CA2374068C - Composition ignifuge exempte d'halogene - Google Patents
Composition ignifuge exempte d'halogene Download PDFInfo
- Publication number
- CA2374068C CA2374068C CA002374068A CA2374068A CA2374068C CA 2374068 C CA2374068 C CA 2374068C CA 002374068 A CA002374068 A CA 002374068A CA 2374068 A CA2374068 A CA 2374068A CA 2374068 C CA2374068 C CA 2374068C
- Authority
- CA
- Canada
- Prior art keywords
- melamine
- composition according
- component
- compound
- flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 82
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 239000003063 flame retardant Substances 0.000 title claims abstract description 24
- -1 melamine - phosphorus compound Chemical class 0.000 claims abstract description 41
- 150000001875 compounds Chemical class 0.000 claims abstract description 29
- 229920000642 polymer Polymers 0.000 claims abstract description 20
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 18
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229920000728 polyester Polymers 0.000 claims abstract description 15
- 239000004952 Polyamide Substances 0.000 claims abstract description 10
- 229920002647 polyamide Polymers 0.000 claims abstract description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 7
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 7
- 150000002903 organophosphorus compounds Chemical class 0.000 claims abstract description 6
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 15
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 12
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 11
- 239000005977 Ethylene Substances 0.000 claims description 10
- 229920002292 Nylon 6 Polymers 0.000 claims description 8
- 239000003365 glass fiber Substances 0.000 claims description 8
- 229920001897 terpolymer Polymers 0.000 claims description 8
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 5
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 5
- 239000007859 condensation product Substances 0.000 claims description 4
- 239000011112 polyethylene naphthalate Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 3
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 claims description 3
- 229920006149 polyester-amide block copolymer Polymers 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 229920002302 Nylon 6,6 Polymers 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims 1
- 239000002253 acid Substances 0.000 abstract description 7
- 150000008065 acid anhydrides Chemical class 0.000 abstract description 4
- 239000000126 substance Substances 0.000 description 7
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 6
- YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-n-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 229920001634 Copolyester Polymers 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 150000007974 melamines Chemical class 0.000 description 4
- OWICEWMBIBPFAH-UHFFFAOYSA-N (3-diphenoxyphosphoryloxyphenyl) diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1)(=O)OC1=CC=CC=C1 OWICEWMBIBPFAH-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 229920006351 engineering plastic Polymers 0.000 description 3
- YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- LIAWCKFOFPPVGF-UHFFFAOYSA-N 2-ethyladamantane Chemical compound C1C(C2)CC3CC1C(CC)C2C3 LIAWCKFOFPPVGF-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 2
- 229920001281 polyalkylene Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000012744 reinforcing agent Substances 0.000 description 2
- 238000004904 shortening Methods 0.000 description 2
- NFLGAXVYCFJBMK-RKDXNWHRSA-N (+)-isomenthone Natural products CC(C)[C@H]1CC[C@@H](C)CC1=O NFLGAXVYCFJBMK-RKDXNWHRSA-N 0.000 description 1
- XMNDMAQKWSQVOV-UHFFFAOYSA-N (2-methylphenyl) diphenyl phosphate Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 XMNDMAQKWSQVOV-UHFFFAOYSA-N 0.000 description 1
- GGHBKCSNURXPNB-UHFFFAOYSA-N 2-n,4-n,6-n-triphenyl-1,3,5-triazine-2,4,6-triamine Chemical compound N=1C(NC=2C=CC=CC=2)=NC(NC=2C=CC=CC=2)=NC=1NC1=CC=CC=C1 GGHBKCSNURXPNB-UHFFFAOYSA-N 0.000 description 1
