ATE105277T1 - Verfahren zur racemisierung von optisch aktiven 4-phenylbuttersaeureestern. - Google Patents

Verfahren zur racemisierung von optisch aktiven 4-phenylbuttersaeureestern.

Info

Publication number: ATE105277T1
Authority: AT; Austria
Prior art keywords: acid esters; optically active; racemization; phenyl; alkali metal
Prior art date: 1989-10-06

Application number

AT9090119178T

Other languages

English (en)

Inventor

Hiroyuki Nohira

Takashi Onishi

Kazuo Yamamoto

Noriaki Kumagai

Original Assignee

Kuraray Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-10-06

Filing date

1990-10-05

Publication date

1994-05-15

1990-10-05 Application filed by Kuraray Co filed Critical Kuraray Co

1994-05-15 Application granted granted Critical

1994-05-15 Publication of ATE105277T1 publication Critical patent/ATE105277T1/de

Links

230000006340 racemization Effects 0.000 title abstract 2
239000001582 butter acid Substances 0.000 title 1
150000002148 esters Chemical class 0.000 title 1
OBKXEAXTFZPCHS-UHFFFAOYSA-N 4-phenylbutyric acid Chemical class OC(=O)CCCC1=CC=CC=C1 OBKXEAXTFZPCHS-UHFFFAOYSA-N 0.000 abstract 2
229910052783 alkali metal Inorganic materials 0.000 abstract 2
125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 abstract 1
125000004423 acyloxy group Chemical group 0.000 abstract 1
-1 alkali metal amides Chemical class 0.000 abstract 1
229910000102 alkali metal hydride Inorganic materials 0.000 abstract 1
150000008046 alkali metal hydrides Chemical class 0.000 abstract 1
150000001340 alkali metals Chemical class 0.000 abstract 1
125000000217 alkyl group Chemical group 0.000 abstract 1
239000002585 base Substances 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B55/00—Racemisation; Complete or partial inversion
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

AT9090119178T 1989-10-06 1990-10-05 Verfahren zur racemisierung von optisch aktiven 4-phenylbuttersaeureestern. ATE105277T1 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
JP26251689		1989-10-06
EP90119178A EP0421472B1 (de)	1989-10-06	1990-10-05	Verfahren zur Racemisierung von optisch aktiven 4-Phenylbuttersäureestern

Publications (1)

Publication Number	Publication Date
ATE105277T1 true ATE105277T1 (de)	1994-05-15

Family

ID=17376891

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AT9090119178T ATE105277T1 (de)	1989-10-06	1990-10-05	Verfahren zur racemisierung von optisch aktiven 4-phenylbuttersaeureestern.

Country Status (6)

Country	Link
US (1)	US5066826A (de)
EP (1)	EP0421472B1 (de)
JP (1)	JP2507163B2 (de)
AT (1)	ATE105277T1 (de)
DE (1)	DE69008653T2 (de)
ES (1)	ES2056331T3 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5202457A (en) *	1990-04-12	1993-04-13	Chisso Corporation	Optically active alkyl 3-aryl-3-hydroxypropionates and a method for producing thereof
US5290955A (en) *	1991-12-29	1994-03-01	Kuraray Co., Ltd.	Process for producing L-ambrox
JPH06116217A (ja) *	1992-10-02	1994-04-26	Kuraray Co Ltd	（±）−シス−４−アミノシクロペント−２−エンカルボン酸誘導体の光学分割法
US6342636B1 (en) *	1997-11-06	2002-01-29	Yamakawa Chemical Industry Co., Ltd.	Process for preparing optically active amines and optically active carboxylic acids, and intermediates for preparation
CN101412672B (zh) *	2008-11-18	2012-05-23	浙江大学	R-2-羟基-4-苯基丁酸乙酯的化学合成方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3621835A1 (de) *	1986-06-28	1988-01-07	Hoechst Ag	Verfahren zur racemisierung optisch aktiver (alpha)-phenoxypropionsaeure und deren derivate
US4837354A (en) *	1987-02-26	1989-06-06	Merrell Dow Pharmaceuticals Inc.	Process for making and isolating (R)-2-hydroxy-4-phenylbutyric acid and esters
EP0325971A3 (de) *	1988-01-26	1990-07-25	F. Hoffmann-La Roche Ag	Verfahren zur Herstellung optisch reiner Hydroxyarylalkansäuren und -ester
US4904822A (en) *	1988-02-19	1990-02-27	Kuraray Co., Ltd.	Process for the optical resolution of (+)-2-hydroxy-4-phenylbutanoic acid
JPH0216954A (ja) *	1988-07-05	1990-01-19	Muronoki Shokuhin Kk	魚卵を主成分とするシート食品及びその製造方法
JPH0247100A (ja) *	1988-08-09	1990-02-16	Murata Kinpaku:Kk	転写箔を部分的に転写する方法
JP2817145B2 (ja) *	1988-09-17	1998-10-27	カシオ計算機株式会社	エンベロープ発生装置

1990
- 1990-09-25 JP JP2256027A patent/JP2507163B2/ja not_active Expired - Fee Related
- 1990-09-26 US US07/588,545 patent/US5066826A/en not_active Expired - Lifetime
- 1990-10-05 ES ES90119178T patent/ES2056331T3/es not_active Expired - Lifetime
- 1990-10-05 EP EP90119178A patent/EP0421472B1/de not_active Expired - Lifetime
- 1990-10-05 DE DE69008653T patent/DE69008653T2/de not_active Expired - Fee Related
- 1990-10-05 AT AT9090119178T patent/ATE105277T1/de active

Also Published As

Publication number	Publication date
DE69008653D1 (de)	1994-06-09
ES2056331T3 (es)	1994-10-01
JP2507163B2 (ja)	1996-06-12
JPH03204838A (ja)	1991-09-06
EP0421472A1 (de)	1991-04-10
DE69008653T2 (de)	1994-12-01
US5066826A (en)	1991-11-19
EP0421472B1 (de)	1994-05-04

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