ATE458742T1 - Verfahren zur herstellung substituierter metallocenverbindungen zur olefinpolymerisierung - Google Patents
Verfahren zur herstellung substituierter metallocenverbindungen zur olefinpolymerisierungInfo
- Publication number
- ATE458742T1 ATE458742T1 AT05853949T AT05853949T ATE458742T1 AT E458742 T1 ATE458742 T1 AT E458742T1 AT 05853949 T AT05853949 T AT 05853949T AT 05853949 T AT05853949 T AT 05853949T AT E458742 T1 ATE458742 T1 AT E458742T1
- Authority
- AT
- Austria
- Prior art keywords
- substituted
- metal atom
- olefin polymerization
- metallocene compounds
- compound
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 5
- 150000001336 alkenes Chemical class 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 abstract 2
- 229910052768 actinide Inorganic materials 0.000 abstract 1
- 150000001255 actinides Chemical class 0.000 abstract 1
- 229910052747 lanthanoid Inorganic materials 0.000 abstract 1
- 150000002602 lanthanoids Chemical class 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 125000002950 monocyclic group Chemical group 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 125000003367 polycyclic group Chemical group 0.000 abstract 1
- 150000003624 transition metals Chemical group 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/08—Heteroatom bridge, i.e. Cp or analog where the bridging atom linking the two Cps or analogs is a heteroatom different from Si
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US63666204P | 2004-12-16 | 2004-12-16 | |
| PCT/US2005/045140 WO2006065844A2 (en) | 2004-12-16 | 2005-12-14 | Process for producing substituted metallocene compounds for olefin polymerization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE458742T1 true ATE458742T1 (de) | 2010-03-15 |
Family
ID=34982508
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT05853949T ATE458742T1 (de) | 2004-12-16 | 2005-12-14 | Verfahren zur herstellung substituierter metallocenverbindungen zur olefinpolymerisierung |
Country Status (5)
| Country | Link |
|---|---|
| US (4) | US7446216B2 (de) |
| EP (3) | EP1866322B1 (de) |
| AT (1) | ATE458742T1 (de) |
| DE (1) | DE602005019629D1 (de) |
| WO (4) | WO2006065844A2 (de) |
Families Citing this family (56)
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|---|---|---|---|---|
| US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
| US20080153997A1 (en) * | 2006-12-20 | 2008-06-26 | Exxonmobil Research And Engineering | Polymer production at supercritical conditions |
| US8178636B2 (en) | 2004-05-04 | 2012-05-15 | Basell Polyolefine Gmbh | Process for the preparation of atactic 1-butene polymers |
| EP1866322B1 (de) | 2004-12-16 | 2010-02-24 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung substituierter metallocenverbindungen zur olefinpolymerisierung |
| US7803887B2 (en) * | 2005-03-18 | 2010-09-28 | Basell Polyolefine Gmbh | Metallocene compounds |
| WO2006134046A1 (en) * | 2005-06-13 | 2006-12-21 | Basell Polyolefine Gmbh | Process for the copolymerization of propylene |
| DE102005055866A1 (de) * | 2005-11-23 | 2007-05-24 | Hte Ag The High Throughput Experimentation Company | Verfahren zur Herstellung von Aryl-Aryl gekoppelter Verbindungen |
| US8242237B2 (en) * | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
| US20080287619A1 (en) * | 2007-05-18 | 2008-11-20 | William Gauthier | Supported metallocene catalysts |
| JP2010529253A (ja) | 2007-06-04 | 2010-08-26 | エクソンモービル・ケミカル・パテンツ・インク | 非常に均一なプロピレンの溶液重合法 |
| WO2009027075A2 (en) | 2007-08-27 | 2009-03-05 | Borealis Technology Oy | Catalysts |
| KR101278336B1 (ko) * | 2007-10-25 | 2013-06-25 | 루머스 노보렌 테크놀로지 게엠베하 | 안사-메탈로센 화합물의 라세모선택적 합성, 안사-메탈로센 화합물, 이를 포함하는 촉매, 그 촉매를 이용한 올레핀 폴리머 제조 공정, 그리고 올레핀 호모- 및 코폴리머 |
| EP2070953A1 (de) | 2007-12-11 | 2009-06-17 | Total Petrochemicals Research Feluy | Träger zur Aktivierung auf der Basis von Phosphoniumkomplexen |