- 239000004953 Aliphatic polyamide Substances 0.000 description 1
- 241000531908 Aramides Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- 239000004608 Heat Stabiliser Substances 0.000 description 1
- NFLGAXVYCFJBMK-UHFFFAOYSA-N Menthone Chemical compound CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920003298 Nucrel® Polymers 0.000 description 1
- 229920001283 Polyalkylene terephthalate Polymers 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 229920003231 aliphatic polyamide Polymers 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229930007503 menthone Natural products 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000005487 naphthalate group Chemical group 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229920006012 semi-aromatic polyamide Polymers 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 125000005425 toluyl group Chemical group 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
La présente invention concerne une composition ignifuge exempte d'halogène. Cette composition comprend au moins (A) un composé de phosphore organique et (B) de la mélamine ou un composé dérivé de la mélamine, ou un composé mélamine-phosphore (AB) et un composé polymère comprenant un oléfine contenant de 2 à 12 atomes de carbone et 0,1 à 30 % en poids (par rapport au poids du composé polymère) d'un composé contenant des groupes acide, anhydride d'acide ou epoxy. L'invention concerne également une composition de polycondensat contenant la composition ignifuge décrite dans l'invention. Cette composition ignifuge présente l'avantage de raccourcir le temps de combustion de la composition du polycondensat dans laquelle elle est utilisée. De préférence, la composition ignifuge est utilisée dans les polyesters et les polyamides.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL1012176 | 1999-05-28 | ||
| NL1012176A NL1012176C2 (nl) | 1999-05-28 | 1999-05-28 | Halogeenvrije brandvertragende samenstelling. |
| PCT/NL2000/000293 WO2000073375A2 (fr) | 1999-05-28 | 2000-05-08 | Composition ignifuge exempte d'halogene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2374068A1 CA2374068A1 (fr) | 2000-12-07 |
| CA2374068C true CA2374068C (fr) | 2009-08-25 |
Family
ID=19769275
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002374068A Expired - Fee Related CA2374068C (fr) | 1999-05-28 | 2000-05-08 | Composition ignifuge exempte d'halogene |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6767941B2 (fr) |
| EP (1) | EP1189980B1 (fr) |
| JP (1) | JP2004506048A (fr) |
| CN (1) | CN100410303C (fr) |
| AT (1) | ATE277113T1 (fr) |
| AU (1) | AU4625600A (fr) |
| CA (1) | CA2374068C (fr) |
| DE (1) | DE60014080T2 (fr) |
| NL (1) | NL1012176C2 (fr) |
| TW (1) | TW553987B (fr) |
| WO (1) | WO2000073375A2 (fr) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7138448B2 (en) * | 2002-11-04 | 2006-11-21 | Ciba Specialty Chemicals Corporation | Flame retardant compositions |
| CN1331931C (zh) * | 2003-04-30 | 2007-08-15 | 刘信东 | 无卤低烟磷氮层状硅酸盐复合聚乙烯电线电缆护套料及制备方法 |
| US8034870B2 (en) * | 2003-12-17 | 2011-10-11 | Sabic Innovative Plastics Ip B.V. | Flame-retardant polyester composition |
| US8188172B2 (en) * | 2003-12-17 | 2012-05-29 | Sabic Innovative Plastics Ip B.V. | Polyester compositions, method of manufacture, and uses thereof |
| DE102004048876A1 (de) * | 2004-09-13 | 2006-03-30 | Bayer Ag | Halogenfreie flammgeschützte thermoplastische Formmassen auf Basis von Polyamid mit erhöhter Glühdrahtbeständigkeit |
| US7893141B2 (en) * | 2004-09-30 | 2011-02-22 | Sabic Innovative Plastics Ip B.V. | Halogen-free flame retardant polyester |
| KR20080072970A (ko) * | 2004-11-22 | 2008-08-07 | 제너럴 일렉트릭 캄파니 | 난연성 폴리(아릴렌 에테르)/폴리아미드 조성물 및 그의제조 방법 |
| US20060111548A1 (en) * | 2004-11-22 | 2006-05-25 | Mark Elkovitch | Method of making a flame retardant poly(arylene ether)/polyamide composition and the composition thereof |
| US7592382B2 (en) * | 2004-11-22 | 2009-09-22 | Sabic Innovative Plastics Ip B.V. | Flame retardant poly(arylene ether)/polyamide compositions, methods, and articles |
