTXBBMMP-UHFFFAOYSA-N 0.000 description 2
241000251468 Actinopterygii Species 0.000 description 2
229920000881 Modified starch Polymers 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
229920002472 Starch Polymers 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
GOAZYYRCOLPZIS-UHFFFAOYSA-N [2-(2-ethylhexylperoxy)-4-methylpentan-2-yl] 2,2-dimethylpropaneperoxoate Chemical compound CCCCC(CC)COOC(C)(CC(C)C)OOC(=O)C(C)(C)C GOAZYYRCOLPZIS-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
238000000149 argon plasma sintering Methods 0.000 description 2
ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 2
GLYJVQDYLFAUFC-UHFFFAOYSA-N butyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCC GLYJVQDYLFAUFC-UHFFFAOYSA-N 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
YCZJVRCZIPDYHH-UHFFFAOYSA-N ditridecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCC YCZJVRCZIPDYHH-UHFFFAOYSA-N 0.000 description 2
238000009472 formulation Methods 0.000 description 2
235000019426 modified starch Nutrition 0.000 description 2
239000012188 paraffin wax Substances 0.000 description 2
150000004978 peroxycarbonates Chemical class 0.000 description 2
235000021317 phosphate Nutrition 0.000 description 2
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000008107 starch Substances 0.000 description 2
235000019698 starch Nutrition 0.000 description 2
239000000725 suspension Substances 0.000 description 2
BRNLBFSWJWJCPQ-UHFFFAOYSA-N (2-hydroperoxy-4-methylpentan-2-yl) 2,2-dimethylpropaneperoxoate Chemical compound CC(C)CC(C)(OO)OOC(=O)C(C)(C)C BRNLBFSWJWJCPQ-UHFFFAOYSA-N 0.000 description 1
QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
RLPSARLYTKXVSE-UHFFFAOYSA-N 1-(1,3-thiazol-5-yl)ethanamine Chemical compound CC(N)C1=CN=CS1 RLPSARLYTKXVSE-UHFFFAOYSA-N 0.000 description 1
MUOYRBYBTJDAOT-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-yl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)CC(C)(C)OOC(=O)C(C)(C)C MUOYRBYBTJDAOT-UHFFFAOYSA-N 0.000 description 1
ZACVGCNKGYYQHA-UHFFFAOYSA-N 2-ethylhexoxycarbonyloxy 2-ethylhexyl carbonate Chemical compound CCCCC(CC)COC(=O)OOC(=O)OCC(CC)CCCC ZACVGCNKGYYQHA-UHFFFAOYSA-N 0.000 description 1
IFXDUNDBQDXPQZ-UHFFFAOYSA-N 2-methylbutan-2-yl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)CC IFXDUNDBQDXPQZ-UHFFFAOYSA-N 0.000 description 1
WTBPWOVBWKJVPF-UHFFFAOYSA-N 3-(2-ethylhexylperoxymethyl)heptane Chemical compound CCCCC(CC)COOCC(CC)CCCC WTBPWOVBWKJVPF-UHFFFAOYSA-N 0.000 description 1
AMEMLELAMQEAIA-UHFFFAOYSA-N 6-(tert-butyl)thieno[3,2-d]pyrimidin-4(3H)-one Chemical compound N1C=NC(=O)C2=C1C=C(C(C)(C)C)S2 AMEMLELAMQEAIA-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
239000004604 Blowing Agent Substances 0.000 description 1
NDKYEUQMPZIGFN-UHFFFAOYSA-N Butyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCC NDKYEUQMPZIGFN-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical class OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 1
JHJSICJSIOGNMW-UHFFFAOYSA-N [2-(2,2-dimethylpropanoylperoxy)-4-methylpentan-2-yl] 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(CC(C)C)OOC(=O)C(C)(C)C JHJSICJSIOGNMW-UHFFFAOYSA-N 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
239000002280 amphoteric surfactant Substances 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
150000001558 benzoic acid derivatives Chemical class 0.000 description 1
239000003139 biocide Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
SGWHIVHMTJJAGX-UHFFFAOYSA-N bis(10-methylundecyl) benzene-1,2-dicarboxylate Chemical compound CC(C)CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCC(C)C SGWHIVHMTJJAGX-UHFFFAOYSA-N 0.000 description 1
BCSGAWBQJHXXSE-UHFFFAOYSA-N bis(11-methyldodecyl) benzene-1,2-dicarboxylate Chemical compound CC(C)CCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCC(C)C BCSGAWBQJHXXSE-UHFFFAOYSA-N 0.000 description 1
NSGQRLUGQNBHLD-UHFFFAOYSA-N butan-2-yl butan-2-yloxycarbonyloxy carbonate Chemical compound CCC(C)OC(=O)OOC(=O)OC(C)CC NSGQRLUGQNBHLD-UHFFFAOYSA-N 0.000 description 1
ZGPBOPXFOJBLIV-UHFFFAOYSA-N butoxycarbonyloxy butyl carbonate Chemical compound CCCCOC(=O)OOC(=O)OCCCC ZGPBOPXFOJBLIV-UHFFFAOYSA-N 0.000 description 1
ZRNCNTSXSYXHOW-UHFFFAOYSA-N butyl decanoate Chemical compound CCCCCCCCCC(=O)OCCCC ZRNCNTSXSYXHOW-UHFFFAOYSA-N 0.000 description 1
DHAZIUXMHRHVMP-UHFFFAOYSA-N butyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCC DHAZIUXMHRHVMP-UHFFFAOYSA-N 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
