BRPI0515025A - composição de procatalisador ziegler-natta, método para preparar uma composição de procatalisador e processo para produzir um polìmero - Google Patents
composição de procatalisador ziegler-natta, método para preparar uma composição de procatalisador e processo para produzir um polìmeroInfo
- Publication number
- BRPI0515025A BRPI0515025A BRPI0515025-6A BRPI0515025A BRPI0515025A BR PI0515025 A BRPI0515025 A BR PI0515025A BR PI0515025 A BRPI0515025 A BR PI0515025A BR PI0515025 A BRPI0515025 A BR PI0515025A
- Authority
- BR
- Brazil
- Prior art keywords
- procatalyst composition
- ziegler
- composition
- preparing
- polymer
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 5
- 229920000642 polymer Polymers 0.000 title abstract 2
- 239000002245 particle Substances 0.000 abstract 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000002344 surface layer Substances 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- 239000011800 void material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
COMPOSIçãO DE PROCATALISADOR ZIEGLER-NATTA, MéTODO PARA PREPARAR UMA COMPOSIçãO DE PROCATALISADOR E PROCESSO PARA PRODUZIR UM POLìMERO Composição de procatalisador Ziegler-Natta na forma de partículas sólidas e compreendendo parcelas de magnésio, haleto e metal de transição, as ditas parcelas tendo um tamanho médio (D~ 50~) de 10 a 70 <109>m, distinguidas por pelo menos 5 por cento das partículas terem volume vazio interno substancialmente ou completamente circundado por uma camada superficial monolítica (película), a dita película distinguida por uma razão de espessura média de película/tamanho de partícula (razão de espessura) determinadas por técnicas de SEM para partículas tendo tamanho de partícula maior que 30 <109>m maior que 0,2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BR122018006665-2A BR122018006665B1 (pt) | 2004-08-09 | 2005-06-24 | Método para preparar uma composição de procatalisador ziegler-natta e processo para preparar um polímero |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60008204P | 2004-08-09 | 2004-08-09 | |
| PCT/US2005/022492 WO2006023057A1 (en) | 2004-08-09 | 2005-06-24 | Robust spray-dried ziegler-natta procatalyst and polymerization process employing same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0515025A true BRPI0515025A (pt) | 2008-07-01 |
| BRPI0515025B1 BRPI0515025B1 (pt) | 2019-02-05 |
Family
ID=35395595
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0515025A BRPI0515025B1 (pt) | 2004-08-09 | 2005-06-24 | composição de procatalisador ziegler-natta |
| BR122018006665-2A BR122018006665B1 (pt) | 2004-08-09 | 2005-06-24 | Método para preparar uma composição de procatalisador ziegler-natta e processo para preparar um polímero |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR122018006665-2A BR122018006665B1 (pt) | 2004-08-09 | 2005-06-24 | Método para preparar uma composição de procatalisador ziegler-natta e processo para preparar um polímero |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US8173569B2 (pt) |
| EP (2) | EP1778744B1 (pt) |
| JP (1) | JP5363728B2 (pt) |
| KR (2) | KR101200656B1 (pt) |
| CN (3) | CN102516423A (pt) |
| AR (1) | AR050111A1 (pt) |
| AU (1) | AU2005277920B2 (pt) |
| BR (2) | BRPI0515025B1 (pt) |
| CA (2) | CA2574364C (pt) |
| ES (1) | ES2535821T3 (pt) |
| MX (1) | MX2007001644A (pt) |
| MY (1) | MY177635A (pt) |
| RU (2) | RU2377256C2 (pt) |
| TW (1) | TW200613054A (pt) |
| WO (1) | WO2006023057A1 (pt) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2005272951A1 (en) * | 2004-08-09 | 2006-02-23 | Union Carbide Chemicals & Plastics Technology Llc | Robust spray-dried Ziegler-Natta procatalyst and polymerization process employing same |
| KR20090024671A (ko) | 2006-04-07 | 2009-03-09 | 다우 글로벌 테크놀로지스 인크. | 폴리올레핀 조성물, 그로부터 제조된 물품 및 그의 제조 방법 |
| PL2267070T3 (pl) | 2006-10-23 | 2012-11-30 | Dow Global Technologies Llc | Sposób wytwarzania kompozycji polietylenowych |
| CN102030846B (zh) * | 2009-09-29 | 2012-06-13 | 中国石油化工股份有限公司 | 一种能制备高熔融流动比聚乙烯的催化剂及其制备方法 |
| BR112012026163A2 (pt) | 2010-04-14 | 2016-06-28 | Dow Global Technologies Llc | recipiente de combustível, processo para moldar a sopro uma composição de polietileno em um recipiente para combustível e método para preparar uma composição de polietileno |
| KR20140001993A (ko) * | 2010-12-31 | 2014-01-07 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 엘엘씨 | 중합체, 이의 제조 방법, 및 이로부터 만든 물품 |
