CA2063264C - Composition de detersif liquide - Google Patents

Composition de detersif liquide Download PDF

Info

Publication number: CA2063264C
Authority: CA; Canada
Prior art keywords: nonionic; composition according; weight; fatty; detergent
Prior art date: 1989-06-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002063264A

Other languages

English (en)

Other versions

CA2063264A1 (fr

Inventor

Frederik J. Schepers

Albertus Jurgens

Johannes C. Van De Pas

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Original Assignee

Unilever PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-06-26

Filing date

1990-06-12

Publication date

2001-10-02

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=10659051&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2063264(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1990-06-12 Application filed by Unilever PLC filed Critical Unilever PLC

1990-12-27 Publication of CA2063264A1 publication Critical patent/CA2063264A1/fr

2001-10-02 Application granted granted Critical

2001-10-02 Publication of CA2063264C publication Critical patent/CA2063264C/fr

2010-06-12 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 74
239000003599 detergent Substances 0.000 title claims abstract description 27
239000007788 liquid Substances 0.000 title claims abstract description 18
239000000463 material Substances 0.000 claims abstract description 44
PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 39
235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 20
239000000194 fatty acid Substances 0.000 claims abstract description 20
229930195729 fatty acid Natural products 0.000 claims abstract description 20
150000004665 fatty acids Chemical class 0.000 claims abstract description 17
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 16
-1 pentose sugars Chemical class 0.000 claims abstract description 16
125000000217 alkyl group Chemical group 0.000 claims abstract description 11
125000002947 alkylene group Chemical group 0.000 claims abstract description 7
239000003945 anionic surfactant Substances 0.000 claims abstract description 7
150000002402 hexoses Chemical class 0.000 claims abstract description 7
125000003545 alkoxy group Chemical group 0.000 claims abstract description 6
230000015572 biosynthetic process Effects 0.000 claims abstract description 6
239000002736 nonionic surfactant Substances 0.000 claims abstract description 6
125000003342 alkenyl group Chemical group 0.000 claims abstract description 5
235000000346 sugar Nutrition 0.000 claims abstract description 5
150000002148 esters Chemical class 0.000 claims abstract description 4
150000002193 fatty amides Chemical class 0.000 claims abstract description 4
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract 2
235000019256 formaldehyde Nutrition 0.000 claims abstract 2
229920000642 polymer Polymers 0.000 claims description 33
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
125000001165 hydrophobic group Chemical group 0.000 claims description 8
238000000034 method Methods 0.000 claims description 8
230000002209 hydrophobic effect Effects 0.000 claims description 4
238000005191 phase separation Methods 0.000 claims description 3
150000001720 carbohydrates Chemical group 0.000 claims description 2
UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 claims description 2
150000002972 pentoses Chemical group 0.000 claims description 2
238000002360 preparation method Methods 0.000 claims description 2
150000001412 amines Chemical class 0.000 abstract description 5
229920005862 polyol Polymers 0.000 abstract description 4
150000003077 polyols Chemical class 0.000 abstract description 4
150000005690 diesters Chemical class 0.000 abstract description 2
239000003792 electrolyte Substances 0.000 description 29
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 13
229910052708 sodium Inorganic materials 0.000 description 13
239000011734 sodium Substances 0.000 description 13
239000004094 surface-active agent Substances 0.000 description 12
239000011149 active material Substances 0.000 description 8
LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 8
229920001983 poloxamer Polymers 0.000 description 8
239000007787 solid Substances 0.000 description 8
239000002253 acid Substances 0.000 description 7
150000001298 alcohols Chemical class 0.000 description 7
229910021538 borax Inorganic materials 0.000 description 7
150000001875 compounds Chemical class 0.000 description 7
239000012071 phase Substances 0.000 description 7
239000004328 sodium tetraborate Substances 0.000 description 7
235000010339 sodium tetraborate Nutrition 0.000 description 7
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