PBAYDYUZOSNJGU-UHFFFAOYSA-N chelidonic acid Natural products OC(=O)C1=CC(=O)C=C(C(O)=O)O1 PBAYDYUZOSNJGU-UHFFFAOYSA-N 0.000 description 1
239000007979 citrate buffer Substances 0.000 description 1
150000001860 citric acid derivatives Chemical class 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
239000012933 diacyl peroxide Substances 0.000 description 1
ZFTFAPZRGNKQPU-UHFFFAOYSA-N dicarbonic acid Chemical compound OC(=O)OC(O)=O ZFTFAPZRGNKQPU-UHFFFAOYSA-N 0.000 description 1
HCQHIEGYGGJLJU-UHFFFAOYSA-N didecyl hexanedioate Chemical compound CCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCC HCQHIEGYGGJLJU-UHFFFAOYSA-N 0.000 description 1
PUFGCEQWYLJYNJ-UHFFFAOYSA-N didodecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCC PUFGCEQWYLJYNJ-UHFFFAOYSA-N 0.000 description 1
GHKVUVOPHDYRJC-UHFFFAOYSA-N didodecyl hexanedioate Chemical compound CCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCC GHKVUVOPHDYRJC-UHFFFAOYSA-N 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
WKXCGJKBBBBNPF-UHFFFAOYSA-N dihexadecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCCCCC WKXCGJKBBBBNPF-UHFFFAOYSA-N 0.000 description 1
MQKMBXOZOISLIV-UHFFFAOYSA-N dioctadecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCCCCCCC MQKMBXOZOISLIV-UHFFFAOYSA-N 0.000 description 1
GYFBKUFUJKHFLZ-UHFFFAOYSA-N dioctadecyl hexanedioate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCCCCCCCC GYFBKUFUJKHFLZ-UHFFFAOYSA-N 0.000 description 1
VBZDYERVMPSZPG-UHFFFAOYSA-N dipentadecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCCCC VBZDYERVMPSZPG-UHFFFAOYSA-N 0.000 description 1
OHRKDLWUOVWNLM-UHFFFAOYSA-N dipentadecyl hexanedioate Chemical compound CCCCCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCCCCC OHRKDLWUOVWNLM-UHFFFAOYSA-N 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
DISZQMPRUTYNJL-UHFFFAOYSA-N ditetradecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCCC DISZQMPRUTYNJL-UHFFFAOYSA-N 0.000 description 1
QZQPCVVMCYMSFX-UHFFFAOYSA-N ditetradecyl hexanedioate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCCCC QZQPCVVMCYMSFX-UHFFFAOYSA-N 0.000 description 1
QQVHEQUEHCEAKS-UHFFFAOYSA-N diundecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCC QQVHEQUEHCEAKS-UHFFFAOYSA-N 0.000 description 1
POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000004945 emulsification Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000000417 fungicide Substances 0.000 description 1
230000009036 growth inhibition Effects 0.000 description 1
231100001261 hazardous Toxicity 0.000 description 1
IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
150000002432 hydroperoxides Chemical class 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229940033357 isopropyl laurate Drugs 0.000 description 1
229940070765 laurate Drugs 0.000 description 1
239000000463 material Substances 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
239000003002 pH adjusting agent Substances 0.000 description 1
125000005634 peroxydicarbonate group Chemical group 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000008363 phosphate buffer Substances 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
239000010734 process oil Substances 0.000 description 1
OVFMRFMJVFDSAA-UHFFFAOYSA-N propyl decanoate Chemical compound CCCCCCCCCC(=O)OCCC OVFMRFMJVFDSAA-UHFFFAOYSA-N 0.000 description 1
BTAXGNQLYFDKEF-UHFFFAOYSA-N propyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCC BTAXGNQLYFDKEF-UHFFFAOYSA-N 0.000 description 1
DPBVJRXPSXTHOL-UHFFFAOYSA-N propyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCC DPBVJRXPSXTHOL-UHFFFAOYSA-N 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical class OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 1
239000003352 sequestering agent Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
WYKYCHHWIJXDAO-UHFFFAOYSA-N tert-butyl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)C WYKYCHHWIJXDAO-UHFFFAOYSA-N 0.000 description 1
PFBLRDXPNUJYJM-UHFFFAOYSA-N tert-butyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(C)(C)C PFBLRDXPNUJYJM-UHFFFAOYSA-N 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
229950011008 tetrachloroethylene Drugs 0.000 description 1
125000005591 trimellitate group Chemical group 0.000 description 1
229920006337 unsaturated polyester resin Polymers 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
- C07C407/003—Separation; Purification; Stabilisation; Use of additives
- C07C407/006—Stabilisation; Use of additives
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Polymerisation Methods In General (AREA)
Detergent Compositions (AREA)

