BRPI0706486C8 - processo para a preparação de compostos, composto, complexo de ferro não simétrico, sistema catalisador, uso de um sistema catalisador, e, processo para a preparação de poliolefinas - Google Patents

processo para a preparação de compostos, composto, complexo de ferro não simétrico, sistema catalisador, uso de um sistema catalisador, e, processo para a preparação de poliolefinas

Info

Publication number
BRPI0706486C8
BRPI0706486C8 BRPI0706486A BRPI0706486A BRPI0706486C8 BR PI0706486 C8 BRPI0706486 C8 BR PI0706486C8 BR PI0706486 A BRPI0706486 A BR PI0706486A BR PI0706486 A BRPI0706486 A BR PI0706486A BR PI0706486 C8 BRPI0706486 C8 BR PI0706486C8
Authority
BR
Brazil
Prior art keywords
preparation
catalyst system
compounds
compound
polyolefins
Prior art date
Application number
BRPI0706486A
Other languages
English (en)
Inventor
Solchinger Alexander
Bildstein Benno
Kölling Lars
Schlawjinski Sascha
Mihan Shahram
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Publication of BRPI0706486A2 publication Critical patent/BRPI0706486A2/pt
Publication of BRPI0706486B1 publication Critical patent/BRPI0706486B1/pt
Publication of BRPI0706486C8 publication Critical patent/BRPI0706486C8/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/26—Radicals substituted by halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
    • C07D213/53—Nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

processo para a preparação de compostos, composto, complexo de ferro não simetrico, sistema catalisador, uso de um sistema catalisador, e, processo para a preparaçao de poliolefinas processo para a preparação de compostos de monoimina, em que um composto de dicarbonila é reagido em um solvente alifático, não-aromático, com anilina. compostos de monoimina apresentando substituintes retiradores de elétron na posição orto e compostos de bis(imino) não simétricos e complexos de ferro não simétricos preparados dos mesmos, e o uso dos mesmos na polimerização de olefinas.
BRPI0706486A 2006-01-13 2007-01-08 processo para a preparação de compostos, composto, complexo de ferro não simétrico, sistema catalisador, uso de um sistema catalisador, e, processo para a preparação de poliolefinas BRPI0706486C8 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE102006001959A DE102006001959A1 (de) 2006-01-13 2006-01-13 Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen
DE102006001959.8 2006-01-13
US81101306P 2006-06-05 2006-06-05
US60/811,013 2006-06-05
PCT/EP2007/000096 WO2007080081A2 (en) 2006-01-13 2007-01-08 Process for the preparation of unsymmetric bis(imino) compounds

Publications (3)

Publication Number Publication Date
BRPI0706486A2 BRPI0706486A2 (pt) 2011-03-29
BRPI0706486B1 BRPI0706486B1 (pt) 2019-03-19
BRPI0706486C8 true BRPI0706486C8 (pt) 2019-08-13

Family

ID=38190018

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0706486A BRPI0706486C8 (pt) 2006-01-13 2007-01-08 processo para a preparação de compostos, composto, complexo de ferro não simétrico, sistema catalisador, uso de um sistema catalisador, e, processo para a preparação de poliolefinas

Country Status (11)