239000004615 ingredient Substances 0.000 description 6
239000002245 particle Substances 0.000 description 6
239000011591 potassium Substances 0.000 description 6
229910052700 potassium Inorganic materials 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
239000008346 aqueous phase Substances 0.000 description 5
239000007795 chemical reaction product Substances 0.000 description 5
239000000047 product Substances 0.000 description 5
239000007864 aqueous solution Substances 0.000 description 4
239000003240 coconut oil Substances 0.000 description 4
235000019864 coconut oil Nutrition 0.000 description 4
239000006185 dispersion Substances 0.000 description 4
238000009472 formulation Methods 0.000 description 4
229930182478 glucoside Natural products 0.000 description 4
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
230000001105 regulatory effect Effects 0.000 description 4
239000000344 soap Substances 0.000 description 4
239000001509 sodium citrate Substances 0.000 description 4
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 4
229960001790 sodium citrate Drugs 0.000 description 4
235000011083 sodium citrates Nutrition 0.000 description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
125000000129 anionic group Chemical group 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
GTZOYNFRVVHLDZ-UHFFFAOYSA-N dodecane-1,1-diol Chemical compound CCCCCCCCCCCC(O)O GTZOYNFRVVHLDZ-UHFFFAOYSA-N 0.000 description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
239000004744 fabric Substances 0.000 description 3
150000002191 fatty alcohols Chemical class 0.000 description 3
239000003752 hydrotrope Substances 0.000 description 3
238000005185 salting out Methods 0.000 description 3
235000019832 sodium triphosphate Nutrition 0.000 description 3
238000003756 stirring Methods 0.000 description 3
239000003760 tallow Substances 0.000 description 3
239000010457 zeolite Substances 0.000 description 3
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
XDAVBNHKLPHGGU-UHFFFAOYSA-N 2-methylpentadec-2-enoic acid Chemical compound CCCCCCCCCCCCC=C(C)C(O)=O XDAVBNHKLPHGGU-UHFFFAOYSA-N 0.000 description 2
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
244000060011 Cocos nucifera Species 0.000 description 2
235000013162 Cocos nucifera Nutrition 0.000 description 2
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
239000005642 Oleic acid Substances 0.000 description 2
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
229910021536 Zeolite Inorganic materials 0.000 description 2
239000003377 acid catalyst Substances 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
229910001424 calcium ion Inorganic materials 0.000 description 2
125000001589 carboacyl group Chemical group 0.000 description 2
150000007942 carboxylates Chemical class 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
230000003301 hydrolyzing effect Effects 0.000 description 2
238000010348 incorporation Methods 0.000 description 2
SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
239000000693 micelle Substances 0.000 description 2
GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
238000001935 peptisation Methods 0.000 description 2
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 2
125000003703 phosphorus containing inorganic group Chemical group 0.000 description 2
229920001296 polysiloxane Polymers 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
159000000001 potassium salts Chemical class 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
239000011343 solid material Substances 0.000 description 2
239000002195 soluble material Substances 0.000 description 2
239000000243 solution Substances 0.000 description 2
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 2
150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
239000000725 suspension Substances 0.000 description 2
239000004711 α-olefin Substances 0.000 description 2
XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
FKOKUHFZNIUSLW-UHFFFAOYSA-N 2-Hydroxypropyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(C)O FKOKUHFZNIUSLW-UHFFFAOYSA-N 0.000 description 1
YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 1
102000013142 Amylases Human genes 0.000 description 1
108010065511 Amylases Proteins 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
229910021532 Calcite Inorganic materials 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
108090000790 Enzymes Proteins 0.000 description 1
102000004190 Enzymes Human genes 0.000 description 1
CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
239000004367 Lipase Substances 0.000 description 1
102000004882 Lipase Human genes 0.000 description 1
108090001060 Lipase Proteins 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
