CA2060698C - Compositions de detergent - Google Patents

Compositions de detergent

Info

Publication number: CA2060698C
Authority: CA; Canada
Prior art keywords: detergent composition; composition according; formula; glycolipid; surfactant
Prior art date: 1991-02-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA 2060698

Other languages

English (en)

Other versions

CA2060698A1 (fr

Inventor

Peter J. Hall

Johan Haverkamp

Cornelis G. Van Kralingen

Michael Schmidt

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Original Assignee

Unilever PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-02-12

Filing date

1992-02-05

Publication date

1997-09-30

1991-02-12 Priority claimed from GB919102945A external-priority patent/GB9102945D0/en

1992-02-05 Application filed by Unilever PLC filed Critical Unilever PLC

1992-08-13 Publication of CA2060698A1 publication Critical patent/CA2060698A1/fr

1997-09-30 Application granted granted Critical

1997-09-30 Publication of CA2060698C publication Critical patent/CA2060698C/fr

2012-02-05 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 95
239000003599 detergent Substances 0.000 title claims abstract description 48
239000004094 surface-active agent Substances 0.000 claims abstract description 84
229930186217 Glycolipid Natural products 0.000 claims abstract description 55
HVCOBJNICQPDBP-UHFFFAOYSA-N 3-[3-[3,5-dihydroxy-6-methyl-4-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxyoxan-2-yl]oxydecanoyloxy]decanoic acid;hydrate Chemical compound O.OC1C(OC(CC(=O)OC(CCCCCCC)CC(O)=O)CCCCCCC)OC(C)C(O)C1OC1C(O)C(O)C(O)C(C)O1 HVCOBJNICQPDBP-UHFFFAOYSA-N 0.000 claims abstract description 53
239000003876 biosurfactant Substances 0.000 claims abstract description 46
239000002736 nonionic surfactant Substances 0.000 claims abstract description 15
239000003945 anionic surfactant Substances 0.000 claims abstract description 9
125000004432 carbon atom Chemical group C* 0.000 claims description 31
-1 rhamnolipids Chemical class 0.000 claims description 19
FCBUKWWQSZQDDI-UHFFFAOYSA-N rhamnolipid Chemical compound CCCCCCCC(CC(O)=O)OC(=O)CC(CCCCCCC)OC1OC(C)C(O)C(O)C1OC1C(O)C(O)C(O)C(C)O1 FCBUKWWQSZQDDI-UHFFFAOYSA-N 0.000 claims description 18
229920006395 saturated elastomer Polymers 0.000 claims description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
150000001768 cations Chemical class 0.000 claims description 9
150000002430 hydrocarbons Chemical class 0.000 claims description 9
125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 8
239000004215 Carbon black (E152) Substances 0.000 claims description 7
229930195733 hydrocarbon Natural products 0.000 claims description 7
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 4
239000007864 aqueous solution Substances 0.000 claims description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims description 3
125000002791 glucosyl group Chemical class C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims description 3
230000003287 optical effect Effects 0.000 claims description 3
150000001773 cellobioses Chemical class 0.000 claims description 2
150000003396 sophoroses Chemical class 0.000 claims description 2
150000003625 trehaloses Chemical class 0.000 claims description 2
125000001183 hydrocarbyl group Chemical class 0.000 claims 3
125000000686 lactone group Chemical group 0.000 claims 2
150000001298 alcohols Chemical class 0.000 claims 1
239000004744 fabric Substances 0.000 abstract description 24
238000005406 washing Methods 0.000 abstract description 13
239000002689 soil Substances 0.000 abstract description 6
125000000217 alkyl group Chemical group 0.000 description 22
238000000855 fermentation Methods 0.000 description 22
230000004151 fermentation Effects 0.000 description 22
239000000463 material Substances 0.000 description 22
238000012360 testing method Methods 0.000 description 14
238000000034 method Methods 0.000 description 13
150000001875 compounds Chemical class 0.000 description 12
PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
150000003839 salts Chemical class 0.000 description 9
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 8
239000000047 product Substances 0.000 description 8
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
229920001577 copolymer Polymers 0.000 description 7
235000014113 dietary fatty acids Nutrition 0.000 description 7
239000000194 fatty acid Substances 0.000 description 7
229930195729 fatty acid Natural products 0.000 description 7
229920000642 polymer Polymers 0.000 description 7
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
229910052783 alkali metal Inorganic materials 0.000 description 6
150000001340 alkali metals Chemical class 0.000 description 6
239000011734 sodium Substances 0.000 description 6
