ATE163018T1 - Verfahren zur herstellung von styrol-polymeren und katalysator dafür - Google Patents
Verfahren zur herstellung von styrol-polymeren und katalysator dafürInfo
- Publication number
- ATE163018T1 ATE163018T1 AT92911400T AT92911400T ATE163018T1 AT E163018 T1 ATE163018 T1 AT E163018T1 AT 92911400 T AT92911400 T AT 92911400T AT 92911400 T AT92911400 T AT 92911400T AT E163018 T1 ATE163018 T1 AT E163018T1
- Authority
- AT
- Austria
- Prior art keywords
- catalyst
- styrenic polymer
- highly syndiotactic
- styrene polymers
- syndiotactic styrenic
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 229920000642 polymer Polymers 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title 2
- 229940100198 alkylating agent Drugs 0.000 abstract 1
- 239000002168 alkylating agent Substances 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract 1
- -1 tetra(pentafluorophenyl)borate Chemical compound 0.000 abstract 1
- 150000003623 transition metal compounds Chemical class 0.000 abstract 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3139955A JPH04366109A (ja) | 1991-06-12 | 1991-06-12 | スチレン系重合体の製造方法及びその触媒 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE163018T1 true ATE163018T1 (de) | 1998-02-15 |
Family
ID=15257566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT92911400T ATE163018T1 (de) | 1991-06-12 | 1992-06-09 | Verfahren zur herstellung von styrol-polymeren und katalysator dafür |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5391661A (de) |
| EP (1) | EP0543022B1 (de) |
| JP (1) | JPH04366109A (de) |
| AT (1) | ATE163018T1 (de) |
| DE (1) | DE69224353T2 (de) |
| WO (1) | WO1992022589A1 (de) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05331228A (ja) * | 1971-11-18 | 1993-12-14 | Idemitsu Kosan Co Ltd | ポリオレフィンの製造方法 |
| US5384299A (en) * | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| EP0698619B1 (de) * | 1993-03-31 | 2001-11-07 | Idemitsu Kosan Company Limited | Katalysator zur herstellung von vinylpolymer und verfahren zur herstellung von vinylaromatischem polymer |
| JPH0733812A (ja) * | 1993-07-02 | 1995-02-03 | Idemitsu Kosan Co Ltd | スチレン系重合体製造触媒及びそれを用いたスチレン系重合体の製造方法 |
| JP3216748B2 (ja) * | 1993-07-23 | 2001-10-09 | 出光興産株式会社 | 芳香族ビニル化合物重合体組成物の製造触媒及びそれを用いた芳香族ビニル化合物重合体組成物の製造方法 |
| US5428120A (en) * | 1993-10-08 | 1995-06-27 | The Dow Chemical Company | Process for preparation of syndiotactic vinylidene aromatic polymers using chain transfer agent |
| US5594080A (en) * | 1994-03-24 | 1997-01-14 | Leland Stanford, Jr. University | Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor |
| US5721183A (en) * | 1995-03-10 | 1998-02-24 | The Dow Chemical Company | Catalyst system comprising amine or phosphine adducts of tris(organyl)borane compounds |
| DE19509785A1 (de) * | 1995-03-17 | 1996-09-19 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von vinylaromatischen Verbindungen unter Druck in Gegenwart von leicht flüchtigen Kohlenwasserstoffen |
| AU717137B2 (en) * | 1995-11-24 | 2000-03-16 | Ciba Specialty Chemicals Holding Inc. | Borate coinitiators for photopolymerization |
| US6291695B1 (en) | 1996-02-20 | 2001-09-18 | Northwestern University | Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon |
| US6274752B1 (en) | 1996-02-20 | 2001-08-14 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
| US5856256A (en) * | 1996-02-20 | 1999-01-05 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
| US5854166A (en) * | 1996-08-19 | 1998-12-29 | Northwestern University | Synthesis and use of (perfluoroaryl) fluoro-aluminate anion |