235000019483 Peanut oil Nutrition 0.000 description 1
102000035195 Peptidases Human genes 0.000 description 1
108091005804 Peptidases Proteins 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
229920000388 Polyphosphate Polymers 0.000 description 1
239000004365 Protease Substances 0.000 description 1
101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
235000019484 Rapeseed oil Nutrition 0.000 description 1
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000004480 active ingredient Substances 0.000 description 1
238000007259 addition reaction Methods 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
235000019418 amylase Nutrition 0.000 description 1
229940025131 amylases Drugs 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
125000002843 carboxylic acid group Chemical group 0.000 description 1
239000004359 castor oil Substances 0.000 description 1
235000019438 castor oil Nutrition 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
229960000541 cetyl alcohol Drugs 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
235000011180 diphosphates Nutrition 0.000 description 1
VUJGKADZTYCLIL-YHPRVSEPSA-L disodium;5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfonatophenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 VUJGKADZTYCLIL-YHPRVSEPSA-L 0.000 description 1
238000001493 electron microscopy Methods 0.000 description 1
229940088598 enzyme Drugs 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000007046 ethoxylation reaction Methods 0.000 description 1
239000002979 fabric softener Substances 0.000 description 1
238000005189 flocculation Methods 0.000 description 1
230000016615 flocculation Effects 0.000 description 1
239000007850 fluorescent dye Substances 0.000 description 1
230000002070 germicidal effect Effects 0.000 description 1
150000008131 glucosides Chemical class 0.000 description 1
RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 description 1
ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
229910052816 inorganic phosphate Inorganic materials 0.000 description 1
229940045996 isethionic acid Drugs 0.000 description 1
229940099367 lanolin alcohols Drugs 0.000 description 1
235000019421 lipase Nutrition 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
230000002535 lyotropic effect Effects 0.000 description 1
238000005259 measurement Methods 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000000178 monomer Substances 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
238000001683 neutron diffraction Methods 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
239000011368 organic material Substances 0.000 description 1
238000012856 packing Methods 0.000 description 1
239000003346 palm kernel oil Substances 0.000 description 1
235000019865 palm kernel oil Nutrition 0.000 description 1
239000000312 peanut oil Substances 0.000 description 1
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
239000002304 perfume Substances 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920005646 polycarboxylate Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
235000015497 potassium bicarbonate Nutrition 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
235000011181 potassium carbonates Nutrition 0.000 description 1
TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical class [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
235000013966 potassium salts of fatty acid Nutrition 0.000 description 1
150000003138 primary alcohols Chemical class 0.000 description 1
238000012545 processing Methods 0.000 description 1
229940093625 propylene glycol monostearate Drugs 0.000 description 1
238000000518 rheometry Methods 0.000 description 1
WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
229960003656 ricinoleic acid Drugs 0.000 description 1
FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000003352 sequestering agent Substances 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000004289 sodium hydrogen sulphite Substances 0.000 description 1
235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
235000013875 sodium salts of fatty acid Nutrition 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000007784 solid electrolyte Substances 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
230000008719 thickening Effects 0.000 description 1
229940087291 tridecyl alcohol Drugs 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0026—Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/42—Amino alcohols or amino ethers
- C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/526—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Crystallography & Structural Chemistry (AREA)
Detergent Compositions (AREA)
Cosmetics (AREA)