Country Link
US (1) US8252875B2 (pt)
EP (1) EP1971577B1 (pt)
JP (1) JP5165587B2 (pt)
KR (1) KR101373915B1 (pt)
CN (1) CN101370778B (pt)
AU (1) AU2007204447A1 (pt)
BR (1) BRPI0706486C8 (pt)
DE (1) DE102006001959A1 (pt)
RU (1) RU2434854C2 (pt)
WO (1) WO2007080081A2 (pt)
ZA (1) ZA200805967B (pt)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050187418A1 (en) 2004-02-19 2005-08-25 Small Brooke L. Olefin oligomerization
US20070043181A1 (en) 2005-08-19 2007-02-22 Knudsen Ronald D Methods of preparation of an olefin oligomerization catalyst
US20050187098A1 (en) 2004-02-20 2005-08-25 Knudsen Ronald D. Methods of preparation of an olefin oligomerization catalyst
US9550841B2 (en) 2004-02-20 2017-01-24 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US7384886B2 (en) 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
US7271121B2 (en) 2005-07-21 2007-09-18 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
US7727926B2 (en) 2005-07-21 2010-06-01 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization
US7268096B2 (en) 2005-07-21 2007-09-11 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
DE102006001959A1 (de) 2006-01-13 2007-07-19 Basell Polyolefine Gmbh Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen
DE102007017903A1 (de) 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
US7902415B2 (en) 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins
CN101903418A (zh) * 2007-12-21 2010-12-01 巴塞尔聚烯烃股份有限公司 包含菲咯啉的络合物
US20100267910A1 (en) * 2007-12-21 2010-10-21 Basell Polyolefine Gmbh Catalyst system for olefin polymerization comprising phenanthroline-comprising iron complexes
CN101391979B (zh) * 2008-10-24 2011-08-31 中南民族大学 含卤素的不对称吡啶双亚胺类铁和钴配合物、制备方法及用途
WO2012152857A1 (en) * 2011-05-12 2012-11-15 Basell Polyolefine Gmbh Process for the manufacture of a mixed catalyst system for the copolymerization of ethylene with c1-c12 alpha-olefins
US9586872B2 (en) 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods
US9944661B2 (en) 2016-08-09 2018-04-17 Chevron Phillips Chemical Company Lp Olefin hydroboration
FI3517553T3 (fi) * 2016-09-23 2024-02-02 China Petroleum & Chem Corp Katalyyttikomponentti käytettäväksi olefiinin polymeroinnissa, katalyytti, ja niiden käyttö
US10927204B2 (en) 2017-11-14 2021-02-23 Exxonmobil Chemical Patents Inc. Iron tridentate carbene single site catalysts
RU2672868C1 (ru) * 2017-12-07 2018-11-20 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) Способ получения производных 2,6-бис[1-(фенилимино)этил]пиридина с электроноакцепторными заместителями
CN107855134B (zh) * 2017-12-11 2020-08-07 中国科学院理化技术研究所 一种不对称亚胺-吡啶-钴类金属催化剂及其制备方法和应用
CN110092744B (zh) * 2018-01-29 2023-04-18 中国科学院化学研究所 一类高热稳定的含叔丁基不对称二亚胺吡啶配合物、其制备方法及应用
CN109718855A (zh) * 2018-12-22 2019-05-07 中国科学院山西煤炭化学研究所 一种封装金属配合物于材料表面的方法
CN111961090B (zh) * 2019-05-20 2021-10-22 中国科学院化学研究所 一类含大位阻取代基的不对称吡啶亚胺配合物、其制备方法及应用
CN112851711B (zh) * 2019-11-27 2022-04-08 中国科学院化学研究所 吡啶二亚胺铬配合物及其制备方法和用于制备聚烯烃的用途
WO2021126692A1 (en) 2019-12-16 2021-06-24 Exxonmobil Chemical Patents Inc. Iron bis(imino) aryl catalysts and methods thereof
US11738334B2 (en) 2020-08-11 2023-08-29 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
US20230322972A1 (en) 2020-10-08 2023-10-12 Exxonmobil Chemical Patents Inc. Supported Catalyst Systems and Processes for Use Thereof
EP4493567A1 (en) 2022-03-14 2025-01-22 ExxonMobil Chemical Patents Inc. Metal bis(imino) aryl compounds and methods thereof
EP4493598A1 (en) 2022-03-14 2025-01-22 ExxonMobil Chemical Patents Inc. Metal-containing bis(imino) per-substituted aryl compounds and methods thereof
CN120904255B (zh) * 2025-10-09 2025-12-16 北京大学 一种乙烯非选择性齐聚催化剂及其制备方法和应用