| US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
| EP2223944A1 (de) | 2009-02-26 | 2010-09-01 | Borealis AG | Verfahren zur Herstellung von Semikristallin-Propylenpolymeren |
| US8058461B2 (en) | 2010-03-01 | 2011-11-15 | Exxonmobil Chemical Patents Inc. | Mono-indenyl transition metal compounds and polymerization therewith |
| HUE025363T2 (en) | 2010-12-01 | 2016-02-29 | Boehringer Ingelheim Int | Indanyl Oxide Hydrobenzofuranylacetic Acids that can be used to treat metabolic syndrome |
| KR101824760B1 (ko) | 2011-01-14 | 2018-02-01 | 더블유.알. 그레이스 앤드 캄파니-콘. | 개질된 메탈로센 촉매 제조 방법, 제조된 촉매 및 이의 용도 |
| KR101212637B1 (ko) | 2011-06-09 | 2012-12-14 | 에스케이종합화학 주식회사 | 신규한 사이클로펜타［ｂ］플루오레닐 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
| US8664461B2 (en) | 2012-03-19 | 2014-03-04 | Exxonmobil Chemical Patents Inc. | Catalysts for producing polyalpha-olefins and processes related thereto |
| JP6051738B2 (ja) * | 2012-03-29 | 2016-12-27 | 日本ポリエチレン株式会社 | メタロセン化合物、それを含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びにそのオレフィン重合用触媒を用いたオレフィン重合体の製造方法 |
| JP6015306B2 (ja) * | 2012-09-28 | 2016-10-26 | 日本ポリエチレン株式会社 | メタロセン化合物、それを含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びにそのオレフィン重合用触媒を用いたオレフィン重合体の製造方法 |
| WO2014070655A1 (en) * | 2012-10-31 | 2014-05-08 | Exxonmobil Chemical Patents Inc. | Supported metallocene catalyst systems and methods of preparation thereof |
| CN105358586A (zh) | 2013-07-17 | 2016-02-24 | 埃克森美孚化学专利公司 | 环丙基取代的茂金属催化剂 |
| KR101593175B1 (ko) | 2013-09-30 | 2016-02-12 | 주식회사 엘지화학 | 폴리프로필렌의 제조방법 및 이로부터 수득되는 폴리프로필렌 |
| JP6182443B2 (ja) * | 2013-12-06 | 2017-08-16 | 日本ポリエチレン株式会社 | 架橋ビスインデニル化合物の製造方法 |
| US9315526B2 (en) | 2014-03-03 | 2016-04-19 | Exxonmobil Chemical Patents Inc. | Pyridyldiamido transition metal complexes, production and use thereof |
| GB201406406D0 (en) * | 2014-04-09 | 2014-05-21 | Isis Innovation | Lactide polymerisation |
| ES2770021T3 (es) * | 2014-04-17 | 2020-06-30 | Borealis Ag | Sistema catalítico mejorado para producir copolímeros de polietileno en un proceso de polimerización en solución a alta temperatura |
| EP2933275A1 (de) * | 2014-04-17 | 2015-10-21 | Borealis AG | Neues Katalysatorsystem zur Herstellung von Polyethylen-Copolymeren in einem Hochtemperaturlösungspolymerisationsverfahren |
| JP6593178B2 (ja) * | 2015-01-30 | 2019-10-23 | 日本ポリエチレン株式会社 | メタロセン化合物、それを含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びにそのオレフィン重合用触媒を用いたオレフィン重合体の製造方法 |
| KR101910701B1 (ko) | 2015-07-02 | 2018-10-22 | 주식회사 엘지화학 | 전이금속 화합물 및 이를 포함하는 촉매 조성물 |
| EP3424937B1 (de) * | 2016-03-04 | 2020-06-10 | Japan Polyethylene Corporation | Metallocenverbindung, katalysatorkomponente für die olefinpolymerisation damit, katalysator für die olefinpolymerisation mit der metallocenverbindung und verfahren zur herstellung von olefinpolymer unter verwendung eines katalysators zur olefinpolymerisation |
| KR102117650B1 (ko) * | 2016-03-14 | 2020-06-01 | 주식회사 엘지화학 | 올레핀 중합체 및 이의 제조 방법 |
| US9803037B1 (en) | 2016-05-03 | 2017-10-31 | Exxonmobil Chemical Patents Inc. | Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof |
| WO2018132247A2 (en) * | 2017-01-13 | 2018-07-19 | Exxonmobil Chemical Patents Inc. | Bridged bis(indenyl) transitional metal complexes, production, and use thereof |
| US10807998B2 (en) | 2017-01-13 | 2020-10-20 | Exxonmobil Chemical Patents Inc. | Bridged bis(indenyl) transitional metal complexes, production, and use thereof |
| JP7248404B2 (ja) * | 2017-09-27 | 2023-03-29 | 三井化学株式会社 | 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| JP7223540B2 (ja) * | 2017-09-27 | 2023-02-16 | 三井化学株式会社 | 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| WO2019093789A1 (ko) * | 2017-11-08 | 2019-05-16 | 주식회사 엘지화학 | 부직포용 호모 폴리프로필렌 수지 및 그의 제조 방법 |