229910052708 sodium Inorganic materials 0.000 description 6
239000000243 solution Substances 0.000 description 6
241000894006 Bacteria Species 0.000 description 5
BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 description 5
PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 5
239000002253 acid Substances 0.000 description 5
125000003342 alkenyl group Chemical group 0.000 description 5
239000003792 electrolyte Substances 0.000 description 5
150000004665 fatty acids Chemical class 0.000 description 5
PMZURENOXWZQFD-UHFFFAOYSA-L sodium sulphate Substances [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 5
PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 5
229940117972 triolein Drugs 0.000 description 5
241000222120 Candida <Saccharomycetales> Species 0.000 description 4
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
240000004808 Saccharomyces cerevisiae Species 0.000 description 4
239000011149 active material Substances 0.000 description 4
230000001580 bacterial effect Effects 0.000 description 4
239000002585 base Substances 0.000 description 4
239000001768 carboxy methyl cellulose Substances 0.000 description 4
239000004615 ingredient Substances 0.000 description 4
239000007788 liquid Substances 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
239000003921 oil Substances 0.000 description 4
235000019198 oils Nutrition 0.000 description 4
229920001983 poloxamer Polymers 0.000 description 4
229920000058 polyacrylate Polymers 0.000 description 4
229920005646 polycarboxylate Polymers 0.000 description 4
239000000843 powder Substances 0.000 description 4
239000000758 substrate Substances 0.000 description 4
235000000346 sugar Nutrition 0.000 description 4
229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
229920000742 Cotton Polymers 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
229910000503 Na-aluminosilicate Inorganic materials 0.000 description 3
241000589516 Pseudomonas Species 0.000 description 3
238000010936 aqueous wash Methods 0.000 description 3
239000007844 bleaching agent Substances 0.000 description 3
235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
239000008112 carboxymethyl-cellulose Substances 0.000 description 3
229940105329 carboxymethylcellulose Drugs 0.000 description 3
239000003093 cationic surfactant Substances 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
239000004064 cosurfactant Substances 0.000 description 3
239000008367 deionised water Substances 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
150000002303 glucose derivatives Chemical class 0.000 description 3
150000002596 lactones Chemical group 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
229920000728 polyester Polymers 0.000 description 3
229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 3
238000012545 processing Methods 0.000 description 3
239000000344 soap Substances 0.000 description 3
235000012217 sodium aluminium silicate Nutrition 0.000 description 3
229910052938 sodium sulfate Inorganic materials 0.000 description 3
235000011152 sodium sulphate Nutrition 0.000 description 3
239000010457 zeolite Substances 0.000 description 3
239000002888 zwitterionic surfactant Substances 0.000 description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 2
SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
241000233866 Fungi Species 0.000 description 2
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
239000002202 Polyethylene glycol Substances 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
229910021536 Zeolite Inorganic materials 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
229920006243 acrylic copolymer Polymers 0.000 description 2
150000001335 aliphatic alkanes Chemical class 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
229910052910 alkali metal silicate Inorganic materials 0.000 description 2
150000004996 alkyl benzenes Chemical class 0.000 description 2
WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 2
230000008901 benefit Effects 0.000 description 2
SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 2
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
229910001424 calcium ion Inorganic materials 0.000 description 2
150000001720 carbohydrates Chemical group 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
229920003086 cellulose ether Polymers 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
239000003240 coconut oil Substances 0.000 description 2
235000019864 coconut oil Nutrition 0.000 description 2
238000009833 condensation Methods 0.000 description 2
230000005494 condensation Effects 0.000 description 2
239000002537 cosmetic Substances 0.000 description 2
239000002781 deodorant agent Substances 0.000 description 2
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
