BE840903R - Procede de preparation d'une composition tensio-active obtenue par transesterification du saccharose avec un ou plusieurs triglycerides - Google Patents

Procede de preparation d'une composition tensio-active obtenue par transesterification du saccharose avec un ou plusieurs triglycerides

Info

Publication number: BE840903R
Authority: BE; Belgium
Prior art keywords: emi; sucrose; salt; fatty acid; metal
Prior art date: 1975-04-18

Application number

BE166281A

Other languages

English (en)

French (fr)

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-04-18

Filing date

1976-04-20

Publication date

1976-10-20

1975-04-18 Priority claimed from GB16216/75A external-priority patent/GB1500341A/en

1976-04-20 Application filed filed Critical

1976-10-20 Application granted granted Critical

1976-10-20 Publication of BE840903R publication Critical patent/BE840903R/fr

Links

229930006000 Sucrose Natural products 0.000 title claims description 31
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 title claims description 27
150000003626 triacylglycerols Chemical class 0.000 title claims description 13
239000000203 mixture Substances 0.000 title description 26
238000005809 transesterification reaction Methods 0.000 title description 6
238000004519 manufacturing process Methods 0.000 title description 2
235000013681 dietary sucrose Nutrition 0.000 title 1
229960004793 sucrose Drugs 0.000 title 1
239000007787 solid Substances 0.000 claims description 41
150000003839 salts Chemical class 0.000 claims description 33
239000005720 sucrose Substances 0.000 claims description 30
229910052751 metal Inorganic materials 0.000 claims description 28
239000002184 metal Substances 0.000 claims description 28
238000011282 treatment Methods 0.000 claims description 26
239000000126 substance Substances 0.000 claims description 22
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical group CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 21
239000000344 soap Substances 0.000 claims description 21
238000000034 method Methods 0.000 claims description 20
235000014113 dietary fatty acids Nutrition 0.000 claims description 17
239000000194 fatty acid Substances 0.000 claims description 17
229930195729 fatty acid Natural products 0.000 claims description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
150000002148 esters Chemical class 0.000 claims description 16
150000004665 fatty acids Chemical class 0.000 claims description 15
150000003445 sucroses Chemical class 0.000 claims description 14
238000000605 extraction Methods 0.000 claims description 13
239000000243 solution Substances 0.000 claims description 13
-1 fatty acid salts Chemical class 0.000 claims description 7
150000005690 diesters Chemical class 0.000 claims description 6
125000005456 glyceride group Chemical group 0.000 claims description 6
239000003960 organic solvent Substances 0.000 claims description 6
238000006243 chemical reaction Methods 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 4
238000001704 evaporation Methods 0.000 claims description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
239000007864 aqueous solution Substances 0.000 claims description 3
229910052791 calcium Inorganic materials 0.000 claims description 3
239000011575 calcium Substances 0.000 claims description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
229910052782 aluminium Inorganic materials 0.000 claims description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
229910052749 magnesium Inorganic materials 0.000 claims description 2
239000011777 magnesium Substances 0.000 claims description 2
239000002002 slurry Substances 0.000 claims description 2
229910052725 zinc Inorganic materials 0.000 claims description 2
239000011701 zinc Substances 0.000 claims description 2
159000000009 barium salts Chemical class 0.000 claims 1
238000004090 dissolution Methods 0.000 claims 1
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 24
239000000047 product Substances 0.000 description 18
239000002904 solvent Substances 0.000 description 15
239000001110 calcium chloride Substances 0.000 description 12
229910001628 calcium chloride Inorganic materials 0.000 description 12
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 11
239000004094 surface-active agent Substances 0.000 description 10
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