| US20060167143A1 (en) * | 2004-11-22 | 2006-07-27 | General Electric Company | Flame Retardant Poly(Arylene Ether)/Polyamide Composition |
| CN101460591A (zh) * | 2006-04-04 | 2009-06-17 | 帝斯曼知识产权资产管理有限公司 | 无卤阻燃性聚酯组合物 |
| US20080075983A1 (en) * | 2006-09-25 | 2008-03-27 | Ming-Ming Chen | Flame-retardant filament and method of manufacture thereof and protective sleeves constructed therefrom |
| US8795557B2 (en) * | 2008-03-31 | 2014-08-05 | Sabic Innovative Plastics Ip B.V. | Flame resistant polyphthalamide/poly(arylene ether) composition |
| US7829614B2 (en) * | 2008-12-30 | 2010-11-09 | Sabic Innovative Plastics Ip B.V. | Reinforced polyester compositions, methods of manufacture, and articles thereof |
| US8138244B2 (en) * | 2008-12-30 | 2012-03-20 | Sabic Innovative Plastics Ip B.V. | Reinforced polyester compositions, method of manufacture, and articles thereof |
| US8871843B2 (en) * | 2009-12-15 | 2014-10-28 | Apple Inc. | Halogen-free flame retardant material |
| US8686072B2 (en) | 2010-06-29 | 2014-04-01 | Sabic Innovative Plastics Ip B.V. | Flame resistant polyester compositions, method of manufacture, and articles therof |
| US8716378B2 (en) | 2010-06-29 | 2014-05-06 | Sabic Innovative Plastics Ip B.V. | Flame resistant polyester compositions, method of manufacture, and articles thereof |
| US8604105B2 (en) | 2010-09-03 | 2013-12-10 | Eastman Chemical Company | Flame retardant copolyester compositions |
| KR101215315B1 (ko) * | 2011-01-07 | 2013-01-04 | (주)시너지매트리얼 | 할로겐 비함유 난연성 수지 조성물 |
| US8653168B2 (en) * | 2011-05-10 | 2014-02-18 | Basf Se | Flame-retardant thermoplastic molding composition |
| CN102367324B (zh) * | 2011-06-24 | 2013-01-16 | 深圳市科聚新材料有限公司 | 一种pbt复合材料及其制备方法 |
| JP2013189512A (ja) * | 2012-03-13 | 2013-09-26 | Ube Industries Ltd | ポリアミド樹脂組成物 |
| DE112012006785T5 (de) | 2012-08-09 | 2015-07-16 | Empire Technology Development Llc | Flammhemmendes Nylon |
| US8865279B2 (en) | 2013-03-04 | 2014-10-21 | Sabic Global Technologies B.V. | Reinforced polyphthalamide/poly(phenylene ether) composition |
| US20160312121A1 (en) * | 2013-10-02 | 2016-10-27 | Empire Technology Development Llc | Bromine-free fire retardant (fr) agents capable of using a cyclization mechanism |
| EP2927272B1 (fr) | 2014-03-31 | 2017-08-16 | Ems-Patent Ag | Masses de formage en polyamide, leur procédé de fabrication et utilisations de ces masses de formage en polyamide |
| SE1650882A1 (en) | 2016-06-21 | 2017-11-07 | Pp Polymer Ab | Flame retardant additive for polymers |
| CN112409786B (zh) * | 2020-10-12 | 2022-05-20 | 金发科技股份有限公司 | 一种低模垢无卤阻燃热塑性聚酰胺组合物及其制备方法和应用 |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2827867A1 (de) * | 1978-06-24 | 1980-01-17 | Hoechst Ag | Schwerentflammbare thermoplasten |
| JPS5592758A (en) * | 1978-11-06 | 1980-07-14 | Toray Ind Inc | Resin composition |
| JPS55139448A (en) * | 1979-04-17 | 1980-10-31 | Toray Ind Inc | Thermoplastic polyester composition for molding |
| JPS5755957A (en) * | 1980-09-22 | 1982-04-03 | Toray Ind Inc | Flame-retardant polyester composition |
| WO1988000953A1 (fr) * | 1986-08-04 | 1988-02-11 | Toray Industries, Inc. | Composition de resine et son procede de preparation |
| US5091478A (en) * | 1986-11-14 | 1992-02-25 | E. I. Du Pont De Nemours And Company | Partially grafted thermoplastic compositions |
| EP0307802B1 (fr) * | 1987-09-09 | 1995-01-11 | Nippon Petrochemicals Company, Limited | Composition thermoplastique et procédé pour sa préparation |
| DE3732907A1 (de) * | 1987-09-30 | 1989-04-13 | Basf Ag | Selbstverloeschende, thermoplastische polyphenylenether-polyamid-formmassen und ihre verwendung zur herstllung von formkoerpern |
| AU627176B2 (en) * | 1988-05-13 | 1992-08-20 | E.I. Du Pont De Nemours And Company | Thermoplastic elastomeric compositions |
| JPH02163153A (ja) * | 1988-12-16 | 1990-06-22 | Nippon Petrochem Co Ltd | 難燃性ポリエステル樹脂組成物 |
| US5380774A (en) * | 1989-11-28 | 1995-01-10 | Hoechst Celanese Corporation | Nylon molding compositions exhibiting improved protection against UV-light degradation |