229940079593 drug Drugs 0.000 description 2
239000003814 drug Substances 0.000 description 2
238000004453 electron probe microanalysis Methods 0.000 description 2
239000003995 emulsifying agent Substances 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
229930182830 galactose Natural products 0.000 description 2
239000008103 glucose Substances 0.000 description 2
229930182478 glucoside Natural products 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
125000001165 hydrophobic group Chemical group 0.000 description 2
229910052816 inorganic phosphate Inorganic materials 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
239000011976 maleic acid Substances 0.000 description 2
229920000609 methyl cellulose Polymers 0.000 description 2
150000004702 methyl esters Chemical class 0.000 description 2
239000001923 methylcellulose Substances 0.000 description 2
235000010981 methylcellulose Nutrition 0.000 description 2
KJPHTXTWFHVJIG-UHFFFAOYSA-N n-ethyl-2-[(6-methoxypyridin-3-yl)-(2-methylphenyl)sulfonylamino]-n-(pyridin-3-ylmethyl)acetamide Chemical compound C=1C=C(OC)N=CC=1N(S(=O)(=O)C=1C(=CC=CC=1)C)CC(=O)N(CC)CC1=CC=CN=C1 KJPHTXTWFHVJIG-UHFFFAOYSA-N 0.000 description 2
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CTQNGGLPUBDAKN-UHFFFAOYSA-N o-dimethylbenzene Natural products CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
239000002304 perfume Substances 0.000 description 2
235000021317 phosphate Nutrition 0.000 description 2
229920001223 polyethylene glycol Polymers 0.000 description 2
239000001267 polyvinylpyrrolidone Substances 0.000 description 2
229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
239000011591 potassium Substances 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000002994 raw material Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000001694 spray drying Methods 0.000 description 2
150000008163 sugars Chemical class 0.000 description 2
230000002195 synergetic effect Effects 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
PJVXUVWGSCCGHT-ZPYZYFCMSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal;(3s,4r,5r)-1,3,4,5,6-pentahydroxyhexan-2-one Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O.OC[C@@H](O)[C@@H](O)[C@H](O)C(=O)CO PJVXUVWGSCCGHT-ZPYZYFCMSA-N 0.000 description 1
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CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
150000000180 1,2-diols Chemical class 0.000 description 1
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OHVLMTFVQDZYHP-UHFFFAOYSA-N 1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-2-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]ethanone Chemical compound N1N=NC=2CN(CCC=21)C(CN1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)=O OHVLMTFVQDZYHP-UHFFFAOYSA-N 0.000 description 1
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125000006539 C12 alkyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
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OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 1
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WQZGKKKJIJFFOK-WHZQZERISA-N D-aldose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-WHZQZERISA-N 0.000 description 1
WQZGKKKJIJFFOK-IVMDWMLBSA-N D-allopyranose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@H](O)[C@@H]1O WQZGKKKJIJFFOK-IVMDWMLBSA-N 0.000 description 1
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208000001840 Dandruff Diseases 0.000 description 1
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
102000004190 Enzymes Human genes 0.000 description 1
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108090001060 Lipase Proteins 0.000 description 1
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229920001007 Nylon 4 Polymers 0.000 description 1
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235000019482 Palm oil Nutrition 0.000 description 1
235000019483 Peanut oil Nutrition 0.000 description 1
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239000004698 Polyethylene Substances 0.000 description 1
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SRBFZHDQGSBBOR-STGXQOJASA-N alpha-D-lyxopyranose Chemical compound O[C@@H]1CO[C@H](O)[C@@H](O)[C@H]1O SRBFZHDQGSBBOR-STGXQOJASA-N 0.000 description 1
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230000009286 beneficial effect Effects 0.000 description 1
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150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
210000004027 cell Anatomy 0.000 description 1
238000012512 characterization method Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
150000001860 citric acid derivatives Chemical class 0.000 description 1
239000004927 clay Substances 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