238000001030 gas--liquid chromatography Methods 0.000 description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
235000019482 Palm oil Nutrition 0.000 description 5
239000012043 crude product Substances 0.000 description 5
239000000706 filtrate Substances 0.000 description 5
239000007788 liquid Substances 0.000 description 5
239000002540 palm oil Substances 0.000 description 5
239000003760 tallow Substances 0.000 description 5
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
230000001476 alcoholic effect Effects 0.000 description 4
239000007795 chemical reaction product Substances 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
239000000725 suspension Substances 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 3
239000006227 byproduct Substances 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
239000012535 impurity Substances 0.000 description 3
238000000746 purification Methods 0.000 description 3
238000000638 solvent extraction Methods 0.000 description 3
UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 3
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 3
235000008733 Citrus aurantifolia Nutrition 0.000 description 2
235000011941 Tilia x europaea Nutrition 0.000 description 2
ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
238000001914 filtration Methods 0.000 description 2
235000021588 free fatty acids Nutrition 0.000 description 2
239000011521 glass Substances 0.000 description 2
239000004571 lime Substances 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
239000011780 sodium chloride Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000004246 zinc acetate Substances 0.000 description 2
239000011592 zinc chloride Substances 0.000 description 2
235000005074 zinc chloride Nutrition 0.000 description 2
HSEYYGFJBLWFGD-UHFFFAOYSA-N 4-methylsulfanyl-2-[(2-methylsulfanylpyridine-3-carbonyl)amino]butanoic acid Chemical compound CSCCC(C(O)=O)NC(=O)C1=CC=CN=C1SC HSEYYGFJBLWFGD-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
239000012267 brine Substances 0.000 description 1
VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
239000001639 calcium acetate Substances 0.000 description 1
235000011092 calcium acetate Nutrition 0.000 description 1
229960005147 calcium acetate Drugs 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
150000003841 chloride salts Chemical class 0.000 description 1
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
239000000498 cooling water Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
239000003599 detergent Substances 0.000 description 1
239000003814 drug Substances 0.000 description 1
238000004945 emulsification Methods 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
230000001804 emulsifying effect Effects 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
239000003925 fat Substances 0.000 description 1
239000012065 filter cake Substances 0.000 description 1
235000013305 food Nutrition 0.000 description 1
235000021552 granulated sugar Nutrition 0.000 description 1
150000002484 inorganic compounds Chemical class 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
229910052943 magnesium sulfate Inorganic materials 0.000 description 1
235000019341 magnesium sulphate Nutrition 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
230000020477 pH reduction Effects 0.000 description 1
239000003973 paint Substances 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
239000005060 rubber Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000006228 supernatant Substances 0.000 description 1
235000013904 zinc acetate Nutrition 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/34—Higher-molecular-weight carboxylic acid esters
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
- C07H13/02—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids
- C07H13/04—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids having the esterifying carboxyl radicals attached to acyclic carbon atoms
- C07H13/06—Fatty acids
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Organic Chemistry (AREA)
General Health & Medical Sciences (AREA)
Engineering & Computer Science (AREA)
Public Health (AREA)
Animal Behavior & Ethology (AREA)
Veterinary Medicine (AREA)
Materials Engineering (AREA)
Epidemiology (AREA)
Birds (AREA)
Dispersion Chemistry (AREA)
Biotechnology (AREA)
Molecular Biology (AREA)
Genetics & Genomics (AREA)
Biochemistry (AREA)
Dermatology (AREA)
Saccharide Compounds (AREA)
Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