ZA200307380A 2001-03-23 2003-09-22 Storage stable aqueous organic peroxide emulsions. ZA200307380B (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
EP01201118		2001-03-23

Publications (1)

Publication Number	Publication Date
ZA200307380B true ZA200307380B (en)	2004-07-06

Family

ID=8180066

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ZA200307380A ZA200307380B (en)	2001-03-23	2003-09-22	Storage stable aqueous organic peroxide emulsions.

Country Status (20)

Country	Link
US (1)	US7214329B2 (de)
EP (1)	EP1373198B2 (de)
JP (1)	JP2004528436A (de)
KR (1)	KR100823447B1 (de)
CN (1)	CN1219762C (de)
AT (1)	ATE393142T1 (de)
BR (1)	BR0208184A (de)
CA (1)	CA2441583A1 (de)
CZ (1)	CZ20032571A3 (de)
DE (1)	DE60226219T3 (de)
HU (1)	HU229629B1 (de)
IL (1)	IL158049A0 (de)
MA (1)	MA26010A1 (de)
MX (1)	MXPA03008566A (de)
NO (1)	NO20034210D0 (de)
PL (1)	PL363747A1 (de)
RU (1)	RU2285011C2 (de)
SK (1)	SK11772003A3 (de)
WO (1)	WO2002076936A1 (de)
ZA (1)	ZA200307380B (de)