238000010411 cooking Methods 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
210000003298 dental enamel Anatomy 0.000 description 1
235000011180 diphosphates Nutrition 0.000 description 1
238000004851 dishwashing Methods 0.000 description 1
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239000012153 distilled water Substances 0.000 description 1
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238000001035 drying Methods 0.000 description 1
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238000007046 ethoxylation reaction Methods 0.000 description 1
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239000003925 fat Substances 0.000 description 1
235000019197 fats Nutrition 0.000 description 1
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239000000835 fiber Substances 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000007850 fluorescent dye Substances 0.000 description 1
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239000013505 freshwater Substances 0.000 description 1
230000002070 germicidal effect Effects 0.000 description 1
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230000007062 hydrolysis Effects 0.000 description 1
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125000002768 hydroxyalkyl group Chemical group 0.000 description 1
CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical compound O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 description 1
239000001863 hydroxypropyl cellulose Substances 0.000 description 1
235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
229940071676 hydroxypropylcellulose Drugs 0.000 description 1
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239000012535 impurity Substances 0.000 description 1
239000002563 ionic surfactant Substances 0.000 description 1
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
239000010985 leather Substances 0.000 description 1
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150000002632 lipids Chemical class 0.000 description 1
239000002932 luster Substances 0.000 description 1
229910052943 magnesium sulfate Inorganic materials 0.000 description 1
235000019341 magnesium sulphate Nutrition 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
244000005700 microbiome Species 0.000 description 1
238000012544 monitoring process Methods 0.000 description 1
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ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
239000004006 olive oil Substances 0.000 description 1
235000008390 olive oil Nutrition 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
238000010422 painting Methods 0.000 description 1
239000002540 palm oil Substances 0.000 description 1
239000000312 peanut oil Substances 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
235000020030 perry Nutrition 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
125000003703 phosphorus containing inorganic group Chemical group 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
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235000011176 polyphosphates Nutrition 0.000 description 1
229920001451 polypropylene glycol Polymers 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
239000002243 precursor Substances 0.000 description 1
230000002265 prevention Effects 0.000 description 1
150000003138 primary alcohols Chemical class 0.000 description 1
239000000700 radioactive tracer Substances 0.000 description 1
WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
229960003656 ricinoleic acid Drugs 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
210000002374 sebum Anatomy 0.000 description 1
150000003333 secondary alcohols Chemical class 0.000 description 1
239000003352 sequestering agent Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
229910001388 sodium aluminate Inorganic materials 0.000 description 1
239000000429 sodium aluminium silicate Substances 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000008247 solid mixture Substances 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000003890 succinate salts Chemical class 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229950009390 symclosene Drugs 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
229920003002 synthetic resin Polymers 0.000 description 1
239000000057 synthetic resin Substances 0.000 description 1
239000003760 tallow Substances 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
241000556533 uncultured marine bacterium Species 0.000 description 1
125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
210000005253 yeast cell Anatomy 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0026—Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Molecular Biology (AREA)
Crystallography & Structural Chemistry (AREA)
Detergent Compositions (AREA)