Family Cites Families (74)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242150A (en) 1960-03-31 1966-03-22 Phillips Petroleum Co Method and apparatus for the recovery of solid olefin polymer from a continuous path reaction zone
US3125547A (en) 1961-02-09 1964-03-17 Extrudable composition consisting of
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
US4438238A (en) 1981-01-30 1984-03-20 Sumitomo Chemical Company, Limited Low density copolymer composition of two ethylene-α-olefin copolymers
US4461873A (en) 1982-06-22 1984-07-24 Phillips Petroleum Company Ethylene polymer blends
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US7163907B1 (en) 1987-01-30 2007-01-16 Exxonmobil Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5382630A (en) 1988-09-30 1995-01-17 Exxon Chemical Patents Inc. Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distribution
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
WO1991009882A1 (en) 1990-01-02 1991-07-11 Exxon Chemical Patents Inc. Supported ionic metallocene catalysts for olefin polymerization
JPH05194796A (ja) 1991-09-18 1993-08-03 Phillips Petroleum Co ポリエチレン ブレンド
KR930006091A (ko) 1991-09-18 1993-04-20 제이 이이 휘립프스 폴리에틸렌 블렌드 및 그로부터 제조된 필름, 병 또는 파이프
KR930006090A (ko) 1991-09-18 1993-04-20 제이 이이 휘립프스 에틸렌 중합체 조성물
CA2078366A1 (en) 1991-09-18 1993-03-19 Joel L. Martin Polyethylene blends
TW309523B (pt) 1991-11-30 1997-07-01 Hoechst Ag
US5530065A (en) 1992-01-07 1996-06-25 Exxon Chemical Patents Inc. Heat sealable films and articles made therefrom
TW294669B (pt) 1992-06-27 1997-01-01 Hoechst Ag
EP0662989B1 (en) 1992-10-02 1997-01-29 E.I. Du Pont De Nemours And Company Improved shrink film and methods relating thereto
US5372980A (en) 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
US5350807A (en) 1993-06-25 1994-09-27 Phillips Petroleum Company Ethylene polymers
EP0724604B2 (en) 1993-10-21 2005-12-14 Exxonmobil Oil Corporation Polyolefin blends of bimodal molecular weight distribution
FI945958L (fi) 1993-12-21 1995-06-22 Hoechst Ag Menetelmä polyolefiinien valmistamiseksi
FI945959L (fi) 1993-12-21 1995-06-22 Hoechst Ag Metalloseenejä ja niiden käyttö katalyytteinä
JPH09511273A (ja) 1994-03-31 1997-11-11 モービル・オイル・コーポレーション Ｌｌｄｐｅ樹脂ブレンド
DE69514661T2 (de) 1994-06-24 2000-08-03 Exxon Chemical Patents, Inc. Polymerisationskatalysatorsystem, ihre herstellung und gebrauch
IT1275573B (it) 1995-07-20 1997-08-07 Spherilene Spa Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine
DE69703438T2 (de) 1996-03-29 2001-03-08 The Dow Chemical Co., Midland Metallocen cokatalysator
EA199900152A1 (ru) 1996-07-23 1999-08-26 Е.И.Дюпон Де Немур Энд Компани Способ полимеризации олефинов
IL129929A0 (en) 1996-12-17 2000-02-29 Du Pont Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt
US6432862B1 (en) * 1996-12-17 2002-08-13 E. I. Du Pont De Nemours And Company Cobalt catalysts for the polymerization of olefins
US6423848B2 (en) 1996-12-17 2002-07-23 E. I. Du Pont De Nemours And Company Tridentate ligand
DE19757563A1 (de) 1997-03-07 1999-07-08 Targor Gmbh Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen
CN100451024C (zh) * 1997-03-07 2009-01-14 巴塞尔聚烯烃股份有限公司 金属茂化合物和茚类化合物以及其应用
DE19733017A1 (de) 1997-07-31 1999-02-04 Hoechst Ag Chemische Verbindung
ES2178247T3 (es) * 1997-09-05 2002-12-16 Bp Chem Int Ltd Catalizadores de polimerizacion.
JP2002506095A (ja) 1998-03-12 2002-02-26 ビーピー ケミカルズ リミテッド エチレンのホモポリマー
PT1062249E (pt) 1998-03-12 2004-12-31 Bp Chem Int Ltd Catalisadores de polimerizacao
DE19828271A1 (de) 1998-06-25 1999-12-30 Elenac Gmbh Verfahren zur Herstellung eines geträgerten Katalysatorsystems