| DE4026475A1 (de) * | 1990-08-22 | 1992-02-27 | Bayer Ag | Ternaere mischungen |
| JP2682921B2 (ja) * | 1990-11-30 | 1997-11-26 | 三井石油化学工業株式会社 | 熱可塑性樹脂組成物 |
| JPH0781016B2 (ja) * | 1991-03-18 | 1995-08-30 | 東レ株式会社 | ポリアミド吹込成形品 |
| JP3150733B2 (ja) * | 1991-10-09 | 2001-03-26 | デーエスエム ナムローゼ フェンノートシャップ | 樹脂組成物 |
| JP3438992B2 (ja) * | 1995-05-09 | 2003-08-18 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 難燃性ポリエステル樹脂組成物 |
| JPH08319406A (ja) * | 1995-05-26 | 1996-12-03 | Kanegafuchi Chem Ind Co Ltd | 難燃性樹脂組成物 |
| EP0751186A3 (fr) * | 1995-06-28 | 1997-11-12 | Ube Industries, Ltd. | Composition de résine thermoplastique |
| JP3396485B2 (ja) * | 1996-02-29 | 2003-04-14 | 鐘淵化学工業株式会社 | 難燃性熱可塑性樹脂組成物 |
| DE19643280A1 (de) * | 1996-10-21 | 1998-04-23 | Basf Ag | Flammgeschützte Formmassen |
| US6020414A (en) * | 1996-10-23 | 2000-02-01 | Hoechst Celanese Corporation | Method and compositions for toughening polyester resins |
| WO1998023684A1 (fr) * | 1996-11-27 | 1998-06-04 | The Dow Chemical Company | Compositions de melanges a base de polycarbonate |
| DE19653042A1 (de) * | 1996-12-19 | 1998-06-25 | Basf Ag | Flammgeschützte Formmassen |
| DE69817823D1 (de) * | 1997-06-27 | 2003-10-09 | Kaneka Corp | Flammhemmende thermoplastische harzzusammensetzung |
| NL1006525C2 (nl) * | 1997-07-10 | 1999-01-12 | Dsm Nv | Halogeenvrije vlamdovende thermoplastische polyester samenstelling. |
| JPH11100498A (ja) * | 1997-07-29 | 1999-04-13 | Toray Ind Inc | 難燃性ポリアミド樹脂組成物 |
| JPH11323105A (ja) * | 1998-05-19 | 1999-11-26 | Kanegafuchi Chem Ind Co Ltd | 難燃性ポリエステル樹脂組成物 |
| ATE249496T1 (de) * | 1998-05-22 | 2003-09-15 | Kyowa Chem Ind Co Ltd | Flammhemmende, thermoplastische harzzusammensetzung |
| JP2000136297A (ja) * | 1998-08-24 | 2000-05-16 | Toray Ind Inc | 難燃性樹脂組成物および成形品 |
| JP2000160031A (ja) * | 1998-12-01 | 2000-06-13 | Chisso Corp | 難燃性熱可塑性樹脂組成物 |
| US6616998B2 (en) * | 1999-02-02 | 2003-09-09 | Eastman Chemical Company | Polyester packaging films producing a peelable seal |
| JP2000327854A (ja) * | 1999-03-18 | 2000-11-28 | Calp Corp | 難燃性樹脂組成物及びその成形品 |
| US6476158B1 (en) * | 1999-08-31 | 2002-11-05 | General Electric Company | Process for colored polycarbonate-polyester compositions with improved weathering |
| US6727324B2 (en) * | 2000-08-28 | 2004-04-27 | E. I. Du Pont De Nemours And Company | Calcium reactants in blends containing copolyether ester elastomers and ethylene(meth)acrylate/unsaturated epoxide copolymers |
-
1999
- 1999-05-28 NL NL1012176A patent/NL1012176C2/nl not_active IP Right Cessation
-
2000
- 2000-05-08 JP JP2001500699A patent/JP2004506048A/ja active Pending
- 2000-05-08 WO PCT/NL2000/000293 patent/WO2000073375A2/fr not_active Ceased
- 2000-05-08 CN CNB00808131XA patent/CN100410303C/zh not_active Expired - Fee Related
- 2000-05-08 CA CA002374068A patent/CA2374068C/fr not_active Expired - Fee Related
- 2000-05-08 EP EP00927954A patent/EP1189980B1/fr not_active Expired - Lifetime
- 2000-05-08 AU AU46256/00A patent/AU4625600A/en not_active Abandoned
- 2000-05-08 DE DE60014080T patent/DE60014080T2/de not_active Expired - Lifetime
- 2000-05-08 AT AT00927954T patent/ATE277113T1/de not_active IP Right Cessation
- 2000-05-09 TW TW089108813A patent/TW553987B/zh not_active IP Right Cessation
-
2001
- 2001-11-27 US US09/993,927 patent/US6767941B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| NL1012176C2 (nl) | 2000-11-30 |
| WO2000073375A2 (fr) | 2000-12-07 |
| US6767941B2 (en) | 2004-07-27 |
| CN100410303C (zh) | 2008-08-13 |
| CN1382180A (zh) | 2002-11-27 |
| CA2374068A1 (fr) | 2000-12-07 |
| EP1189980A2 (fr) | 2002-03-27 |
| WO2000073375A3 (fr) | 2002-01-24 |
| ATE277113T1 (de) | 2004-10-15 |
| DE60014080D1 (de) | 2004-10-28 |
| JP2004506048A (ja) | 2004-02-26 |
| AU4625600A (en) | 2000-12-18 |
| TW553987B (en) | 2003-09-21 |
| US20020096669A1 (en) | 2002-07-25 |
| DE60014080T2 (de) | 2005-10-06 |
| EP1189980B1 (fr) | 2004-09-22 |
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| EEER | Examination request | ||
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