CA 2060698 1991-02-12 1992-02-05 Compositions de detergent Expired - Fee Related CA2060698C (fr)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
GB919102945A GB9102945D0 (en)	1991-02-12	1991-02-12	Detergent composition
GB929201582A GB9201582D0 (en)	1991-02-12	1992-01-24	Detergent composition
GB9201582.5		1992-01-24
GB9102945.4		1992-01-24

Publications (2)

Publication Number	Publication Date
CA2060698A1 CA2060698A1 (fr)	1992-08-13
CA2060698C true CA2060698C (fr)	1997-09-30

Family

ID=26298430

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2060698 Expired - Fee Related CA2060698C (fr)	1991-02-12	1992-02-05	Compositions de detergent

Country Status (5)

Country	Link
EP (1)	EP0499434B1 (fr)
JP (1)	JPH0559394A (fr)
CA (1)	CA2060698C (fr)
DE (1)	DE69203473T2 (fr)
ES (1)	ES2075608T3 (fr)

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FR2689138B1 (fr) *	1992-03-26	1994-05-20	Institut Francais Petrole	Procede de lavage de particules solides comportant une solution de sophorosides.
FR2699928B1 (fr) *	1992-12-30	1995-01-27	Inst Francais Du Petrole	Composition contenant un composé tensio-actif et des sophorolipides et procédé de décontamination d'un milieu poreux pollué par des hydrocarbures.
FR2713655B1 (fr) *	1993-12-15	1998-05-22	Inst Francais Du Petrole	Procédé de décontamination d'un milieu poreux pollué par des hydrocarbures utilisant une composition contenant un composé tensio-actif et des glycolipides.
US5393453A (en) *	1994-02-03	1995-02-28	Colgate Palmolive Co.	Thickened composition containing glycolipid surfactant and polymeric thickener
NZ294826A (en) *	1994-11-04	1998-05-27	Novo Nordisk As	Use of a composition containing glycolipid and polyalcohol in making detergent gels
NL9500292A (nl) *	1995-02-16	1996-10-01	Stichting Nl Instituut Voor Ko	Werkwijze voor omzetting van een zetmeelmateriaal, en daarvoor bruikbaar enzympreparaat.
FR2740779B1 (fr) *	1995-11-08	1997-12-05	Rhone Poulenc Chimie	Composition a base d'enzyme et de sophorolipide sous forme lactone et son utilisation dans les formulations detergentes pour le lavage du linge
DE19600743A1 (de) *	1996-01-11	1997-07-24	Henkel Kgaa	Verwendung von Mischungen aus Glycolipiden und Tensiden
JP4280888B2 (ja) *	2001-03-23	2009-06-17	独立行政法人産業技術総合研究所	生分解性多価カルボン酸エステル・カルボン酸の製造方法
JP2002332496A (ja) *	2001-05-08	2002-11-22	Osaka City	洗浄剤組成物、その製造方法および消臭性繊維
JP2003013093A (ja) *	2001-06-27	2003-01-15	Saraya Kk	低泡性洗浄剤組成物
FR2827192B1 (fr) *	2001-07-13	2004-06-04	Cognis France Sa	Preparations contenant des agents tensio-actifs non ioniques comme agents d'extraction
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JP4548827B2 (ja) *	2004-09-06	2010-09-22	サラヤ株式会社	生分解性の液体洗浄剤組成物
JP2006083238A (ja) *	2004-09-14	2006-03-30	Saraya Kk	洗浄剤組成物
JP5649268B2 (ja) *	2008-05-15	2015-01-07	サラヤ株式会社	ソホロリピッドを含む吸着抑制組成物
US8664373B2 (en) *	2008-10-28	2014-03-04	Kaneka Corporation	Method for producing sophorose lipid
JO3416B1 (ar) *	2009-04-27	2019-10-20	Jeneil Biosurfactant Co Llc	تركيبات مضادة للبكتيريا وطرق استخدامها
WO2011120776A1 (fr)	2010-03-31	2011-10-06	Unilever Plc	Composition détergente moussante, douce pour la peau
CN103052704A (zh)	2010-07-22	2013-04-17	荷兰联合利华有限公司	用于提高清洁的鼠李糖脂和酶的组合物
EP2410039A1 (fr)	2010-07-22	2012-01-25	Unilever PLC	Rhamnolipides à nettoyage amélioré
WO2012167815A1 (fr) *	2011-06-06	2012-12-13	Ecover Co-Ordination Center N.V.	Compositions de sophorolactone et leurs utilisations
US10287615B2 (en)	2011-06-06	2019-05-14	Ecover Co-Ordination Center N.V.	Sophorolactone production
US9441115B2 (en) *	2011-11-14	2016-09-13	Tantz Environmental Technologies Ltd.	Aqueous phase pore sealing agent imroving PCB coating oxidation-resistant and corrosion-resistant properties and method for using same
DE102011090030B4 (de)	2011-12-28	2025-11-06	Evonik Operations Gmbh	Wässrige Haar- und Hautreinigungszusammensetzungen, enthaltend Biotenside
JPWO2013129667A1 (ja)	2012-03-02	2015-07-30	サラヤ株式会社	高純度酸型ソホロリピッド含有物及びその製造方法
EP2847285B1 (fr)	2012-05-07	2016-07-13	Rhodia Operations	Revêtements et peintures aqueux incorporant un ou plusieurs biosurfactants antimicrobiens et leurs procédés d'utilisation
FR2991688B1 (fr)	2012-06-06	2015-05-22	Soliance	Biosolubilisant
DE102013205755A1 (de) *	2013-04-02	2014-10-02	Evonik Industries Ag	Waschmittelformulierung für Textilien enthaltend Rhamnolipide mit einem überwiegenden Gehalt an di-Rhamnolipiden
DE102013205756A1 (de)	2013-04-02	2014-10-02	Evonik Industries Ag	Mischungszusammensetzung enthaltend Rhamnolipide
DE102013206314A1 (de)	2013-04-10	2014-10-16	Evonik Industries Ag	Kosmetische Formulierung enthaltend Copolymer sowie Sulfosuccinat und/oder Biotensid
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1992
- 1992-02-05 CA CA 2060698 patent/CA2060698C/fr not_active Expired - Fee Related
- 1992-02-10 ES ES92301101T patent/ES2075608T3/es not_active Expired - Lifetime
- 1992-02-10 EP EP92301101A patent/EP0499434B1/fr not_active Expired - Lifetime
- 1992-02-10 DE DE1992603473 patent/DE69203473T2/de not_active Expired - Fee Related
- 1992-02-12 JP JP2551992A patent/JPH0559394A/ja active Pending

