BRPI0515025A - composição de procatalisador ziegler-natta, método para preparar uma composição de procatalisador e processo para produzir um polìmero - Google Patents
composição de procatalisador ziegler-natta, método para preparar uma composição de procatalisador e processo para produzir um polìmeroInfo
- Publication number
- BRPI0515025A BRPI0515025A BRPI0515025-6A BRPI0515025A BRPI0515025A BR PI0515025 A BRPI0515025 A BR PI0515025A BR PI0515025 A BRPI0515025 A BR PI0515025A BR PI0515025 A BRPI0515025 A BR PI0515025A
- Authority
- BR
- Brazil
- Prior art keywords
- procatalyst composition
- ziegler
- composition
- preparing
- polymer
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 5
- 229920000642 polymer Polymers 0.000 title abstract 2
- 239000002245 particle Substances 0.000 abstract 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000002344 surface layer Substances 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- 239000011800 void material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
COMPOSIçãO DE PROCATALISADOR ZIEGLER-NATTA, MéTODO PARA PREPARAR UMA COMPOSIçãO DE PROCATALISADOR E PROCESSO PARA PRODUZIR UM POLìMERO Composição de procatalisador Ziegler-Natta na forma de partículas sólidas e compreendendo parcelas de magnésio, haleto e metal de transição, as ditas parcelas tendo um tamanho médio (D~ 50~) de 10 a 70 <109>m, distinguidas por pelo menos 5 por cento das partículas terem volume vazio interno substancialmente ou completamente circundado por uma camada superficial monolítica (película), a dita película distinguida por uma razão de espessura média de película/tamanho de partícula (razão de espessura) determinadas por técnicas de SEM para partículas tendo tamanho de partícula maior que 30 <109>m maior que 0,2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BR122018006665-2A BR122018006665B1 (pt) | 2004-08-09 | 2005-06-24 | Método para preparar uma composição de procatalisador ziegler-natta e processo para preparar um polímero |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60008204P | 2004-08-09 | 2004-08-09 | |
| PCT/US2005/022492 WO2006023057A1 (en) | 2004-08-09 | 2005-06-24 | Robust spray-dried ziegler-natta procatalyst and polymerization process employing same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0515025A true BRPI0515025A (pt) | 2008-07-01 |
| BRPI0515025B1 BRPI0515025B1 (pt) | 2019-02-05 |
Family
ID=35395595
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0515025A BRPI0515025B1 (pt) | 2004-08-09 | 2005-06-24 | composição de procatalisador ziegler-natta |
| BR122018006665-2A BR122018006665B1 (pt) | 2004-08-09 | 2005-06-24 | Método para preparar uma composição de procatalisador ziegler-natta e processo para preparar um polímero |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR122018006665-2A BR122018006665B1 (pt) | 2004-08-09 | 2005-06-24 | Método para preparar uma composição de procatalisador ziegler-natta e processo para preparar um polímero |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US8173569B2 (pt) |
| EP (2) | EP1778744B1 (pt) |
| JP (1) | JP5363728B2 (pt) |
| KR (2) | KR101200656B1 (pt) |
| CN (3) | CN1993391A (pt) |
| AR (1) | AR050111A1 (pt) |
| AU (1) | AU2005277920B2 (pt) |
| BR (2) | BRPI0515025B1 (pt) |
| CA (2) | CA2574364C (pt) |
| ES (1) | ES2535821T3 (pt) |
| MX (1) | MX2007001644A (pt) |
| MY (1) | MY177635A (pt) |
| RU (2) | RU2377256C2 (pt) |
| TW (1) | TW200613054A (pt) |
| WO (1) | WO2006023057A1 (pt) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006020623A1 (en) * | 2004-08-09 | 2006-02-23 | Union Carbide Chemicals & Plastics Technology Corporation | Robust spray-dried ziegler-natta procatalyst and polymerization process employing same |
| EP2010603B1 (en) | 2006-04-07 | 2010-01-13 | Dow Global Technologies Inc. | Polyolefin compositions, articles made therefrom and methods for preparing the same |
| WO2008051824A2 (en) | 2006-10-23 | 2008-05-02 | Dow Global Technologies Inc. | Polyethylene compositions, methods of making the same, and articles prepared therefrom |
| CN102030846B (zh) * | 2009-09-29 | 2012-06-13 | 中国石油化工股份有限公司 | 一种能制备高熔融流动比聚乙烯的催化剂及其制备方法 |
| US20130075409A1 (en) | 2010-04-14 | 2013-03-28 | Mridula Kapur | Fuel containers made from polyethylene compositions with improved creep resistance |
| SG191342A1 (en) * | 2010-12-31 | 2013-08-30 | Union Carbide Chem Plastic | Polymers, method of producing the same, and articles made therefrom |
