ZA200607465B - Process for purifying mesotrione - Google Patents

Process for purifying mesotrione Download PDF

Info

Publication number: ZA200607465B
Authority: ZA; South Africa
Prior art keywords: mesotrione; sample; aqueous solution; cyanide; distillation
Prior art date: 2004-03-26

Application number

ZA200607465A

Other languages

English (en)

Inventor

Benke Alan Henry

Wichert Julie Marie

Original Assignee

Syngenta Participations Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2004-03-26

Filing date

2006-09-06

Publication date

2008-05-28

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=32188804&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ZA200607465(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2006-09-06 Application filed by Syngenta Participations Ag filed Critical Syngenta Participations Ag

2008-05-28 Publication of ZA200607465B publication Critical patent/ZA200607465B/en

Links

KPUREKXXPHOJQT-UHFFFAOYSA-N mesotrione Chemical compound [O-][N+](=O)C1=CC(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O KPUREKXXPHOJQT-UHFFFAOYSA-N 0.000 title claims description 37
239000005578 Mesotrione Substances 0.000 title claims description 36
238000000034 method Methods 0.000 title claims description 27
239000007864 aqueous solution Substances 0.000 claims description 17
238000004821 distillation Methods 0.000 claims description 16
XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 14
238000002425 crystallisation Methods 0.000 claims description 12
239000003125 aqueous solvent Substances 0.000 claims description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
229910052757 nitrogen Inorganic materials 0.000 claims description 3
239000000243 solution Substances 0.000 claims description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
239000000203 mixture Substances 0.000 description 6
239000002904 solvent Substances 0.000 description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
230000005494 condensation Effects 0.000 description 4
238000006462 rearrangement reaction Methods 0.000 description 4
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
238000006482 condensation reaction Methods 0.000 description 3
238000011282 treatment Methods 0.000 description 3
SKDDBIWRHFHMKM-UHFFFAOYSA-N 4-methylsulfonyl-2-nitrobenzoyl chloride Chemical compound CS(=O)(=O)C1=CC=C(C(Cl)=O)C([N+]([O-])=O)=C1 SKDDBIWRHFHMKM-UHFFFAOYSA-N 0.000 description 2
241000196324 Embryophyta Species 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
150000002825 nitriles Chemical group 0.000 description 2
238000010926 purge Methods 0.000 description 2
230000008707 rearrangement Effects 0.000 description 2
238000004448 titration Methods 0.000 description 2
OXBDLEXAVKAJFD-UHFFFAOYSA-N 1-methyl-4-methylsulfonyl-2-nitrobenzene Chemical compound CC1=CC=C(S(C)(=O)=O)C=C1[N+]([O-])=O OXBDLEXAVKAJFD-UHFFFAOYSA-N 0.000 description 1
NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
MWFMGBPGAXYFAR-UHFFFAOYSA-N 2-hydroxy-2-methylpropanenitrile Chemical compound CC(C)(O)C#N MWFMGBPGAXYFAR-UHFFFAOYSA-N 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
240000008042 Zea mays Species 0.000 description 1
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
235000002017 Zea mays subsp mays Nutrition 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
238000010923 batch production Methods 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
235000005822 corn Nutrition 0.000 description 1
OILAIQUEIWYQPH-UHFFFAOYSA-N cyclohexane-1,2-dione Chemical compound O=C1CCCCC1=O OILAIQUEIWYQPH-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
-1 enol ester Chemical class 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
230000002363 herbicidal effect Effects 0.000 description 1
239000004009 herbicide Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000003021 water soluble solvent Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/24—Sulfones; Sulfoxides having sulfone or sulfoxide groups and doubly-bound oxygen atoms bound to the same carbon skeleton
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C315/00—Preparation of sulfones; Preparation of sulfoxides
- C07C315/06—Separation; Purification; Stabilisation; Use of additives
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/02—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to acyclic carbon atoms

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Preparation Of Compounds By Using Micro-Organisms (AREA)

ZA200607465A 2004-03-26 2006-09-06 Process for purifying mesotrione ZA200607465B (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GBGB0406894.6A GB0406894D0 (en)	2004-03-26	2004-03-26	Process

Publications (1)

Publication Number	Publication Date
ZA200607465B true ZA200607465B (en)	2008-05-28