CA002063264A 1989-06-26 1990-06-12 Composition de detersif liquide Expired - Fee Related CA2063264C (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
GB898914602A GB8914602D0 (en)	1989-06-26	1989-06-26	Liquid detergent composition
GB8914602.1		1989-06-26
PCT/EP1990/000971 WO1991000331A1 (fr)	1989-06-26	1990-06-12	Composition de detergent liquide

Publications (2)

Publication Number	Publication Date
CA2063264A1 CA2063264A1 (fr)	1990-12-27
CA2063264C true CA2063264C (fr)	2001-10-02

Family

ID=10659051

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002063264A Expired - Fee Related CA2063264C (fr)	1989-06-26	1990-06-12	Composition de detersif liquide

Country Status (11)

Country	Link
EP (1)	EP0479846B2 (fr)
JP (1)	JPH04506367A (fr)
KR (1)	KR960000200B1 (fr)
AU (1)	AU639243B2 (fr)
BR (1)	BR9007474A (fr)
CA (1)	CA2063264C (fr)
DE (1)	DE69004432T3 (fr)
ES (1)	ES2060182T5 (fr)
GB (1)	GB8914602D0 (fr)
WO (1)	WO1991000331A1 (fr)
ZA (1)	ZA904960B (fr)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB9025248D0 (en) *	1990-11-20	1991-01-02	Unilever Plc	Detergent compositions
CA2060698C (fr) *	1991-02-12	1997-09-30	Peter J. Hall	Compositions de detergent
GB9102945D0 (en) *	1991-02-12	1991-03-27	Unilever Plc	Detergent composition
DE4236109A1 (de) *	1992-10-26	1994-04-28	Henkel Kgaa	Flüssiges Waschmittel
DE69321562T3 (de) *	1992-11-26	2002-04-18	The Procter & Gamble Company, Cincinnati	Reinigungsmittelzusammensetzungen mit einer Kombination aus stark hydrophilen und stark hydrophoben nichtionischen Tensiden
SK53294A3 (en)	1993-05-07	1995-04-12	Albright & Wilson	Concentrated aqueous mixture containing surface active matter and its use
US6090762A (en) *	1993-05-07	2000-07-18	Albright & Wilson Uk Limited	Aqueous based surfactant compositions
US5520839A (en) *	1993-09-10	1996-05-28	Lever Brothers Company, Division Of Conopco, Inc.	Laundry detergent composition containing synergistic combination of sophorose lipid and nonionic surfactant
TW294720B (fr) *	1994-09-30	1997-01-01	Unilever Nv
DE19517033A1 (de) *	1995-05-10	1996-11-14	Hoechst Ag	Tensidgemisch
JP3556806B2 (ja) *	1996-07-24	2004-08-25	サンスター株式会社	洗浄剤組成物
US6194371B1 (en) *	1998-05-01	2001-02-27	Ecolab Inc.	Stable alkaline emulsion cleaners
KR100462314B1 (ko) *	2001-05-07	2004-12-23	(주)네오팜	산업용 세정제 조성물 및 그 제조 방법
EP1747260A4 (fr) *	2004-04-15	2008-07-30	Rhodia	Compositions de tensio-actifs structures
JP5046714B2 (ja)	2007-04-06	2012-10-10	花王株式会社	衣料用洗剤組成物
US8034757B2 (en)	2007-12-28	2011-10-11	Kao Corporation	Detergent composition for clothing
JP6093691B2 (ja) *	2011-02-25	2017-03-08	ライオン株式会社	衣料用液体洗浄剤
JP7691229B2 (ja) *	2019-11-25	2025-06-11	花王株式会社	繊維製品用液体洗浄剤組成物

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4206070A (en) *	1975-12-24	1980-06-03	The Procter & Gamble Company	Detergent compositions
CA1081574A (fr) *	1975-12-24	1980-07-15	Kenneth L. Jones	Detergents
JPS5920754B2 (ja) *	1980-09-08	1984-05-15	日産自動車株式会社	工業用金属洗浄剤
GB8308263D0 (en) *	1983-03-25	1983-05-05	Unilever Plc	Aqueous liquid detergent composition
JPH0678550B2 (ja) *	1986-07-09	1994-10-05	旭電化工業株式会社	すすぎ助剤組成物
DE3626224A1 (de) *	1986-08-02	1988-02-04	Henkel Kgaa	Reinigungsmittel
GB8718215D0 (en) *	1987-07-31	1987-09-09	Unilever Plc	Liquid detergent compositions
GB8813978D0 (en) *	1988-06-13	1988-07-20	Unilever Plc	Liquid detergents
JP2693827B2 (ja) *	1988-06-13	1997-12-24	ユニリーバー・ナームローゼ・ベンノートシヤープ	液体洗剤組成物
MA21850A1 (fr) *	1989-05-22	1990-12-31	Procter & Gamble	Comosition detergente pour vaisselle liquide ou sous forme de gel domestique contenant un agent tensio - actif a base d'alcoyl - ethoxy - carboxylate .