| WO2014109832A1 (en) | 2013-01-14 | 2014-07-17 | Univation Technologies, Llc | Methods for preparing catalyst systems with increased productivity |
| CN104776687B (zh) * | 2014-09-05 | 2017-09-29 | 山东诚创医药技术开发有限公司 | 盐酸考来维仑聚合物的干燥方法 |
| US10266618B2 (en) * | 2014-11-24 | 2019-04-23 | Univation Technologies, Llc | Chromium-based catalyst compositions for olefin polymerization |
| EP3519170B1 (en) * | 2016-09-27 | 2023-08-16 | DSM IP Assets B.V. | Transparent drawn article |
| WO2019036376A1 (en) * | 2017-08-14 | 2019-02-21 | Braskem America, Inc. | BORON-BASED ELECTRON DONORS FOR ZIEGLER-NATTA CATALYST SYSTEMS |
| WO2019079068A1 (en) | 2017-10-19 | 2019-04-25 | Univation Technologies, Llc | METHOD FOR DETERMINING BIMODALITY OF PARTICLE SIZE |
| CN109694425B (zh) * | 2017-10-24 | 2021-10-19 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法和催化剂及其应用 |
| SG11202008431UA (en) * | 2018-03-23 | 2020-10-29 | Univation Tech Llc | Catalyst formulations |
| EP3830140A1 (en) * | 2018-08-02 | 2021-06-09 | Borealis AG | Process for polymerizing ethylene in a multi-stage polymerization process |
| KR102771001B1 (ko) * | 2019-08-09 | 2025-02-21 | 주식회사 엘지화학 | 촉매 조성물 내 무기물의 제거 방법 |
| US11214633B2 (en) * | 2019-09-10 | 2022-01-04 | Braskem America, Inc. | Ziegler-Natta catalyst systems and methods of controlling particle size |
| CN113563496B (zh) | 2020-04-28 | 2023-05-09 | 中国石油化工股份有限公司 | 一种烯烃聚合或共聚合的催化剂组分和其制备方法与应用 |
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-
2005
- 2005-06-24 WO PCT/US2005/022492 patent/WO2006023057A1/en not_active Ceased
- 2005-06-24 CA CA2574364A patent/CA2574364C/en not_active Expired - Fee Related
- 2005-06-24 US US11/632,325 patent/US8173569B2/en active Active
- 2005-06-24 AU AU2005277920A patent/AU2005277920B2/en not_active Ceased
- 2005-06-24 KR KR20077003260A patent/KR101200656B1/ko not_active Expired - Lifetime
- 2005-06-24 CN CNA200580026783XA patent/CN1993391A/zh active Pending
- 2005-06-24 ES ES05767314.7T patent/ES2535821T3/es not_active Expired - Lifetime
- 2005-06-24 EP EP20050767314 patent/EP1778744B1/en not_active Expired - Lifetime
- 2005-06-24 BR BRPI0515025A patent/BRPI0515025B1/pt active IP Right Grant
- 2005-06-24 BR BR122018006665-2A patent/BR122018006665B1/pt active IP Right Grant
- 2005-06-24 RU RU2007108542A patent/RU2377256C2/ru not_active IP Right Cessation
- 2005-06-24 CN CN2011102957038A patent/CN102516423A/zh active Pending
- 2005-06-24 MX MX2007001644A patent/MX2007001644A/es active IP Right Grant
- 2005-06-24 JP JP2007525611A patent/JP5363728B2/ja not_active Expired - Lifetime
- 2005-08-08 MY MYPI20053682A patent/MY177635A/en unknown
- 2005-08-08 TW TW094126726A patent/TW200613054A/zh unknown
- 2005-08-08 AR ARP050103306 patent/AR050111A1/es active IP Right Grant
- 2005-08-09 RU RU2007108543/04A patent/RU2007108543A/ru not_active Application Discontinuation
- 2005-08-09 EP EP20050784444 patent/EP1778746A1/en not_active Withdrawn
- 2005-08-09 CN CNA2005800270974A patent/CN101001890A/zh active Pending
- 2005-08-09 KR KR20077003261A patent/KR20070061522A/ko not_active Withdrawn
- 2005-08-09 CA CA 2576560 patent/CA2576560A1/en not_active Abandoned
-
2012
- 2012-03-22 US US13/427,194 patent/US9133287B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR20070051272A (ko) | 2007-05-17 |
| US8173569B2 (en) | 2012-05-08 |
| RU2007108543A (ru) | 2008-09-20 |
| EP1778746A1 (en) | 2007-05-02 |
| EP1778744B1 (en) | 2015-03-25 |
| BR122018006665B1 (pt) | 2019-04-02 |
| KR101200656B1 (ko) | 2012-11-12 |
| CA2576560A1 (en) | 2006-02-23 |
| JP5363728B2 (ja) | 2013-12-11 |
| CN101001890A (zh) | 2007-07-18 |
| RU2377256C2 (ru) | 2009-12-27 |
| MY177635A (en) | 2020-09-23 |
| ES2535821T3 (es) | 2015-05-18 |
| AU2005277920B2 (en) | 2011-08-25 |
| CA2574364C (en) | 2012-11-27 |
| CN102516423A (zh) | 2012-06-27 |
| US20120178888A1 (en) | 2012-07-12 |
| KR20070061522A (ko) | 2007-06-13 |
| RU2007108542A (ru) | 2008-09-20 |
| US20080076951A1 (en) | 2008-03-27 |
| MX2007001644A (es) | 2007-04-23 |
| AR050111A1 (es) | 2006-09-27 |
| WO2006023057A1 (en) | 2006-03-02 |
| US9133287B2 (en) | 2015-09-15 |
| AU2005277920A1 (en) | 2006-03-02 |
| BRPI0515025B1 (pt) | 2019-02-05 |
| CN1993391A (zh) | 2007-07-04 |
| EP1778744A1 (en) | 2007-05-02 |
| TW200613054A (en) | 2006-05-01 |
| JP2008509274A (ja) | 2008-03-27 |
| CA2574364A1 (en) | 2006-03-02 |
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