| RU2647855C2 (ru) * | 2013-01-14 | 2018-03-21 | ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи | Способы получения каталитических систем с повышенной производительностью |
| CN104776687B (zh) * | 2014-09-05 | 2017-09-29 | 山东诚创医药技术开发有限公司 | 盐酸考来维仑聚合物的干燥方法 |
| WO2016085842A2 (en) * | 2014-11-24 | 2016-06-02 | Univation Technologies, Llc | Chromium-based catalyst compositions for olefin polymerization |
| WO2018060224A1 (en) * | 2016-09-27 | 2018-04-05 | Dsm Ip Assets B.V. | Transparent drawn article |
| US11291981B2 (en) | 2017-08-14 | 2022-04-05 | Braskem America, Inc. | Boron-based electron donors for Ziegler-Natta catalyst systems |
| SG11202002820RA (en) * | 2017-10-19 | 2020-05-28 | Univation Tech Llc | A method for the determination of particle size bimodality |
| CN109694425B (zh) * | 2017-10-24 | 2021-10-19 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法和催化剂及其应用 |
| SG11202008431UA (en) * | 2018-03-23 | 2020-10-29 | Univation Tech Llc | Catalyst formulations |
| CN112424235B (zh) * | 2018-08-02 | 2023-04-21 | 北欧化工公司 | 在多阶段聚合工艺中聚合乙烯的方法 |
| KR102771001B1 (ko) * | 2019-08-09 | 2025-02-21 | 주식회사 엘지화학 | 촉매 조성물 내 무기물의 제거 방법 |
| US11214633B2 (en) * | 2019-09-10 | 2022-01-04 | Braskem America, Inc. | Ziegler-Natta catalyst systems and methods of controlling particle size |
| CN113563496B (zh) | 2020-04-28 | 2023-05-09 | 中国石油化工股份有限公司 | 一种烯烃聚合或共聚合的催化剂组分和其制备方法与应用 |
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-
2005
- 2005-06-24 EP EP20050767314 patent/EP1778744B1/en not_active Expired - Lifetime
- 2005-06-24 CN CN2011102957038A patent/CN102516423A/zh active Pending
- 2005-06-24 ES ES05767314.7T patent/ES2535821T3/es not_active Expired - Lifetime
- 2005-06-24 MX MX2007001644A patent/MX2007001644A/es active IP Right Grant
- 2005-06-24 BR BRPI0515025A patent/BRPI0515025B1/pt active IP Right Grant
- 2005-06-24 US US11/632,325 patent/US8173569B2/en active Active
- 2005-06-24 RU RU2007108542A patent/RU2377256C2/ru not_active IP Right Cessation
- 2005-06-24 JP JP2007525611A patent/JP5363728B2/ja not_active Expired - Lifetime
- 2005-06-24 KR KR20077003260A patent/KR101200656B1/ko not_active Expired - Lifetime
- 2005-06-24 BR BR122018006665-2A patent/BR122018006665B1/pt active IP Right Grant
- 2005-06-24 CA CA2574364A patent/CA2574364C/en not_active Expired - Fee Related
- 2005-06-24 AU AU2005277920A patent/AU2005277920B2/en not_active Ceased
- 2005-06-24 CN CNA200580026783XA patent/CN1993391A/zh active Pending
- 2005-06-24 WO PCT/US2005/022492 patent/WO2006023057A1/en not_active Ceased
- 2005-08-08 TW TW094126726A patent/TW200613054A/zh unknown
- 2005-08-08 AR ARP050103306 patent/AR050111A1/es active IP Right Grant
- 2005-08-08 MY MYPI20053682A patent/MY177635A/en unknown
- 2005-08-09 CN CNA2005800270974A patent/CN101001890A/zh active Pending
- 2005-08-09 KR KR20077003261A patent/KR20070061522A/ko not_active Withdrawn
- 2005-08-09 CA CA 2576560 patent/CA2576560A1/en not_active Abandoned
- 2005-08-09 EP EP20050784444 patent/EP1778746A1/en not_active Withdrawn
- 2005-08-09 RU RU2007108543/04A patent/RU2007108543A/ru not_active Application Discontinuation
-
2012
- 2012-03-22 US US13/427,194 patent/US9133287B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| RU2007108543A (ru) | 2008-09-20 |
| EP1778744B1 (en) | 2015-03-25 |
| MY177635A (en) | 2020-09-23 |
| BR122018006665B1 (pt) | 2019-04-02 |
| BRPI0515025B1 (pt) | 2019-02-05 |
| US8173569B2 (en) | 2012-05-08 |
| TW200613054A (en) | 2006-05-01 |
| KR101200656B1 (ko) | 2012-11-12 |
| CN102516423A (zh) | 2012-06-27 |
| RU2007108542A (ru) | 2008-09-20 |
| CA2574364A1 (en) | 2006-03-02 |
| WO2006023057A1 (en) | 2006-03-02 |
| US20080076951A1 (en) | 2008-03-27 |
| US9133287B2 (en) | 2015-09-15 |
| KR20070061522A (ko) | 2007-06-13 |
| RU2377256C2 (ru) | 2009-12-27 |
| CA2574364C (en) | 2012-11-27 |
| EP1778746A1 (en) | 2007-05-02 |
| JP5363728B2 (ja) | 2013-12-11 |
| JP2008509274A (ja) | 2008-03-27 |
| AR050111A1 (es) | 2006-09-27 |
| AU2005277920B2 (en) | 2011-08-25 |
| CN101001890A (zh) | 2007-07-18 |
| CN1993391A (zh) | 2007-07-04 |
| EP1778744A1 (en) | 2007-05-02 |
| KR20070051272A (ko) | 2007-05-17 |
| MX2007001644A (es) | 2007-04-23 |
| US20120178888A1 (en) | 2012-07-12 |
| CA2576560A1 (en) | 2006-02-23 |
| AU2005277920A1 (en) | 2006-03-02 |
| ES2535821T3 (es) | 2015-05-18 |
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