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US7988883B2 (en) *	2006-02-10	2011-08-02	Dupont Tate & Lyle Bio Products Company, Llc	Heat transfer compositions comprising renewably-based biodegradable 1,3-propanediol
SG177701A1 (en) *	2009-08-06	2012-02-28	Akzo Nobel Chemicals Int Bv	Storage stable and safe peroxide emulsions with a high active oxygen content
EP2508507A1 (de) *	2011-04-07	2012-10-10	LANXESS Deutschland GmbH	Acylierte Glycerolverbindungen und deren Verwendung als Stabilisatoren bzw. Phlegmatisierungsmittel für Peroxide und Peroxidformulierungen
EP2861688B1 (de) *	2012-06-15	2019-04-24	Arkema, Inc.	Peroxiddispersionen
FR2995906B1 (fr) *	2012-09-21	2015-02-20	Arkema France	Composition d'emulsion aqueuse de peroxyde organique
KR102120091B1 (ko) *	2016-03-18	2020-06-09	누리온 케미칼즈 인터내셔널 비.브이.	저장 안정한 수성 유기 퍼옥사이드 에멀젼
DE102019110214A1 (de)	2019-04-17	2020-10-22	Pergan Hilfsstoffe für industrielle Prozesse GmbH	Organische Peroxidemulsion, Verfahren zu deren Herstellung und deren Verwendung
US20230167054A1 (en) *	2020-05-20	2023-06-01	Arkema France	Di-sec-butyl peroxydicarbonate emulsion
EP4541788A1 (de) *	2023-10-20	2025-04-23	Nouryon Chemicals International B.V.	Kontinuierliche herstellung von wässrigen emulsionen organischer peroxide
EP4545573A1 (de) *	2023-10-20	2025-04-30	Nouryon Chemicals International B.V.	Wässrige organische peroxidemulsionen
CN119977862B (zh) *	2025-04-16	2025-07-18	兰州助剂厂股份有限公司	一种低温稳定型有机过氧化物乳液及其安全制备方法

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US2437420A (en) *	1944-02-25	1948-03-09	Prophylactic Brush Co	Vulcanizable copolymers of a vinyl aryl compound, butadiene, and vinyl ethers
DE1595428A1 (de) *	1965-07-10	1970-03-12	Chisso Corp	Verfahren zur Herstellung von Polyvinylchlorid mit innerer Weichmachung
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US3535422A (en) *	1968-03-11	1970-10-20	Stiefel Laboratories	Stable benzoyl peroxide composition
DE1922171C3 (de)	1969-04-30	1979-03-01	Peroxid-Chemie Gmbh, 8021 Hoellriegelskreuth	Verfahren zur Herstellung einer Peroxidpaste
JPS546263B1 (de)	1970-07-17	1979-03-27
US4255277A (en) *	1979-01-29	1981-03-10	General Electric Company	Storage stable peroxide paste composition
NL8000260A (nl)	1980-01-16	1981-08-17	Akzo Nv	Waterige peroxyde emulsie en de toepassing ervan in suspensie(co-)polymerisatiereacties.
DE3164532D1 (en) *	1980-04-26	1984-08-09	Interox Chemicals Ltd	Organic peroxide compositions
JPH0635484B2 (ja) *	1985-10-14	1994-05-11	化薬アクゾ株式会社	有機過酸化物のエマルジヨン配合物
JPH021472A (ja)	1988-05-26	1990-01-05	Kayaku Akzo Kk	パーオキサイド組成物
RU2046807C1 (ru) *	1992-09-25	1995-10-27	Государственное предприятие "Капролактам"	Способ суспензионной полимеризации винилхлорида
US5690856A (en) *	1995-03-07	1997-11-25	Akzo Nobel N.V.	Solid diacyl organic peroxide dispersions
BE1009969A3 (fr)	1996-01-25	1997-11-04	Solvay	Procede pour la polymerisation en suspension aqueuse du chlorure de vinyle a l'intervention de peroxydicarbonates de dialkyle.
BE1011295A3 (fr)	1997-07-22	1999-07-06	Solvay	Solution organique de peroxydicarbonate de dialkyle, procede pour l'obtenir, preparation de polymeres halogenes a l'intervention de celle-ci et polymeres halogenes obtenus.
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2002
- 2002-02-20 IL IL15804902A patent/IL158049A0/xx unknown
- 2002-02-20 CZ CZ20032571A patent/CZ20032571A3/cs unknown
- 2002-02-20 EP EP02724174.4A patent/EP1373198B2/de not_active Expired - Lifetime
- 2002-02-20 RU RU2003131182/04A patent/RU2285011C2/ru not_active IP Right Cessation
- 2002-02-20 MX MXPA03008566A patent/MXPA03008566A/es active IP Right Grant
- 2002-02-20 US US10/468,907 patent/US7214329B2/en not_active Expired - Fee Related
- 2002-02-20 BR BR0208184-9A patent/BR0208184A/pt not_active IP Right Cessation
- 2002-02-20 AT AT02724174T patent/ATE393142T1/de not_active IP Right Cessation
- 2002-02-20 CN CNB028071034A patent/CN1219762C/zh not_active Expired - Fee Related
- 2002-02-20 WO PCT/EP2002/001812 patent/WO2002076936A1/en not_active Ceased
- 2002-02-20 KR KR1020037011878A patent/KR100823447B1/ko not_active Expired - Fee Related
- 2002-02-20 JP JP2002576198A patent/JP2004528436A/ja not_active Withdrawn
- 2002-02-20 CA CA002441583A patent/CA2441583A1/en not_active Abandoned
- 2002-02-20 PL PL02363747A patent/PL363747A1/xx not_active Application Discontinuation
- 2002-02-20 SK SK1177-2003A patent/SK11772003A3/sk unknown
- 2002-02-20 DE DE60226219.4T patent/DE60226219T3/de not_active Expired - Lifetime
- 2002-02-20 HU HU0303602A patent/HU229629B1/hu not_active IP Right Cessation
2003
- 2003-09-22 NO NO20034210A patent/NO20034210D0/no not_active Application Discontinuation
- 2003-09-22 MA MA27317A patent/MA26010A1/fr unknown
- 2003-09-22 ZA ZA200307380A patent/ZA200307380B/en unknown

Also Published As

Publication number	Publication date
HU229629B1 (en)	2014-03-28
WO2002076936A1 (en)	2002-10-03
KR100823447B1 (ko)	2008-04-17
EP1373198A1 (de)	2004-01-02
JP2004528436A (ja)	2004-09-16
HUP0303602A2 (hu)	2004-01-28
SK11772003A3 (sk)	2003-12-02
PL363747A1 (en)	2004-11-29
EP1373198B2 (de)	2015-02-25
DE60226219T2 (de)	2009-05-28
RU2003131182A (ru)	2005-02-27
MA26010A1 (fr)	2003-12-31
BR0208184A (pt)	2004-03-02
NO20034210L (no)	2003-09-22
CA2441583A1 (en)	2002-10-03
CZ20032571A3 (cs)	2004-02-18
US7214329B2 (en)	2007-05-08
CN1498207A (zh)	2004-05-19
NO20034210D0 (no)	2003-09-22
HUP0303602A3 (en)	2011-04-28
KR20030086300A (ko)	2003-11-07
MXPA03008566A (es)	2003-12-08
DE60226219T3 (de)	2015-06-18
ATE393142T1 (de)	2008-05-15
CN1219762C (zh)	2005-09-21
EP1373198B1 (de)	2008-04-23
DE60226219D1 (de)	2008-06-05
US20040132938A1 (en)	2004-07-08
RU2285011C2 (ru)	2006-10-10
WO2002076936A8 (en)	2003-11-27
IL158049A0 (en)	2004-03-28

Publication	Publication Date	Title
EP3429991B1 (de)	2020-05-06	Lagerstabile wässrige organische peroxydemulsion
EP1373198B1 (de)	2008-04-23	Lagerstabile wässrige emulsionen aus organischen peroxiden
KR100984714B1 (ko)	2010-10-01	낮은 화학적 산소 요구량 값을 가지며 안정하고 안전한 고농도의 디아실 퍼옥시드와 퍼옥시디카르보네이트 유탁액
SK284473B6 (sk)	2005-04-01	Vodná emulzia peroxyesteru a jej použitie
AU2002254899A1 (en)	2002-10-08	Storage stable aqueous organic peroxide emulsions
BRPI0208184B1 (pt)	2018-10-02	Emulsão aquosa de peróxido orgânico compreendendo um agente anticongelante, um colóide protetor e um plastificante, e uso da emulsão
EP4450527A1 (de)	2024-10-23	Methanolfreie organische peroxidemulsion
MXPA00000826A (en)	2001-11-21	Emulsions of peroxyesters