Family

ID=32188804

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ZA200607465A ZA200607465B (en)	2004-03-26	2006-09-06	Process for purifying mesotrione

Country Status (29)

Country	Link
US (1)	US7863482B2 (de)
EP (1)	EP1740534B1 (de)
JP (1)	JP4690388B2 (de)
KR (1)	KR101147281B1 (de)
CN (1)	CN100475788C (de)
AR (1)	AR048040A1 (de)
AT (1)	ATE394369T1 (de)
AU (1)	AU2005225485B2 (de)
BR (1)	BRPI0509263B1 (de)
CA (1)	CA2558077C (de)
CY (1)	CY1108079T1 (de)
DE (1)	DE602005006550D1 (de)
DK (1)	DK1740534T3 (de)
ES (1)	ES2304003T3 (de)
GB (1)	GB0406894D0 (de)
GT (1)	GT200500066A (de)
HN (1)	HN2005000114A (de)
IL (1)	IL177723A (de)
MX (1)	MXPA06010765A (de)
MY (1)	MY146013A (de)
PL (1)	PL1740534T3 (de)
PT (1)	PT1740534E (de)
RU (1)	RU2373193C2 (de)
SI (1)	SI1740534T1 (de)
SV (1)	SV2006002057A (de)
TW (1)	TWI363750B (de)
UA (1)	UA83737C2 (de)
WO (1)	WO2005092846A1 (de)
ZA (1)	ZA200607465B (de)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB0419075D0 (en)	2004-08-26	2004-09-29	Syngenta Participations Ag	Process
RU2459804C2 (ru) *	2006-01-18	2012-08-27	Зингента Партисипейшнс Аг	Способ кристаллизации мезотриона
JP4124793B2 (ja) *	2006-06-09	2008-07-23	美津濃株式会社	手袋
CN102649774A (zh) *	2012-02-02	2012-08-29	北京颖泰嘉和生物科技有限公司	一种降低磺草酮中氰化物的方法
CN103588685B (zh) *	2013-10-18	2016-01-13	浙江省诸暨合力化学对外贸易有限公司	三酮类铵盐化合物及其制备方法及应用
CN104086438B (zh) *	2014-06-30	2016-07-06	浙江中山化工集团股份有限公司	一种甲基磺草酮溶剂回收工艺
GB2530838B (en)	2015-06-08	2020-01-22	Rotam Agrochem Int Co Ltd	Process for purifying mesotrione
CN110078647B (zh) *	2019-05-15	2021-04-13	北京颖泰嘉和生物科技股份有限公司	一种硝磺草酮反应产物的后处理方法
CN111440099B (zh) *	2020-04-09	2022-01-04	利民化学有限责任公司	一种环磺酮产品的纯化方法
CN112939826B (zh) *	2021-02-05	2023-04-07	浙江工业大学	利用大孔吸附树脂从反应液中提取分离硝磺草酮的方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5085688A (en) *	1982-03-25	1992-02-04	Ici Americas Inc.	Certain 2-(2-chloro-3-alkoxy-4-substituted benzoyl)-5-methyl-5-1,3-cyclohexanediones as herbicides
US4695673A (en) *	1985-11-20	1987-09-22	Stauffer Chemical Company	Process for the production of acylated 1,3-dicarbonyl compounds
JPH0219355A (ja) *	1988-07-07	1990-01-23	Nippon Soda Co Ltd	４，４，５−トリメチル−２−（２−ニトロ−４−メチルスルホニルベンゾイル）シクロヘキサン−１，３−ジオン、その製造方法及び除草剤
GB9725135D0 (en) *	1997-11-27	1998-01-28	Zeneca Ltd	Chemical process
JP3911237B2 (ja) *	2001-03-26	2007-05-09	シンジェンタリミテッド	２−ニトロ−４−メチルスルホニル安息香酸の精製
TWI348999B (en) *	2003-10-02	2011-09-21	Syngenta Participations Ag	Process

2004
- 2004-03-26 GB GBGB0406894.6A patent/GB0406894D0/en not_active Ceased
2005
- 2005-03-03 CA CA2558077A patent/CA2558077C/en not_active Expired - Lifetime
- 2005-03-03 DE DE602005006550T patent/DE602005006550D1/de not_active Expired - Lifetime
- 2005-03-03 JP JP2007504283A patent/JP4690388B2/ja not_active Expired - Lifetime
- 2005-03-03 WO PCT/EP2005/002230 patent/WO2005092846A1/en not_active Ceased
- 2005-03-03 CN CNB2005800098808A patent/CN100475788C/zh not_active Expired - Lifetime
- 2005-03-03 MX MXPA06010765A patent/MXPA06010765A/es active IP Right Grant
- 2005-03-03 EP EP05707695A patent/EP1740534B1/de not_active Expired - Lifetime
- 2005-03-03 US US10/598,993 patent/US7863482B2/en not_active Expired - Lifetime
- 2005-03-03 PT PT05707695T patent/PT1740534E/pt unknown
- 2005-03-03 PL PL05707695T patent/PL1740534T3/pl unknown
- 2005-03-03 ES ES05707695T patent/ES2304003T3/es not_active Expired - Lifetime
- 2005-03-03 DK DK05707695T patent/DK1740534T3/da active
- 2005-03-03 AT AT05707695T patent/ATE394369T1/de active
- 2005-03-03 UA UAA200611159A patent/UA83737C2/ru unknown
- 2005-03-03 AU AU2005225485A patent/AU2005225485B2/en not_active Expired
- 2005-03-03 SI SI200530277T patent/SI1740534T1/sl unknown
- 2005-03-03 RU RU2006137659/04A patent/RU2373193C2/ru active
- 2005-03-03 KR KR1020067019799A patent/KR101147281B1/ko not_active Expired - Lifetime
- 2005-03-03 BR BRPI0509263-9A patent/BRPI0509263B1/pt not_active IP Right Cessation
- 2005-03-07 TW TW094106794A patent/TWI363750B/zh not_active IP Right Cessation
- 2005-03-15 AR ARP050101005A patent/AR048040A1/es active IP Right Grant
- 2005-03-18 SV SV2005002057A patent/SV2006002057A/es unknown
- 2005-03-18 HN HN2005000114A patent/HN2005000114A/es unknown
- 2005-03-22 GT GT200500066A patent/GT200500066A/es unknown
- 2005-03-24 MY MYPI20051287A patent/MY146013A/en unknown
2006
- 2006-08-28 IL IL177723A patent/IL177723A/en active IP Right Grant
- 2006-09-06 ZA ZA200607465A patent/ZA200607465B/en unknown
2008
- 2008-05-20 CY CY20081100522T patent/CY1108079T1/el unknown

Also Published As

Publication number	Publication date
MY146013A (en)	2012-06-15
DK1740534T3 (da)	2008-10-27
EP1740534B1 (de)	2008-05-07
CN1938267A (zh)	2007-03-28
TW200533645A (en)	2005-10-16
AU2005225485B2 (en)	2010-11-18
RU2373193C2 (ru)	2009-11-20
CN100475788C (zh)	2009-04-08
PL1740534T3 (pl)	2008-07-31
ES2304003T3 (es)	2008-09-01
ATE394369T1 (de)	2008-05-15
MXPA06010765A (es)	2006-12-15
RU2006137659A (ru)	2008-05-10
SI1740534T1 (sl)	2008-08-31
IL177723A0 (en)	2006-12-31
TWI363750B (en)	2012-05-11
BRPI0509263A (pt)	2007-09-04
CY1108079T1 (el)	2014-02-12
CA2558077A1 (en)	2005-10-06
HN2005000114A (es)	2009-03-17
CA2558077C (en)	2012-11-20
PT1740534E (pt)	2008-06-20
AU2005225485A1 (en)	2005-10-06
US7863482B2 (en)	2011-01-04
WO2005092846A1 (en)	2005-10-06
AR048040A1 (es)	2006-03-22
GB0406894D0 (en)	2004-04-28
BRPI0509263B1 (pt)	2015-06-30
DE602005006550D1 (de)	2008-06-19
GT200500066A (es)	2005-10-31
JP4690388B2 (ja)	2011-06-01
IL177723A (en)	2011-04-28
KR101147281B1 (ko)	2012-05-18
UA83737C2 (ru)	2008-08-11
SV2006002057A (es)	2006-10-04
EP1740534A1 (de)	2007-01-10
KR20070010010A (ko)	2007-01-19
JP2007530468A (ja)	2007-11-01
US20080039661A1 (en)	2008-02-14

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JP4428730B2 (ja)	2010-03-10	２，５−ジヒドロフランの製造法