BE166281A 1975-04-18 1976-04-20 Procede de preparation d'une composition tensio-active obtenue par transesterification du saccharose avec un ou plusieurs triglycerides BE840903R (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB16216/75A GB1500341A (en)	1975-02-11	1975-04-18	Purification of sucrose esters

Publications (1)

Publication Number	Publication Date
BE840903R true BE840903R (fr)	1976-10-20

Family

ID=10073287

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
BE166281A BE840903R (fr)	1975-04-18	1976-04-20	Procede de preparation d'une composition tensio-active obtenue par transesterification du saccharose avec un ou plusieurs triglycerides

Country Status (5)

Country	Link
JP (1)	JPS5951960B2 (tr)
BE (1)	BE840903R (tr)
SE (1)	SE7604387L (tr)
TR (1)	TR19384A (tr)
ZA (1)	ZA762286B (tr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS63138270U (tr) *	1987-03-03	1988-09-12

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US374824A (en) *		1887-12-13		Stock-car
US3054789A (en) *	1959-02-06	1962-09-18	Ledoga Spa	Process for the preparation of pure sucrose esters
JPS5037168A (tr) *	1973-08-08	1975-04-07
JPS5317575A (en) *	1976-08-02	1978-02-17	Hitachi Ltd	Treating method for water by use of zeolite

1976
- 1976-04-14 SE SE7604387A patent/SE7604387L/xx not_active Application Discontinuation
- 1976-04-15 ZA ZA762286A patent/ZA762286B/xx unknown
- 1976-04-19 TR TR19384A patent/TR19384A/tr unknown
- 1976-04-20 BE BE166281A patent/BE840903R/fr active
1981
- 1981-05-21 JP JP56075819A patent/JPS5951960B2/ja not_active Expired

Also Published As

Publication number	Publication date
JPS5716897A (en)	1982-01-28
JPS5951960B2 (ja)	1984-12-17
TR19384A (tr)	1979-02-20
ZA762286B (en)	1977-04-27
SE7604387L (sv)	1976-10-19

Publication	Publication Date	Title
JPH05339595A (ja)	1993-12-21	脂肪酸およびヒドロキシ脂肪酸の単離および精製方法
US4032702A (en)	1977-06-28	Production of surface active material
FR2567149A1 (fr)	1986-01-10	Procede pour l'extraction de poly-beta-hydroxybutyrates au moyen d'un solvant a partir d'une suspension aqueuse de micro-organismes
EP0377260A1 (fr)	1990-07-11	Procédé pour la préparation d'esters de l'acide bêta-hydroxybutyrique
FR2547813A1 (fr)	1984-12-28	3-(3-hydroxybutoxy)-1-butanol et sa preparation
US4104464A (en)	1978-08-01	Purification of sucrose esters
CH631151A5 (fr)	1982-07-30	Procede de preparation d'hemiacetal-esters de l'acide glyoxylique.
BE840903R (fr)	1976-10-20	Procede de preparation d'une composition tensio-active obtenue par transesterification du saccharose avec un ou plusieurs triglycerides
EP0880538B1 (fr)	2002-05-15	Procede de preparation d'agents tensioactifs
EP3560916B1 (fr)	2022-02-23	Procédé de synthèse de 5-dialkylacétal-2-furoates d'alkyle et leur utilisation dans la préparation d'agents tensioactifs biosourcés
EP0719752B1 (fr)	2008-03-12	Procédé pour l'obtention de polyglycérols et d'esters de polyglycérols
WO2001030299A2 (en)	2001-05-03	Method of synthesizing alkyl gallates
US4605430A (en)	1986-08-12	Plant growth promoter from rice bran and processes for making and using
BE834607R (fr)	1976-02-16	Procede de preparation d'une composition tensio-active obtenue par transesterification du saccharose avec un ou plusieurs iriglycerines
US2167931A (en)	1939-08-01	Purification of relatively water insoluble derivatives of fatty acids
JPS60155143A (ja)	1985-08-15	天然ロウからの脂肪族高級アルコ−ルの分離法
CA2116666A1 (en)	1993-03-18	Process to improve the color of sulf(on)ated surfactants without bleach
FR2605314A1 (fr)	1988-04-22	Procede pour la fabrication de l'acide beta-hydroxybutyrique et de ses sels par hydrolyse d'oligomeres de l'acide beta-hydroxybutyrique en milieu basique.
JP2686966B2 (ja)	1997-12-08	ショ糖脂肪酸エステル合成反応混合物中の未反応糖を粉末状として回収する方法
JPS61227543A (ja)	1986-10-09	高級アルコ−ルの分離法
WO1993002039A1 (fr)	1993-02-04	Alcoyl galactarates, leurs procedes de preparation et leurs applications
BE505352A (tr)
CH106039A (fr)	1924-08-16	Procédé pour transférer la vitamine soluble dans les corps gras (vitamine A), de la matière grasse qui la contient à ses solvants organiques.
JPS6330346B2 (tr)	1988-06-17
BE505856A (tr)