1989
- 1989-06-26 GB GB898914602A patent/GB8914602D0/en active Pending
1990
- 1990-06-12 DE DE69004432T patent/DE69004432T3/de not_active Expired - Fee Related
- 1990-06-12 BR BR909007474A patent/BR9007474A/pt not_active IP Right Cessation
- 1990-06-12 ES ES90909723T patent/ES2060182T5/es not_active Expired - Lifetime
- 1990-06-12 AU AU58559/90A patent/AU639243B2/en not_active Ceased
- 1990-06-12 CA CA002063264A patent/CA2063264C/fr not_active Expired - Fee Related
- 1990-06-12 EP EP90909723A patent/EP0479846B2/fr not_active Expired - Lifetime
- 1990-06-12 KR KR1019910701967A patent/KR960000200B1/ko not_active Expired - Fee Related
- 1990-06-12 WO PCT/EP1990/000971 patent/WO1991000331A1/fr not_active Ceased
- 1990-06-12 JP JP2509164A patent/JPH04506367A/ja active Pending
- 1990-06-26 ZA ZA904960A patent/ZA904960B/xx unknown

Also Published As

Publication number	Publication date
ES2060182T3 (es)	1994-11-16
EP0479846A1 (fr)	1992-04-15
EP0479846B1 (fr)	1993-11-03
DE69004432T2 (de)	1994-02-24
DE69004432T3 (de)	2004-03-18
JPH04506367A (ja)	1992-11-05
EP0479846B2 (fr)	2003-08-27
AU639243B2 (en)	1993-07-22
ES2060182T5 (es)	2004-05-01
CA2063264A1 (fr)	1990-12-27
GB8914602D0 (en)	1989-08-16
WO1991000331A1 (fr)	1991-01-10
ZA904960B (en)	1992-02-26
DE69004432D1 (de)	1993-12-09
AU5855990A (en)	1991-01-17
BR9007474A (pt)	1992-06-16
KR920702718A (ko)	1992-10-06
KR960000200B1 (ko)	1996-01-03

Legal Events

Date	Code	Title	Description
1997-01-20	EEER	Examination request
2004-06-14	MKLA	Lapsed

Publication	Publication Date	Title
CA2063264C (fr)	2001-10-02	Composition de detersif liquide
AU643849B2 (en)	1993-11-25	Detergent compositions
EP0526539B1 (fr)	1994-01-12	Compositions pour detergents liquides
US5205957A (en)	1993-04-27	Structured aqueous liquid detergents containing functional polymers
CA1323280C (fr)	1993-10-19	Detergents liquides
CA1334919C (fr)	1995-03-28	Compositions de detergents liquides
EP1115833B1 (fr)	2004-12-15	Composition detergente
JPH11508933A (ja)	1999-08-03	発泡系を含む非水性洗剤組成物
EP0499623B1 (fr)	1996-03-27	Compositions detergentes
GB2237813A (en)	1991-05-15	Liquid detergent
EP0362916B1 (fr)	1995-04-19	Compositions détergentes liquides
EP0498806B1 (fr)	1994-06-22	Compositions detergentes
EP0423968A1 (fr)	1991-04-24	Composition détergente
CA1335646C (fr)	1995-05-23	Compositions de detergents liquides
CA2066623C (fr)	2001-03-06	Detersifs liquides des polymeres deflocucants
EP0514434B2 (fr)	2002-08-14	Composition de blanchissage liquide
EP0491532A1 (fr)	1992-06-24	Compositions détergentes
EP0491723B1 (fr)	1994-11-17	Detergents liquides
GB2255352A (en)	1992-11-04	Liquid detergent compositions and their use
EP0798372A2 (fr)	1997-10-01	Composition détergente
CA2201456A1 (fr)	1997-09-29	Composition de detergent