Also Published As

Publication number	Publication date
DE69203473T2 (de)	1996-01-11
ES2075608T3 (es)	1995-10-01
EP0499434A1 (fr)	1992-08-19
CA2060698A1 (fr)	1992-08-13
JPH0559394A (ja)	1993-03-09
DE69203473D1 (de)	1995-08-24
EP0499434B1 (fr)	1995-07-19

Legal Events

Date	Code	Title	Description
1992-04-08	EEER	Examination request
1999-02-05	MKLA	Lapsed

Publication	Publication Date	Title
US5520839A (en)	1996-05-28	Laundry detergent composition containing synergistic combination of sophorose lipid and nonionic surfactant
US5417879A (en)	1995-05-23	Synergistic dual-surfactant detergent composition containing sophoroselipid
EP0499434B1 (fr)	1995-07-19	Compositions détergentes
EP0377261B1 (fr)	1996-04-10	Composition détergente
USH1818H (en)	1999-11-02	Detergent and cleaning compositions derived from new detergent alcohols
EP0342917B2 (fr)	2006-10-25	Composition détergente
CA1328065C (fr)	1994-03-29	Compositions detergentes
AU643849B2 (en)	1993-11-25	Detergent compositions
CA2713280C (fr)	2012-02-21	Detergent a lessive comportant un agent tensio-actif non ionique hautement ethoxyle
AU639243B2 (en)	1993-07-22	Liquid detergent composition
CA1334919C (fr)	1995-03-28	Compositions de detergents liquides
CA2057462A1 (fr)	1992-06-19	Composition detergente
CA1323276C (fr)	1993-10-19	Compositions detergentes
WO2002050223A1 (fr)	2002-06-27	Compositions detergentes contenant des tensioactifs non ioniques a base d'ethoxy alcool
EP0423968A1 (fr)	1991-04-24	Composition détergente
AU621374B2 (en)	1992-03-12	Liquid detergent compositions
US5866525A (en)	1999-02-02	Laundry detergent compositions containing lipase and soil release polymer
CA2236438A1 (fr)	1997-05-09	Peroxyacides
EP0754216B1 (fr)	1998-07-15	Compositions detergentes contenant des aldobionamides
EP0491532A1 (fr)	1992-06-24	Compositions détergentes
CA2148096A1 (fr)	1994-06-09	Compositions detergentes renfermant un amide d'acide gras polyhydroxyle, un amide d'acide gras polyhydroxyle sulfate et du savon
MXPA98007084A (en)	1999-02-24	Detergent compositions for the