DE19833170A1 (de) 1998-07-23 2000-01-27 Targor Gmbh Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz
EP1117670B1 (en) 1998-10-02 2003-01-02 BP Chemicals Limited Polymerisation catalysts
US6160145A (en) 1998-10-23 2000-12-12 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components
US6492292B2 (en) 1998-10-23 2002-12-10 Albemarle Corporation Gelatinous compositions formed from hydroxyaluminoxane, solid compositions formed therefrom, and the use of such compositions as catalyst components
US6812182B2 (en) * 1998-10-23 2004-11-02 Albemarle Corporation Compositions formed from hydroxyaluminoxane and their use as catalyst components
ES2280674T3 (es) 1998-11-25 2007-09-16 Basell Polyolefine Gmbh Monohalogenuros de metaloceno.
ES2192408T3 (es) 1998-11-25 2003-10-01 Basell Polyolefine Gmbh Procedimiento para la fabricacion de monoariloxi-ansa-metalocenos.
GB9906296D0 (en) 1999-03-18 1999-05-12 Bp Chem Int Ltd Polymerisation catalysts
US6365690B1 (en) 1999-05-06 2002-04-02 E. I. Du Pont De Nemours And Company Polymerization of ethylene
CA2285723C (en) 1999-10-07 2009-09-15 Nova Chemicals Corporation Multimodal polyolefin pipe
US6548442B1 (en) 1999-12-03 2003-04-15 Phillips Petroleum Company Organometal compound catalyst
US6710006B2 (en) * 2000-02-09 2004-03-23 Shell Oil Company Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins
SG124236A1 (en) 2000-03-30 2006-08-30 Sumitomo Chemical Co Prepolymerization catalyst for use in gas phase polymerization of olefins and process for producing the same
GC0000291A (en) * 2000-06-30 2006-11-01 Shell Int Research Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins
US7037988B2 (en) * 2000-10-03 2006-05-02 Shell Oil Company Process for the co-oligomerisation of ethylene and alpha olefins
CN1139574C (zh) * 2001-01-21 2004-02-25 中国科学院上海有机化学研究所 卤代苯基吡啶基双亚胺后过渡金属配合物、合成方法及用途
US6900153B2 (en) 2001-03-28 2005-05-31 E.I. Du Pont De Nemours And Company Supported olefin polymerization catalysts
CN1255441C (zh) * 2001-09-14 2006-05-10 巴塞尔聚烯烃股份有限公司 烯烃的聚合方法
JP2005536566A (ja) * 2002-08-22 2005-12-02 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング モノシクロペンタジエニル錯体
CN100371075C (zh) * 2002-09-25 2008-02-27 国际壳牌研究有限公司 用于乙烯低聚为直链α-烯烃的催化剂体系
EP1403288A1 (en) 2002-09-27 2004-03-31 ATOFINA Research Dual site catalyst system comprising a hafnocene component for the production of bimodal polyolefins
DE10317395A1 (de) 2003-04-15 2004-11-04 Basell Polyolefine Gmbh Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren und ein Verfahren zu deren Herstellung
EP1740598B1 (en) * 2004-03-24 2008-03-05 Shell Internationale Researchmaatschappij B.V. Transition metal complexes
EP1732894B1 (en) * 2004-04-08 2007-06-27 Basell Polyolefine GmbH Process for preparing diimine compounds
US7674910B2 (en) 2004-04-08 2010-03-09 Basell Polyolefine Gmbh Process for preparing diimine compounds
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
CN100372609C (zh) 2005-04-22 2008-03-05 中国科学院化学研究所 一种用于乙烯齐聚和聚合的催化剂及制备方法和用途
JP2009511681A (ja) 2005-10-14 2009-03-19 バーゼル・ポリオレフィン・ゲーエムベーハー ハロゲン化マグネシウム上に担持された複合触媒系
DE102006001959A1 (de) 2006-01-13 2007-07-19 Basell Polyolefine Gmbh Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen
US7795411B2 (en) * 2006-10-05 2010-09-14 Fred Hutchinson Cancer Research Center Vectors for expressing in vivo biotinylated recombinant proteins
CA2679131C (en) 2007-03-06 2015-06-16 Basell Polyolefine Gmbh Iron complexes and their use in polymerization processes
DE102007017903A1 (de) 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
CN101903418A (zh) 2007-12-21 2010-12-01 巴塞尔聚烯烃股份有限公司 包含菲咯啉的络合物

Also Published As

Publication number Publication date
RU2434854C2 (ru) 2011-11-27
JP5165587B2 (ja) 2013-03-21
BRPI0706486A2 (pt) 2011-03-29
WO2007080081A2 (en) 2007-07-19
KR101373915B1 (ko) 2014-03-14
RU2008133220A (ru) 2010-02-20
US20090054609A1 (en) 2009-02-26
CN101370778B (zh) 2014-10-22
ZA200805967B (en) 2009-04-29
JP2009523146A (ja) 2009-06-18
DE102006001959A1 (de) 2007-07-19
KR20080083316A (ko) 2008-09-17
AU2007204447A1 (en) 2007-07-19
EP1971577A2 (en) 2008-09-24
EP1971577B1 (en) 2014-11-26
US8252875B2 (en) 2012-08-28
BRPI0706486B1 (pt) 2019-03-19
CN101370778A (zh) 2009-02-18
WO2007080081A3 (en) 2007-08-30

Similar Documents

Publication Publication Date Title
BRPI0706486C8 (pt) processo para a preparação de compostos, composto, complexo de ferro não simétrico, sistema catalisador, uso de um sistema catalisador, e, processo para a preparação de poliolefinas
CR10157A (es) Compuestos químicos
BR0015200A (pt) Fosfita, processo para preparar a mesma, uso da mesma, complexo de metal de transição, processo para preparar o mesmo, uso do mesmo, e processos para a adição de ácido cianìdrico em uma ligação dupla olefìnica, e, para a isomerização de nitrilas orgânicas
UY31502A1 (es) Proceso mejorado para sintetizar 5-cyclopentyl-5-11-dihydro-10-oxa-1-aza-dibenzo[a,d]cyclohepten-5-ol usando tmeda
BR112012032251A2 (pt) processo para a preparação de derivados da 2, 2-difluoroetilamina pela alquilação com 2,2 difluoroetil-1-haloetanos
BR112015000784A2 (pt) grupo auxiliar assimétrico
WO2009076622A3 (en) Ligands for transition-metal-catalyzed cross-couplings, and methods of use thereof
BRPI0518701B8 (pt) Processos para a preparação de um sistema catalisador e para a polimerização de olefinas
BRPI0817168A2 (pt) "método para a preparação de um composto"
TW200606171A (en) Process for the alkylation of phosphorus-containing compounds
BR112013015854A2 (pt) complexos de organozinco e processos de fabricação e uso dos mesmos
ES2538500T3 (es) Procedimiento de carbonilación mediando la adición de unas aminas secundarias impedidas estéricamente
ATE526314T1 (de) Ionische flüssigkeiten basierend auf imidazoliumsalzen mit einer nitrilfunktionalität
BR0212965A (pt) Fosfonita, uso da mesa, complexos de metal de transição, processo para a preparação e uso dos mesmos, e, processos para a adição de ácido cianìdrico a uma ligação dupla olefìnica na presença de um catalisador, e para a isomerização de nitrilas orgânicas na presença de um catalisador
BR112015027980A8 (pt) Complexo de metal, processo para produzir o complexo de metal, sistema de catalisador, e processo para preparar um polímero
BRPI0514961A (pt) catalisador ziegler-natta, preparação e uso para polimerização de alcenos
AR080921A1 (es) Proceso para la preparacion de amidas de acido pirazolcarboxilico
BRPI0507900A (pt) métodos de preparo de um catalisador de oligomerização de olefina
DE502006009282D1 (de) Verfahren zur substitution von indenofluorenen
BR112012014500A2 (pt) método para aumentar o número de troca (ton) de um sistema de catalisador
ATE482924T1 (de) Alkylierung einer diphenylaminverbindung in einer ionischen flüssigkeit
UA89463C2 (ru) Применение производных антрахинона как маркеров для жидкостей, жидкость, которая содержит указанные соединения, и производные антрахинона
BRPI0512310A (pt) compostos quìmicos
BRPI0418130A (pt) sistema catalisador para a polimerização de olefinas
AR058823A1 (es) Nuevos materiales cataliticos y su uso en la preparacion de materiales polimericos

Legal Events

Date Code Title Description
B15K Others concerning applications: alteration of classification

Ipc: C07D 213/26 (2006.01), C07F 15/02 (2006.01), C08F

B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 19/03/2019, OBSERVADAS AS CONDICOES LEGAIS.

B16C Correction of notification of the grant [chapter 16.3 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 19/03/2019, OBSERVADAS AS CONDICOES LEGAIS. (CO) REFERENTE A RPI 2515 DE 19/03/2019, QUANTO AO ENDERECO DO TITULAR.

B16C Correction of notification of the grant [chapter 16.3 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 19/03/2019, OBSERVADAS AS CONDICOES LEGAIS. (CO) REFERENTE A RPI 2533 DE 23/07/2019, QUANTO AO ITEM (30) PRIORIDADE UNIONISTA.