| KR102317015B1 (ko) * | 2017-11-08 | 2021-10-26 | 주식회사 엘지화학 | 부직포용 호모 폴리프로필렌 수지 및 그의 제조 방법 |
| JP2020050615A (ja) * | 2018-09-27 | 2020-04-02 | 三井化学株式会社 | 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| KR102584267B1 (ko) * | 2019-09-30 | 2023-10-05 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 및 이를 이용한 폴리에틸렌 공중합체의 제조 방법 |
| US12146020B2 (en) | 2019-09-30 | 2024-11-19 | Lg Chem, Ltd. | Hybrid supported metallocene catalyst and process for preparing polyethylene copolymer using the same |
| US11186665B2 (en) | 2019-10-04 | 2021-11-30 | Chevron Phillips Chemical Company Lp | Catalyst composition and method for preparing polyethylene |
| KR102614265B1 (ko) * | 2019-11-01 | 2023-12-19 | 주식회사 엘지화학 | 메탈로센 담지 촉매의 제조방법 및 메탈로센 담지 촉매 |
| JP7676863B2 (ja) * | 2020-03-24 | 2025-05-15 | 日本ポリプロ株式会社 | オレフィン重合用担持系触媒、及び、当該オレフィン重合用担持系触媒を用いたプロピレン系重合体の製造方法 |
| CN114702532B (zh) * | 2021-01-01 | 2024-08-06 | 中国石油化工股份有限公司 | 一种茂金属、含有其的催化剂及其合成和应用 |
| CN114702531B (zh) * | 2021-01-01 | 2024-12-06 | 中国石油化工股份有限公司 | 茂金属、含有其的催化剂及其合成和应用 |
| CN112939756B (zh) * | 2021-03-03 | 2022-07-08 | 上海鼎素精细化工有限公司 | 一种制备5-氯茚酮的改进工艺方法 |
| US11859041B2 (en) * | 2021-08-16 | 2024-01-02 | Chevron Phillips Chemical Company Lp | Modulating co-monomer selectivity using non-covalent dispersion interactions in group 4 olefin polymerization catalysts |
| CN116410238B (zh) * | 2021-12-31 | 2026-01-20 | 中国石油天然气股份有限公司 | 含硫手性桥联茂金属化合物及其制备和应用 |
| WO2023226318A1 (zh) * | 2022-05-27 | 2023-11-30 | 中国石油化工股份有限公司 | 茂金属配合物及制备方法和催化剂组合物及烯烃聚合方法和烯烃聚合物 |
| CN115232175B (zh) * | 2022-08-17 | 2024-06-14 | 山东金诚石化集团有限公司 | 一种含氟准c2对称硅桥联茂金属配合物及其应用 |
| CN119912600B (zh) * | 2023-10-31 | 2025-11-28 | 中国石油化工股份有限公司 | 烯烃聚合用催化剂载体及其制备方法与应用 |
| WO2026024944A1 (en) | 2024-07-25 | 2026-01-29 | ExxonMobil Technology and Engineering Company | Metallocene catalyst compounds for producing polyolefins |
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-
2005
- 2005-12-14 EP EP05853949A patent/EP1866322B1/de not_active Expired - Lifetime
- 2005-12-14 AT AT05853949T patent/ATE458742T1/de not_active IP Right Cessation
- 2005-12-14 WO PCT/US2005/045140 patent/WO2006065844A2/en not_active Ceased
- 2005-12-14 WO PCT/US2005/045245 patent/WO2006065906A2/en not_active Ceased
- 2005-12-14 US US11/300,054 patent/US7446216B2/en not_active Expired - Lifetime
- 2005-12-14 US US11/302,997 patent/US7709670B2/en not_active Expired - Fee Related
- 2005-12-14 WO PCT/US2005/045138 patent/WO2006065843A2/en not_active Ceased
- 2005-12-14 EP EP05849844A patent/EP1833858A2/de not_active Withdrawn
- 2005-12-14 US US11/300,032 patent/US7557171B2/en not_active Expired - Fee Related
- 2005-12-14 EP EP05853948A patent/EP1833859A2/de not_active Withdrawn
- 2005-12-14 DE DE602005019629T patent/DE602005019629D1/de not_active Expired - Lifetime
- 2005-12-14 WO PCT/US2005/045056 patent/WO2006065809A2/en not_active Ceased
-
2009
- 2009-12-17 US US12/641,123 patent/US9163046B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP1833858A2 (de) | 2007-09-19 |
| WO2006065809A3 (en) | 2006-09-28 |
| US20060160967A1 (en) | 2006-07-20 |
| WO2006065843A2 (en) | 2006-06-22 |
| EP1866322B1 (de) | 2010-02-24 |
| WO2006065906A2 (en) | 2006-06-22 |
| US7446216B2 (en) | 2008-11-04 |
| US7557171B2 (en) | 2009-07-07 |
| EP1866322A2 (de) | 2007-12-19 |
| US20100113717A1 (en) | 2010-05-06 |
| US7709670B2 (en) | 2010-05-04 |
| EP1833859A2 (de) | 2007-09-19 |
| DE602005019629D1 (de) | 2010-04-08 |
| WO2006065844A2 (en) | 2006-06-22 |
| WO2006065906A3 (en) | 2007-02-22 |
| US20060183874A1 (en) | 2006-08-17 |
| WO2006065809A2 (en) | 2006-06-22 |
| WO2006065844A3 (en) | 2007-05-18 |
| US20060160968A1 (en) | 2006-07-20 |
| WO2006065843A3 (en) | 2006-12-07 |
| US9163046B2 (en) | 2015-10-20 |
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