| US6262200B1 (en) | 1996-08-19 | 2001-07-17 | Northwestern University | (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon |
| US6130302A (en) * | 1996-08-19 | 2000-10-10 | Northwestern University | Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium |
| US5895771A (en) * | 1997-06-05 | 1999-04-20 | Akzo Nobel Nv | Fluorinated alkoxy and/or aryloxy aluminates as cocatalysts for metallocene-catalyzed olefin polymerizations |
| US6670299B1 (en) * | 1999-07-03 | 2003-12-30 | Northwestern University | Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts |
| US6489480B2 (en) | 1999-12-09 | 2002-12-03 | Exxonmobil Chemical Patents Inc. | Group-15 cationic compounds for olefin polymerization catalysts |
| US6822057B2 (en) | 1999-12-09 | 2004-11-23 | Exxon Mobil Chemical Patents Inc. | Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them |
| ES2249320T3 (es) * | 1999-12-09 | 2006-04-01 | Exxonmobil Chemical Patents Inc. | Cocatalizadores para la polimerizacion de olefinas derivados de compuestos cationicos del grupo 15 y procesos que los utilizan. |
| US6538081B2 (en) * | 2000-12-18 | 2003-03-25 | Univation Tech Llc | Polymerization process |
| US7759489B2 (en) * | 2006-01-27 | 2010-07-20 | Idemitsu Kosan Co., Ltd. | Transition metal complex compound and organic electroluminescence device using the compound |
| EP3719041A4 (de) * | 2017-12-01 | 2021-08-18 | Idemitsu Kosan Co.,Ltd. | Styrolharz, styrolharzzusammensetzung, formartikel daraus und styrolharzherstellungsverfahren |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3418303A (en) * | 1964-09-16 | 1968-12-24 | Du Pont | Coordination catalyst system and polymerization process |
| US3459825A (en) * | 1967-10-26 | 1969-08-05 | Sun Oil Co | Catalyst and process for dimerization of olefins |
| JP2531583B2 (ja) * | 1987-01-28 | 1996-09-04 | 出光興産株式会社 | スチレン系共重合体およびその製造方法 |
| JPS62187708A (ja) * | 1985-11-11 | 1987-08-17 | Idemitsu Kosan Co Ltd | スチレン系重合体の製造法 |
| JPH085929B2 (ja) * | 1987-01-22 | 1996-01-24 | 出光興産株式会社 | スチレン系重合体の製造法 |
| US5153157A (en) * | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| JPH075524B2 (ja) * | 1989-03-29 | 1995-01-25 | 日本ペイント株式会社 | 新規ベンジルアンモニウム塩 |
| US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| US5066741A (en) * | 1990-03-22 | 1991-11-19 | The Dow Chemical Company | Process for preparation of syndiotactic vinyl aromatic polymers |
| CA2024830A1 (en) * | 1989-09-29 | 1991-03-30 | Richard E. Campbell, Jr. | Process for preparation of syndiotactic vinyl aromatic polymers |
| US5066740A (en) * | 1989-12-26 | 1991-11-19 | The B. F. Goodrich Company | Pyridinium metathesis catalysts for cycloolefin polymerization |
| EP0481480B1 (de) * | 1990-10-17 | 1995-01-25 | Idemitsu Kosan Company Limited | Verfahren zur Herstellung von Oligomeren auf Basis von Propylen |
-
1991
- 1991-06-12 JP JP3139955A patent/JPH04366109A/ja active Pending
-
1992
- 1992-06-09 WO PCT/JP1992/000736 patent/WO1992022589A1/ja not_active Ceased
- 1992-06-09 US US07/965,290 patent/US5391661A/en not_active Expired - Fee Related
- 1992-06-09 EP EP92911400A patent/EP0543022B1/de not_active Expired - Lifetime
- 1992-06-09 DE DE69224353T patent/DE69224353T2/de not_active Expired - Fee Related
- 1992-06-09 AT AT92911400T patent/ATE163018T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| WO1992022589A1 (fr) | 1992-12-23 |
| US5391661A (en) | 1995-02-21 |
| EP0543022A1 (de) | 1993-05-26 |
| EP0543022A4 (en) | 1994-11-23 |
| DE69224353D1 (de) | 1998-03-12 |
| DE69224353T2 (de) | 1998-06-10 |
| JPH04366109A (ja) | 1992-12-18 |
| EP0543022B1 (de) | 1998-02-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |